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Uppp2 2022 Sem 1 Ans

1. The document contains a series of letters and numbers. 2. It appears to be summarizing chemistry concepts and equations across multiple topics including stoichiometry, gas laws, equilibrium, and thermochemistry. 3. Key concepts addressed include the ideal gas law, Le Chatelier's principle, Van't Hoff analysis of equilibrium constants, and bond types in different compounds.

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0% found this document useful (0 votes)
157 views1 page

Uppp2 2022 Sem 1 Ans

1. The document contains a series of letters and numbers. 2. It appears to be summarizing chemistry concepts and equations across multiple topics including stoichiometry, gas laws, equilibrium, and thermochemistry. 3. Key concepts addressed include the ideal gas law, Le Chatelier's principle, Van't Hoff analysis of equilibrium constants, and bond types in different compounds.

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yijiee
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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1. A 2. C 3 C 4. B 5.

6. C 7. C 8. C 9. B 10. A

11. D 12. A 13. C 14. D 15. B

16. (a)(i) mass of one mol of magnesium compare to 1/12 19 (a) m1:(86.1 x 103) (1.00 x 10-3) = n x 8.31 x (25+273) [1]
mass of carbon-12 atom. [1] m2 : n = 3.48 x 10-2 mol [1]
(ii) RAM Mg = (24x80) + (25x10) + (26x10) / 80+10+10 [1] m3 : MR = 1.11 / 3.48 x 10-2 ; MR = 31.8 [1]
= 24.3 [1] [Alternative ; m1 : MR = dRT / P [1]
(b)(i) Mg + 2 HCl  MgCl2 + H2 [1] m2 : MR = (1.11 x 103) (8.31) (25 + 273) / 86.1 x 103 [1]
(ii) mol Mg = 3.24 / 24.3 @ 0.1333 mol [1] m3 : MR = 31.9 [1]
V H2 = 0.1333 x 24.4 [1] m4 : Gas = oxygen gas or O2 [1]
= 3.25 dm3 [1] ii. m5 : allotropes = ozone [1]
m6 : formula = O3 [1] + m7 : Lewis [1]
17 (a) sum of the powers to which all reactant concentrations
appearing in the rate law are raised [1]
(b) rate = k [CH3COCH3] [H+] [1]
(c) each graph [1] x 2 [2]
(b)(i) m8 : - Ice has open lattice structure [1]
m9 : Ice occupied larger volume than water [1]
m10 : when ice melt, the hydrogen bond broken [1]
m11 : hence water molecule become closer / distance smaller
(ii) m12 : As T increase, dry ice sublime [1]
m13 : heat is absorbed from the surrounding [1]
(d) (i) 1.24 x 10-3 = k (0.300)(0.025) [1] m14 : surrounding become cool hence act as refrigerant [1]
k = 0.165 mol-3 dm3 s-1 [1] m15 : water vapour from surrounding condensed and form a
(ii) x = (0.165) (0.400) (0.060) [1] white fog of water vapour which give the smoky effect [1]
= 0.00396 mol dm3 s-1 [1]
20 (a) m1 : system reaches equilibrium while the reaction is
18. (a) m1 : Be and Ba are metals [1] still ongoing [1]
m2 : hold by strong metallic bonds [1] m2 : at the rate of forward reaction = rate of backward
m3 : since Me has smaller metallic / atomic radius therefore reaction [1]
stronger metallic bond [1] (b) m3 : heterogeneous catalyst [1]
(b) (i) m4 , m5 : Lewis structure [1] x 2 [2] m4 : since Fe is a solid and will not involve / disturb the
system at equilibrium [1]
(c) m5 : Kc = [NH3]2 / [N2] x [H2]3 [1]
m6 : as V of vessel is halved ; P is doubled / increased [1]
m7 : equilibrium shift to direction less total mol of gas [1]
(ii) m6 : BeCl2 is an insulator while BaCl2 is conductor [1]
m8 : equilibrium shift to the right [1]
m7 : since BeCl2 do not have free moving ion [1]
m8 : while BaCl2 forms free moving ion in molten state [1] (d) m9 : Expressed Vant Hoff eq : ln K = –H/ RT + C [1]
(iii) m9 : BeCl2 has lower melting point since it is a simple m10 : express table of ln K and 1/T [1]
covalent molecule [1] 1/T 0.00143 0.0025 0.00167 0.00125
m10 : hold by weak Van Der Waals forces [1] ln K -1.22 8.28 1.51 -3.23
m11 : BaCl2 has higher melting point as it is hold by giant m11-13 : Plot graph – Axis [1] ; Plotting [1] ; Linear [1] [3]
ionic crystal lattice [1] 10
m12 : which has strong electrostatic attraction forces between
8
the ions [1]
(c) m13 : Draw monomer of AlCl3 m14 draw dimer Al2Cl6 6
m15 : label dative bond and covalent bond [3]
Monomer of AlCl3 Dimer of Al2Cl6 4

0
0.001 0.00125 0.0015 0.00175 0.002 0.00225 0.0025
-2

-4

m14 : Gradient = (8.28 – (-1.22) / (0.0025–0.00143) @ 8879


m15 : 8879 = –H / 8.31 ; H = –73.4 kJ mol-1 (accept 70-80)

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