You are provided with two solutions as follows:

1. C-10 is a solution containing 3.20 g of potassium manganate (VIl)KMnO, Per itre of the
solution.

2. C-11 is a solution containing 6.30 g oxalic acidcrystals (H,C,0, xH,0) per litre of the
solution.

Procedure

Rinse and fillthe burette with C-10 solution of potassium manganate (VII). Pipette out 20 mlor
25 ml of the solution C-11 of oxalic acid in a clean conical flask. To this add 20 ml of dilute sulphuric
acid (C-12) specially provided for titration. Warm the contents to about 60°C, (till the bubbles appear
at the bottom of the flask).

Now titrate the contents in hot condition by dropping C-10 solution from the burette till the
permanent light pink colour to the C-11 solution in the titration or conical flask appears.

Repeatthe above procedure to get at least two concordant readings.

The equation for the above reaction may be given as follows:

2KMnO4 + 3H,S04 + 5H,C,04 KzSO4 + 2MnSO4 + 8H,O + 10CO,

or

2MnO4 + SC,0% + 16Ht 2Mnt2 + 1000, + 8H,0

Relative atomiC masses:
Mn = 55, O = 16, H=1, K=39, C=12
Calculate the following
1.The molarity of potassium manganate (VII) solution (C-10).
2. The molarity of hydrated oxalic acid solution (C-11).
 3. The molecular másS UI

value ofx in H,C,04 xH,0.

4. The numerical
at least upto 4 decimal places.
of solutions
Note : Calculate the molarity

Observation Table
Volume of KMnO4
of oxalic Burette reading Titrevalue
Volume solution (ml) (mi
S.No.
acid (m) Initial (ml) Final (ml)
24.4
0.0 24.4
1 25.0 24.4 244mi
0.0 24.4
2 25.0 24.3
24.3
3 25.0 0.0

Capacity of the pipette used

=25 ml
Titre value =24.4 ml.
Calculations
manganate (VI) solution C-10
1. Molarity of potassium
Strength
Molarity (M)=
Molecular Weight

3.20
= 0.02025M
158

(M)of hydrated oxalic acid solution C-11

2. Molarity
MV (KMnO4)
M,V, (H,C,04 xH,0)
0.02025 x 24.4
M, x 25 5
M, =0.04941 M
Strength
3. Molecular mass
Molarity (M,)
6.30
0.04941

=127.504
4. The numerical value of x
H,Cz04 xH,0 = 127.504
(2 + 24+ 64) 18x + = 127.504

90 18x + = 127.504
18x =37.504
X= 2.08 2
Hence, the molecular formula of hydrated oxalic acid is H,Cz04- 2H,0.
 You are provided tvwo solutions:

1. C-10 is a solution containing 3.50 g of impure potassium manganate (VI)per 1tre o te

solution.

2. C-11 is a solution containing 6.50 g of hydrated oxalic acid (H,C,0, 2H,0) per litre of the
solution.

Procedure

Rinse and fill the burette with C-10 solucion. Pipette out 20 ml or 25 ml of C-11 solurion of oxalic
acid in a clean conical flask. To this add 20 ml of dilute sulphuric acid (C-12) specially provided for
titration. Warm the contents between 50-60°C (till some bubbles are seen at the bottom of the conical
flask).

Now titrate the hot solution by dropping C-10 solution from the burette to it rill a permanent
light pink colour to the C-1l solution in the conical flask appears.
Repeat the aboveprocedure to get two concordant readings.
The following equation can be written forthe above reaction:

2KMnO4 + 3H,SO4 + SH,C,04 K,SO4 2MnSO4 SH,0 10C0,

2MnO4+ SC,0 + l6H 2Mn2 + 10CO, SH,0

Relative atomicmasses:
Mn = 55, K=39, 0= 16, H = 1, C= 12
Calculate the following

1.The molarity of oxalic acid (C-11) solution.

2. The molarity of potassium manganate (VII) (C-10) solution.
3. The concentration of potassium manganate (VII) solution in g/1.
4. The percentage purity of potassium manganate (VII).

Note: Calculatethe molarityof solutions at least upto 4 decimal places.

Observation Table

Volume of oxalic Burette reading Volume of KMnO4

S.No. Titre value (ml)
acid solution (ml) Initial (ml) Final (ml) used (ml)

1 25.0 0.0 24.0 24.0

2 25.0 0.0 24.1 24.1 24.1 ml

3 25.0 0.0 24.1 24.1

Capacity of pipette = 25 ml
 1. Molarity of hydrated oxalic acid solution (C-11)
Strength or weight in g/1
Molarity (M;) = Mol.weight

6.5
126
=0.05158 M
2. Molarity (M)of C-10 (KMn Oz) solution
MV,(Oxalic acid) _ n
MzV, (KMn Og)
0.05158 25 5
M, x 24.1 2
My = 0.02140 M
3. Concentration of potassium manganate (VII) solution

Concentration or strength of KMnO4 solution =Molarity (M)x Mol. weight

=0.02140 x 158
=3.3812 g/1.

Pure substance
4. 96 Purity of KMnO4 x 100
Impure sample

3.3812
x 100
3.5

=96.60%
 Object
You are provided two solutions :
1. C-10 is a solution containing 6.50 g of impure hydrated oxaliccacid
the solution. H,C,0,2H,0:

2. C-11 is a solution containing 3.250g of potassium manganate (V) KMn0, per

solution.

Procedure
Rinse and the burette with given C-11 solution of potassium manganate (VI).Ppe
fill

20 ml or 25 ml of C-10 solution of oxalicacid in a clean conical flask. To this add 20 m d

sulphuric acid (C-12) specially provided to you for titration. Warm the contents of the fzsi

50°C-60°C till the bubbles appear at the bottom of the flask.

 Now titrate the contents of hot solution by dropping C-11 solutionfrom the burette to the conical
lask containing C-10 solution with constant shaking
till the permanent light pink colour appa
the conicalflask.
Repeat the above procedure to get
two concordant readings.
The above reaction can be written in the
form of following chemical equation.
2KMnO,+ 3H,S0, SH,C,04 K,SO 10C0, 2MasO 8H,0

+
2MnO4+ 5C,0 + 16H* 2Mn 2 + 10CO2 + 8H,0
Relative atomic masses :
Mn K=
39,O 16, C= 12,
55, H1
-
Calculate the following
1. The molarity of potassium manganate (VI)
solution C-11.
2. The molarity of hydrated oxalic acid solution C-10.
3.The concentration of pure hydrated oxalic acid in g/1.

4.The percentage purity of hydrated oxalic acid.

Note: Calculate the molarity of solutions at least upto 4 decimal places.

Observation Table
Volume of oxalic Burette reading Volume of KMnO4
S.No. Titre value (ml)
acid (ml) Initial (ml) Final (ml) solution used (ml)

1 25.0 0.0 24.5 24.5

2 25.0 0.0 24.4 24.4 24.4 ml
3. 25.0 0.0 24.4 24.4

Capacity of the pipette used =25 ml

Titre value =24.4 ml
Calculations

1. Molarity (M) of potassium manganate (VI) C-11 solution

Strength (g/1)
Molarity (M) = Molecular weight

3.250
158

0.02056 M
2. Molarity (M,) of hydrated oxalic acid solution (C-10)
MV,
(KMnO4)
M,V, (H,Cz0,2H,0)
0.02056x 24.4 2
M, x 25 5
M) 0.05016 M
3. Concentration or strength of hydrated Oxalic acid = Molarity (M,) x Mol.

=0.05016 x 126 weight

=6.32 g/1.
Pure substance
4. Percentage purity of hydrated oxalic acid x 100
Impure sample
6.32
x 100
6.50

=97.23%