FIITJEE

ALL INDIA TEST SERIES

JEE (Advanced)-2023
FULL TEST – IV
PAPER –2
TEST DATE: 08-02-2023
Time Allotted: 3 Hours Maximum Marks: 180
General Instructions:

 The test consists of total 54 questions.

 Each subject (PCM) has 18 questions.
 This question paper contains Three Parts.
 Part-I is Physics, Part-II is Chemistry and Part-III is Mathematics.
 Each Part is further divided into Two Sections: Section-A & Section-B.
Section – A (01 – 04, 19 – 22, 37 – 40): This section contains TWELVE (12) questions. Each question has
FOUR options. ONLY ONE of these four options is the correct answer.
Section – A (05 –10, 23 – 28, 41 – 46): This section contains EIGHTEEN (18) questions. Each question has
FOUR options. ONE OR MORE THAN ONE of these four option(s) is(are) correct answer(s).
Section – B (11 – 18, 29 – 36, 47 – 54): This section contains TWENTY FOUR (24) numerical based
questions. The answer to each question is a Single Digit Integer, ranging from 0 to 9 both inclusive.

MARKING SCHEME
Section – A (Single Correct): Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct option is chosen.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –1 In all other cases.
Section – A (One or More than One Correct): Answer to each question will be evaluated according to the following
marking scheme:
Full Marks : +4 If only (all) the correct option(s) is (are) chosen;
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen;
Partial marks : +2 if three or more options are correct but ONLY two options are chosen and both
of which are correct;
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a
correct option;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –2 In all other cases.
Section – B: Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct integer is entered;
Zero Marks : 0 Question is unanswered;
Negative Marks : –1 In all other cases.

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AITS-FT-IV (Paper-2)-PCM-JEE(Advanced)/2023 2

Physics PART – I

Section – A (Maximum Marks: 12)

This section contains FOUR (04) questions. Each question has FOUR options. ONLY ONE of these four
options is the correct answer.

1. A thin lens of refractive index 1.5, and focal length in air

20 cm is placed inside, a large container containing two
immiscible liquids as shown. If an object is placed at an
infinite distance close to principle axis (common
intersection line of the layers), the distance between
images
(A) 25 cm (B) 45 cm
(C) 65 cm (D) 85 cm

2. There is a uniform magnetic field B in circular region of radius

R as shown in figure, whose magnitude changes at the rate of
dB/dt. The e.m.f. induced across the ends of a circular
concentric conducting arc of radius R1 having an angle  as
shown (OAO) is:
 2 dB  dB
(A) R1 (B) R2
2 dt 2 dt
 2 dB
(C) R (D) none of these
2 dt

3.

If (I) represents isothermal and (II) represents adiabatic, which of the graphs given
above in respect of an ideal gas are correct?
(A) I and II (B) II and III
(C) I and III (D) I, II and III

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 3 AITS-FT-IV (Paper-2)-PCM-JEE(Advanced)/2023

4. A travelling wave is given by

0.8
y
3x  12xt  12t 2  4
2

Where x and y are in m and t is in sec, then velocity and amplitude of wave will be
(A) 2 m/s, 0.2 m (B) 4 m/s, 0.2 m
(C) 2 m/s, 0.4 m (D) none of these

Section – A (Maximum Marks: 24)

This section contains SIX (06) questions. Each question has FOUR options (A), (B), (C) and (D). ONE OR
MORE THAN ONE of these four option(s) is (are) correct answer(s).

5. Three unlike point charges are arranged as shown in given

figure, where AOB is the right angle formed by two conducting
half-planes. The magnitude of each of the charges is | q | and
the distances between them are shown in the figure. Total
charge induced on the conducting half-planes and the force
acting on the charge –q is
(A) charge = –q
(B) charge = –3q
 2 2  1  q2
(C) Force  
 4   2a2
 0 

 4 2  1  q2
(D) Force  
 4   2a2
 0 

6. Consider an arrangement of cells shown in the

figure. There are m-branches and in each
branch there are n-cells. Suppose this
combination of cells can be replaced by a
single battery of emf V and internal resistance
R, then V and R.
n(m  1)E
(A) V 
2
m(n  1)E
(B) V 
2
n(n  1)r
(C) R 
2m
m(m  1)r
(D) R 
2n

7. Consider the shown case of a freezing lake due to

negative environmental temperature (–0C). Thickness (x)
of ice layer is small in comparison to depth of lake. Rate of
increase in x will be greater:
(A) if environmental temperature increases.
(B) for larger thickness of ice layer.
(C) if environmental temperature decreases.
(D) for smaller thickness of ice layer.

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AITS-FT-IV (Paper-2)-PCM-JEE(Advanced)/2023 4

8. For a certain transverse standing wave on a long string, an antinode is formed at x = 0

and next to it, a node is formed at x = 0.10 meter, the displacement y(t) of the sting
particle at x = 0 is shown in figure.

(A) Transverse displacement of the particle at x = 0.05 m and t = 0.05 sec is 2 2 cm

(B) Transverse displacement of the particle at x = 0.04 m and t = 0.025 sec is 2 2 cm
(C) Speed of travelling wave that interfere to produce this standing wave is 2 m/s.
1
(D) The transverse velocity of the string particle at x  m and t = 0.1 sec is 20
15
cm/sec.

9. A particle performing simple harmonic motion undergoes initial displacement of A/2

(where A is the amplitude of simple harmonic motion) in 1s At t = 0, the particle may be
at the extreme position or mean position. The time period of the simple harmonic motion
can be
(A) 6 s (B) 2.4 s
(C) 12 s (D) 1.2 s

10. A sky lab of mass m is first launched from the surface of earth (radius R) in a circular
orbit of radius 2R (from centre of earth) and then it is shifted from this circular orbit to
another circular orbit of radius 3R.
3
(A) Minimum energy required to place the lab in first orbit is equal to mgR.
4
mgR
(B) Minimum energy required to shift lab from first orbit to second orbit is .
12
(C) Energy of sky lab in second orbit is greater than its energy in firsts orbit.
(D) Energy of sky lab in second orbit is less than its energy in first orbit.

Section – B (Maximum Marks: 24)

This section contains EIGHT (08) numerical based questions. The answer to each question is a Single
Digit Integer, ranging from 0 to 9 both inclusive.

11. A glass of refractive index 1.5 is coated with a thin layer of thickness t, of refractive index
1.8. Light of wavelength  travelling in air is incident normally on the layer. It is partly
reflected at the upper and at the lower surfaces of the layer. The two reflected rays
interfere. If  = 648 nm, obtain the least value of t (in 10–8 m) for which the rays interfere
constructively.

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 5 AITS-FT-IV (Paper-2)-PCM-JEE(Advanced)/2023

12. A Bohr hydrogen atom undergoes a transition n = 5 to n = 4 and emits a photon of

f
frequency f. Frequency of circular motion of electron in n = 4 orbit is f 4. The ratio is
f4
18
found to be . State the value of m.
5m

13. Two uniform spheres shown in given figure rotate separately on two parallel horizontal
axis passing though their centres. The upper sphere has an angular speed 0 and the
lower sphere is at rest. Now the two spheres are moved together so that their surfaces
touch. After a short time the two spheres, now in contact, are rotating without slipping.
Find the final rate of rotation of upper sphere in rad/s [given moment of inertia of the
upper sphere II = 4 kg m2, moment of inertia of lower sphere I2 = 2 kg m2, radius of upper
sphere a = 2 m, radius of lower sphere b = 1 m, 0 = 12 rad/s].

14. A solid cylinder of height h and mass m is floating in a liquid of

h/4
density  as shown in the figure. Find the acceleration of the vessel
(in m/s2) containing liquid for which the relative downward
acceleration of the completely immersed cylinder w.r.t. vessel m
becomes equal to one-third of that of the vessel acceleration in
magnitude. (Take g = 10 m/s2) 

15. A barometer contains two uniform capillaries of radii 1.44 × 10–3 m and 7.2 × 10–4 m. If
the height of liquid in narrow tube is 0.2 m more than that in wide tube. The true
pressure difference is 310 × N. Then the value of ‘N’ is ______.
Density of liquid = 103 kg/m3, surface tension = 72 × 10–3 N/m and g = 9.8 m/s2. (Angle of
contact = 0)

1
16. Two electrode each of radius a = are embedded a large distance apart in a

homogeneous conducting medium of resistivity  = 1. Resistance between the
4
electrodes is . Then the value of ‘n’ is ______ .
n

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AITS-FT-IV (Paper-2)-PCM-JEE(Advanced)/2023 6

17. Time constant in given network.  = 2.1 × n. Then the value of ‘n’ is ______ .

1F 2F

1F
2F
1F

4 4
4
+
A
4 8
20
8

4 3 6

B 2

18. Plane of height h = 1.6 meter and inclination  = 30°

to the horizontal has a smooth groove cut in it
inclined at an angle  = 45° to the line of greatest
slope as shown in figure. Time that a particle would
take to move top point A to bottom point O in groove,
3.2
starting from rest at the top is . Then value of ‘k’
k
is (g = 10 m/sec2)

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 7 AITS-FT-IV (Paper-2)-PCM-JEE(Advanced)/2023

Chemistry PART – II

Section – A (Maximum Marks: 12)

This section contains FOUR (04) questions. Each question has FOUR options. ONLY ONE of these four
options is the correct answer.

19. End product of the following sequence of reaction is

O
1. I2  NaOH,
 
C—CH3 2. H ,

O
O O
(A) Yellow ppt. of CHI3, (B) Yellow ppt. of CHI3,
COOH CHO
O
(C) (D) Yellow ppt. of CHI3, COOH
Yellow ppt. of CHI3, COOH

20. The following reactions takes place in stratosphere

U.V radiation
O2  O  O
O  O2  M  O3  M  exothermic 
What is the role of ‘M’ in above reaction?
(A) It is used as a catalyst
(B) It absorbs some heat energy and prevents decomposition of O3
(C) It converts ground state O2 to excited O*2
(D) It reduces the reactivity of nascent oxygen

21. The temperature of a definite amount of an ideal monoatomic gas becomes four times in
an isoentropic process. Which of the following is correct relation between the final and
initial parameters of gas?
(A) Vf = 8Vi (B) Vf = 16 Vi
(C) Pf = 32 Pi (D) Pf = Pi

22. 0.1 M acetic acid solution is titrated against 0.1 M NaOH solution. What would be the
difference in pH between ¼ and ¾ stages of neutralization of acid.
(A) 2 log 3/4 (B) 2 log ¼
(C) log 1/3 (D) 2 log 3

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AITS-FT-IV (Paper-2)-PCM-JEE(Advanced)/2023 8

Section – A (Maximum Marks: 24)

This section contains SIX (06) questions. Each question has FOUR options (A), (B), (C) and (D). ONE OR
MORE THAN ONE of these four option(s) is (are) correct answer(s).

23. -
O

H3C O

O
Br
Which of the statements regarding the product formed in the above reaction is correct?
(A) If Br is replaced with NO2 rate of reaction increases
(B) Inversion of configuration takes place.
(C) Nucleophillic acyl substitution takes place.
(D) Configuration at chiral carbon does not change

24. Which of the following statements is/are true about an azeotropic mixture?
(A) An azeotropic mixture boils at constant temperature
(B) The composition of an azeotropic mixture changes on distillation
(C) An azeotropic solution of two liquids has a boiling point lower than that of either of
them when it shows positive deviation from the Raoult’s law
(D) An azeotropic solution of two liquids has a boiling point higher than that of either of
them if it shows positive deviation from Raoult’s law

25. The following data are given for the reaction

X  g   Y  g  Product
No. of Initial concentration of Initial concentration of Rate of reaction in M s–1
expt. ‘X’ in ‘M’ ‘Y’ in ‘M’ unit
1. 0.1 0.1 2  10–8
2. 0.2 0.2 4  10–8
3. 0.4 0.2 8  10–8
Choose the correct statement(s) from the following
(A) The order of reaction with respect to X is one
(B) The overall order of reaction is one
(C) The rate constant of the reaction is 2  10–7 s–1
(D) The half-life of ‘Y’ does not depend on its concentration

26. Which of the following substance(s) produce(s) gases when treated with water?
(A) CaC2 (B) Mg3N2
(C) Na2S (D) KNO3

27. What is/are the product of reaction?

Ph
Cl2

CCl
 Product / s
4

Cl Ph
Ph Cl
(A) (B)
H Cl
Cl H

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 9 AITS-FT-IV (Paper-2)-PCM-JEE(Advanced)/2023

Cl Ph
H Cl
(C) (D)
Cl H
Ph Cl

28. Which of the following complex(es) show(s) geometrical isomerism?

(A) [Cr(H2O)5Cl]Cl2.H2O (B) [Pt(NH2CH2COO)2]
(C) [PtCl2P(C2H5)3]2 (D) K2[Fe(CN)4(NH3)2]

Section – B (Maximum Marks: 24)

This section contains EIGHT (08) numerical based questions. The answer to each question is a Single
Digit Integer, ranging from 0 to 9 both inclusive.

29. NH3 , 
 X     Y

CH3CHO
40% NaOH dil.HNO 3

CH2OH (Z)

HOH2C  C  CH2OH

CH2OH
Total how many sp2 hybridised N are present in (Z)

30. Among the following

The total number of aromatic species is

31. The MoMo bond order in [(5-C5H5)Mo(CO)2]2 which obeys the 18- electron rule is__.

HCl Na Fe CN NO

32. X  s   2
 Y  
NaOH
5 
 Purple solution gas
Y has been allowed to react with following species in neutral/acidic medium
(a) FeCl3 (b) CuSO4 (c) BaCl2 (d) SO2 (e) Cr2O72 (f) CH3COONa (g) Hg2+
The calculate the value of P + Q – R
P : Number of species which undergoes redox reaction with gas Y
Q: Number of species with which gas Y undergoes precipitation
R: Number of species with which gas Y produce no observable change

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AITS-FT-IV (Paper-2)-PCM-JEE(Advanced)/2023 10

33. On heating a sample of 25 mg hydrated compound(molecular weight = 250 g/mol) in

thermogravimetric analysis, 16 mg of dehydrated compound remains. The number of
water molecules lost per molecule of hydrated compound is _________
(Molecular weight of water = 18 g/mol)

34. Number of carbonyl groups present in the final product of the following reaction
sequence is

35. A tetrapeptide, made up of natural amino acids, has alanine as the N-terminal residue
which is coupled to a chiral amino acid. Upon complete hydrolysis, the tetrapeptide gives
glycine, alanine, phenylalanine and leucine. The number of possible sequences of the
tetrapeptide is

36. The number of possible stereoisomers for cyclononene is ______

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 11 AITS-FT-IV (Paper-2)-PCM-JEE(Advanced)/2023

Mathematics PART – III

Section – A (Maximum Marks: 12)

This section contains FOUR (04) questions. Each question has FOUR options. ONLY ONE of these four
options is the correct answer.

37. Let A and B be 2 × 2 matrices with real entries satisfying (AB – BA)n = I2 for some
positive integer n, then n is
(A) even (B) odd
(C) prime (D) any integer

38. Let A & B be two n × n matrices that do not commute and for which there exist non zero
real numbers p, q, r such that pAB + qBA = In and A2 = rB2 then
(A) p + q = 0 (B) p – q = 0
(C) p2 + q = 0 (D) p = 2q

d2 y
39. The solution of the differential equation 2
 sin 3x  e x  x 2 when y1  0   1 and
dx
y  0   0 is
 sin 3x x4 1  sin 3x x4 1
(A)  ex   x 1 (B)  ex   x
9 12 3 9 12 3
 cos 3x x4 1
(C)  ex   x 1 (D) none of these
3 12 3

40. Consider a circle of diameter AB and center O, and the tangent t at B. A variable tangent
to the circle with contact point M intersects t at P. The locus of the point Q where the line
OM intersects the parallel through P to the line AB is
(A) straight line (B) parabola
(C) ellipse (D) hyperbola

Section – A (Maximum Marks: 24)

This section contains SIX (06) questions. Each question has FOUR options (A), (B), (C) and (D). ONE OR
MORE THAN ONE of these four option(s) is (are) correct answer(s).

41. Variable circle is described to pass through point (1, 0) and tangent to the curve
 
y  tan tan1 x . The locus of the centre of the circle is a parabola whose:
(A) length of the latus rectum is 2 2
(B) axis of symmetry has the equation x  y  1
3 1
(C) vertex has the co – ordinates  , 
4 4
(D) none of these

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AITS-FT-IV (Paper-2)-PCM-JEE(Advanced)/2023 12

x2 y2
42. Line through P(a, 2) meets the ellipse   1 at A and D and meets the coordinate
9 4
axes at B and C so that PA, PB, PC, PD are in G.P., then possible values of a can be:
(A) 5 (B) 8
(C) 10 (D) –7

43. Let  be a real number, then the integral,  n  I

1 sin  dx
I   1 1  2x cos   x 2 
 
(A) if    2n,  2n  1  (B) if     2n  1 ,  2n  2   
2 2
 
(C) if     2n  1 ,  2n  2    (D) if    2n,  2n  1  
2 2

44. Let u  ax  by  a 3 b  0, v  bx  ay  b 3 a  0, where a,b  R be two straight lines.

The equations of the bisectors of the angles formed by k 1u  k 2 v  0 and
k1u  k 2 v  0 for non zero real k1 and k 2 are:
(A) u  0 (B) k 2u  k 1v  0
(C) k 2u  k 1v  0 (D) v  0

45. If f :   , such that f  x  

x 2
 x 1  , then
x6  x3  1
3
(A) minimum value of f  x  is 1 (B) minimum value of f  x  is
1 3
(C) maximum value of f  x  is 1 (D) maximum value of f  x  is 9

46. Let z, iz and z + iz represent three vertices of a triangle then,

1 2 2
(A) area of  is given by, Area  z (B) area of  is given by, Area  z
2
(C) orthocentre of  is given by z  iz (D) None of these

Section – B (Maximum Marks: 24)

This section contains EIGHT (08) numerical based questions. The answer to each question is a Single
Digit Integer, ranging from 0 to 9 both inclusive.

x2 y2
47. Tangent are drawn from any point on the hyperbola   1 to the circle x 2  y 2  9 .
9 4
2
If the locus of the mid – point of the chord of contact is a x 2  y 2    bx 2  cy 2 , then the
value of a 2  b2  c 2  7870 is equal to

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 13 AITS-FT-IV (Paper-2)-PCM-JEE(Advanced)/2023

 
48. Let b  4i  3j and c be two vectors perpendicular to each other in the xy – plane. If
 
r i , i  1,2,....n are the vectors in the same plane having projection 1 and 2 along b and
 n  2
k
c respectively  r i is equal to k then equals to
i 1 4

      1
49. If the value of greater of sin x  tan x and 2x  0  x   at is g   then g   
 2 4 4 4 2
is equal to

50. Let A & B be 2 × 2 matrices with integer entries such that A, A + B, A + 2B, A + 3B and
A + 4B are all invertible matrices whose inverse have integer entries, then find I det (A +
5B) I

51. Let  an  be an arithmetic sequence such that arithmetic mean of

50 r r 1
a1,a3 ,a5 ,.....a97 ,a 99 is 1. Find the value of   1
r 1
2 .a2r 1

2
52. Let f  x   ax  bx  c, where a  0, a,b,c are integers and f 1  1, 6  f  3   8
x
and 18  f  5   22 . Then the number of solutions of equation f  x   e is ______

53. If z1,z 2 are complex numbers, then the maximum value of

z1 z 2  z1z 2  z1z 2  z1 z 2
is equal to ____________.
z1z 2

2
54. Let f  x   ax  bx  c,  a  b  and f  x   0  x  R . If the minimum value of
abc
is k then value of k is
ba

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