Name ................................................

Batch.................... Roll No. ............... UNIT EXAMINATION

23-07-2023

24G
TP/JM/H/ONLINE Alcohol Phenol and Ether
Time: 1 hr Mark: 100

Section 1 - Only one option correct type (4, -1)

1. The general molecular formula, which represents the homologous series of alkanol is:
1) CnH2nO 2) CnH2n+1O 3) CnH2n+2O 4) CnH2nO2
2. Total number of isomeric (structural isomerism only) alcohols with formula C4H10O is
1) 2 2) 1 3) 3 4) 4
3. An industrial method for the preparation of methanol is:
1) by reacting CH4 with steam at 900°C with a nickel catalyst
2) by reduction of HCHO with LiAlH4
3) by catalytic reduction of CO in presence of ZnO–Cr2O3
4) by reaction of HCHO with NaOH(aq)
4. Which reagent can bring about,

RCOOH  RCH 2OH transformation?

1) Sn+HCl 2) LiAlH4 in ether 3) Na and C2H5OH 4) H2 and Pt
5. Which of the following can be used for the synthesis of 3-methyl-1-butanol?

1) n  C3H 7 MgBr  CH 3CHO 2)  CH3 2 CHCH 2 MgBr  CH 2O

O
3) 4)  CH3 3 CMgBr  CH 2O
C2H5MgBr + CH3 C CH3

CH3
  F 

6. H Br2
 C4H8Br2
H3C OH  H 2O CCl 4
5 such proudcts
are possible
How many structures of [F] are possible?
1) 2 2) 5 3) 6 4) 3
CH3
7. X X is
NH2   (Major product)
HNO 2
CH3 CH CH2

CH3 CH3

1) CH3 CH CH2 OH 2) CH3 CH2 CH CH2OH

CH3 CH3

3) CH3 C OH 4) CH3 C CH2

CH3
24G/JM/H/ONLINE 2 J-CHEMISTRY

OH –+
ONa

8. + CHCl3+ NaOH . The electrophile involved in the above reaction is

CHO

 
1) C HCl2 2) :CCl2 3) CCl3 4) C HO

9. What is formed when glycerol reacts with HIO4?

1) Two molecules of formic acid and one molecule of formaldehyde

2) Two molecules of formaldehyde and one molecule of formic acid

3) Three molecules of formic acid

4) Three molecules of formaldehyde

10. Among the following compounds which can be dehydrated very easily in acidic medium

OH

1) CH3CH2CH2CH2CH2OH 2) CH3CH2CH2CHCH3

CH3

3) CH3CH2 C CH2CH3 4) CH3CH2CHCH2CH2OH

OH CH3

11. In the following reaction sequence

P I2
R  OH   R  I 
AgNO2
 RNO 2 
HNO 2
 no reaction, the alcohol is a

1) Primary alcohol 2) Secondary alcohol 3) Tertiary alcohol 4) Phenol

12. The acidity of p-nitrophenol (I), 0-nitrophenol (II), m-nitrophenol (III) and phenol (IV) decreases in the
order

1) I > II > III > IV 2) IV > I > II > III 3) II > III > I > IV 4) III > II > I > IV


13. Phenol 
1.NaOH
2.CO /140 C
 A 
H /H 2O
B  C
Ac2O
2 H

In this reaction, the end product C is

1) Salicylaldehyde 2) salicylic acid 3) phenyl acetate 4) aspirin

14. A compound ‘X’ undergoes reduction with LiAlH4 to yield ‘y’. When vapours of ‘y’ are passed over
copper at 300°C, ‘X’ is formed. What is ‘y’?

1) CH3COCH3 2) CH3CHO

3) CH3CH2OH 4) CH3–O–CH3
24G/JM/H/ONLINE 3 J-CHEMISTRY

15. Benzyl magnesium bromide reacts with methanol to give

1) a mixture of anisole and Mg(OH)Br 2) a mixture of benzene and Mg (OMe) Br

3) a mixture of toluene and Mg(OCH3)Br 4) a mixture of phenol and Mg(Me)Br

16. The reaction, C2 H 5ONa  C 2 H5 I  C 2 H5OC2 H5  NaI is called

1) Wurtz reaction 2) Kolb’s reaction

3) Williamson’s synthesis 4) Grignard synthesis

17. An organic compound of molecular formula C4H10O does not react with sodium. With excess of HI, it
gives only one type of alkyl iodide. The compound is

1) ethoxy ethane 2) 2-methoxy propane 3) 1-methoxy propane 4) 1-butanol

18. Which of the following is not cleaved by Hl even at 525K?

1) C6 H5  O  CH 3 2) C6 H 5  O  C6 H 5

3) C6H5OC3H7 4)
O

19. A simple method to remove peroxides from ethers is to treat them with an aqueous solution of

1) KI 2) KCNS 3) Na2S2O3 4) Br2

20. Tert. butyl methyl ether react with one mole Hl gives

1) Tert. butyl alcohol and methyl iodide 2) methyl alcohol and tert. butyl iodide

3) 2 moles methyl iodide 4) methyl iodide and tert. butyl iodide

Section II: Numerical type (4, –1)

For each question enter the correct integer value. Rounded off to the next integer if the answer
is decimal. Eg: If the answer is 25.67, rounded off to 26. If the answer is 9.35, rounded off to 9. If
the answer is 0.75, rounded off to 1. If the answer is 0.45, rounded off to 0.

21. A solution of phenol in chloroform when treated with aqueous NaOH gives P as the major product. The
mass percentage of carbon in P is (To the nearest integer)

22. How many structural isomers of C6H14O will answer iodoform reaction

23. Number of oxygen atoms present in a crown ether with ring size 18

24. Number of OH groups present in phloroglucinol

25. Total number of –COOH groups present in picric acid is

Name ................................................

Batch.................... Roll No. ............... UNIT EXAMINATION

23-07-2023

24G
TP/JM/H/ONLINE Alcohol Phenol and Ether

1. 3

2. 4 Alcohols: OH OH
OH OH
butan-1-ol 2-methylpropan-1-ol butan-2-ol 2-methylpropan-2-ol

3. 3
4. 2
O

5. 2  CH3 2 CHCH 2MgBr  H C H 

dry
ether
  CH3  2 CHCH 2CH 2OMgBr 
H 3O 

CH3

CH3 CH CH2 CH2 OH

6. 4 But-1-ene, But - 2-ene (cis and trans)

7. 3
8. 2

CH2OH

CH OH
9. 2 
2HIO 4

 2HCHO  HCOOH
CH2OH

10. 3 Based on stability of carbocations

11. 3
12. 1
13. 4
14. 3 X=Ethanal Y=Ethanol
15. 3
16. 3
17. 1
18. 2
19. 2
20. 2 SN1 mechanism
24G/JM/R/151 2 J-CHEMISTRY

21. 69

22. 4 Hexan-2-ol, 3-methyl pentan-2-ol, 4-methyl pentan-2-ol, 3,3-dimethylbutan-2-ol

23. 6
24. 3 Benzene-1,3-5-triol
25. 0