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Class Notes 2021-22-2
C.R.E
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Class Notes 2021-22-2
C.R.E
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27, Reptember 2021. CRE Dy Reptemben 20, CRE Ig50 , 1GS4, CRE qive Name Mahavasta & Guyeak —> 607). (CRE Compan) raodle+| Lame - 66x19" qr mol ! oe Oxegen —y» 16 taka = 6.022xi0 aby = 16x 16E x10 ¢.022 x17 qo~ =. |e Rabe of Run -: No -0f male (ny al) Perunth Ge » Pee Unk volume a x time 0 trnw =t (a-x) tm = 4+db (A-x-dx) Roke = X_ € Concectrabion of. A = Ina dk tma = Rate~ —dcy (Rote of Ren) \ Ok Conc. A eae tay wth Bine > IN,05 = 4NO, [n=] f +0 Fox Reoskank eee a “L At. ee ae ere Ppl t AL NOT a aTRate. of Run of0,.= ALO 7 clt —> WA FAB +c am CctmDt...., = «lf .aAtAa _-| dlel. Rote of Ren A = te C — = mi de = | afte] ~-1tdeoi, mo dt Mec tt Unik of Ryn —' (Ya) or (-Ya) Pedant Reet Uk of Rea s Volume inn = Wile deb al bs! te Rote constant (K) — Tre =Kilaexy Ls Totally depend upom Tempera 180s og £ . = a Pt -T "Fh ty C Foe dite Mlonpe ter For Sine temperabure [Ral conto = Ago | — iy eke Stert if eneryy give onteke AEs te Unt of Rake COwkad = Kf a kK = Rokeot Rx» Ba"kK _ male Mati seion| K = mole ated mole”, Lede” [K = mmole! mete pete | rt in| ( THs (6 Uwe of Bish aclh cece ane oilandl KK) 28, heptember 2021 rn aan derot Ry Rate = KCK Oot Be ! Order of Rxn —: 2NO, +0, ——> 2NO2 Case -1 Rote of Ren ok Cevel Peal Orderof Run = 2+! =8 Case-2 coc 2A TB — > Produk (exces) Rode = KEC,T CeeT° O.of Ren = 2 Carse-3 4 +6 aa Prrockuk Cexcesa) Robe = ELC. T° Pep! 0. of Ryn = toS He Half Life Pentod —1 The tim to complete jay) TT of veaction ('s called reactant bem “He ore Holt Life Pemied + oy ~Y ty « pal” Where n = order of Ryn at Types of orden of Ryn —: (1) Zer Order Rxn —' A —> Produth t=0 a aes (a-x> Rat~ = kCa-xj? Rate = K dae =k After integration Kt= X Ralf Life Pertod 5 fy Xtal (2) M Order Ren A —> Product te Breler Kun Robe =k JS ax ae > © ed? Kt= In 9 Kt = 2-202 lag _4& CA-x) Half Life Period ts Cndopemelack of Petit) ae.ty Xray? 1392. order Ren -! oat - — Product — = a ae Ca-x) Rate = KLO-KI™ oe =” CalxI* ws a2 ax Cape Cape-2 A +k ——? Produc tat (a-x), (b-x) Rate = (FAX Cb-x7 Ox =kCa-x7 Cb-xT After inkegrabion , KxXtE = 2-303 b(a-x) (Q-b) “ aAlb-x)" Half Life Period -! pout Vuela a yecay! / He Clemency and Non- elemest a! Png. ot =e areackion _ A reaction in whieh react exactly as per it Stoichiocsck fe enpakion (2 called Ren-! pre motets as an elementy reaction.’ Por eXarwale-\ CoH OH CH, COOH —> HySPOG He ty Non - Element, Rem -! “Those YX th havin multr—ctep TR es, Called Pees Rear Ryn. The wencdion fe win foomabin: of Pl som Oren al veactimt occurs Hhreugd ty, Serves of Steps are called Mens en ent a Wy) A+® ——>R+5 R+p > Produck OD on > 5 —%e =kee,7% ast 2 For examiples ~' a HL + Qr, ——> 2HOr ti) Udo ——> cyHco . 04, october 2021 CPE He Difference belween charm encry and non element Veations —* = = nt Elementry Rem Neon king Reon 1-Elame, Ren Are hin Noneleme reackions g Step ea ve muktister Rein * Dew Elemnenstoy. Ren are Aimple Noneleme, wteoakion Oe tn nature : COMPLE an spat tie 3+ For clemerty Rin, He order! For mon clhimentny, Rye of each specter’ ip tderbicat [O° ofead tye With the ctotchtometric toefficr of Hak species,(A A Aidterence betwee, Oder and ctoidhiomebie efficient). ,, foran lam ity Ren, | Fox ninnahninsiding Rien, the orde, J order of Rin’ wrust be | OF Ren he an btager o, an deen if 1 © | have frockional vobu. 5: for an clement Rees, Formmonelemedry Ran, DAR the Yacke tds 2B FS Ye rote tay ma ov, = kcal . be —Yg HK Leal utter tf 9 g, An ex of an elemento} Ex, of nonelmanta Raw Ren if ay HatBr. —>2Ha, Ca HOH +H, 00H —>cy,cove +H,0 GU CH, HO > cry ten 1 te Moleculanty of Ren (m) =; >The yuembser, of jrnulen tad porbive peck! WW ‘ony chumteet Ren Ce cab moleetartty of Ryn. Molecslar ty le posscbl for chemertry Rin, # ok The moleeari, ta hefinad aa He number of molewtes, Aten. OF Cons PieBinhpsttinty tr the rake determ ong, Step of the Ren, aHE Difference between Moleculerty and Banas — : _ ___Orcley of Ren [ molecslarty L-. Nowof swoteoules Vihosd NO. Of moleculea of , COncentyation dlekermines tale part by Chtetict fests vate Of Ren VERSE » : NH4No, —> N, 4,0 pagel NH — > Na te2Ho Yoke — & CAH NO,7! wee : “orderap Pens 4 Teele =1 2. TE mow be zera) frackinll Nettle Zero and Nor Or inkeaer. Fractional. 3. It ts derived from vate | TE ts cherived Hon ex prediton , Mechanism of Ren, As TE Us experimental Tt ts a theoretkeat Gps . Wentity... S+ It depends On predsure | Moleatlar. ta independ! and temperadtiine , Of Pressure & Cemperckure, 6. TR order Of Ran ts defined Od the bum ef the ex por ents of te or Co ne | 7 lOnd parbetonds Concenkyedion ty te vate | the vale deter, vend quuaticen, SP op aD Qn A read, proceeds 5 4 foun MY more at 40°. as (t coer at aoe, Est¥meke EQ oo meet yl ak T, Mme kta” ox Tx WW SE Pea Sp: Ki Cx"- Qn-t Caleutate the yede constant and hell Jip. a . ne femeck for +e first owcler Ren haveng an Activote n Enensy Ea = 393 KCOW wrol at Bove 9 R= = I Itxtoll poet R= 987 cal glution.. yioae “tf a= K=bt4xiot <1 Am ty = 6078 sen Am OL, OCtober 2021 te Reackon Mechanism (Elem exbry & Kis
Peodiust Rkes KCN Order of Ren =1 Mee 1 A+teg ——> AD Rote = -k ECA T'CtaT! OR = (ltl =2 mad @) Nom -alementany Ran —" Room Co-ordinagke R—> & CSlow) A 2B Chaat BY —> 2 Chast) SF —> PCat) R— +Pa jeser Hue pues veqpniceddt > foster the-voadkis,, 2 Te Wri He take ot Rim for Hats Wenn lamers Rion » We VeGpived He Slowest reackso,, , a Rake Sk Cond! Points ee tip Complor i nature. ti), Intivmediote produits are forma: did: Rate ef Reh possible nla for thowdst Rens OY m step. | we DA +28 > A, 8, Ate ks Ap Step | (Stem) ast) UP Agta Ka 5 Ag, Step 2 ( Pewt)/ Slow) Wii) ABtAtE Ke sA,e, steps (fast) Fincdoukt U1) Orclr of Ryn 7 (fer slowort step) (2) Rote law of Roy (3) ihe Solstion -: A+R pn AR Roke = Kk Len! [ee]! J oR = [422 / f™ = o/ 4 Fi / TH city Cr Clow BCL ave fast tha, / Rode =< ky pares! ced! ; wake Eidnake n/t Onn interest Ate —» AB —— ArAume Ran Us in equild foctuny eeSo, pA aS Pre » |r / Ky va G Cay / raed = pe ‘ ale “4 = “Paice / Ft / j OR = iy p pa = KK ¢aTced' - ee ey Le Rate = ke CAT QI> oe “bt Mn tie, Rate constat = Kepe y= Kok Recaktng, | ' K4 |} Dont inte, ~diok 4," co. ‘ Of, vctybe- 254 “= # . , ze He Gemeval male folance Eqgrodson —! Ons Solutio. The second step ta Slow and roe oe 2So tHe vote of veackion is aren Rake = -K, LAB TAI ql) “SY v (Eliminate thir terme becaue it CA inteme drake teomu) From step i, Auetstene which ta fart ak equi bron, A+R Ens ARS Atssume Ren ta to eqpethibertin, A+e Kt» Ag ~ Be Keq - CAel = Cone. of Prockut CAICRY Come Of Reaekemt Keg = AL - CAGI keg. LAIceySa Pind the Yolu of LAGI by Hs 2KPtebatby Cael] = kK, CAICB8I Ky Pulting te values 6463 im eagpsotion (1) Robe = k, Ky pAILR1 Ce ky Roke = kaki cagcei* ke Rake = Keppetive LAT COI” be tA the Rabe law of Ren) “4 Rate combi = Kepp = Kokr ky CO) Order of Ram = ita =% Armas ne, og Ct) AB+B —__y Ap, Glow Ren) ‘stencil =(tiz=a2 Avs 08, october 2:02 ee 4= General Mole bolane Equokion =! A mole balance of Speotes Tat any tna + Fa. FF #85 = ans| Vella Ha foliowly eatin Ab Yate of How vate af qererakin Reke of ft. eof of Tin He + FT by Chamu'ecl yon lof tate an SE? walt Syitens moldtine| [OFA system, | 7 [OF the tn ey On Syrtem neya” . ysten, Vardb le (temp, Cone, Cadel hy) We Unt form, Hrrouighs Pig sytem, ‘, GF es . He Rake of generaklon ag tk He. rake . ” : r and ‘y a Ha. eat wrolay fun, = TEXV Totol Volume Rocke p qorersbsn, Tote Way, lf OM He ig Qeaby 2 Gi =, 4Y, Gd, = Vip aV> ' ' ' ! Gm = Vy Van uM Gea 2 Si: = Gay; if Mise. ave \ Vv Si= [xg dy Fy, ¥ efi +P pau =olNy fe ee [Nottie £ Nov cuba ubThite! are 2! types ef bakch ‘aie C6) Contant Volume 7 uti) Constant, Pros surett) Cote’ Meshing Pra Abe Von’ E e poy preasure Fy, =0 2 Fy so (ey dvb ony (2) Constant Pressure —* Noles NOrnidubte Piston y ’ By Fy + (Gdv = ANg' 6 dk Tt veqckon is cOnttont Honugho we Yrdv = Ns fegav = aN WV = AN [* dt =fdny+E CSTR eet ondsnual® ebtrred tank reacton a ain ~ a Bokel, mex Reackor ¢ ‘ » Alwsoays ack at set sede ane =o) Cz) We dt sume tha concentration & tempered, tO be Constant thro ugliouk the Suyatem, : fF. ae Plug Flow Reactor (PER) ~* Ch) rt consist @ cy Linderitah Pipe. (2) Tt Ope rakes at cheat gtee . 03) Flow trcde Hu veactor Wylaly ts feudenk (4y No radveat Vor aio ' Bn Coneenb rade' \ Fro | ay | Fi Otay) ry y+ay Contembyedite, a Vorcne ohong fe ANA 4 Pine Froy Fs ly tay) ; Fi, Fr + [dv = SRE ky _ say fue ANS 20 dau te clendpstate, Ot Nv Fy.- fy + fay 29 [: ; fied vex] Frey) — Ariytaw) +¥pV =O [Av = Axeyd (Volum = Greaxdictince) Fy) — Fy tay) = 7p AY wg A = Fey tay— BIO? ows Ay . : by) bk Fy lytay) — pO) = ate . to oe a 4s ms ——p7OOOCOSC~S Mea ayoo ae er ‘ abs Ars te kh cay. A- vy = LF dv (olistonce Ares =Noluns)12, October ,202L- CRE —- i ce AE Reversitde Ryn - <——~ both forward 2 basknard 2CgHe EL CypHyo + He Benzene, kL ditgh 2CgHe Kis CiaHio AH 4! (Tp) Rate =k, [coHeI Ccel* CipHig +H ke aceHe (%) Rake =ek, [coH, al CHI (e539 Lewd tack =Xo Php a ae Ky Eechel* KK [Cp Cer 2 K, C¢ad* EL Ky [ (Ceo) tend) - ceed” | Ynek = KI [ CepIlH] _ teed" L KY, Key = AE, Taek =k; (a = teat | Pt ire Fag ty Rien =! catabyte alo th pame phase» Prodtut 2 Rea tembs Ore Par phe—®! we eee ci) Atco ke 5 R24 catalyst | —Aey A, Pint {it ender Ea iW Re. a \ alt ~ ACA, = bx: [eat Ee ak “9 _ = (yea rk ca Ce] at dA = Op (kit Kate) fe a C Comatenct) Kdideriied ~ btn = K opserved CA , clicompo) ion One “Ht Ako Codmlykic Rem 1 [ AH iy clicomys cabulyds] aes Ne Hy > 2A + HL . Arshino ‘ A+R, —— > R42 —A Sa =KCyAte ak x aePR ick Concereemon a Oo = Cate ‘ok tm t Ce = (CoCr) — Aen | = b Cy (to -—A) ak fa + j -don = ( k dt Ca (CoCr) to ° mile th T Proelen <'n Porteurized tf vu heoked ™ « for 290 wainutes bak if tk Cy heated +o S745 Ue talees Pic beeonda for Hee Sarre veatt find that activation ener ayy fo He vshole proces CEa) = ? ve : Ea = “2000 Tat A Solution -: Ty = 68 ee £ = Zo whudu = goxgo = 1850 hesond Ts, = Tye. tr = 18 becond *aeatg fel = ba (ati ar Ti 5 + Padre Th tim) ret AL Ce Be 4PH,(9) ———> P. 46H J phogiing seq) +64, cg tobe ef decomposition he = 2Sxto? mole. Ca) Expres He roke iy 4, eh x Pee ves heft. Usin differential — sap, are way (b) End rete of formalron of Py 2 Hy.Pr, 2 GOK ad pga, Y Ans Ai SB. 8Ris® wolt/y 54, ~ 22, Ocko ber, 2021 ColLosion ae Oo The rectonkt melewle cobLor td eae ou Amd to focm produck « @ Every collection doe not take part tin Hh Retna nt tbs of preducck . ® Prope pte baben § —N o> } abe 6). OB a 0 O Cfroduc formebin. more) Fi ced A+R sy Pracut CAD = C8] = 1 wel /pit ( Yeo ks YO a4 Rote =k According to color ion, theen » a Reckeo § Ren ox No. of! co Lacon per Ut time Per Unk Volume(Z) Whhire , Z=colloston Freqpe Chaning oti Bren @ nergy) dD Rake of Ram 0 No. of ackive noleamtes (4) Rate of rym = Ze a _ A = Nov of cedave waleades = \t=n2 Toted qolecute a Yieeen'COm ble cohatlated from Maruell Goldene ict Ubution haw ome cme No of molectls thls contain ackiedin enera na fotet Vimo er of yolecules, es / Where © = yok mean 84 ae valouity = a o- = collosion dliameker a = No, of Powteles = La cpa | [ze bet [2 = 2a [RTA Reke Constant =! he = =z DS 2etnr (DET), Shy (z3 (e Oo. Jintbedions —[ Gt ipa Op Leable only fox qe XN @® Rotcbonad and vibration @neve-, daca not (ncludid. 7 hetow ake Complex Theory Cie Premas tes Zone Activated Complue Max mestinn energy AMAXI amet — —The potesds al pe wb h Siena vlads ko -moanemun, ond ys MAbe_ OF ottom thet corvesponds to Hy Feqton ob, 7 y Chose fo he mn ee Crtvaked Complex a "G7 cal Ee . be i Ao. a Erevan, of atiebed ea plese —E, | OF Reartent ww | 23, October 9021 + Or vereion > aA +bR — yee +dD Atbhe—5»cc+dDd a a a A,B,C, D —> Regstont Q,b,6, hd —»s Storehlometric coefpieent Kp — males of a yeaked — Na moles of A fed Nas Nag = NAoXa Ofter some Ermey, Na = Nao-NaoXA Na = Nagll-Xq) Tyihtal Nag after sone Hew Nas Design Equation of Batch Reactor =. Equediov of Batch Rearter, Poa lhe rdv =d Ne Toe ky + [ogy qe fv dv =a fie . MarConstonk Vo bums patel weeds Cty =Writaty | sav cate. cae HTP = — NG ak 2g eal ANS Vv Tole Na =Nay (l-Xad . ANA Hd (Nactt-xar| Constant vols Reactor av = aha. AA elas We Nae tpn =r dA fe Se: cake] ~¥a = —l oP ~ erat_ TPM Vohums batch Reactor -' Fl —TAV = No AXA Oe , \““s = Nac dXa lr If a ts -funebo, of — me —-TA — Contant voltunun Reakor [* = Nao AXA aia} tf yoluns ts function of ~YAV conversion a6: ,)V, = NAe & Nac =Ca, Lok Vi Thin Cm fv freee ° —TA to = NA * che | I, -tav | x "Tat rok fowry of batch Gealie., Vartable Voli fo ee Vo = (nikeal Volum. Vo= Volume ak He t V = Vol lt, xa) Ep = feachonal change tn Volume of the Sytem between mo Converstess And Complete COM verso, of wreachion £p ct Vyeq = —_— Vig ao Vxq nDuppers a weackro»-! A —@R (complete conversidy ) so mole oh A, Sd) mee sf, beats Cio Figo) too) 200-09 4 aa joo i) zor Order Ryn Witt Varelble Volume — Ly 2 aL ANA ok Leal? Vv \otk ; ca =@B) = NAS CI- Xa? Vi We UI ba Xa) kK = LL ACN a 1 -xAIT Cl +€ aya) dt Cao =Nao Vo K = ShodXa Cl+ EgXq ak Xp é aka =f it 5 GFEAKA) Cae ds MG ie ln Cit enn) | eo kt EA wal 2 Cho (eqpokvon fox Zoro order Verialobe Volume bake veacker)D8, October 7 2021 _ Empi { yal gudler
Produk -TA = -LdNa ok (tal! TA = Kea + B Var eb Na = Naoll-%a) » VeVe (I+ EaXa) Pak Hare valu fo 1 avo Rien -' -Ta = —lL A (Na IT EKG Vo + &,aX) abe Ey = Vayu —Veqzo Viggzo -TA = — Nao d Ul-Xa) Vo Cl +eyxqy Ak Cy = Naw Vo AXa =k = of CA, Gee =KA —i ye =e Cl + yadaCa =Na TT he ax Gee das > em ae 4 em, = Mae ia Vo Cl + @,%a? be = & fla gies Reape yom Wier 2 Fit ordi. Rog —> =|- boa 1-4v_ yet ss) equation tte of Volume:aye 24, Otm@Ner ,202| | Var OTL Volume bokeh @reader fox Lords, 2A 3 Poduct —@ A+B Intra Cp. > Prodisk ——li = Cp, =WA = k[caP ¢, te dkny — Kono (%4— ~ I+E,%a dt Gaal x, ‘A + It€aXA dyn — Kae [ bt 3 A-X,) > ' Xp Xe + (Ldn t6f Ga aay kee, [ at NUH XQ)” 3 Cl Xay> ° het [-% ay [ttt Ano, ys Xp =l-y MEXA sal Xy Ax, =—-dy IX, Xp -{ dy En (2) a =kG,t \e: a \ yr leX -Lt] 7 Es = t Aa] nea [gc] tetera [Xp _1-%a ZA 4 SAMA + Gal (Xa) = Kent [—Xa | —Xay . [a+ Soe + Eqln Cm =(Kene} mS d, s x bas t Ca | Cay CAL Ca " undecstend ) peels | © for a Seine of 14 Cmemital mabefee we rivet kmow that robe eaureckion”, ee cpeetft, weackionk, Lihtch ts tnvolved (rn He desis» eapahis Of & Veacter | iL we heave UY revere ble veachion, QA +b@-—scC 44D thre rede expression vq = KexePFrom eGprcclian tir velwek help reactor hearin co The volo of Kx, R omwt Known de 0+ Thy, Velues con be caleutetect pHeK With Hx halp of experiments » and Parforn, reacdkon TUM, colle He kinel'e data, andl onal dH Acta, Kin tee doe LS The exper'menk< performed h Colle Kinde rund and deta obtuind fx, experiments (s called the Linekic dota. The collected dala can be tabutetecl as — * (Ln Fogle Book, exarple qven we Com Sean) | Procedure =a, “ Assume the rete eq, Cvalucte ALL terms of vate eq" Peat Aiea AC’ and olt bebe tha fit Of Hu aba te dh anak anual Suppose we have an eqpchen, —rpn = -dCr _ c = KFCeI @ Plot a grep of Concenky dien, Ve time from dre data collected by Pecfo-coning Be. experimen:4 Draw Q Smooth curve thaw ugls Ahose data | D draw a Room gant to The curve be seco Slope , these slope ACA are te vetec ofa at Hw selected cath ae s > Eveluabe FCO) fer each of He silent Concentvelio,,, \ O Plot a aes of —dCa (o~ —ta) Vs fcr. Ef Wwe get go* & stim Mel passing thew origi then Att imal paunttig, thosugd the the vod < eq” ts comer's tewk why te dete - fcc) 29, october 202| — U4 = cH, +, £0, ——> Gyo AH = Ht S08, Bee Qeo, 42,0 & isi, ——ty A ts ¢ aiiAt Ca pracdon iis =% = dt ky Ca Os=addin, olt Y Net vote = —Ath a a KK the) Ga G . (ee “(ki thy at Cas “f — Se Ca by th ye Cae The vote of formation of R&S TR =k tq = der Robe of foeratin. Aiwale , Ab = Redan of dgsinpch Oy oh eae at ace ; bs = oe =k ay dee ak ey Acs k. ae, E: fen! = ase Cs [ace =F fa Ceo 2 From tHe following date shew thet Ha decomperthin of Hydreaes Pereyicle iy AGuous golition ib a fivst order Pen. n " ‘ ys Aue, value ot Rate content ? Exel. aA Ps hy = 0. 02314 win) OT Ex: + Trveverstbl xn Un Server —" nee = rs & ks & ( dnkermadseste) = Hae, =k CA Ab =YA = Ye = Ace =(kit -kece) At my = =o = Ko Ce $o0 I- Nn CAw =k,t | ne be] (ca ae 4 Aimclaoly , iu ce = (kKA-k eT] ae 1st order Ailferenbiat ac = “ [ eh thete = Bea i2 P=Fe yF aC ‘uh oa. ase coe u ys Rs, x= a Wag . aff'd Ceca SP J Pde yo (alls conte cock be “ IP ove kot Cexe i Ce -EDE Exe 0 kK, Cro { ¢ at + Comwtad Popa Ry kee : ce - we debe-m> 2. 2 Eek CO Coratent debwite Ckm-kD At tinctio 7 Ce=O Comtemt —. —Ki Cac le" | Gk2Ak) 9 ; “- qe Er 419 b = &ilin he. , aw EiCro ehh, (kk) Cer ey) Comcentantion Ce = ax Ey Cae okt gket) -@ WGK aK Initially we c tak net A torel ONE Ce = Cat CF | TES ae HFS = Cae Cao & BE Gre Pakit sty’ jen —\S Cenk! 1 Cs Gs = Calf t= en eb} | * Ga er) |pote tf bk, then bgt ee Ce = Cas f ie ey cose tf bk) Sok, th fg =a [tte 7] Xz In Sty Hae binds of cle vormparihirw ‘of a Rim +n cone: of Renton were dobermine Omalylbitically Zh dif parent: Home determing He ode & Rote comtat of Rom + Rabe conated +e Fecous gxardy) wre BY Hee 24, eval gl phen Zoro. Solidion “4 FesscaalaineesIs [I [2021 te ee F aa Space time (@)-: HE (2 L reade- Vobteme pace one to-2 Se | S a Dhy th Rance in fories ow Muli reactors Sipten, GAIN gat CcTR PER Aeivenkins -! @ Ineveanes converclay,, woke a Numb ev twa Lewtes decreases . tmeseares , He total Volime @ Cost with deeveases. disadvan Le: s7} © More Space re ©) Maintenance (Robour cost) pe ed. cort with Inerean. CSTR tn Sevres —! ———_™ SeriesCy,X, ov G, F, FLV of XV Cr Xa er Gy Fe XX = Conversion vate |. - - N ow av Ny Mg iViolome of wacidine SE te Co = malar cone. ‘ne he Vo hu. Vo = Vohumedade flee tit tom: Fo = molar flow vate (cs} rae x = OLOnVecsion ak too We knoe, Na Nac lx) CA = Cho (lL - Xa) Fa = Fao (1- ma) — . A — Product fox ——» alas A fed SALA Hime meee A . fel PK —— > moles of Avreceted ten[msla~ ous vote ak wild A or feel + Meet | = relax vote af ushich A uy consumed] +f molar flor ie at Mush, A - leaves Wu Ren Fa sXe 50 ) ( FX Fa = Fax, +Fy Fa =FfaXi = Py a fa [t-X] ———@ Tee, pie senchy) Fix, Fa Xx For sceona reactor a ——_— F, = fa (1-%,) Po . Here X= tote moles of A venehed cpte pom 2A wale balance om s peatea A fo the esTR tn fu cetond gives, ty ~ouk + qemeeabion = © for CSTR-2 F\ “1 | (Second veacor) Fe Fy Fo +N =O yi [ete -OL (ea es 1 [ v- = FA (X, -X) —O}y t This Yeqpivedd volume for Second Yeaster 1g] root TRE Came) Veo = X-*] Ss a Le Vie = Vee e Sia Me ic e (4 \* . ul 7 r 1 x im Zs > 4 Pr bp pFe = Fo (tie) for C8TR-2 C, =VC2. + ©%) V,- outs Reackoy "Ce. i Cy =| (Lo Vo bre chi * | pare 2 flowrate T, = Cor fe comet I =m \ [ ” = eats fo- CSTR-n — VeCSTRee ‘Ge tin te, =n Qy = eo (I - XD G. =€e i“) wr, a [eo Xy = os C6 — CoX — Bt CoXr = tl Co (X,-Xi) eg Te CT, ‘a = coe) | Co Oe -X1) = Ma: Ce a MON] for eoTR? & Ce eTigs —) Hence for nh read Tn = Xn —Xn-} aol. eee eee Gs |Ss \4 * - 4 ot hare iize = OF Fapok-a, FE CSTR ty Series CSTRs ty Ser. Or CSTR- Capek Voltine bn go t mu Volume dre Aa €o, Fo Vy X=) > CSTR-L Veem et YW Hen =Ve/ Hy V = wce=-¢)) “Terps! THM = So % v am for’ Csr &2. T= o5% mee- 22] 11] 2021 =P Skit, f temp c if temp ore sam fer each yeacter Ri = Bk, ce ae Be oe SM; = ke, est Res Ty = Cont ke, Cy ss Co 14 TR csTR-2 7 z= SA (+k Co ee ce | SR tt (+t) Cl+Uk) ee eo 9 eee Cn C+ Tk) CI+TK)~-- -- ClL+TAk) for eqyprck volume ,Or Equek &ize CSTR Un Sopian G leben ao Ex = Co Cay "= GeTES Cy = Co (l— Xn) ce = -|— fe «| ety AU-Xw) = 1 or C+ THN {is Req, | (4TEON Ga = Vell Interma of Conversion) Clete) %os Where Tk ts vefferecdl to dds san Dombot Number (Da) Da=tk Cp re Co (1+ Days Co = (1 +Da)" Cn £2 = u¢te® Cu Co Jy sey Tk) (a) Cl Tk (er) (eh For N equat-Atze Cops In cords TN reader &N-T tu = NOT =i yh 1] Plot ef conversion x , Vs no. of 6: for fivst orcdy Ren, lo oT - ' 3.8 as OG / Toes = = “LA a qpret Mize CSTR2 If Dasl » OPP TPXxI mate I+), conversion ts Obtained th tue o tHrree yeacters, - Da . @ EP DAK ON He hnvercdyomdslanes Sgr Fice dy WIR He addilic., of each reece. G, Dec 20921 22 Dee PES CSTR tr Panett =! oe tome rst rreackor Bs : L Xa TH yveactoy ( nth veartov Xnfor each roackr , =m == =) Sor ee Mg ae or” near Conversion fee each wcenchor with also be ng, Xp =X,2--- Xm =* vo = NL N — Serta will Be mere benef tn care of Parollel. Steady stote Plug flow reactor > Concentration chan 3 Turbuteme flow In & bmalh voluna of dv tnpek of A, weler/ La Output of A = Prtdty Heegpecwing of A oy Vn mela] Line = — Tq AV -from qe mmole balanced equok on, \ oO Snpok — Output + gemereckion = Actupllako, Fa-(Fatolfa) + Craydv so A =(K tclta) ary dv Fa = Fagll—-Xq) ara = -Fho dxXa Mug a = AF, +a dv oO = - Fro dX, +¥adv Fro AXA = Yad ay = Axa Fre awa (doubt VA Or ~ vA) te [Xe = Xae | 07, Dec 202| eS Plug flow reactor (PFR) t. Ser ted -! Xyee ye Move Fiot, Fog V, 7 Assume — Us megligrbl.- than as for shane Stabe, PERL ( Performance eapratio, for PFRA) ax i v, =f Axa he | Keo For PER-2 x V2. =.{ Axa hy, CM) For Combined corves , ee x Nort Vy vy | { dna" | as | fe Frac Fire See xt = We have tue dens covmitant Sojv ts Con dep Xe VTetek ( axa Exe Kaen) for N, PER reactor tn con's , Mth 2 MGV Wk Ss: OMEa “the Syaters of N PPR of Totel volunulV) wilt qe he Stim conversion. gu a Binge voachoy of Vohunme (Vv). Qn-: Two mixed veackers of Unequal size fo. Joduction A cpeccfred Produk nek ferns by peeegeneoud first orckr Ren, How Showd Huw yeatky be Commeted fo achteve maxtnun, producto. vete. soliton <7 (geen on hook page 4:46) 3 (Convey ston tA cervos ts afires faster conversion) 5» There U8 mo voblum Us givens ,So = esTRel or CSTR-2 ty vematy Hater cecondy post Kner. LO, Dec 2021 Bp aie Yeackor (PER) tn pavalul—* xvy = Fe) Va Fo, Todt z Fo = for + Fo, varston, frame 2 | eT | iG. Qn 2: Tha veacky cobup comet 3 plugtte, Teacto. tn two paral branche. Gren here veackey of. Volume CO bikers followed hy a Yeacter of Volume Bo Uhre. Branch © has | veouker of Vola Ao Sikes! whet deackto, fel — shreutot FP branch D> es Soaluto., FR=2 Fe Am z He Toleol Batch veaeto Betty 16) A ==> Produgel inp — tt Gameredkt t ous a weston = Attiesuiielion Gy = Ang “ae X x N Sy = [eaidv 2 vady Fa = Fo (l—Xay Cr = Co (l-x,) Na = Nae (1~ xa)AaNa —". = —NaAe AKA Eas “oe Ya AV = dna ot Ya dv =-Nacdxa (for comstank volume|4, Dec 202] Sea ctors of didferents tapes in Sewtea —' tn — out + grnerabte, =o flows equshimfer Certty Fy = Fo (IX!) PFR 7? Es = Fo IX) CstR-1 => Fy = Fel l=Kg) X, fomedion of (X)X)) bene -X_ 4 - * X= FU%) For CsTRot E> F + Yrwrcdion [ Molay flow » fe = Fell -%)) + (-Y)v, we Fo Ny© for PER aT How eq) FL = fit%Vi Xo a { ax Fe (4) 2 xX) qhis Ue Pre deeapaeoas
Cmala ) 3 An Vi= 86-7 dn} Creoat, ae A Fe vy, x " a led vy = 0-467 —_ aa, Lx 8 Woe Fe fore @6o | | 0-8 VY, = 2xX0:867 og Violet =X) Xe =¥a Viet = O 2x0.86 > (Oo o2 oy ob 8 Toru arson Por the two PR Fox are —| wos [ Fro ~YA xy Nay SS Fae ( he ova hoKimpson L rahe tees foe [ie +44 (018) en az fen OF h= vy om [ (| { = =TA ec BD « 4 A b-a 27 0 v= Fin (dx (op ene He “TA alu th ° formula) = Alb dwt ((itees) | Ame, flar = eve 199 a = DO ow 4 ( ge = Qiise [tse + 4 (oto) H8 Rd —TA 2X2 ° [ies +4 £94 + rom os [isea] 2 Ub dt fa. ( AL ~ V. = Fre a Ou Total volume ,V = Ni tVe i = FHGHIS2 99u.G 228 [ihee. Veet \ ye O86 9 XOM PLQ4+4{ 200) +230 |woe BERS eit 8 pee - Sdeal flow — : EL ato Eton, eo Veasdhence E,n¢ Non golea! Gaent Re ParHetow moles fe be ri! aug! et me hae Regal Reach, (Secu on MTo copy)Unct-§ OAfor [2022 ) Shor Bante of ANow - Gdeat flow —: Three interrelated fedterr wake OP He G tm cotepling we flow pattern ' OD "bec Hone Aibibhiol ef wolerbl unk QD ‘s Flowing “Hrouel vessel QD Ne State of Ac Pgalhie. of sptastel.« ® Te eoob on eM and latemes of flovd on Im the Vogeek | ne (cdenew de The Aevide., for (deat bo rem heal He uw Petter meg anise by D Crection of Segrant veaien, fF "MW. -_ — out te tes, newt Yeon, yasO Short
Few Smelt freecho, of Li write aM = Cvat ( AM = (ovat (2 vw Comte M = Codt — Vvaus [esha [™ af (for teo-Hmes) ow M= [eat (fo time ote >) \\ \l Ko
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