Sec: JR.IIT_*CO SC(MODEL-A) WAT-13 Date: 01.08.

21
Time: 3HRS 2014_P2 Max. Marks: 180
KEY SHEET
PHYSICS
1 B 2 A 3 B 4 C 5 C
6 A 7 B 8 D 9 D 10 C
11 A 12 B 13 C 14 A 15 A
16 A 17 A 18 B 19 C 20 B

CHEMISTRY
21 C 22 C 23 A 24 D 25 B
26 C 27 D 28 C 29 A 30 D

31 B 32 B 33 C 34 B 35 C

36 A 37 C 38 A 39 D 40 B

MATHEMATICS
41 C 42 A 43 D 44 A 45 D

46 B 47 B 48 A 49 C 50 D

51 B 52 C 53 A 54 A 55 D

56 A 57 C 58 A 59 B 60 D
Narayana IIT Academy 01-08-21_JR.IIT_*COSC(MODEL-A) _WAT-13_Key&Sol’s
SOLUTIONS
PHYSICS
1. A is the position of the spring when it is in its normal uncompressed length. The upper
disc compresses the spring by x0 when spring is in equilibrium. So kx0  mg . Hence,
B is the equilibrium position of the spring. Let it be further compressed by y and
released. After releasing it can be proved that the spring will go up to the position D so
that BC  BD . Extension in the spring at this position  y  x0
mg
Now for lifting up of the lower disc: k  y  x0   mg  y   x0
k
 y  x0  x  2 x

2. According to the work-energy theorem,

x
1 2 1
mv0  mg  xdx  kx 2
2 0
2
m
Solving we get, x  v0
k   mg
3. u  2 gh
To lift the block B, the elongation x must be 2 mg / k
Applying work-energy theorem between A and B, we get

1 1 1
0  mu 2   mgx  kx 2
2 2 2
1 2 2mg 1 4m2 g 2
 mu mg  k
2 k 2 k
2
8mg 4mg
 u2   2 gh  h 
k k

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Narayana IIT Academy 01-08-21_JR.IIT_*COSC(MODEL-A) _WAT-13_Key&Sol’s
 U ˆ U ˆ
4. F  i j  6iˆ  8 ˆj
x y
 
a  F / m  3iˆ  4 ˆj has same direction as that of

u  1.5iˆ  2 ˆj
  5
a  5, u 
 2
Since u and a are in same direction, particle will move along a straight line, so the
distance covered
5 1
S   2   5  22  15m
2 2
5. When the string is burnt, the block starts moving down. Due to friction and spring
force, the block slows down and stops.
Applying work-energy theorem between points 1 and 2,
Wtotal  k  for block 
W gravity   W friction   W spring   W final   Kinitial

1
mg sin  x1   mg cos x1  kx12  0  0
2
3 4 1
1  10  x1  0.2  1  10  x1  110  x12  0
5 5 2
 x1  0.08 m or 8 cm
As at position 2, we can find that there is net force on the block in upward direction,
i.e.,
kx1   mg  cos  mg sin 
So the block will not be permanently at rest at position 2, and it will start moving up, let it stop at
position (3). Now consider position 2 and 3, consider the (block + spring) a system.
Now work done by external force = change in total energy of the system.
Let at this position, there be a strength x2 in the spring
W external   E
W friction  E gravitational   E spring 

1 1 
  mg cos  x1  x2   mgy   kx22  kx12 
2 2 

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  mg cos  x1  x2   mg  x1  x2  sin 
1
 l  x1  x2  x1  x2 
2
1
  mg cos  mg sin   k  x1  x2 
2
1
k  x1  x2   mg  sin    cos 
2
2mg  sin    cos 
 x1  x2  
k
2mg  sin    cos 
x2   x1
k
3 4
2  1  10   0.2  
 5 5 64
 0.08  cm
110 11
6. Draw FBD of B to get extension in spring. Instant when block B just looses contact
with ground net force on it is zero.
kx  T cos  0
 T sin   N  mg  0 to rise N  0
kx
sin   mg
cos
mg 80 60
x  
k tan    4 / 3 k
If spring has to just extend till this value at their extension it should be at rest. Now
we apply work energy theorem to get
1
Fx  kx 2 F  30 N
2
7. Elongation in the spring is x  x A  xB
Where x A  displacement of end A measured from original natural length positon
xB  displacement of block measured form original position.
dx dx A dxB
   VA  VB  6  3  3 m / s
dt dt dt
1
Potential energy in the spring U  kx 2
2
dU dx
 kx 
dt dt
 15   kx  3  kx  5 N
5
Acceleration of the block a   2.5 m / s 2
2
8. Spring force is maximum when the system is released

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5
a  2.5 m / s 2
2
The limiting friction on A can be
FlA  1M A g  250 N
Hence, block A remains fixed and does not move at all.
The limiting friction on C can be
Flc   2 M C g
Thus maximum acceleration that friction can provide to C is
ac max  2 g  8.5 m / s 2
Just after the release spring force is maximum and it will cause maximum
acceleration in B. Let us assume that this is no slipping between B and C. In that case
the maximum acceleration is
240
ac max   8.0 m / s 2
28  2
Friction can easily provide this acceleration to block C hence it will not slip over B.
speed is maximum when the spring acquires its natural length.
1 1
 M B  M C  vmax
2
 kx02
2 2
 vmax  4m / s
9. z and x components are useless points.
2
192
So dw  Fy.dy  3 xy.dy   6 x 4 .dx  units
0
5
1
10. If A moves down the incline by 1 metre, B shall move up by metre. If the speed of
2
B is v then the speed of A will be2v.
From conservation of energy
Gain in K.E = loss in P.E
1 1 3 1
mA (2v) 2  mB v 2  mA g   mB g 
2 2 5 2
1 g
Solving we get v 
2 3
11 &
12. u  x4  5x2
E 0
u  0 at x  0 & x  5
u is minimum at 4 x 3  10 x  0
5
x
2

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Narayana IIT Academy 01-08-21_JR.IIT_*COSC(MODEL-A) _WAT-13_Key&Sol’s
25
 u  min  
4
1 25
 mv 2 
2 4
5
 vmax  m/s
2
Particle will confine between  5m to  5m
13 &
14.
v cos  u sin 
v  3u
mv 2
mg l cos  mu 2 
2
gl 3 gl
u ,v 
5 5

1
15. mg (2 x)  f x  kx 2
2
 x  8cm
16. Conceptual
17. Conceptual
18. Conceptual
19. Conceptual
20. Conceptual
CHEMISTRY
x 
2
NH 3  pT kx
21. kp  
x  pT  xH 2  pT 
3
pT2
N2

When equilibrium pressure is doubled, kx increases by four times to keep k P constant.

22. C) G  0 , G 0  Ve because kC  1
23. PCl5 g   PCl3 g   Cl2
1 0.2
0.4 0.6 0.8
0.6 0.8

kC  2 2  0.3  0.4  0.6 .
0.4 0.2
2
24. Conceptual.
25. With increasing the concentration of common ion,
Degree of ionisation of water decreases.
27. Degree of hydrolysis ‘h’, is not negligible.
28. NaCN  Na   CN 

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Narayana IIT Academy 01-08-21_JR.IIT_*COSC(MODEL-A) _WAT-13_Key&Sol’s
 
CN  H 2O  HCN  OH
 Na    CN     HCN  formed
left

 HCN   OH  
 D wrong.
2
 h  h kw
29. kh      kh 
 1 h  1 h k a  kb
h 1014 1
  7 7

1 h 3 10  3  10 3
 3h  1  h  4h  1  h  0.23
30.

32. As per electrical neutrality

Total positive charge of cations = Total negative charge of anions
‘x’ moles CO32 carries, ‘2x’ moles negative charge.
 H 3O     HCO3   2 CO32   OH  
1000 1 10
33.   
11 100 11
CH 3COOH  H 2O  CH 3COO   H 3O 
10C C 10C 10C
C 
11 11 11 11

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Narayana IIT Academy 01-08-21_JR.IIT_*COSC(MODEL-A) _WAT-13_Key&Sol’s
10C 10C

105  11 11  105  100C
C 11
11
 C  11 10 7 M
10 10
 H     C   11 107  106 M
11 11
 pH  6
34.

35.

37. I-Q,R; II-Q,R,S; III-S; IV-Q,R

NH 4 HS s   NH 3 g   H 2 S g 
kC   NH 3  H 2 S 
When volume of container increased (i.e., with decreasing the
pressure) forward reaction favourable. Now when compared with old equilibrium, at
new equilibrium number of modes of NH 3 and H 2 S will increase but molar
concentration of NH 3 and H 2 S increased then kC will increase but kC to be constant.
38. I-P,Q; II-Q; III-Q,S; IV-R.
MATHS
A 6 A
2
41.
A  A 60
2

A  3 A  2
42. Determinant value of every odd order skew symmetric matrix is zero.
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1  3n 9n  1 0   3 9 
43. An       n 
 n 1  3n   0 1  1 3
 2 0   3 9    1  9 
So 2B  C     
0 2  1 3   1 5 
 trace = 4
44. To interchange first and second rows of A,
0 1 0
Let the matrix be P  1 0 0 
 
0 0 1 
0 1 0 1 3 5 7  0 1 0  2 3 1 2
So, PA  1 0 0   2 3 1 2   PA  1 0 0   1 3 5 7   A
       
0 0 1  33  3 1 3 2  34  0 0 1  33  3 1 3 2  34
0 1 0
So, P  1 0 0   1
 
0 0 1 
45. Consider  M 2  2M  2I  M 2  2M  2I 
  M 2  2M  2I  M 2  2M  2I   4I
 Neither of determinant value of will be zero.
46. AT  B  C
BT  C  A
CT  A  B
A T  BT  C T  2  A  B  C 
taking transpose
A + B + C = 2  A T  BT  C T   A  B  C  0
 A T  A
BT  B
CT  C
47. Only possibility for max
2 
 2 
 
 2 
 
 2 
 2 
 
 2
a b  a b   a c  1 0 
48. Let A  ,    
 c d   c d   b d  0 1 

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a  b  I
2 2

ac  bd  0
c2  d 2  1
a 1 b
det  A  I    ad  a  d  bc  1
c d 1
a b c d Det (A-
I)
1 0 0 1 0
1 0 0 -1 0
-1 0 0 1 0
-1 0 0 -1 4
0 1 1 0 2
0 1 -1 0 2
0 -1 1 0 2
0 -1 -1 0 0

x x 2
49. 2 x  x   0  x  2, 2
 
 x 2  x 
 n  2  n  0
4  x 2 6 2 
 
50.  6 9x 2
3   x  x 3 14  x 2 
 2 3 1  x 2 

51-52
1 0 1 0 0 0  1 0 0 
sol: A 2  1 0 1 1 0 1   1 1 0 
     
0 1 00  1 0  1 0 1 
1 0  1
0 0 0 1 0 0
A 3  1 0  1
1 1 0  2 0 1
    
1 1  1
0 0 1   1 1 0 
0 0 0 0 0 0  1 0 0
A 3  A 2  1 1 1  A  1  1 1 1    2 0 1 
     
0 1 1 0 1 1  1 1 0 
 A3  A 2  A  1
 Det A n  1  Det  A  1 1  A  A 2
 ...  A n 1  
 Det  A  1 Det 1  A  A 2  ......  A n 1 
=O

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A3  A 2  A  1 ................ (1)
 A A A A
4 3 2
................ (2)
A5  A 4  A3  A 2  A  1  Usin g 1 
If n is even A n  A n 1  A 2  A ................ (3)
Consider n is even ................ (4)
A  A  A  A  Usin g  3 
n n 1 2

A n 1  A n 2  A  1 Usin g  4  
 A n  A n 2  A 2  1
 A n  A n 2  A 2  1
  A n 4  A 2  1  2  A 2  1
  A n 6  A 2  1  2  A 2  1
n2 2
  A2    A  1
2
n n 2
An    A2   1
2  2 
A 50  25A 2  241
1 0 0  1 0 0 
 25 1 1 0   24 0 1 0 
   
1 0 1  0 0 1 
53. sin   cos 2   sin 3 
or sin   cos 2   sin 3   0
 sin 3   sin 2   sin   1
 sin   sin 2   sin   1  1
L.H.S is  0 & R.H.S = - 1
 no solution
54.  sin   cos   sin   tan   cos   tan    0
  
2solutions 3solutions 2solutions

 cos   tan   sin   cos 2 

 sin 2   sin   1  0
1 5
 sin   
2
55&56: A 2
A
adj A 1  &adj 2A   4adjA
A

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58. A  A. BA    AB  A  BA  A similarly B2  B.
2

59. sol: QT P  PT
PTQ  P
PP T Q  P 2
Q  P2
 0 1  0 1
Q   Q T
 1 0 
 1 0   
 0    0  2 
  
  0   2 0 
Now  2  I  Q T  .adj P 
 adj. I  Q T  .adj P 
 adj.   
2PT .adj 2P 
 2adj. P T P   2I

60. SOL: A 2  A;B2  I and CCT  I  CT C

 A  I  A 1  A T ;B  B1 and CT  C1
A)  ABC   C 1B1  CT BA T   ABT C 
1 T

B) adj 2AB1C 
 64 adjC adjB adjA   64
C) C1B1A 1  A 1B1C1
 CT B  BCT  BC  CB
D) adj 3A 1BC 1   9adj A T B1CT 

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