SAFETY DATA SHEET

Revision Date 24-Feb-2020 Version 5

1. IDENTIFICATION
Product identifier
Product Name LIQUID ELECTRICAL TAPE 4 OZ

Other means of identification

Product Code 85120

Recommended use of the chemical and restrictions on use

Recommended Use Sealant
Uses advised against No information available

Details of the supplier of the safety data sheet

Manufacturer Address May Also Be Distributed by:
ITW Permatex ITW Permatex Canada
6875 Parkland Blvd. 101-2360 Bristol Circle
Solon, Ohio 44139 USA Oakville, ON Canada L6H 6M5
Telephone: 1-87-Permatex Telephone: (800) 924-6994
(866) 732-9502
24-hour emergency phone number
Chem-Tel: 800-255-3924
International Emergency:
00+1+ 813-248-0585
Contract Number: MIS0003453

E-mail address: [email protected]

2. HAZARDS IDENTIFICATION
Classification

OSHA Regulatory Status

This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)

Acute toxicity - Dermal Category 4

Acute toxicity - Inhalation (Dusts/Mists) Category 4
Skin corrosion/irritation Category 2
Serious eye damage/eye irritation Category 2A
Carcinogenicity Category 2
Specific target organ toxicity (single exposure) Category 3
Flammable liquids Category 2

Label elements

Emergency Overview
Signal word
Danger

Harmful in contact with skin or if inhaled

Causes skin irritation
Causes serious eye irritation
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Suspected of causing cancer

May cause respiratory irritation
May cause drowsiness or dizziness
Highly flammable liquid and vapor

Appearance Black Physical state Liquid Odor Solvent

Precautionary Statements - Prevention

Obtain special instructions before use
Do not handle until all safety precautions have been read and understood
Use personal protective equipment as required
Avoid breathing dust/fume/gas/mist/vapors/spray
Use only outdoors or in a well-ventilated area
Wash face, hands and any exposed skin thoroughly after handling
Wear eye/face protection
Keep away from heat/sparks/open flames/hot surfaces. - No smoking
Keep container tightly closed
Ground/bond container and receiving equipment
Use explosion-proof electrical/ ventilating/ lighting/ equipment
Use non-sparking tools
Take precautionary measures against static discharge
Keep cool

Precautionary Statements - Response

IF exposed or concerned: Get medical advice/attention
Specific measures (see .? on this label)
Specific treatment (see .? on this label)

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
If eye irritation persists: Get medical advice/attention
Call a POISON CENTER or doctor/physician if you feel unwell
If skin irritation occurs: Get medical advice/attention
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
Wash contaminated clothing before reuse
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
In case of fire: Use CO2, dry chemical, or foam to extinguish.

Precautionary Statements - Storage

Store locked up
Store in a well-ventilated place. Keep container tightly closed

Precautionary Statements - Disposal

Dispose of contents/container to an approved waste disposal plant

Hazards not otherwise classified (HNOC)

Not applicable

Other Information
May be harmful if swallowed. Very toxic to aquatic life with long lasting effects. Very toxic to aquatic life.

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Unknown acute toxicity 0% of the mixture consists of ingredient(s) of unknown toxicity

3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical Name CAS No Weight-%

XYLENE 1330-20-7 15 - 40
METHYL ETHYL KETONE 78-93-3 10 - 30
(BUTANONE)
ACETONE 67-64-1 3-7
TALC 14807-96-6 1-5
CARBON BLACK 1333-86-4 0.1 - 1

4. FIRST AID MEASURES

Description of first aid measures

General advice Call 911 or emergency medical service. Remove and isolate contaminated clothing and
shoes.

Eye contact In case of contact with substance, immediately flush skin or eyes with running water for at
least 20 minutes.

Skin contact Wash skin with soap and water.

Inhalation Move victim to fresh air. If breathing is irregular or stopped, administer artificial respiration.
Administer oxygen if breathing is difficult.

Ingestion IF SWALLOWED:. Do NOT induce vomiting. Never give anything by mouth to an

unconscious person. Call a physician.

Self-protection of the first aider Ensure that medical personnel are aware of the material(s) involved and take precautions to
protect themselves.

Most important symptoms and effects, both acute and delayed

Symptoms See section 2 for more information.

Indication of any immediate medical attention and special treatment needed

Note to physicians Keep victim warm and quiet.

5. FIRE-FIGHTING MEASURES
Suitable extinguishing media
Dry chemical, CO2, water spray or regular foam, Water spray, fog or regular foam, Use water spray or fog; do not use straight
streams

Unsuitable extinguishing media

CAUTION: All these products have a very low flash point. Use of water spray when fighting fire may be inefficient

Specific hazards arising from the chemical

Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than
air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard
indoors, outdoors or in sewers. Those substances designated with a "P" may polymerize explosively when heated or involved in a
fire. Runoff to sewer may create fire or explosion hazard. Substance may be transported hot.

Explosion data
Sensitivity to Mechanical Impact None.
Sensitivity to Static Discharge None.
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Protective equipment and precautions for firefighters

Move containers from fire area if you can do it without risk.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Personal precautions ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).
All equipment used when handling the product must be grounded. Do not touch or walk
through spilled material. Stop leak if you can do it without risk.

Other Information Water spray may reduce vapor; but may not prevent ignition in closed spaces.

Environmental precautions

Environmental precautions Prevent entry into waterways, sewers, basements or confined areas.

Methods and material for containment and cleaning up

Methods for containment A vapor suppressing foam may be used to reduce vapors. Absorb or cover with dry earth,
sand or other non-combustible material and transfer to containers.

Methods for cleaning up Use clean non-sparking tools to collect absorbed material. Dike far ahead of liquid spill for
later disposal.

Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations.

7. HANDLING AND STORAGE

Precautions for safe handling

Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Avoid breathing
vapors or mists. Avoid contact with skin, eyes or clothing. Wash thoroughly after handling.
Wash contaminated clothing before reuse. Use personal protective equipment as required.
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.

Conditions for safe storage, including any incompatibilities

Storage Conditions Store locked up. Keep away from heat, sparks, flame and other sources of ignition (i.e.,
pilot lights, electric motors and static electricity).

Incompatible materials Strong oxidizing agents, Acids, Amines, Ammonia, Caustics, Aldehydes, Peroxides

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters

Exposure Guidelines .
Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH
XYLENE STEL: 150 ppm TWA: 100 ppm -
1330-20-7 TWA: 100 ppm TWA: 435 mg/m3
(vacated) TWA: 100 ppm
(vacated) TWA: 435 mg/m3
(vacated) STEL: 150 ppm
(vacated) STEL: 655 mg/m3
METHYL ETHYL KETONE STEL: 300 ppm TWA: 200 ppm IDLH: 3000 ppm
(BUTANONE) TWA: 200 ppm TWA: 590 mg/m3 TWA: 200 ppm
78-93-3 (vacated) TWA: 200 ppm TWA: 590 mg/m3
(vacated) TWA: 590 mg/m3 STEL: 300 ppm
(vacated) STEL: 300 ppm STEL: 885 mg/m3
(vacated) STEL: 885 mg/m3
ACETONE STEL: 500 ppm TWA: 1000 ppm IDLH: 2500 ppm
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67-64-1 TWA: 250 ppm TWA: 2400 mg/m3 TWA: 250 ppm
(vacated) TWA: 750 ppm TWA: 590 mg/m3
(vacated) TWA: 1800 mg/m3
(vacated) STEL: 2400 mg/m3
The acetone STEL does not apply
to the cellulose acetate fiber
industry. It is in effect for all other
sectors.
(vacated) STEL: 1000 ppm
TALC TWA: 2 mg/m3 particulate matter (vacated) TWA: 2 mg/m3 respirable IDLH: 1000 mg/m3
14807-96-6 containing no asbestos and <1% dust <1% Crystalline silica, TWA: 2 mg/m3 containing no
crystalline silica, respirable containing no Asbestos Asbestos and <1% Quartz
particulate matter TWA: 20 mppcf if 1% Quartz or respirable dust
more;use Quartz limit
CARBON BLACK TWA: 3 mg/m3 inhalable particulate TWA: 3.5 mg/m3 IDLH: 1750 mg/m3
1333-86-4 matter (vacated) TWA: 3.5 mg/m3 TWA: 3.5 mg/m3
TWA: 0.1 mg/m3 Carbon black in
presence of Polycyclic aromatic
hydrocarbons PAH
NIOSH IDLH Immediately Dangerous to Life or Health

Other Information Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962
(11th Cir., 1992).

Appropriate engineering controls

Engineering Controls Showers

Eyewash stations
Ventilation systems

Individual protection measures, such as personal protective equipment

Eye/face protection Wear safety glasses with side shields (or goggles).

Skin and body protection Wear protective natural rubber, nitrile rubber, Neoprene™ or PVC gloves.

Respiratory protection Use NIOSH-approved air-purifying respirator with organic vapor cartridge or canister, as
appropriate.

General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. Regular cleaning of
equipment, work area and clothing is recommended.

9. PHYSICAL AND CHEMICAL PROPERTIES

9.1. Information on basic physical and chemical properties

Physical state Liquid
Appearance Black
Odor Solvent
Odor threshold No information available

Property Values Remarks • Method

pH No information available
Melting point / freezing point 80 °C / 176 °F
Boiling point / boiling range 82 °C / 180 °F
Flash point 7 °C / 45 °F CC (closed cup)
Evaporation rate < 1 Ether = 1
Flammability (solid, gas) No information available
Flammability Limit in Air
Upper flammability limit: No information available
Lower flammability limit: No information available
Vapor pressure 12.6 kPa
Vapor density 2.4 Air = 1
Relative density 0.96
Water solubility No information available
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Solubility(ies) No information available

Partition coefficient No information available
Autoignition temperature No information available
Decomposition temperature No information available
Kinematic viscosity 2000 cP
Dynamic viscosity No information available
Explosive properties No information available
Oxidizing properties No information available

Other Information
Softening point No information available
Molecular weight No information available
VOC Content (%) 60.5
Density No information available
Bulk density No information available
SADT (self-accelerating No information available
decomposition temperature)

10. STABILITY AND REACTIVITY

Reactivity
No information available

Chemical stability
Stable under normal conditions

Possibility of Hazardous Reactions

None under normal processing.

Conditions to avoid
Heat, flames and sparks.

Incompatible materials
Strong oxidizing agents, Acids, Amines, Ammonia, Caustics, Aldehydes, Peroxides

Hazardous Decomposition Products

Carbon oxides

11. TOXICOLOGICAL INFORMATION

Information on likely routes of exposure

Inhalation Harmful by inhalation. May cause drowsiness or dizziness.

Eye contact Contact with eyes may cause irritation. May cause redness and tearing of the eyes.

Skin contact May be harmful in contact with skin.

Ingestion Ingestion may cause irritation to mucous membranes.

Chemical Name Oral LD50 Dermal LD50 Inhalation LC50

XYLENE = 3500 mg/kg ( Rat ) > 4350 mg/kg ( Rabbit ) > 1700 = 5000 ppm ( Rat ) 4 h = 29.08
1330-20-7 mg/kg ( Rabbit ) mg/L ( Rat ) 4 h
METHYL ETHYL KETONE = 2483 mg/kg ( Rat ) = 2737 mg/kg = 6480 mg/kg ( Rabbit ) = 5000 = 11700 ppm ( Rat ) 4 h
(BUTANONE) ( Rat ) mg/kg ( Rabbit )
78-93-3
ACETONE = 5800 mg/kg ( Rat ) > 15700 mg/kg ( Rabbit ) = 50100 mg/m3 ( Rat ) 8 h
67-64-1
CARBON BLACK > 15400 mg/kg ( Rat ) > 3 g/kg ( Rabbit ) -
1333-86-4

Information on toxicological effects

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Symptoms No information available.

Delayed and immediate effects as well as chronic effects from short and long-term exposure

Sensitization No information available.

Germ cell mutagenicity No information available.
Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen.
Chemical Name ACGIH IARC NTP OSHA
XYLENE - Group 3 - -
1330-20-7
TALC - Group 3 - X
14807-96-6
CARBON BLACK A3 Group 2B - X
1333-86-4
ACGIH (American Conference of Governmental Industrial Hygienists)
A3 - Animal Carcinogen
IARC (International Agency for Research on Cancer)
Not classifiable as a human carcinogen
Group 2B - Possibly Carcinogenic to Humans
OSHA (Occupational Safety and Health Administration of the US Department of Labor)
X - Present
Chronic toxicity May cause adverse liver effects.
Target Organ Effects Central nervous system, Central Vascular System (CVS), Eyes, Respiratory system, Skin,
kidney, Liver.

The following values are calculated based on chapter 3.1 of the GHS document .
ATEmix (oral) 3368 mg/kg
ATEmix (dermal) 1815 mg/kg
ATEmix (inhalation-dust/mist) 2.8 mg/l
ATEmix (inhalation-vapor) 44850 mg/l

12. ECOLOGICAL INFORMATION

Ecotoxicity

31 % of the mixture consists of component(s) of unknown hazards to the aquatic environment

Persistence and degradability

No information available.

Bioaccumulation
No information available.

Mobility
No information available.

Chemical Name Partition coefficient

XYLENE 3.15
1330-20-7
METHYL ETHYL KETONE (BUTANONE) 0.3
78-93-3
ACETONE -0.24
67-64-1

Other adverse effects

No information available

13. DISPOSAL CONSIDERATIONS

Waste treatment methods

Disposal of wastes This material, as supplied, is a hazardous waste according to federal regulations (40 CFR

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261).

Contaminated packaging Do not reuse container.

US EPA Waste Number D001, D035, U002 U159 U239

This product contains one or more substances that are listed with the State of California as a hazardous waste.

Chemical Name California Hazardous Waste Status

XYLENE Toxic
1330-20-7 Ignitable
METHYL ETHYL KETONE (BUTANONE) Toxic mixture of acetone, methyl acetate, and methyl alcohol
78-93-3 Ignitable mixture of acetone, methyl acetate, and methyl alcohol
ACETONE Ignitable
67-64-1

14. TRANSPORT INFORMATION

DOT
UN/ID No UN1133
Proper shipping name: Adhesives, Limited Quantity (LQ)
Hazard Class 3
Packing Group II
Emergency Response Guide 128
Number

IATA
UN/ID No ID 8000
Proper shipping name: Consumer commodity
Hazard Class 9
ERG Code 9L

IMDG
UN/ID No UN1133
Proper shipping name: Adhesives, Limited Quantity (LQ)
Hazard Class 3
Packing Group II
EmS-No F-E, S-E

15. REGULATORY INFORMATION

International Inventories
TSCA Complies
DSL/NDSL Complies
EINECS/ELINCS Complies
ENCS Not determined
IECSC Complies
KECL Complies
PICCS Complies
AICS Complies

Legend:
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances
ENCS - Japan Existing and New Chemical Substances
IECSC - China Inventory of Existing Chemical Substances
KECL - Korean Existing and Evaluated Chemical Substances
PICCS - Philippines Inventory of Chemicals and Chemical Substances

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AICS - Australian Inventory of Chemical Substances

US Federal Regulations

SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical
or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372

Chemical Name SARA 313 - Threshold Values %

XYLENE - 1330-20-7 1.0
SARA 311/312 Hazard Categories
Acute health hazard Yes
Chronic Health Hazard No
Fire hazard Yes
Sudden release of pressure hazard No
Reactive Hazard No

CWA (Clean Water Act)

This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21
and 40 CFR 122.42)

Chemical Name CWA - Reportable CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous
Quantities Substances
XYLENE 100 lb - - X
1330-20-7
CERCLA
This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302)

Chemical Name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ)

XYLENE 100 lb - RQ 100 lb final RQ
1330-20-7 RQ 45.4 kg final RQ
METHYL ETHYL KETONE 5000 lb - RQ 5000 lb final RQ
(BUTANONE) RQ 2270 kg final RQ
78-93-3
ACETONE 5000 lb - RQ 5000 lb final RQ
67-64-1 RQ 2270 kg final RQ
US State Regulations

California Proposition 65
This product contains the following Proposition 65 chemicals
Chemical Name California Proposition 65
CARBON BLACK *Carcinogen (airborne, unbound particles of respirable
1333-86-4 size)

• *The asterisked chemical(s) listed are not subject to Proposition 65 because they are not airborne in the finished product
U.S. State Right-to-Know Regulations

Chemical Name New Jersey Massachusetts Pennsylvania

XYLENE X X X
1330-20-7
METHYL ETHYL KETONE X X X
(BUTANONE)
78-93-3
ACETONE X X X
67-64-1
TALC X X X
14807-96-6
CARBON BLACK X X X
1333-86-4
U.S. EPA Label Information
EPA Pesticide Registration Number Not applicable

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WHMIS Hazard Class

B2 - Flammable liquid, D2A - Very toxic materials

16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OF THE LAST REVISION

NFPA Health hazards 2 Flammability 3 Instability 0 -
HMIS Health hazards 2 Flammability 3 Physical hazards 0 Personal protection B

NFPA (National Fire Protection Association)

HMIS (Hazardous Material Information System)

Revision Date 24-Feb-2020

Disclaimer
Illinois Tool Works Inc. believes the information contained in this data sheet is accurate as of the date compiled.
However, Illinois Tool Works Inc. makes no warranty, express or implied, as to the accuracy, reliability or completeness
of the information. User is responsible for evaluating whether such information or this product is fit for a particular
purpose and suitable for a particular use or application. The information in this data sheet may not be valid if this
product is used in combination with other products or in processes for which it was not designed. Illinois Tool Works Inc.
disclaims any liability for consequential or incidental damages of any kind, including lost profits, arising from the sale or
use of this product. Ensure you have the most current version of this data sheet by contacting us or reviewing our web
site.

End of Safety Data Sheet

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