Topic 14: Temperature

14.1.1 Thermal Energy Transfer

Exam Tip
Thermal Energy Transfer
Sometimes the direction of heat transfer might seem counterintuitive to what we observe in
• The conservation of energy states that energy is never created or destroyed, only everyday life. When ice is placed in room temperature water, it melts. This is because the
transferred from one form to another water transfers heat energy to the ice (not the ice giving it’s ‘cold’ to the water).
• When a thermometer is placed in a beaker of boiling water, the thermometer reading
increases
o This is because the thermometer is a lot cooler than the water 14.1.2 Thermal Equilibrium
• The thermometer gradually becomes hotter from the thermal energy (or heat)
transferring from the water to the thermometer Defining Thermal Equilibrium
• The definition of thermal energy is given below:
• Thermal energy is always transferred from a hotter region to lower region
Thermal energy is defined as the energy possessed by an object due to its temperature. • Thermal equilibrium is defined as:
Thermal energy is transferred from a region of higher temperature to a region of lower
temperature When two substances in physical contact with each other no longer exchange any heat
energy and both reach an equal temperature
• The energy will continue to be transferred until both the thermometer and the water
are at the same temperature • There is no longer thermal energy transfer between the regions
• This means temperature tells us the direction of energy flow when two regions are in
contact (from hotter to cooler)

Two regions of different temperatures reaching thermal equilibrium after some time

Thermal energy is transferred from the hot coffee to the mug and to the cold hands • The two regions need to be in contact for this to occur
• The hotter region will cool down and the cooler region will heat up until they reach the
• The mechanism by which the thermal energy is transferred is by either conduction, same temperature
convection or radiation • The final temperature when two regions are in thermal equilibrium depends on the
initial temperature difference between them
• An example of this is ice in room temperature water. The ice cubes heat up from the
energy transfer from the water and the water cools down due to the ice until the
water’s temperature is in thermal equilibrium
14.1.3 Measurement of Temperature Volume of a Gas at Constant Pressure

Measurement of Temperature • The volume of an ideal gas is directly proportional to its temperature when at constant
pressure (Charles’s law)
• A thermometer is any device that is used to measure temperature
• Each type of thermometer uses a physical property of a material that varies with V∝T
temperature - examples of such properties include:
o The density of a liquid • As the temperature of the gas increases, its volume increases and vice versa
o The volume of a gas at constant pressure • A gas thermometer must be calibrated - by knowing the temperature of the gas at a
o Resistance of a metal certain volume, a temperature scale can be determined depending on how quickly the
o e.m.f. of a thermocouple gas expands with temperature
• In each case, the thermometer must be calibrated at two or more known temperatures
(commonly the boiling and melting points of water, 0oC and 100oC respectively) and the Resistance of a Metal
scale divided into equal divisions
• Recall that electrical resistance changes with temperature e.g. the resistance of a
The Density of a Liquid filament lamp increases when current increases through it
o For metals: resistance increases with temperature at a steady rate
• A liquid-in-glass thermometer depends on the density change of a liquid (commonly o For thermistors: resistance changes rapidly over a narrow range of temperatures
mercury) • As a thermistor gets hotter, its resistance decreases
• It consists of a thin glass capillary tube containing a liquid that expands with • This means a thermometer based on a thermistor can be used to measure a range of
temperature temperatures
• A scale along the side of the tube allows the temperature to be measured based on the • The relationship between the resistance and temperature is non-linear
length of liquid within the tube o This means the graph of temperature against resistance will be a curved line and
the thermistor will have to be calibrated

As the temperature of a thermistor increases, its resistance decreases

As the bulb is heated, the liquid expands and moves along the capillary tube
E.M.F. of a Thermocouple
Exam Tip
• A thermocouple is an electrical device used as the sensor of a thermometer
• It consists of two wires of different, or dissimilar, metals attached to each other, Remember to relate how the temperature is measured for different types of thermometer
producing a junction on one end back to the scenario in the question. For example, make sure you say: the temperature
o The opposite ends are connected to a voltmeter increases as the volume of gas increases or the temperature increases as the e.m.f. between
• When this junction is heated, an e.m.f. is produced between the two wires which is the two wires increases.
measured on the voltmeter
• The greater the difference in temperature between the wires, the greater the e.m.f 14.1.4 The Kelvin Scale

Scale of Thermodynamic Temperature

• As an everyday scale of temperature, Celsius (oC) is the most familiar

• This scale is based on the properties of water - the freezing point of water was taken as
taken as 0 oC and the boiling point as 100 oC
o However, there is nothing special about these two temperatures
o The freezing and boiling point of water will actually change as its pressure
changes
• The Celsius scale is used to measure the temperature in a liquid-in-glass thermometer
o However, the expansion of the liquid might be non-linear
• Other temperature scales include:
o Fahrenheit, commonly used in the US
o Kelvin, used in thermodynamics
A thermocouple consists of two dissimilar wires connected together
• The Kelvin scale is known as the thermodynamic scale and was designed to overcome
• However, a thermocouple requires calibration since the e.m.f. does not vary linearly
the problem with scales of temperature
with temperature
• The thermodynamic scale is said to be an absolute scale that is not defined in terms of a
• The graph against e.m.f. and temperature is a positive, curved line
property of any particular substance
• This is because thermodynamic temperatures do not depend on the property of any
particular substance

Absolute Zero

• On the thermodynamic (Kelvin) temperature scale, absolute zero is defined as:

The lowest temperature possible. Equal to 0 K or -273.15 °C

• It is not possible to have a temperature lower than 0 K

o This means a temperature in Kelvin will never be a negative value
• Absolute zero is defined in kinetic terms as:

The temperature at which the atoms and molecules in all substances have zero kinetic and
The e.m.f. and temperature are not directly proportional in a thermocouple potential energy
 • This means for a system at 0 K, it is not possible to remove any more energy from it
• Even in space, the temperature is roughly 2.7 K, just above absolute zero Exam Tip

Using the Kelvin Scale If you forget in the exam whether it’s +273.15 or −273.15, just remember that 0 oC = 273.15 K. This
way, when you know that you need to +273.15 to a temperature in degrees to get a temperature in
Kelvin. For example: 0 oC + 273.15 = 273.15 K
• To convert between temperatures θ in the Celsius scale, and T in the Kelvin scale, use
the following conversion:

θ / oC = T / K − 273.15 14.2.1 Specific Heat Capacity

T / K = θ / oC + 273.15 Defining Specific Heat Capacity

• The specific heat capacity of a substance is defined as:

The amount of thermal energy required to raise the temperature of 1 kg of a substance by 1

°C

• This quantity determines the amount of energy needed to change the temperature of a
substance
• The specific heat capacity is measured in units of Joules per kilogram per Kelvin (J kg-1 K-
1) or Joules per kilogram per Celsius (J kg-1 °C-1) and has the symbol c

o Different substances have different specific heat capacities

o Specific heat capacity is mainly used in liquids and solids

• From the definition of specific heat capacity, it follows that:

o The heavier the material, the more thermal energy that will be required to raise
its temperature
o The larger the change in temperature, the higher the thermal energy will be
required to achieve this change
Conversion chart relating the temperature on the Kelvin and Celsius scales
Calculating Specific Heat Capacity
• The divisions on both scales are equal. This means:
• The amount of thermal energy Q needed to raise the temperature by Δθ for a
A change in a temperature of 1 K is equal to a change in temperature of 1 oC
mass m with specific heat capacity c is equal to:

Example ΔQ = mcΔθ

In many ideal gas problems, room temperature is considered to be 300 K.What is this • Where:
temperature in Celsius? o ΔQ = change in thermal energy (J)
o m = mass of the substance you are heating up (kg)
o c = specific heat capacity of the substance (J kg-1K-1or J kg-1 °C-1)
o Δθ = change in temperature (K or °C)
 Example
A kettle is rated at 1.7 kW. A mass of 650 g of a liquid at 25°C is poured into a kettle. When
the kettle is switched on, it takes 3.5 minutes to start boiling. Calculate the specific heat
capacity of the liquid.

Exam Tip
Low v high specific heat capacity The difference in temperature Δθ will be exactly the same whether the temperature is given
in Celsius or Kelvin. Therefore, there is no need to convert between the two since
• If a substance has a low specific heat capacity, it heats up and cools down quickly the difference in temperature will be the same for both units.
• If a substance has a high specific heat capacity, it heats up and cools down slowly
• The specific heat capacity of different substances determines how useful they would be
for a specific purpose eg. choosing the best material for kitchen appliances
14.2.2 Specific Latent Heat Capacity
Table of values of specific heat capacity for various substances
Defining Latent Heat Capacity

• Energy is required to change the state of substance

• Examples of changes of state are:
o Melting = solid to liquid
o Evaporation/vaporisation/boiling = liquid to gas
o Sublimation = solid to gas
o Freezing = liquid to solid
o Condensation = gas to liquid

• Good electrical conductors, such as copper and lead, are also excellent conductors of
heat due to their low specific heat capacity
The example of changes of state between solids, liquids and gases
 • When a substance changes state, there is no temperature change Calculating Specific Latent Heat
• The energy supplied to change the state is called the latent heat and is defined as:
• The amount of energy Q required to melt or vaporise a mass of m with latent heat L is:
The thermal energy required to change the state of 1 kg of mass of a substance without any
change of temperature 𝑄 = 𝑚𝐿

• There are two types of latent heat: • Where:

o Specific latent heat of fusion (melting) o Q = amount of thermal energy to change the state (J)
o Specific latent heat of vaporisation (boiling) o L = latent heat of fusion or vaporisation (J kg-1)
o m = mass of the substance changing state (kg)
• The values of latent heat for water are:
o Specific latent heat of fusion = 330 kJ kg-1
o Specific latent heat of vaporisation = 2.26 MJ kg-1
• Therefore, evaporating 1 kg of water requires roughly seven times more energy than
melting the same amount of ice to form water
• The reason for this is to do with intermolecular forces:
o When ice melts: energy is required to just increase the molecular separation
until they can flow freely over each other
o When water boils: energy is required to completely separate the molecules until
there are no longer forces of attraction between the molecules, hence this
requires much more energy

Example

The energy needed to boil a mass of 530 g of a liquid is 0.6 MJ. Calculate the specific latent
heat of the liquid and state whether it is the latent heat of vaporisation or fusion.
The changes of state with heat supplied against temperature. There is no change in
temperature during changes of state

• The specific latent heat of fusion is defined as:

The thermal energy required to convert 1 kg of solid to liquid with no change in temperature

o This is used when melting a solid or freezing a liquid

Exam Tip
• The specific latent heat of vaporisation is defined as: Use these reminders to help you remember which type of latent heat is being referred to:
• Latent heat of fusion = imagine ‘fusing’ the liquid molecules together to become a
The thermal energy required to convert 1 kg of liquid to gas with no change in temperature solid
• Latent heat of vaporisation = “water vapour” is steam, so imagine vaporising the
o This is used when vaporising a liquid or condensing a gas liquid molecules into a gas