SRI GURUKULAM SECONDARY SCHOOL – HOSUR.

SUBJECTIVE - CHEMISTRY
DATE : 03.11.2023 CLASS : 12th TIME: 3HR MAX MARKS: 70M
REVISION TEST-I
General Instructions:
(a) There are 33 questions in this question paper with internal choice.
(b) SECTION A consists of 16 multiple-choice questions carrying 1 mark each.
(c ) SECTION B consists of 5 short answer questions carrying 2 marks each.
(d) SECTION C consists of 7 short answer questions carrying 3 marks each.
( e) SECTION D consists of 2 case-based questions carrying 4 marks each.
(f) SECTION E consists of 3 long answer questions carrying 5 marks each.
(g) All questions are compulsory
(h) Use of log tables and calculators is not allowed.
SECTION-A
1. A first order reaction is half – completed in 45 minutes. How long does it need for 99.9% of the reaction to be
completed?
a) 20 hours b) 10 hours
c) 7.5 hours d) 5 hours
2.∆G and Eo cell for a spontaneous reaction will be
(a) positive, negative b) negative, negative
(c) negative, positive d) positive, negative
3. The reduction potential of Cu/Cu+2 and Ni/Ni+2 are 0.34 an -0.25 volts respectively .The emf of the cell is
a) 0.58 V b) 0.59V c) 0.09 V d) none
4. Chloro benzene when treated with sodium metal dry ether gives diphenyl ,that is called
a) Wurtz reaction b) Fittig reaction c) Wurtz –Fittig reaction d) Friedal-Crafts reaction.
5. Which one of the following halides contains Csp2—X bond?
a) Allyl halide b) Alkyl halide c) Benzyl halide d) Vinyl halide
6. The synthesis of alkyl fluordies is best obtained from
a) Free radicals b) Swartz reaction c) Sandmayer reaction d) Finkelstein reaction
7. Which of the following alcohols will not undergo oxidation ?
a) Butanol b) Butan-2-ol c) 2-methyl butan-2-ol d) 3-methyl butan-2-ol
8. Choose the compound which is more acidic than phenol:
a) O-nitrophenol b) ethanol c) O-methylPhenol d) O-methoxyphenol
9. Aldehydes and ketones react with hydroxyl amine to form
a) Hydrazone b) Cyanohydrin c) Semicarbazones d) Oximes
10. The reagent that can be used to distinguish acetophenone and benzophenone is
a) 2,4 –dinitro phenyl hydrazine b) aq.NaHSO3
c) Fehling’s solution d) I2 and NaOH
11. Which of the following compound will undergo self condensation in the presence of dil.NaOH solution
a) C6H5CHO b) CH3CH2CHO c)(CH3)3C—CHO d) HCHO
12. A compound ‘A’ with molecular ormula (C5H10O),forms a phenyl hydrazone and gives negative Tollen’s and Iodoform
tests.The compound on reduction gives n-pentane .The compound ‘A’ is ------.
a) Pentan-3-one b) Pentanal c) Pentanol d) Pentan-2-one
In the following questions (Q.No.13 -16), a statement of assertion followed by statement of a reason is given. Choose the correct
answer out of the following choices.
(a) Both A and R are correct and R is correct explanation of A.
(b) Both A and R are correct and R is not correct explanation of A.
(c) A is true but R is false.
(d) A is false but R is true.
13). Assertion (A): For a zero order reaction the unit of rate constant and rate of reaction is same.
Reason( R) : Rate of reaction for zero order is independent of concentration of reactants.
14).Assertion(A):Chlorobenzene is resistant to nucleophilic substitution reactions at room temperatures.

Reason(R): C—Cl bond gets weakens due to resonance.

15).Assertion(A): Alcohols have higher boiling point than alkanes of comparable molecular mass.

Reason(R): Alcohols have intramolecular hydrogen bond.

16).Assertion(A): All aldehyes do not take part in aldol condensation.

Reason(R) :In the aldol condensation,carbanion is generated by abstraction of α-H atom by the base.

SECTION-B
17).a) Write the mathematical relation between rate constant and half-life period of a zero order reaction.
b) Define Pseudo first order reaction with an example.
18) Define electrochemical cell. What happens when external potential applied becomes greater than E o of cell?
19).Do the following convertions:
a)Chloro ethane to Butane
b) EthylChloride to propanoic acid
20).Write the chemical reaction involve in the following
a) Riemer Tiemann reaction
b) Acetylation of Salicylic acid
(or)
Carry out the following Conversions a) Phenol to Anisole b) Aniline to Phenol
21) 6.Explain the following reactions
a) Wolff Kishner reduction b) Cannizzaro reaction
(or)
a)Clemmenson reduction b) Stephan’s reaction

SECTION-C
22) A first order reaction takes 30 minutes foe 70% decomposition, calculate t 1/2 value.
[log 2=0.30,log 3= 0.48,log 4 = 0.6 ,log 5 = 0.70]

23) a) The Standard Gibbs energy (∆Go) for the following cell reaction is -300 KJ mol-1

Given Zn (s) +2 Ag+ (aq)---- Zn+2(aq) + 2Ag(s) Calculate E0cell

Given [1F=96500 C mol-1Antilog 2.7072 = 5.095 x 102]
b) Calculate λ o MgCl2 if molar conductivity values of Mg +2 and Cl- are 106 SCm2 mol-1 and 76.35 SCm2 mol-1
respectively.
24).Justify and arrange the following compounds namely: Ethyl chloride, isopropyl chloride, tertiary butyl chloride in
increasing order of reactivity towards the asked displacement name. a)SN 1 b) SN2
25) .a) How will you distinguish between primary,secondary and tertiary alcohols by Lucas test ?
b) Why is o-nitrophenol is steam volatile while p-nitro phenol is not?
26).An organic compound ‘A’ having molecular formula C6H6O gives a characteristic colour with aq.FeCl3 solution.
When ‘A’ is treated with CO2and NaOH at 400 K under pressure ‘B’ is formed .The compound B On acidification
gives ‘C’ which reacts with acetyl chloride to form ‘D’ which is popular pain killer .Write the structure of A,B,C and D.
(or)
a) Give Chemical test to distinguish between the following pairs of compounds.
i.Pentan-2-ol and Pentan-3-ol ii.Phenol and cyclohexanol
b) Write the structure of 2-methylprop-2-en-1-ol.
27).Predict the products when CH3CH2CHO reacts with the following
i.CH3MgBr followed by hydrolysis ii.LiAlH4 iii.HCN
28).Write the main products in the following i).

ii.Write nitration of Benzaldehyde.

(or)

a).Write IUPAC name of

b) Give the equation associated with Fehling’s Test given by CH3CHO.

SECTION-D
29). Read the passage given below and answer the following questions:
The carbon-halogen bond of alkyl halide is polarized due to high electronegativity of halogen. The boiling points of alkyl
halides are comparatively higher than the corresponding hydrocarbons. These are slightly soluble in water but completely
soluble in organic solvents. The polarity of C-X bond of alkyl halides is responsible for their nucleophilic substitution,
elimination and their reaction with metal atoms. Nucleophilic substitution reactions are classified into two types that is
SN1 and SN2 based on their kinetic properties.
a) Why tertiary butyl chloride has lower boiling point than n-butyl chloride?
b) Why are tertiary alkyl halides least reactive towards SN2 reaction?
c) Out of 1-bromo-2-methyl –butane and 1-bromo-3-methyl butane, which is more reactive towards SN 1 and why?
d) Write a chiral compound with formula C5H11Cl .
30). Read the passage given below and answer the following questions:
Alcohols and phenols are most important compounds used in our daily life. Alcohols are prepared by hydration of
alkenes, fermentation of glucose, reduction of aldehydes, ketones, carboxylic acids and esters.
Phenol is prepared from cumene, diazonium salts, anisole, chlorobenzene.Phenol is used to prepare salicylaldehyde,
salicylic acid, and aspirin, p--benzoquinone. Ethers are functional isomers of alcohols, have low boiling points. Ethers are
used as solvents. Unsymmetrical ethers are prepared by Williamson synthesis. Ethers reacts with HI and undergo SN 1 and
SN2 mechanisms depending upon the stability of carbocation formed. Aromatic ethers like anisole undergo electrophilic
substitution at ortho and para positions.
a) Out of tertiary butyl alcohol and n-butanol, which will undergo dehydration faster give reason.
b) Why is C-OH bond length in CH3OH longer than C-OH bond length in phenol?
c) Convert phenol to p-benzoquinone.
d) Convert phenol to Toluene (methyl benzene).

SECTION-E
31) a) A first order reaction is 50% complete in 30 minutes at 300 K and in 10 minutes at 320 K. Calculate
activation energy (Ea) for the reaction.(R= 8.314J K-1 mol-1)(3m)
b) Write two conditions for collisions to be effective collisions.(2m)
(or)
Following data were obtained for the given reaction
X+Y - product
Exp. [X] /M [Y]/M Initial Rate M min-1

1. 0.1 M 0.2 M 0.05

2. 0.2 M 0.2 M 0.10

3. 0.1 M 0.1 M 0.05

i.Find the order of reaction with respect to X and Y.
ii.Write the rate law expression.
iii.Find the rate constant.
b). For the decomposition reaction the values of rate constant, K at two different temperatures are given below: [log 23.9
=1.3783, log2.15=0.3324]
K1=2.15x10-8 L mol-1 s-1 at 650 K
K2 =2.39 x 10 -7 L, mol-1 s-1 at 700 K
Calculate the value of activation energy for this reaction. (R=8.314 J K -1 mol-1)
32) a.Illustrate the mechanism of reaction of carbonyl group with an ammonia derivative, H 2N¾Z
b.Explain Haloform reaction.
 c.Etard reaction
(or)
Explain with suitable examples and mechanism. i.Aldol Condensation
ii.Cross aldol condensation

33)a). Calculate the emf and ΔG of the following cell at 298K : (3M)
Mg(s) | Mg2+ (10-3 M) || Cu2+ (10-4 M) | Cu (s)
o
Given : Ecell = +2.70 V, 1 F = 96500 C mol-1, log 10 = 1
b). How much electricity in terms of Faraday is required to produce (2M)
i) 20 g of Ca from molten CaCl2?
ii) 40 g of Al from molten Al2O3?
(or)
a. Calculate the time to deposit 1.27 g of of copper at cathode when a current of 2 A was passed through the solution of
CuSO4 . (Molar mass of Cu = 63.5 g mol-1 , 1 F= 96500 C mol-1). (2M)
b. zinc rod is dipped in 0.1 M solution of ZnSO4 .The salt is 95% dissociated at this dilution at 298 K. Calculate the
electrode potential.(Given Eo(Zn+2/Zn)= -0.76 V,log 1000 =3.0000,log 95=1.9777).(3M)