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Practica Termo 3

This document summarizes the calculation of equilibrium constants and mole amounts for a chemical system. It provides the initial mole amounts of 5 compounds - A, B, C, D and E. It then calculates the total and individual mole amounts at equilibrium, accounting for any transfers between components. The equilibrium constant Keq is determined to be 4.2551 based on the mole amounts of C, D, A and B at equilibrium.

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15 views

Practica Termo 3

This document summarizes the calculation of equilibrium constants and mole amounts for a chemical system. It provides the initial mole amounts of 5 compounds - A, B, C, D and E. It then calculates the total and individual mole amounts at equilibrium, accounting for any transfers between components. The equilibrium constant Keq is determined to be 4.2551 based on the mole amounts of C, D, A and B at equilibrium.

Uploaded by

daniuli881
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as DOCX, PDF, TXT or read online on Scribd
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Compuesto Pureza % Densidad (g/ml) PM

A 99.7 1.055 60
B 99.2 0.790 46
C 99.8 0.893 88
D 100 1 18
E 36.5 1.185 36.5

Sistema 1
Calculando las moles iniciales de cada componente

Calculando moles de E
°
n E=nE
°
n E=%δ v i

n E=
°
( 0.365 ) ( 1.185
ml )
g
( 5 ml )

36.5 g
mol

°
n E=0.05925 mol
Calculando moles totales de A

nT =n A +n E

n A =nT −n E

n A =0.4399 mol−0.05925 mol

n A =0.38065 mol

Calculando moles de A
°
n A =%δ v i

°
nA=
( 0. 997 ) ( 1. 055
ml )
g
( 60 ml )

60 g
mol

°
n A =1.05 18 mol

Calculando moles de B
°
n A =%δ v i

°
n B=
( 0.99 2 ) ( 0.790
ml )
g
( 60 ml )

46 g
mol

°
n B=1.0 222 mol
Calculando moles de C
°
n D =%δ vi
°
nC =0

Calculando moles de D
°
n D =%δ vi

°
nD=
( 1) ( 1mlg ) ( 3.175 ml)
18 g
mol

°
n D =0.1764 mol
°
nA 1.0518 mol
°
nB 1.0222 mol
°
nC 0 mol
°
nD 0.1764 mol
°
nE 0.05925 mol

Sistema 1

V NaOH N NaOH
nT =
Vm

( 1.173 ml ) ( 0.003 N ) (125 ml)


nT =
( 1 ml )
nT =0.4399 mol

Calculando las moles de A

nT =n A +n E

n A =nT −n E

n A =0.4399 mol−0.05925 mol

n A =0. 38065 mol

Calculando ε

°
ε =n A −n A

ε =1.0518 mol−0.38065 mol


ε =0.6711

Calculo de moles totales


°
n A =n A −ε
°
n B=n B−ε
°
nC =nC +ε
°
n D =n D +ε
°
n E=nE

n A =1.0518 mol−0.6711

n B=1.0222 mol−0.6711

nC =0 mol+ 0.6711

n D =0.1764 mol+ 0.6711


°
n E=0.05925 mol

n A =0.38 07 mol

n B=0. 3511mol

nC =0.6711 mol
n D =0. 8475 mol
°
n E=0.05925 mol
Calculando Keq

( nC ) ( n D )
K eq=
(n A) (nB)

( 0.6711 mol ) ( 0.8475 mol )


Keq=
( 0.3807 mol ) ( 0.3511mol )
Keq=4. 2551
°
nA 1.0518 mol nA 0.3807 mol Keq=4.25
n
°
B
1.0222 mol nB 0.3511mol
n
°
C
0 mol nC 0.6711mol
n
°
D
0.1764 mol nD 0.8475 mol
n
°
E
0.05925 mol nE 0.05925 mol

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