Class Xi I Term Portion
Class Xi I Term Portion
CHEMISTRY 1. Some Basic (i) Precision and accuracy: Quantities and their
Concepts of measurements in Chemistry, significant figures, SI
Chemistry units.
(ii)Dimensional analysis: Conversion of units,
numericals and applications of units. (iii)The concept of
atoms having fixed properties in explaining the laws of
chemical combination. Study about atoms. Dalton’s
atomic theory: Main postulates of the theory; its
limitations. Laws of chemical combinations: Law of
conservation of mass, Law of definite proportions, Law
of multiple proportions, Law of reciprocal proportions,
Gay Lussac’s law of gaseous volumes. Statement,
explanation and simple problems based on these laws.
(iv)Atomic (isotopic masses) and molecular mass.
Relative molecular mass and mole: The atomic mass
unit is one of the experimentally determined unit. It is
equal to 1/12 of the mass of the carbon 12 isotope.
Numerical problems based on mole concept,
Avogadro’s number and gram molecular volume. (v)
Empirical and molecular formula: Numericals based on
the above(vi)Chemical equivalents, volumetric
calculations in terms of normality. C = 12.00 should be
taken as a standard for expressing atomic masses.
Equivalent weight expressing the combining capacity of
the elements with the standard elements such as H, Cl,
O, Ag, etc. Variable equivalent weight. Gram equivalent
weights, relationship between gram equivalent weight,
gram molecular mass and valency. Determination of
equivalent weight of acids, alkalis, salts, oxidising and
reducing agents. (experimental details not required).
Terms used in volumetric calculations such as
percentage (w/w and w/v), normality, molarity,
molality, mole fraction, etc. should be discussed.
Students are required to know the formulae and
normality and molarity equations. Simple calculations
on the above topics. (vii)Chemical reactions –
stoichiometric calculations based on mass-mass, mass-
volume, volume-volume relationships and limiting
reagent.
2. Structure of (i) Types of spectra: emission and absorption spectra.
Atom Band and line spectra to be discussed. (ii) Bohr’s atomic
model. Postulates of Bohr’s theory – based on Planck’s
quantum theory. Merits of Bohr’s atomic model and
explanation of hydrogen spectra. Calculations based on
Rydberg’s formula. Numericals on Bohr’s atomic radii,
velocity and energy of orbits (derivation not required).
Defects in Bohr’s Model. (iii)Quantum mechanical
model of an atom - a simple mathematical treatment.
Quantum numbers; shape, size and orientation of s, p
and d orbitals only (no derivation). aufbau principle,
Pauli’s exclusion principle, Hund’s rule of maximum
multiplicity. Electronic configuration of elements in
terms of s, p, d, f subshells. de Broglie’s equation.
Numericals. Heisenberg’s Uncertainty Principle.
Numericals. Quantum numbers – types of quantum
numbers, shape, size and orientation of the s, p and d
subshells. Information obtained in terms of distance of
electron from the nucleus, node, nodal planes and radial
probability curve, energy of electron, number of
electrons present in an orbit and an orbital. aufbau
principle, (n+l) rule. Pauli’s exclusion principle. Hund’s
rule of maximum multiplicity. Electronic configuration
of elements and ions in terms of s, p, d, f subshells and
stability of half-filled and completely filled orbitals.