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Solution Of: Revision Test (XI Syllabus) Part - I: Chemistry

The document contains a chemistry revision test with multiple choice questions and answers. Some key details include: - The test has questions on topics like ionic compounds, organic chemistry reactions, thermodynamics, and mathematics. - The answers provided are in letter form (A, B, C, etc.) for the multiple choice questions. - Explanations are provided for some of the chemistry questions involving calculations of enthalpy changes and resonance structures. - The mathematics questions cover topics like complex numbers, trigonometry, and binomial expansion.

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0% found this document useful (0 votes)
60 views

Solution Of: Revision Test (XI Syllabus) Part - I: Chemistry

The document contains a chemistry revision test with multiple choice questions and answers. Some key details include: - The test has questions on topics like ionic compounds, organic chemistry reactions, thermodynamics, and mathematics. - The answers provided are in letter form (A, B, C, etc.) for the multiple choice questions. - Explanations are provided for some of the chemistry questions involving calculations of enthalpy changes and resonance structures. - The mathematics questions cover topics like complex numbers, trigonometry, and binomial expansion.

Uploaded by

Bodhisattva Basu
Copyright
© Attribution Non-Commercial (BY-NC)
Available Formats
Download as PDF, TXT or read online on Scribd
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1

Solution of Revision Test (XI Syllabus)


Regd. Office : Aakash Tower, Plot No.-4, Sec-11, MLU, Dwarka, New Delhi-110075
Ph.: 011-47623456, Fax : 011-47623472
PART - I : CHEMISTRY
1. Answer (D)
E =
8
M
charge anionic or cationic Total
wt. Mol.
=
2. Answer (A)
Energy of ideal gas is directly proportional to its temperature and not to its volume.
3. Answer (A)

310
is a 3p orbital, radial node = n l 1, angular node = l
4. Answer (D)
Heat is used to melt ice.
5. Answer (B)
H
solution
= H
lattice
+ H
Hydration
1 = 180 + H
Hydration
H
Hydration
= 179 kcal
179 H H ) (Hydration

Cl Na
= +
+
179 H
6
5
H
Na Na
= +
+ +
11
) 179 ( 6
H
Na

=
+
= 97.5 kcal
6. Answer (D)
7. Answer (B, C)
II, III and IV are 4ne

conjugated systems, hence, anti-aromatic.


8. Answer (B, C)
In (A) and (D) the lone pair on N are participating in resonance and hence, not available easily for an acid attack.
9. Answer (A, B)
Chain and cyclic silicates are formed by sharing two O-atoms by each tetrahedra.
10. Answer (A, B, D)
With K
2
Cr
2
O
7
it forms a blue colour due to formation of CrO
5
.
11. Answer (A)
(As
3+
)
2
2As
5+
+ 4e
(S
2+
)
3
3S
6+
+ 24e
[As
2
S
3
2As
5+
+ 3S
6+
+ 28e] 3
3e + N
5+
N
2+
] 28
RTSS
Code-A
06/02/2010
2
PART - II : MATHEMATICS
12. Answer (D)
No doubt molecule is optically inactive because of plane of symmetry.
13. Answer (D)
O
O
OH
OH
14. Answer (C)
MCPBA
CH Cl
2 2
O CH MgI
3

CH
3
CH
2
CH
2
O

H O
2
CH
3
CH CH
2 2
OH
15. Answer (D)
CH
3
C CH
2
CH
3
O
O
CH C OH CH
3
CH
3
16. Answer A(p, t), B(r), C(p, t), D(s, t)
H
+
+ OH

H
2
O, H = 57.3 kJ/mol
In aprotic solvent, HCl is covalent weakly ionising compound, so some sort of energy is used up in dissociation.
Due to hydration of F

after neutralization higher amount of energy is released.
17. Answer A(q, r), B(q, r, t), C(p, q, t), D(q, s, t)
In presence of common ion, solubility decreases and becomes unsaturated on heating.
18. Answer (3)
19. Answer (9)
20. Answer (6)
21. Answer (B)
22. Answer (D)
23. Answer (A)
4x
2
+ 9y
2
+ 16z
2
= 6xy + 12yz + 8zx
(2x 3y)
2
+ (3y 4z)
2
+ (4z 2x)
2
= 0
2x = 3y, 3y = 4z and 4z = 2x
2x = 3y = 4z
4 1 3 1 2 1
z y x
= =
x, y and z are in H.P.
3
24. Answer (B)
Since, z and
z
subtend a right angle at origin
y
z
x
z z
z

z i z =
x + iy = i(x iy)
= y + ix
x = y
z lies on the line y = x, therefore z, z , z and
z
are the vertices of a square centred at origin.
Thus, z
1
, z
2
, z
3
and z
4
are as shown in figure.
y
z
x
z z
z
z
1
z
4
z
3
z
2
Clearly, area of parallelogram z
1
, z
2
, z
3
and z
4
is equal to area of square z,
z
, z and
z
= 2|z|
2
25. Answer (A)
Let m be the slope of the line which passes through (4, 5), the equation of the line is
y + 5 = m (x 4)
mx y 4m 5 = 0 (i)
Now length of perpendicular from (2, 3) to (i) is 12,
12
1
5 4 3 ) 2 (
2
=
+

m
m m

12
1
8 6
2
=
+

m
m
[2(3m + 4)]
2
= 144 (1 + m
2
)
9m
2
+ 24m + 16 = 36 (1 + m
2
)
27m
2
24m + 20 = 0
Since this equation gives no real value of m, so number of required lines is zero.
26. Answer (A)
The given equation can be put in the form
25
) 5 4 3 (
) 1 ( ) 1 (
2
2 2
+ +
= +
y x
y x
, which shows that (1, 1) is the
focus and 3x + 4y + 5 = 0 is the equation of the directix of the parabola.
Axis of the parabola is the line perpendicular to the directix and passes through the focus
4
Hence, slope of the axis is
3
4
4
3

1
=
|
.
|

\
|
Equation of axis :
( ) 1
3
4
1 x y =
3y 3 = 4x 4
4x 3y 1 = 0
The locus of centroid of the triangle formed by conormal points is the axis of the parabola.
Hence, required locus is 4x 3y 1 = 0
27. Answer (A, B, C, D)
x
1
, x
2
, ...... x
16
form an A.P.
x
1
+ x
16
= x
2
+ x
15
= x
3
+ x
14
= x
4
+ x
13
= x
5
+ x
12
= x
6
+ x
11
= x
7
+ x
10
= x
8
+ x
9
but cosx
1
= sinx
16
x
1
+ x
16
= 90
x
1
= 90 x
16
tan(x
1
) = cot(x
16
) =
) tan(
1
16
x
(tanx
1
) (tanx
16
) = 1
Similarly,
(tanx
2
) (tanx
15
) = 1,
.........................
.........................
tanx
1
.tanx
2
...... tanx
15
.tanx
16
= 1
sin
2
x
1
+ sin
2
x
2
+ ...... + sin
2
x
16
= 8
cos
2
x
1
+ cos
2
x
2
+ ...... + cos
2
x
16
= 8
28. Answer (A, B, D)
29. Answer (A, B, C)
Let, , are the roots of x
2
+ x + 1 = 0, then
+ = 1 = 1 , also = 1

=
1
, as
2
+ + 1 = 0 1 =
2
= .
but
3
=
2
.
2
, hence the value of other root is 1 , . ,
1
2

30. Answer (A, B, C)


The number of legal words in ALLCLEAR is equal to the number of arrangements of
LA LA LE C R
Total number of legal words in ALLCLEAR is also equal to . 60
! 2
! 5
=
(A) Total number of legal words in ALLCLEAN is also equal to . 60
! 2
! 5
=
(B) The number of legal words in LOGICALL is equal to the number of arrangements of
LO LI LA G C
Total number of legal words in LOGICALL = 5! = 120
5
(C) Total number of legal words in CALLNEAR is equal to the number of arrangements of
LA LA C N E R and LA LE C N R A
Total number of legal words in CALLNEAR is equal to ! 6
2
3
! 6
2
! 6
= +
(D) The number of legal words in COLLINEAR is equal to number of arrangements of
LV LV C N R
1 2 3 4
V V
where, V
1
, V
2
, V
3
and V
4
are the four vowels
V
1
and V
2
can be selected in
4
C
2
ways
Total number of legal words in COLLINEAR is equal to
4
C
2
7!
31. Answer (A)
a + c > 0 (i)
At least one of either a and c is positive, but as the equation has no real root, then
b
2
4ac < 0
ac >
4
2
b
(ii)
which shows that either a > 0 & c > 0 or a < 0 & c < 0
from (i) and (ii)
a > 0, and c > 0
ax
2
+ bx + c > 0 for all real value of x
hence, at x = 1, a b + c > 0
hence, statement-1 is true.
Statement-2 is true because
ax
2
+ bx + c = a
|
|
.
|

\
|

|
.
|

\
|
+
2
2
2
4
4
2
a
ac b
a
b
x
If b
2
4ac < 0, then the sign of ax
2
+ bx + c and a are same.
Hence, statement-2 explains statement-1.
32. Answer (B)
Sum of the coefficients is obtained by putting
x = y = z = 1 in (3x + 2y 4z)
n
Hence, sum = (3 + 2 4)
n
= 1
n
= 1
Hence, statement-1 is clearly true.
Sum of the binomial coefficients in (x + y)
n
is 2
n
is clearly true, but statement-2 does not explain
statement-1.
33. Answer (B)
5 3
5 3
4
2
x x
x x
x
+
=
(i)
2
3 1
2
x x
x
+
= (ii)
x
3
2
= x
2
x
4
(iii)
Putting the value x
2
, x
4
from equation (i), (ii) in (iii)
5 3
5 3 3 1 2
3
2
2 x x
x x x x
x
+

+
=
6

) (
) )( (
5 3
5 3 3 1 2
3
x x
x x x x
x
+
+
=
) (
) )( (
5 3
5 3 1
3
x x
x x x
x
+
+
=
x
3
2
+ x
3
x
5
= x
1
x
5
+ x
3
x
5
x
3
2
= x
1
x
5
, hence x
1
, x
3
, x
5
are in G.P.
34. Answer (B)
5 3
5 3
4
2
x x
x x
x
+
=
(i)
2
3 1
2
x x
x
+
= (ii)
x
3
2
= x
2
x
4
(iii)
by (i), (ii) and (iii)
x
3
2
= x
1
x
5

1
2
1 2
1
2
3
5
) 2 (
x
x x
x
x
x

= =
35. Answer (C)
As, x
3
2
= x
1
x
5
(i)
and x
3
2
= x
2
x
4
(ii)
x
1
x
5
= x
2
x
4
5
4
2
1
x
x
x
x
=
36. Answer A(r), B(s), C(q, t), D(p)
37. Answer A(s), B(r, t), C(q), D(p)
(A) The number of non-negative integral solutions of the equation x
1
+ x
2
+ x
3
= 20
= Coefficient of x
20
in (1 + x + x
2
+ + x
20
)
3
= Coefficient of x
20
in (1 x
21
)
3
(1 x)
3
=
20 + 3 1
C
3 1
=
22
C
2
= 231
(B) a = b = 1, c = 2 x
1
+ x
2
+ 2x
3
= 20
The required number of solutions
= Coefficient of x
20
in (1 + x +x
2
+ + x
20
)
2
(1 + x
2
+ x
4
+ )
= Coefficient of x
20
in (1 x
21
)
2
(1 x)
2
(1 + x
2
+ x
4
+ )
= Coefficient of x
20
in (1 +
2
C
1
x +
3
C
2
x
2
+ ) (1 + x
2
+ x
4
+ )
=
21
C
20
+
19
C
18
+
17
C
16
+ +
3
C
2
+
1
C
0
= 21 + 19 + 17 + + 3 + 1
= ) 1 21 (
2
11
+
= 121
7
(C) a = b = 1, c = 3 x
1
+ x
2
+ 3x
3
= 20
The required number of solutions
= Coefficient of x
20
in (1 + x +x
2
+ + x
20
)
2
(1 + x
3
+ x
6
+ )
= Coefficient of x
20
in (1 x
21
)
2
(1 x)
2
(1 + x
3
+ x
6
+ )
= Coefficient of x
20
in (1 +
2
C
1
x +
3
C
2
x
2
+ ) (1 + x
3
+ x
6
+ )
=
21
C
20
+
18
C
17
+
15
C
14
+
3
C
2
= 21 + 18 + 15 + + 3
= ) 3 21 (
2
7
+
= 84
(D) a = 1, b = 2, c = 3 x
1
+ 2x
2
+ 3x
3
= 20 x
1
+ 2x
2
= 20 3x
3
The required number of ways
= The number of solution of x
1
+ 2x
2
= 20, 17, 14, 11, 8, 5, 2
= Coefficient of (x
2
+x
5
+ + x
20
) in (1 + x + x
2
+ x
20
) (1 + x
2
+ x
4
+ + x
20
)
= 2 + 3 + 5 + 6 + 8 + 9 + 11
= 44
38. Answer (2)
39. Answer (3)
40. Answer (2)
PART - III : PHYSICS
41. Answer (D)
By conservation of energy
Loss in P.E. = Gain in K.E.

2
2
2
2
3
12 2
1
2
3

(
(

|
|
.
|

\
|
+ =
|
|
.
|

\
|
l
m
ml R
mg

l
g
5
3 6
=
Speed of centre = r =
2
3
5
3 6 l
l
g

=
l
l g
4 5
3 3 6


=
10
3
3
gl
42. Answer (B)

=

T
l
n T
l
n
4 4
2 1
where, n
1
and n
2
are odd 9 16
8
43. Answer (D)
Slope at point B
=
= = tan x
d
d
x
y
...(i)
Now, R =
g
u 2 sin
2
y
x
B C
3 m
3 =
g
y g 2 sin ) 2 ( 2
...(ii)
From (i) and (ii),
x = 1m
44. Answer (A)
=
I

=
12
) (
2 2
y x m +
mg
mg
2
=
12
) (
2 2
2 2
y x m
y mg
+
|
.
|

\
|
|
.
|

\
|
=
2 2
3
y x
gy
+
45. Answer (D)
W
gravity
= U =
2
) (
2
gh h r g
=
2
2
2
2
|
|
.
|

\
|


rg
T
g r g
=
g
T


2
2
46. Answer (D)
47. Answer (A, B, D)
Motion in option (C) is also S.H.M.
48. Answer (B, D)
Reduced mass =
3
2
2
) 2 ( m
m m
m m
=
+

r
m GM
V
m ) 2 (
3
2
2
1
2
= |
.
|

\
|
V =
r
Gm 6
Total energy at any time = Zero.
9
49. Answer (B, C)
50. Answer (A, B)
M
RT P
=

T =

|
.
|

\
| 1
12
PM
P
V
A B
As T

1
P = constant
V T
51. Answer (D)
By Stefans law
4
AT
dt
dQ
= is same but
dt
dT
by Newtons law is not same.
52. Answer (C)
F also depends on mass.
53. Answer (A)
y = A sin (t + kx + )
At t = T
0
, x = 0, y = 0
0 = A sin (T
0
+ )
= T
0
54. Answer (D)
Phase difference between points S and U may be lesser or greater than .
2

55. Answer (C)


V
P
= 0
56. Answer A(r, t), B(p), C(s), D(q)
57. Answer A(p, r), B(p, t), C(q, s), D(q, s)
58. Answer (4)
F.B.D. of block in frame of box is as shown. By work energy theorem, Wall = K.E.
8x 1 x
2
1
350 x
2
= 0
7x =
2
2
350
x
8
8
10
f = N
= 0.5 2
= 1

x =
25
1
m = 4 cm
59. Answer (5)
60. Answer (5)
1
2
T
f
l m
=
f T
f M

= here, f = f + 6, T = T + 0.44T = 1.44T


10
6 1.44 f T
f T
+
=
f = 30 Hz
Now keeping the original tension (T) and length of given wire is changed
1
1.20
f l
f l

= =

( l= 1 + 0.20l)
f = 25 Hz
f = f f = 25 30 = 5 Hz
Fundamental frequency will decrease by 5 Hz

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