HIT-RE 100

Safety information for 2-Component-products

Issue date: 02/12/2022 Revision date: 02/12/2022 Supersedes: 11/05/2020 Version: 3.1

SECTION 1: Kit identification

1.1 Product identifier

Product name HIT-RE 100

Product code BU Anchor

1.2 Details of the supplier of the Safety information for 2-Component-products

Hilti (Aust.) Pty. Ltd.

Level 5, 1G Homebush Bay Drive
P.O. Box 3217
2138 Rhodes NSW - Australia
T +61 131 292 - F +61 1300 135 042
[email protected]

SECTION 2: General information

Storage Storage temperature : 5 - 25 °C

A SDS for each of these components is included. Please do not separate any component SDS from this cover page

This Kit should be handled in accordance with good laboratory practices and appropriate personal protective equipment should be used

SECTION 3:

Classification of the Product

2.1. Classification of the hazardous chemical

Classification according to the model Work Health and Safety Regulations (WHS Regulations)
Acute toxicity (oral), Category 4 H302
Skin corrosion/irritation, Category 1B H314
Serious eye damage/eye irritation, Category 1 H318
Skin sensitisation, Category 1 H317
Germ cell mutagenicity, Category 2 H341
Reproductive toxicity, Category 1B H360

2.2. Label elements

Hazard pictograms (GHS AU)

GHS05 GHS07 GHS08

Signal word (GHS AU) Danger
Contains Epoxy resin, Amines
Hazard statements (GHS AU) H314 - Causes severe skin burns and eye damage
H317 - May cause an allergic skin reaction
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HIT-RE 100
Safety information for 2-Component-products

H341 - Suspected of causing genetic defects

H360 - May damage fertility.
Precautionary statements (GHS AU) P280 - Wear eye protection, protective gloves, protective clothing.
P262 - Do not get in eyes, on skin, or on clothing.
P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P333+P313 - If skin irritation or rash occurs: Get medical advice/attention.
P337+P313 - If eye irritation persists: Get medical advice/attention.
P302+P352 - IF ON SKIN: Wash with plenty of water.

2.3. Other hazards not contributing to the classification

No additional information available

Additional information
2-component-foilpack, contains:
Component A: Epoxy resin, Reactive diluent, inorganic filler
Component B: Amine hardener, inorganic filler

Name General description Quantity Unit Classification according to

the model Work Health and
Safety Regulations (WHS
Regulations)
HIT-RE 100, A 1 pcs (pieces) Skin Corr. 1C, H314
Skin Sens. 1, H317
Muta. 2, H341
Repr. 1B, H360
HIT-RE 100, B 1 pcs (pieces) Acute Tox. 4 (Oral), H302
Skin Corr. 1B, H314
Skin Sens. 1, H317

SECTION 4: General advice

General advice For professional users only

SECTION 5: Safe handling advice

General measures Spilled material may present a slipping hazard
Environmental precautions Prevent entry to sewers and public waters
Notify authorities if liquid enters sewers or public waters
Avoid release to the environment
Full or only partially emptied cartridges must be disposed of as special waste in accordance
with official regulations.
After curing, the product can be disposed of with household waste.
Storage conditions Protect from sunlight. Store in a well-ventilated place.
Technical measures Comply with applicable regulations
Precautions for safe handling Wear personal protective equipment
Avoid contact with skin and eyes
Wash hands and other exposed areas with mild soap and water before eating, drinking or
smoking and when leaving work
Avoid contact during pregnancy/while nursing
Methods for cleaning up This material and its container must be disposed of in a safe way, and as per local legislation
Mechanically recover the product
On land, sweep or shovel into suitable containers
Store away from other materials.
For containment Collect spillage.
Incompatible materials Sources of ignition
Direct sunlight
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HIT-RE 100
Safety information for 2-Component-products

Incompatible products Strong bases

Strong acids

SECTION 6: First aid measures

First-aid measures after eye contact Get immediate medical advice/attention.
Immediately rinse with water for a prolonged period while holding the eyelids wide open
Remove contact lenses, if present and easy to do. Continue rinsing.
Consult an eye specialist
First-aid measures after ingestion Do not induce vomiting
Rinse mouth
Immediately call a POISON CENTER/doctor.
First-aid measures after inhalation Remove person to fresh air and keep comfortable for breathing.
First-aid measures after skin contact Wash with plenty of water/…
Take off immediately all contaminated clothing.
Wash contaminated clothing before reuse.
If skin irritation or rash occurs: Get immediate medical advice/attention.
First-aid measures general Never give anything by mouth to an unconscious person
If you feel unwell, seek medical advice (show the label where possible)
Symptoms/effects Causes severe skin burns and eye damage.
Symptoms/effects after eye contact Causes serious eye damage.
Symptoms/effects after skin contact May cause an allergic skin reaction.
Other medical advice or treatment Treat symptomatically

SECTION 7: Fire fighting measures

Firefighting instructions Use water spray or fog for cooling exposed containers
Exercise caution when fighting any chemical fire
Prevent fire fighting water from entering the environment
Protection during firefighting Self-contained breathing apparatus
Do not enter fire area without proper protective equipment, including respiratory protection
Hazardous decomposition products in case of Thermal decomposition generates :
fire Carbon dioxide
Carbon monoxide

SECTION 8: Other information

No data available

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HIT-RE 100, B
Safety Data Sheet
according to the Work Health and Safety (WHS) Regulations
Issue date: 02/12/2022 Revision date: 02/12/2022 Supersedes: 11/05/2020 Version: 2.1

SECTION 1: Product identifier

1.1. GHS Product identifier
Product form Mixture
Product name HIT-RE 100, B
Product code BU Anchor

1.2. Other means of identification

No additional information available

1.3. Recommended use of the chemical and restrictions on use

Recommended use Composite mortar component for fasteners in the construction industry
Restrictions on use For professional use only

1.4. Details of manufacturer or importer

Supplier Department issuing data specification sheet:
Hilti (Aust.) Pty. Ltd. Hilti Entwicklungsgesellschaft mbH
Level 5, 1G Homebush Bay Drive Hiltistraße 6
P.O. Box 3217 Kaufering 86916
Rhodes NSW 2138 Deutschland
Australia T +49 8191 906876
T +61 131 292 - F +61 1300 135 042 [email protected]
[email protected]

1.5. Emergency phone number

Emergency number Schweizerisches Toxikologisches Informationszentrum – 24h Service
+41 44 251 51 51 (international)
+61 2 8748 1000

SECTION 2: Hazard identification

2.1. Classification of the hazardous chemical
Classification according to the model Work Health and Safety Regulations (WHS Regulations)
Acute toxicity (oral), Category 4 H302
Skin corrosion/irritation, Category 1B H314
Skin sensitisation, Category 1 H317

2.2. GHS Label elements, including precautionary statements

Hazard pictograms (GHS AU)

Corrosion Exclamation
mark
Signal word (GHS AU) Danger
Contains m-Xylylenediamine (25 - 40 %); Formaldehyde, telomer with 1,3-benzenedimethanamine,
1,3-benzenediol and ethenylbenzene (10 - 25 %); resorcinol (0,1 - 1 %)
Hazard statements (GHS AU) H302 - Harmful if swallowed
H314 - Causes severe skin burns and eye damage
H317 - May cause an allergic skin reaction
Precautionary statements (GHS AU) P280 - Wear eye protection, protective gloves, protective clothing.
P262 - Do not get in eyes, on skin, or on clothing.
P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P333+P313 - If skin irritation or rash occurs: Get medical advice/attention.
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Safety Data Sheet
according to the Work Health and Safety (WHS) Regulations

P337+P313 - If eye irritation persists: Get medical advice/attention.

P302+P352 - IF ON SKIN: Wash with plenty of water.

2.3. Other hazards which do not result in classification

No additional information available

SECTION 3: Composition and information on ingredients

Name CAS-No. % Classification according to the model
Work Health and Safety Regulations
(WHS Regulations)
m-Xylylenediamine 1477-55-0 25 - 40 Acute Tox. 4 (Oral), H302
Acute Tox. 4 (Inhalation:dust,mist), H332
Skin Corr. 1B, H314
Eye Dam. 1, H318
Skin Sens. 1B, H317

Formaldehyde, telomer with 1,3- 710292-85-6 10 - 25 Skin Sens. 1B, H317

benzenedimethanamine, 1,3-benzenediol and
ethenylbenzene

resorcinol 108-46-3 0,1 - 1 Acute Tox. 4 (Oral), H302

Skin Irrit. 2, H315
Eye Dam. 1, H318
Skin Sens. 1B, H317
STOT SE 1, H370
STOT SE 2, H371

SECTION 4: First aid measures

4.1. Description of necessary first-aid measures
First-aid measures general Never give anything by mouth to an unconscious person. If you feel unwell, seek medical
advice (show the label where possible).
First-aid measures after inhalation Remove person to fresh air and keep comfortable for breathing.
First-aid measures after skin contact Wash with plenty of water/…. Take off immediately all contaminated clothing. Wash
contaminated clothing before reuse. If skin irritation or rash occurs: Get immediate medical
advice/attention.
First-aid measures after eye contact Get immediate medical advice/attention. Immediately rinse with water for a prolonged period
while holding the eyelids wide open. Remove contact lenses, if present and easy to do.
Continue rinsing. Consult an eye specialist.
First-aid measures after ingestion Do not induce vomiting. Rinse mouth. Immediately call a POISON CENTER/doctor.

4.2. Symptoms caused by exposure

Symptoms/effects Causes severe skin burns and eye damage.
Symptoms/effects after skin contact May cause an allergic skin reaction.
Symptoms/effects after eye contact Causes serious eye damage.

4.3. Medical attention and special treatment

Other medical advice or treatment Treat symptomatically.

SECTION 5: Fire-fighting measures

5.1. Extinguishing media
Suitable extinguishing media Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Unsuitable extinguishing media Do not use a heavy water stream.

5.2. Specific hazards arising from the chemical

General measures Spilled material may present a slipping hazard.
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HIT-RE 100, B
Safety Data Sheet
according to the Work Health and Safety (WHS) Regulations

Hazardous decomposition products in case of fire Thermal decomposition generates : Carbon dioxide. Carbon monoxide.

5.3. Special protective equipment and precautions for fire-fighters

Firefighting instructions Use water spray or fog for cooling exposed containers. Exercise caution when fighting any
chemical fire. Prevent fire fighting water from entering the environment.
Protection during firefighting Self-contained breathing apparatus. Do not enter fire area without proper protective
equipment, including respiratory protection.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
General measures Spilled material may present a slipping hazard.

6.1.1. For non-emergency personnel

Emergency procedures Evacuate unnecessary personnel.

6.1.2. For emergency responders

Protective equipment Use personal protective equipment as required. Equip cleanup crew with proper protection.
Emergency procedures Ventilate area.

6.2. Environmental precautions

Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. Avoid release to the environment. Full or only
partially emptied cartridges must be disposed of as special waste in accordance with official regulations. After curing, the product can be disposed
of with household waste.

6.3. Methods and materials for containment and cleaning up

For containment Collect spillage.
Methods for cleaning up This material and its container must be disposed of in a safe way, and as per local
legislation. Mechanically recover the product. On land, sweep or shovel into suitable
containers. Store away from other materials.

SECTION 7: Handling and storage

7.1. Precautions for safe handling
Precautions for safe handling Wear personal protective equipment. Avoid contact with skin and eyes. Wash hands and
other exposed areas with mild soap and water before eating, drinking or smoking and when
leaving work. Avoid contact during pregnancy/while nursing.
Hygiene measures Do not eat, drink or smoke when using this product. Always wash hands after handling the
product. Contaminated work clothing should not be allowed out of the workplace. Wash
contaminated clothing before reuse.

7.2. Conditions for safe storage, including any incompatibilities

Technical measures Comply with applicable regulations.
Storage conditions Protect from sunlight. Store in a well-ventilated place.
Incompatible products Strong bases. Strong acids.
Incompatible materials Sources of ignition. Direct sunlight.
Storage temperature 5 – 25 °C
Heat and ignition sources Keep away from heat and direct sunlight.

SECTION 8: Exposure controls and personal protection

8.1. Control parameters - exposure standards
HIT-RE 100, B
Australia - Occupational Exposure Limits
Local name Resorcinol (m-Dihydroxybenzene)

OES TWA [1] 45 mg/m³

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HIT-RE 100, B
Safety Data Sheet
according to the Work Health and Safety (WHS) Regulations

HIT-RE 100, B
OES TWA [2] 10 ppm

OES STEL 90 mg/m³

OES STEL [ppm] 20 ppm

OES C 0.1 mg/m³

Remark (AU) Sk - Absorption through the skin may be a significant source of exposure.

Regulatory reference Workplace exposure standards for airborne contaminants (2022)

m-Xylylenediamine (1477-55-0)
Australia - Occupational Exposure Limits
Local name m-Xylene-alpha,alpha'-diamine (m-Xylylendiamine; 1,3-Benzenedimethanamine)

OES C 0.1 mg/m³

Remark (AU) Sk - Absorption through the skin may be a significant source of exposure.

Regulatory reference Workplace exposure standards for airborne contaminants (2022)

Additional information The product has a pasty consistency. Exposure limit values for respirable dusts are not
relevant for this product.

8.2. Biological Monitoring

No additional information available

8.3. Engineering controls

Appropriate engineering controls Ensure good ventilation of the work station.

8.4. Individual protection measures, such as personal protective equipment (PPE)

Personal protective equipment Safety glasses. Gloves. Avoid all unnecessary exposure. Protective clothing.
Hand protection Wear protective gloves. The permeation time is not the maximum wearing time! Generally
speaking, it must be reduced. Contact with either mixtures of substances or different
substances may shorten the protective function’s effective duration.

Type Material Permeation Thickness (mm) Penetration Standard

Disposable gloves Nitrile rubber (NBR) 6 (> 480 minutes) > 0,4 EN ISO 374
Eye protection Wear security glasses which protect from splashes

Type Field of application Characteristics Standard

Safety glasses Droplet clear EN 166, EN 170

Skin and body protection Long sleeved protective clothing
Personal protective equipment symbol(s)

Environmental exposure controls Avoid release to the environment.

Consumer exposure controls Avoid contact during pregnancy/while nursing.
Other information Do not eat, drink or smoke during use.

SECTION 9: Physical and chemical properties

Physical state Solid
Appearance Thixotropic paste.
Colour Red-brown to black
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Safety Data Sheet
according to the Work Health and Safety (WHS) Regulations

Odour Amine-like
Odour threshold No data available
pH 11.5
pH solution No data available
Relative evaporation rate (butylacetate=1) No data available
Melting point / Freezing point No data available
Boiling point No data available
Flash point No data available
Auto-ignition temperature No data available
Flammability No data available
Vapour pressure No data available
Relative density No data available
Density Density: 1.41 g/cm³ DIN EN ISO 1183-3
Solubility insoluble in water.
Partition coefficient n-octanol/water (Log Pow) No data available
Viscosity, dynamic 43 – 57 Pa·s HN-0333
Explosive properties No data available
Explosive limits No data available
Minimum ignition energy No data available
Fat solubility No data available

SECTION 10: Stability and reactivity

Reactivity Corrosive vapours.
Chemical stability Stable under normal conditions.
Possibility of hazardous reactions No additional information available.
Conditions to avoid Direct sunlight. Extremely high or low temperatures.
Incompatible materials Strong acids. Strong bases.
Hazardous decomposition products Under normal conditions of storage and use, hazardous decomposition products should not
be produced. Thermal decomposition generates : fume. Carbon monoxide. Carbon dioxide.
Corrosive vapours.

SECTION 11: Toxicological information

Acute toxicity (oral) Harmful if swallowed.
Acute toxicity (dermal) Not classified
Acute toxicity (inhalation) Not classified
ATE AU (oral) 500 mg/kg bodyweight

Formaldehyde, telomer with 1,3-benzenedimethanamine, 1,3-benzenediol and ethenylbenzene (710292-85-6)

LD50 oral rat > 2000 mg/kg
LD50 dermal rat > 2000 mg/kg

resorcinol (108-46-3)
LD50 oral 301 mg/kg
LD50 dermal 2830 mg/kg
LC50 Inhalation - Rat (Dust/Mist) 5.3 mg/l/4h

m-Xylylenediamine (1477-55-0)
LD50 oral rat 1090 mg/kg
LD50 dermal rat > 3100 mg/kg
LD50 dermal > 3100 mg/kg
LC50 Inhalation - Rat (Dust/Mist) 1.34 mg/l/4h
Skin corrosion/irritation Causes severe skin burns.
pH: 11.5

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HIT-RE 100, B
Safety Data Sheet
according to the Work Health and Safety (WHS) Regulations

Serious eye damage/irritation Assumed to cause serious eye damage

pH: 11.5
Respiratory or skin sensitisation May cause an allergic skin reaction.
Germ cell mutagenicity Not classified
Carcinogenicity Not classified
Reproductive toxicity Not classified
STOT-single exposure Not classified
resorcinol (108-46-3)
STOT-single exposure Causes damage to organs (central nervous system, blood) (oral). May cause damage to
organs (respiratory system) (oral).
STOT-repeated exposure Not classified
Aspiration hazard Not classified
Potential adverse human health effects and No additional information available
symptoms

SECTION 12: Ecological information

According to the National Code of Practice for the Preparation of Material Safety Data Sheets, Environmental classification information is not
mandatory. Information relevant for GHS classification is available on request

12.1. Ecotoxicity
Ecology - water Harmful to aquatic life with long lasting effects.
Hazardous to the aquatic environment, short–term Not classified
(acute)
Hazardous to the aquatic environment, long–term Not classified
(chronic)
Other information Avoid release to the environment.
Formaldehyde, telomer with 1,3-benzenedimethanamine, 1,3-benzenediol and ethenylbenzene (710292-85-6)
LC50 - Fish [1] ≥ 50 mg/l
LC50 - Other aquatic organisms [1] ≥ 31.8 mg/l
EC50 - Crustacea [1] 2.4 mg/l
NOEC chronic algae 6.25 mg/l
Bioconcentration factor (BCF REACH) ≥ 12.9
Partition coefficient n-octanol/water (Log Pow) 5.14

resorcinol (108-46-3)
EC50 - Crustacea [1] 1.28 mg/l

m-Xylylenediamine (1477-55-0)
LC50 - Fish [1] 75 mg/l
LC50 - Other aquatic organisms [1] 20.3 ppb
EC50 - Crustacea [1] 15 mg/l
LOEC (chronic) 15 mg/l
NOEC (acute) 10.5 mg/kg
NOEC (chronic) 4.7 mg/l
NOEC chronic crustacea 4.7 mg/l

12.2. Persistence and degradability

HIT-RE 100, B
Persistence and degradability May cause long-term adverse effects in the environment.

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HIT-RE 100, B
Safety Data Sheet
according to the Work Health and Safety (WHS) Regulations

m-Xylylenediamine (1477-55-0)
Not rapidly degradable

12.3. Bioaccumulative potential

HIT-RE 100, B
Bioaccumulative potential Not established.

Formaldehyde, telomer with 1,3-benzenedimethanamine, 1,3-benzenediol and ethenylbenzene (710292-85-6)

Bioconcentration factor (BCF REACH) ≥ 12.9
Partition coefficient n-octanol/water (Log Pow) 5.14

12.4. Mobility in soil

Formaldehyde, telomer with 1,3-benzenedimethanamine, 1,3-benzenediol and ethenylbenzene (710292-85-6)
Partition coefficient n-octanol/water (Log Pow) 5.14

12.5. Other adverse effects

Ozone Not classified
Other adverse effects No additional information available

SECTION 13: Disposal considerations

Regional legislation (waste) Disposal must be done according to official regulations.
Product/Packaging disposal recommendations After curing, the product can be disposed of with household waste. . Full or only partially
emptied cartridges must be disposed of as special waste in accordance with official
regulations. Packaging contaminated by the product : Dispose in a safe manner in
accordance with local/national regulations.
Ecology - waste materials Avoid release to the environment.

SECTION 14: Transport information

In accordance with ADR / IMDG / IATA / RID
ADR IMDG IATA RID
14.1. UN number or ID number
UN 3259 UN 3259 UN 3259 UN 3259

14.2. UN proper shipping name

AMINES, SOLID, CORROSIVE, AMINES, SOLID, CORROSIVE, Amines, solid, corrosive, n.o.s. (m- AMINES, SOLID, CORROSIVE,
N.O.S. (m-Xylylenediamine) N.O.S. (m-Xylylenediamine) Xylylenediamine) N.O.S. (m-Xylylenediamine)

Transport document description

UN 3259 AMINES, SOLID, UN 3259 AMINES, SOLID, UN 3259 Amines, solid, corrosive, UN 3259 AMINES, SOLID,
CORROSIVE, N.O.S. (m- CORROSIVE, N.O.S. (m- n.o.s. (m-Xylylenediamine), 8, II CORROSIVE, N.O.S. (m-
Xylylenediamine), 8, II, (E) Xylylenediamine), 8, II Xylylenediamine), 8, II

14.3. Transport hazard class(es)

8 8 8 8

14.4. Packing group

II II II II

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HIT-RE 100, B
Safety Data Sheet
according to the Work Health and Safety (WHS) Regulations

ADR IMDG IATA RID

14.5. Environmental hazards
Dangerous for the environment: No Dangerous for the environment: No Dangerous for the environment: No Dangerous for the environment: No
Marine pollutant: No

No supplementary information available

14.6. Special precautions for user

Overland transport
Classification code (ADR) C8
Special provisions (ADR) 274
Limited quantities (ADR) 1kg
Packing instructions (ADR) P002, IBC08
Mixed packing provisions (ADR) MP10
Transport category (ADR) 2
Orange plates

Tunnel restriction code (ADR) E

Transport by sea
Special provisions (IMDG) 274
Limited quantities (IMDG) 1 kg
Packing instructions (IMDG) P002
EmS-No. (Fire) F-A
EmS-No. (Spillage) S-B
Stowage category (IMDG) A
MFAG-No 154

Air transport
PCA packing instructions (IATA) 859
PCA max net quantity (IATA) 15kg
CAO packing instructions (IATA) 863
Special provisions (IATA) A3

Rail transport
Special provisions (RID) 274
Limited quantities (RID) 1kg
Packing instructions (RID) P002, IBC08

14.7. Maritime transport in bulk according to IMO instruments

Not applicable

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations specific for the product in question
Australian Industrial Chemicals Introduction Scheme (AICIS)
Australian Inventory of Industrial Chemicals (AICIS All the chemicals contained in this product are listed introductions
Inventory) status

15.2. International agreements

No additional information available

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HIT-RE 100, B
Safety Data Sheet
according to the Work Health and Safety (WHS) Regulations

SECTION 16: Other information

Indication of changes:
Composition/information on ingredients. Hazards identification. Modified.

Indication of changes
Section Changed item Change Comments
Legislation Modified

Abbreviations and acronyms ADN - European Agreement concerning the International Carriage of Dangerous Goods by
Inland Waterways
ADR - European Agreement concerning the International Carriage of Dangerous Goods by
Road
ATE - Acute Toxicity Estimate
BCF - Bioconcentration factor
CLP - Classification Labelling Packaging Regulation; Regulation (EC) No 1272/2008
DMEL - Derived Minimal Effect level
DNEL - Derived-No Effect Level
EC50 - Median effective concentration
IARC - International Agency for Research on Cancer
IATA - International Air Transport Association
IMDG - International Maritime Dangerous Goods
LC50 - Median lethal concentration
LD50 - Median lethal dose
LOAEL - Lowest Observed Adverse Effect Level
NOAEC - No-Observed Adverse Effect Concentration
NOAEL - No-Observed Adverse Effect Level
NOEC - No-Observed Effect Concentration
OECD - Organisation for Economic Co-operation and Development
PBT - Persistent Bioaccumulative Toxic
PNEC - Predicted No-Effect Concentration
REACH - Registration, Evaluation, Authorisation and Restriction of Chemicals Regulation
(EC) No 1907/2006
RID - Regulations concerning the International Carriage of Dangerous Goods by Rail
SDS - Safety Data Sheet
vPvB - Very Persistent and Very Bioaccumulative
Revision date 02/12/2022
Other information None.

Classification
Acute Tox. 4 (Oral) H302

Skin Corr. 1B H314

Skin Sens. 1 H317

Full text of H-statements

Acute Tox. 4 (Inhalation:dust,mist) Acute toxicity (inhalation:dust,mist) Category 4

Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4

Eye Dam. 1 Serious eye damage/eye irritation, Category 1

Skin Corr. 1B Skin corrosion/irritation, Category 1B

Skin Irrit. 2 Skin corrosion/irritation, Category 2

Skin Sens. 1 Skin sensitisation, Category 1

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HIT-RE 100, B
Safety Data Sheet
according to the Work Health and Safety (WHS) Regulations

Full text of H-statements

Skin Sens. 1B Skin sensitisation, category 1B

STOT SE 1 Specific target organ toxicity – single exposure, Category 1

STOT SE 2 Specific target organ toxicity – Single exposure, Category 2

H302 Harmful if swallowed

H314 Causes severe skin burns and eye damage

H315 Causes skin irritation

H317 May cause an allergic skin reaction

H318 Causes serious eye damage

H332 Harmful if inhaled

H370 Causes damage to organs

H371 May cause damage to organs

SDS_AU_Hilti

This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental
requirements only. It should not therefore be construed as guaranteeing any specific property of the product.

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HIT-RE 100, A
Safety Data Sheet
according to the Work Health and Safety (WHS) Regulations
Issue date: 02/12/2022 Revision date: 02/12/2022 Supersedes: 11/05/2020 Version: 3.1

SECTION 1: Product identifier

1.1. GHS Product identifier
Product form Mixture
Product name HIT-RE 100, A
Product code BU Anchor

1.2. Other means of identification

No additional information available

1.3. Recommended use of the chemical and restrictions on use

Recommended use Composite mortar component for fasteners in the construction industry
Restrictions on use For professional use only

1.4. Details of manufacturer or importer

Supplier Department issuing data specification sheet:
Hilti (Aust.) Pty. Ltd. Hilti Entwicklungsgesellschaft mbH
Level 5, 1G Homebush Bay Drive Hiltistraße 6
P.O. Box 3217 Kaufering 86916
Rhodes NSW 2138 Deutschland
Australia T +49 8191 906876
T +61 131 292 - F +61 1300 135 042 [email protected]
[email protected]

1.5. Emergency phone number

Emergency number Schweizerisches Toxikologisches Informationszentrum – 24h Service
+41 44 251 51 51 (international)
+61 2 8748 1000

SECTION 2: Hazard identification

2.1. Classification of the hazardous chemical
Classification according to the model Work Health and Safety Regulations (WHS Regulations)
Skin corrosion/irritation, Category 1C H314
Skin sensitisation, Category 1 H317
Germ cell mutagenicity, Category 2 H341
Reproductive toxicity, Category 1B H360

2.2. GHS Label elements, including precautionary statements

Hazard pictograms (GHS AU)

Corrosion Exclamation Health hazard

mark
Signal word (GHS AU) Danger
Contains 2,2'-[(1-methylethylidene)bis(4,1-phenyleneoxymethylene)]bisoxirane (25 - 40 %);
Formaldehyde, oligomeric reaction products with 1-chloro-2,3-epoxypropane and phenol (10
– 25 %); Reaction products of hexane-1,6-diol with 2-(chloromethyl) (10 - 25 %); 1,3
Propanediol, 2 ethyl-2-(hydroxymethyl)-, polymer with 2-(chloromethyl)oxirane (5 – 10 %)
Hazard statements (GHS AU) H314 - Causes severe skin burns and eye damage
H317 - May cause an allergic skin reaction
H341 - Suspected of causing genetic defects
H360 - May damage fertility.
Precautionary statements (GHS AU) P280 - Wear eye protection, protective gloves, protective clothing.
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P262 - Do not get in eyes, on skin, or on clothing.

P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P333+P313 - If skin irritation or rash occurs: Get medical advice/attention.
P337+P313 - If eye irritation persists: Get medical advice/attention.
P302+P352 - IF ON SKIN: Wash with plenty of water.

2.3. Other hazards which do not result in classification

No additional information available

SECTION 3: Composition and information on ingredients

Name CAS-No. % Classification according to the model
Work Health and Safety Regulations
(WHS Regulations)
2,2'-[(1-methylethylidene)bis(4,1- 1675-54-3 25 - 40 Skin Irrit. 2, H315
phenyleneoxymethylene)]bisoxirane Eye Irrit. 2A, H319
Skin Sens. 1, H317

Formaldehyde, oligomeric reaction products with 1- 9003-36-5 10 – 25 Skin Irrit. 2, H315

chloro-2,3-epoxypropane and phenol Eye Irrit. 2A, H319
Skin Sens. 1, H317

Reaction products of hexane-1,6-diol with 2- 933999-84-9 10 - 25 Skin Irrit. 2, H315

(chloromethyl) Eye Irrit. 2A, H319
Skin Sens. 1, H317

1,3 Propanediol, 2 ethyl-2-(hydroxymethyl)-, polymer 30499-70-8 5 – 10 Skin Corr. 1C, H314

with 2-(chloromethyl)oxirane Eye Dam. 1, H318
Skin Sens. 1B, H317
Muta. 2, H341
Repr. 1B, H360

SECTION 4: First aid measures

4.1. Description of necessary first-aid measures
First-aid measures general Never give anything by mouth to an unconscious person. If you feel unwell, seek medical
advice (show the label where possible).
First-aid measures after inhalation Remove person to fresh air and keep comfortable for breathing. Allow affected person to
breathe fresh air. Allow the victim to rest.
First-aid measures after skin contact Gently wash with plenty of soap and water. Wash contaminated clothing before reuse. If
skin irritation occurs: Get immediate medical advice/attention.
First-aid measures after eye contact Rinse immediately with plenty of water. Remove contact lenses, if present and easy to do.
Continue rinsing. Obtain medical attention if pain, blinking or redness persists.
First-aid measures after ingestion Rinse mouth. Get medical advice/attention. Do not induce vomiting. Obtain emergency
medical attention.

4.2. Symptoms caused by exposure

Symptoms/effects after skin contact Causes skin irritation. May cause an allergic skin reaction.
Symptoms/effects after eye contact Causes serious eye irritation.

4.3. Medical attention and special treatment

Other medical advice or treatment Treat symptomatically.

SECTION 5: Fire-fighting measures

5.1. Extinguishing media
Suitable extinguishing media Water spray. Carbon dioxide. Dry powder. Foam. Sand.

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Unsuitable extinguishing media Do not use a heavy water stream.

5.2. Specific hazards arising from the chemical

General measures Spilled material may present a slipping hazard.
Hazardous decomposition products in case of fire Thermal decomposition generates : Carbon dioxide. Carbon monoxide.

5.3. Special protective equipment and precautions for fire-fighters

Firefighting instructions Use water spray or fog for cooling exposed containers. Exercise caution when fighting any
chemical fire. Prevent fire fighting water from entering the environment.
Protection during firefighting Self-contained breathing apparatus. Do not enter fire area without proper protective
equipment, including respiratory protection.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
General measures Spilled material may present a slipping hazard.

6.1.1. For non-emergency personnel

Emergency procedures Evacuate unnecessary personnel.

6.1.2. For emergency responders

Protective equipment Use personal protective equipment as required. Equip cleanup crew with proper protection.
Emergency procedures Ventilate area.

6.2. Environmental precautions

Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. Avoid release to the environment. Full or only
partially emptied cartridges must be disposed of as special waste in accordance with official regulations. After curing, the product can be disposed
of with household waste.

6.3. Methods and materials for containment and cleaning up

For containment Collect spillage.
Methods for cleaning up This material and its container must be disposed of in a safe way, and as per local
legislation. Mechanically recover the product. On land, sweep or shovel into suitable
containers. Store away from other materials.

SECTION 7: Handling and storage

7.1. Precautions for safe handling
Precautions for safe handling Wear personal protective equipment. Avoid contact with skin and eyes. Wash hands and
other exposed areas with mild soap and water before eating, drinking or smoking and when
leaving work.
Hygiene measures Do not eat, drink or smoke when using this product. Always wash hands after handling the
product. Contaminated work clothing should not be allowed out of the workplace. Wash
contaminated clothing before reuse.

7.2. Conditions for safe storage, including any incompatibilities

Storage conditions Protect from sunlight.
Incompatible products Strong bases. Strong acids.
Incompatible materials Sources of ignition. Direct sunlight.
Storage temperature 5 – 25 °C
Heat and ignition sources Keep away from heat and direct sunlight.

SECTION 8: Exposure controls and personal protection

8.1. Control parameters - exposure standards
Additional information The product has a pasty consistency. Exposure limit values for respirable dusts are not
relevant for this product.

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8.2. Biological Monitoring

No additional information available

8.3. Engineering controls

Appropriate engineering controls Ensure good ventilation of the work station.

8.4. Individual protection measures, such as personal protective equipment (PPE)

Personal protective equipment Safety glasses. Gloves. Avoid all unnecessary exposure. Protective clothing.
Hand protection Wear protective gloves. The permeation time is not the maximum wearing time! Generally
speaking, it must be reduced. Contact with either mixtures of substances or different
substances may shorten the protective function’s effective duration.

Type Material Permeation Thickness (mm) Penetration Standard

Disposable gloves Nitrile rubber (NBR) 6 (> 480 minutes) > 0,4 EN ISO 374
Eye protection Wear security glasses which protect from splashes

Type Field of application Characteristics Standard

Safety glasses Droplet clear EN 166, EN 170

Skin and body protection Long sleeved protective clothing
Personal protective equipment symbol(s)

Environmental exposure controls Avoid release to the environment.

Consumer exposure controls Avoid contact during pregnancy/while nursing.
Other information Do not eat, drink or smoke during use.

SECTION 9: Physical and chemical properties

Physical state Solid
Appearance Thixotropic paste.
Colour Light grey
Odour characteristic
Odour threshold No data available
pH 6.2
pH solution No data available
Relative evaporation rate (butylacetate=1) No data available
Melting point / Freezing point No data available
Boiling point No data available
Flash point No data available
Auto-ignition temperature No data available
Flammability No data available
Vapour pressure No data available
Relative density No data available
Density Density: 1.46 g/ml DIN EN ISO 1183-3
Solubility insoluble in water.
Partition coefficient n-octanol/water (Log Pow) No data available
Viscosity, dynamic 36 – 53 Pa·s HN-0333
Explosive properties Product is not explosive.
Explosive limits No data available
Minimum ignition energy No data available
Fat solubility No data available

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SECTION 10: Stability and reactivity

Reactivity No additional information available
Chemical stability Stable under normal conditions.
Possibility of hazardous reactions No additional information available.
Conditions to avoid Direct sunlight. Extremely high or low temperatures.
Incompatible materials Strong acids. Strong bases.
Hazardous decomposition products Under normal conditions of storage and use, hazardous decomposition products should not
be produced. Thermal decomposition generates : fume. Carbon monoxide. Carbon dioxide.

SECTION 11: Toxicological information

Acute toxicity (oral) Not classified
Acute toxicity (dermal) Not classified
Acute toxicity (inhalation) Not classified
2,2'-[(1-methylethylidene)bis(4,1-phenyleneoxymethylene)]bisoxirane (1675-54-3)
LD50 oral rat > 2000 mg/kg (Rat; OECD 420: Acute Oral toxicity – Acute Toxic Class Method;
Experimental value)
LD50 oral 11400 mg/kg
LD50 dermal rat > 2000 mg/kg (Rat; Experimental value; OECD 402: Acute Dermal Toxicity)

Reaction products of hexane-1,6-diol with 2-(chloromethyl) (933999-84-9)

LD50 oral rat 3010 mg/kg
LD50 dermal rat > 2000 mg/kg

Formaldehyde, oligomeric reaction products with 1-chloro-2,3-epoxypropane and phenol (9003-36-5)

LD50 oral rat > 5000 mg/kg bodyweight (Rat; ECHA)
LD50 dermal rat > 2000 mg/kg bodyweight (Rat; ECHA)
Skin corrosion/irritation Causes severe skin burns.
pH: 6.2
Serious eye damage/irritation Assumed to cause serious eye damage
pH: 6.2
Respiratory or skin sensitisation May cause an allergic skin reaction.
Germ cell mutagenicity Suspected of causing genetic defects.
Carcinogenicity Not classified
Reproductive toxicity May damage fertility.
STOT-single exposure Not classified
STOT-repeated exposure Not classified
Aspiration hazard Not classified
Potential adverse human health effects and No additional information available
symptoms

SECTION 12: Ecological information

According to the National Code of Practice for the Preparation of Material Safety Data Sheets, Environmental classification information is not
mandatory. Information relevant for GHS classification is available on request

12.1. Ecotoxicity
Ecology - water Toxic to aquatic life with long lasting effects.
Hazardous to the aquatic environment, short–term Not classified
(acute)
Hazardous to the aquatic environment, long–term Not classified
(chronic)
Other information Avoid release to the environment.

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2,2'-[(1-methylethylidene)bis(4,1-phenyleneoxymethylene)]bisoxirane (1675-54-3)
LC50 - Fish [1] 1.2 mg/l (96 h; Oncorhynchus mykiss; Lethal)
LC50 - Fish [2] 2.3 mg/l (96 h; Oncorhynchus mykiss; Nominal concentration)
EC50 - Crustacea [1] 2 mg/l (OECD 202: Daphnia sp. Acute Immobilisation Test, 48 h, Daphnia magna, Static
system, Fresh water, Experimental value, Nominal concentration)
Partition coefficient n-octanol/water (Log Pow) ≥ 2.918 (Experimental value; EU Method A.8: Partition Coefficient; 25 °C)
Threshold limit - Algae [1] > 11 mg/l (72 h; Scenedesmus sp.)
Threshold limit - Algae [2] 4.2 mg/l (72 h; Scenedesmus sp.)

Reaction products of hexane-1,6-diol with 2-(chloromethyl) (933999-84-9)

LC50 - Fish [1] 30 mg/l
LC50 - Other aquatic organisms [1] 23.1 mg/l
EC50 - Crustacea [1] 47 mg/l
NOEC (acute) 18 mg/l

12.2. Persistence and degradability

HIT-RE 100, A
Persistence and degradability May cause long-term adverse effects in the environment.

2,2'-[(1-methylethylidene)bis(4,1-phenyleneoxymethylene)]bisoxirane (1675-54-3)
Not rapidly degradable

Reaction products of hexane-1,6-diol with 2-(chloromethyl) (933999-84-9)

Not rapidly degradable

1,3 Propanediol, 2 ethyl-2-(hydroxymethyl)-, polymer with 2-(chloromethyl)oxirane (30499-70-8)

Not rapidly degradable

Formaldehyde, oligomeric reaction products with 1-chloro-2,3-epoxypropane and phenol (9003-36-5)

Not rapidly degradable

12.3. Bioaccumulative potential

HIT-RE 100, A
Bioaccumulative potential Not established.

2,2'-[(1-methylethylidene)bis(4,1-phenyleneoxymethylene)]bisoxirane (1675-54-3)
Partition coefficient n-octanol/water (Log Pow) ≥ 2.918 (Experimental value; EU Method A.8: Partition Coefficient; 25 °C)
Bioaccumulative potential Low bioaccumulation potential (BCF < 500).

12.4. Mobility in soil

2,2'-[(1-methylethylidene)bis(4,1-phenyleneoxymethylene)]bisoxirane (1675-54-3)
Surface tension 59 mN/m (20 °C, 0.09 g/l)
Ecology - soil No (test)data on mobility of the substance available.
Partition coefficient n-octanol/water (Log Pow) ≥ 2.918 (Experimental value; EU Method A.8: Partition Coefficient; 25 °C)

12.5. Other adverse effects

Ozone Not classified
Other adverse effects No additional information available

SECTION 13: Disposal considerations

Regional legislation (waste) Disposal must be done according to official regulations.

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Product/Packaging disposal recommendations After curing, the product can be disposed of with household waste. . Full or only partially
emptied cartridges must be disposed of as special waste in accordance with official
regulations. Packaging contaminated by the product : Dispose in a safe manner in
accordance with local/national regulations.
Ecology - waste materials Avoid release to the environment.

SECTION 14: Transport information

In accordance with ADR / IMDG / IATA / RID
ADR IMDG IATA RID
14.1. UN number or ID number
UN 1759 UN 1759 UN 1759 UN 1759

14.2. UN proper shipping name

CORROSIVE SOLID, N.O.S. CORROSIVE SOLID, N.O.S. Corrosive solid, n.o.s. CORROSIVE SOLID, N.O.S.
(trimethylolpropane triglycidylether) (trimethylolpropane triglycidylether) (trimethylolpropane triglycidylether) (trimethylolpropane triglycidylether)

Transport document description

UN 1759 CORROSIVE SOLID, UN 1759 CORROSIVE SOLID, UN 1759 Corrosive solid, n.o.s. UN 1759 CORROSIVE SOLID,
N.O.S. (trimethylolpropane N.O.S. (trimethylolpropane (trimethylolpropane N.O.S. (trimethylolpropane
triglycidylether), 8, III, (E), triglycidylether), 8, III, MARINE triglycidylether), 8, III, triglycidylether), 8, III,
ENVIRONMENTALLY POLLUTANT/ENVIRONMENTALL ENVIRONMENTALLY ENVIRONMENTALLY
HAZARDOUS Y HAZARDOUS HAZARDOUS HAZARDOUS

14.3. Transport hazard class(es)

8 8 8 8

14.4. Packing group

III III III III

14.5. Environmental hazards

Dangerous for the environment: Dangerous for the environment: Dangerous for the environment: Dangerous for the environment:
Yes Yes Yes Yes
Marine pollutant: Yes

No supplementary information available

14.6. Special precautions for user

Overland transport
Classification code (ADR) C10
Special provisions (ADR) 274
Limited quantities (ADR) 5kg
Packing instructions (ADR) P002, IBC08, LP02, R001
Mixed packing provisions (ADR) MP10
Transport category (ADR) 3
Orange plates

Tunnel restriction code (ADR) E

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Transport by sea
Special provisions (IMDG) 223, 274
Packing instructions (IMDG) P002, LP02
EmS-No. (Fire) F-A
EmS-No. (Spillage) S-B
Stowage category (IMDG) A

Air transport
PCA packing instructions (IATA) 860
PCA max net quantity (IATA) 25kg
CAO packing instructions (IATA) 864
Special provisions (IATA) A3, A803

Rail transport
Special provisions (RID) 274
Packing instructions (RID) P002, IBC08, LP02, R001

14.7. Maritime transport in bulk according to IMO instruments

Not applicable

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations specific for the product in question
Australian Industrial Chemicals Introduction Scheme (AICIS)
Australian Inventory of Industrial Chemicals (AICIS All the chemicals contained in this product are listed introductions
Inventory) status

15.2. International agreements

No additional information available

SECTION 16: Other information

Indication of changes:
Composition/information on ingredients. Modified.

Indication of changes
Section Changed item Change Comments
Legislation Modified

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Abbreviations and acronyms ADN - European Agreement concerning the International Carriage of Dangerous Goods by
Inland Waterways
ADR - European Agreement concerning the International Carriage of Dangerous Goods by
Road
ATE - Acute Toxicity Estimate
BCF - Bioconcentration factor
CLP - Classification Labelling Packaging Regulation; Regulation (EC) No 1272/2008
DMEL - Derived Minimal Effect level
DNEL - Derived-No Effect Level
EC50 - Median effective concentration
IARC - International Agency for Research on Cancer
IATA - International Air Transport Association
IMDG - International Maritime Dangerous Goods
LC50 - Median lethal concentration
LD50 - Median lethal dose
LOAEL - Lowest Observed Adverse Effect Level
NOAEC - No-Observed Adverse Effect Concentration
NOAEL - No-Observed Adverse Effect Level
NOEC - No-Observed Effect Concentration
OECD - Organisation for Economic Co-operation and Development
PBT - Persistent Bioaccumulative Toxic
PNEC - Predicted No-Effect Concentration
REACH - Registration, Evaluation, Authorisation and Restriction of Chemicals Regulation
(EC) No 1907/2006
RID - Regulations concerning the International Carriage of Dangerous Goods by Rail
SDS - Safety Data Sheet
vPvB - Very Persistent and Very Bioaccumulative
Revision date 02/12/2022

Classification
Skin Corr. 1C H314

Skin Sens. 1 H317

Muta. 2 H341

Repr. 1B H360

Full text of H-statements

Eye Dam. 1 Serious eye damage/eye irritation, Category 1

Eye Irrit. 2A Serious eye damage/eye irritation, Category 2A

Muta. 2 Germ cell mutagenicity, Category 2

Repr. 1B Reproductive toxicity, Category 1B

Skin Corr. 1C Skin corrosion/irritation, Category 1C

Skin Irrit. 2 Skin corrosion/irritation, Category 2

Skin Sens. 1 Skin sensitisation, Category 1

Skin Sens. 1B Skin sensitisation, category 1B

H314 Causes severe skin burns and eye damage

H315 Causes skin irritation

H317 May cause an allergic skin reaction

H318 Causes serious eye damage

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Full text of H-statements

H319 Causes serious eye irritation

H341 Suspected of causing genetic defects

H360 May damage fertility or the unborn child

SDS_AU_Hilti

This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental
requirements only. It should not therefore be construed as guaranteeing any specific property of the product.

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