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Theories of Covalent Bonding and Shapes of Molecules

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26 views3 pages

Theories of Covalent Bonding and Shapes of Molecules

Your prayers are you

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rahimullahkhanruk.14
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THEORIES OF COVALE (Be @! Which one cannot be a central atom? (b) ct (br On Mine nee erry sg ‘What Is the electron pair geometry of Nb? ©) 6) Pyramidal (b) Tetrahedral | (e)Square planner (d) Octahedral 1 A NH(? and S0;? ions have: 04) Tearahedral geometry {b) Triangular geometry {@) Pyramidal geometry {@) Square planner geometry MTBE is a constituent of petrol. 0) \Wnat are the values of angle P and Q ina pokcule of MTBE? “CHa <4 chLC.07CHs | “ee CHs (a) Angle P= 90%, angle @ = 105° (t) Angle P= 90°, angle @ = 180° (o) Angle P= 109°, angle @ = 105° (@ Angle P= 109°, angle @ = 180° 9 Which ofthe following molecules is not ar? (a) Benzene (0) Ethene (©) Boron trifuride (@ Phosphorous trichloride Q) Themolecular structure of BeCls is: (0) Linear (b) Tetrahedral (6) Trigonal (d) None of these 8 Whatis the approximate value of the O-C-O bond angle in ethanoic acid? (ase (b) 90° (10 (a) 120° MOLEC — [PAAR ee ae) ‘TT BOND AND SHAP’ Q9) In which one of the following pairs of molecules have similar shapes? (@)AlClyand BCly—(b) AlClyand PCI ' (¢) BFsand NHy (4) BeClsand 11:0 | Q10) Octet rule ts not followed in. (0) NHy (b) BFS (©) PCI (8) None. Q11) Which of the following best describes the change in the bond angle in water when the jon 10" is formed? % (a) Decreases to approximately 90° (6) Decreases to approximately 109° (€) Increases slightly a) Increases to approximately 120° a es ee Q12) Among the following the molecule which shows resonance? (@) SOz (b) Os () CoHe () All of them Q13) What is the necessary condition for resonance? (a) The position of the nuclei in each structure must be the same (b) The structure differs only in the position of pi electrons (c) The number of unpaired electrons in each structure must be the same (d) All statements are correct 3 nan ‘The molecular orbitals formed as a result o LCAO method obey: (a) Pauli exclusion principle (b) Hund’s rule Qa) (c) Aufbau principle (4) All of these ral overlapping expected in: (a) Sigma bonds (b) x Bonds (¢) lonic Bonds (@) Metallic Bonds Q16) In the molecule CH: = C= CH, the hybrid state of carbon number 2 is: (a) sp? (b) sp (©) sp () dsp* Q17) In SO; molecule, S atom is: (a) sp* hybridized ——_(b) sp* hybridized (c) sp hybridized (d) dsp? hybridized Q18) In PCls molecule the phosphorus atom is: (a) sp’ hybridized —_—_(b) sp*d hybridized rr 162 IMM Coaching Academy ciarr (©)sp' hybridized (4) sp* hybridized Q19) Which hybridization occurs in SOs? ()sp* (b) sp (©) dsp? @sp Q20) Which of the following compounds gives sp? hybridization? (@)H:0 (NHS (CH (4) All the above Q21)_In which one ofthe following sp* hybridization occurs? (CH (0) KMn0. (©H:80, (8) Allof them Q22)_In which of the following compounds carbon is sp-hybridized: CH, WOH (6) Cats (@ Calle Q23) In ground state the unpaired electrons Im carbon are: é @1 2 ()3 @4 Q24) Hybridization in carbon monoxide is: (EEE Q25) “Winch among the following pairs are netic? paramagnetic? (On and Nz (b) Oz and CO Qorseano (@) CO and NO Q26) ‘The bond order is maximum is diamagnetic? (a) Of () 0; © 0: (aor Q31) The molecule of Ne: does not exist because: (a) Nb> Na (b) Nb=Na (c)Nb and covalent in CCla Q9) Thetypes of bonds present in CuSOx5 H30 are: (@ Ionic and covalent (0) Ionic and co-ordinate covalent (6) lonic, covalent and coordinate (@ Covalent and co-ordinate covalent QS) The compound which contains both ionic and ‘covalent bond Is: (@) CBee (&) KON (Ket (@) ‘The two fluorine atoms form a bond with each other, the bond will be: {a) Sigma (b) Sigma star hich of the following does ionic bonding occur between the named ators? (@) Atuminum and chlorine in the wifluoride {(b) Boron and fluorine in boron trifluoride (c) Hydrogen and chlorine in hydrogen chloride (@) Hydrogen and sodium in sodium hydride Q57) Chlorobenzeno is a molecule: (a) Polar (b) Non polar (c) both (a) and (b) (d) None of these Q58) The lattice energy of fonie compounds is: (a) Low () High (c) Zero None ER Ss Q59) Which one has maximum dipole moment? (a) 0~ Dichlorobenzene (b) m~ Dichlorobenzene (©) p—Dichlorobenzene (@) All have same dipole moment. Q60) CO: has zero dipole moment white 1:0 has a dipole moment. It is because: (a) 120 is linear while COs is a bent molecule (b) of intermolecular H-bonding in H:0 molecule (€) CO> is linear while H:0 is a bent molecule (4) COs is a gas while H:0 is liquid at room temperature Q61)_ How many covalent bonds are present in carbon monoxide molecule? ai (b)2 ©3 @4 Q.62)_ The dipole moments of NH3, HF, H:0 and SO; are 1.44D, 1.92, 1.84D and 1.600, respectively. The order of decreasing polarity: (a) HF > SO:> 20 > NH (b) H20 > NHs> SO:> HE (c) HF > NHy> SO2 > H:0 a) HE > Hi Q63) Which one is the directional bonds? (a) Covalent (c) Hydrogen bonding (4) All of the above, —_—o 55 164 (b) Coordinate covalent

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