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Model Question Paper
Total Duration (H: M): 3:00
Course: Engineering Chemistry Maximum Marks:100
Note: Attempt all questions. All questions carry equal marks.
Course Outcomes: 1. To bridge the knowledge of chemical science with technical aspect of Engineering Chemistry. 2. To give technical knowledge of several industries, where Engineering chemistry is used as an integral part, like: Polymer chemistry, Paints, Lubricants, Fuel, Glass etc. 3. To give knowledge of chemical aspect of water and its treatment. 4. To give knowledge of different type of corrosions and pollutions and there minimization. 5. To give brief knowledge of different advance techniques of Instrumental Chemistry, like Principal of spectroscopy, NMR and MRI spectroscopy. Elementary idea about organic reactions and synthesis of Drugs.
Q.No. Questions Marks CO BL PI
Code 1 Answer any four parts of the following. UNIT-I a. State de-Broglie hypothesis. 5 CO1 BL1
b. Derive Schrodinger equation for particle in one 5 CO1 BL3
dimensional box.
c. On the basis of band theory, differentiate 5 CO1 BL3
between insulator, conductor and semiconductor.
d. How crystal field theory applied in tetrahedral 5 CO1 BL2
complexes? e. What is meant by bond order? Calculate the 5 CO1 BL2 bond order of He2+, O2- and O2+ molecules.
2 Answer any four parts of the following. UNIT-II
a. What is an electrochemical series? Discuss its 5 CO1 BL1 three important applications.
b. Define and explain entropy. Write note on 5 CO1 BL2
entropy change in reversible and irreversible processes.
c. Derive Nernst’s equation for simple electrode 5 CO1 BL3
potential and explain the terms involved in it. d. What is the Hess Law. 5 CO1 BL2 e. What do you understand by Lewis theory of 5 CO1 BL2 Acid and Bases. 3 Answer any two parts of the following. UNIT-III a. Write short note on 10 CO3 BL1 i. Reverse osmosis ii. Reactions involved in L-S Process iii. Prevention of Corrosion iv. Waterline Corrosion
b. Explain the Zeolite process for water softening 10 CO3 BL3
and regeneration of Zeolite. What are the limitations of this process.
c. Define the Corrosion? Discuss the mechanism 10 CO4 BL2
of Electro-chemical corrosion and Dry corrosion.
4 Answer any two parts of the following. UNIT-IV
a. Differentiate between thin film or thick film 10 CO2 BL2 lubrication mechanism. b. i. What are the limitations of raw rubber? 10 CO2 BL3 Explain the process of vulcanization of rubber. ii. Write the method of preparation for the following polymers a. Nylon-6 b. Buna S c. Polyacrylonitrile d. PMMA
c. What is meant by calorific value of a fuel. What 10 CO2 BL3
is the difference between gross calorific value and net calorific value. A coal has the following composition by weight C=90%, O=3.0%, S=0.5%, ash= 2.5% and N=0.5%. NCV of the coal was found to be 8490.5Kcal/Kg. Calculate the percentage of H and GCV of coal.
5 Answer any two parts of the following. UNIT-V
a. (i) Write note on the electronic transition caused 10 CO5 BL2 by energy absorbed in the UV region. (ii) What do you understand by modes of vibration? Explain with suitable example.
b. i. Explain the stereochemistry of SN1 And SN2 10 CO5 BL3
reaction. ii. Synthesis of Asprin. c. Write Note On 10 CO5 BL3 i. Application of NMR spectroscopy ii. Diels-Alder reaction