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SDS Hardener 2750 EN 221004

The document provides safety information for Hardener 2750 in 20 kg packaging. It lists the product identifier and supplier contact information. Hardener 2750 is classified as an eye irritant. The document outlines first aid measures and recommendations for handling spills of the product. It identifies ingredients including ammonium chloride and notes the product should not be used by consumers.

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0% found this document useful (0 votes)
70 views10 pages

SDS Hardener 2750 EN 221004

The document provides safety information for Hardener 2750 in 20 kg packaging. It lists the product identifier and supplier contact information. Hardener 2750 is classified as an eye irritant. The document outlines first aid measures and recommendations for handling spills of the product. It identifies ingredients including ammonium chloride and notes the product should not be used by consumers.

Uploaded by

jupryka
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
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SAFETY DATA SHEET

Hardener 2750 20 kg

Section 1. Identification
GHS product identifier : Hardener 2750 20 kg
CAS number : Not applicable.
EC number : Mixture.
Product code : AV275000020
UN number : Not available.
Other means of : Not available.
identification
Product type : Solid.

Relevant identified uses of the substance or mixture and uses advised against

Product is not intended for consumer use.

Supplier's details : AKZO NOBEL VIETNAM LTD


Lot 107, Amata Industrial Zone
Bien Hoa City, Dong Nai Province, Vietnam
(+84) 251 393 6389

Emergency telephone : (+84) 909 043 900


number (with hours of
operation)

Section 2. Hazards identification


Classification of the : EYE IRRITATION - Category 2A
substance or mixture

GHS label elements


Hazard pictograms :

Signal word : Warning


Hazard statements : Causes serious eye irritation.
Precautionary statements
Prevention : Wear eye or face protection. Wash hands thoroughly after handling.
Response : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get
medical attention.
Storage : Not applicable.
Disposal : Not applicable.

Routes of entry : Not available.


Other hazards which do not : None known.
result in classification

Date of issue/Date of revision : 10/4/2022 Date of previous issue : 10/4/2022 Version : 1.04 1/10
Hardener 2750 20 kg

Section 3. Composition, information on ingredients


Substance/mixture : Mixture
Other means of : Not available.
identification

CAS number/other identifiers


CAS number : Not applicable.
EC number : Mixture.
Product code : AV275000020
Ingredient name CAS number Chemical formula %
ammonium chloride 12125-02-9 NH4Cl ≥10 - ≤25

There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require
reporting in this section.
Occupational exposure limits, if available, are listed in Section 8.

Section 4. First aid measures


Description of necessary first aid measures
Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing.
If not breathing, if breathing is irregular or if respiratory arrest occurs, provide
artificial respiration or oxygen by trained personnel. It may be dangerous to the
person providing aid to give mouth-to-mouth resuscitation. Get medical attention if
adverse health effects persist or are severe. If unconscious, place in recovery
position and get medical attention immediately. Maintain an open airway. Loosen
tight clothing such as a collar, tie, belt or waistband. In case of inhalation of
decomposition products in a fire, symptoms may be delayed. The exposed person
may need to be kept under medical surveillance for 48 hours.
Skin contact : Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. Get medical attention if symptoms occur. Wash clothing before reuse.
Clean shoes thoroughly before reuse.
Ingestion : Wash out mouth with water. Remove dentures if any. Remove victim to fresh air
and keep at rest in a position comfortable for breathing. If material has been
swallowed and the exposed person is conscious, give small quantities of water to
drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not
induce vomiting unless directed to do so by medical personnel. If vomiting occurs,
the head should be kept low so that vomit does not enter the lungs. Get medical
attention if adverse health effects persist or are severe. Never give anything by
mouth to an unconscious person. If unconscious, place in recovery position and get
medical attention immediately. Maintain an open airway. Loosen tight clothing such
as a collar, tie, belt or waistband.

Most important symptoms/effects, acute and delayed


Potential acute health effects
Eye contact : Causes serious eye irritation.
Inhalation : No known significant effects or critical hazards.
Skin contact : No known significant effects or critical hazards.
Ingestion : No known significant effects or critical hazards.
Over-exposure signs/symptoms
Eye contact : Adverse symptoms may include the following:
pain or irritation
watering
redness

Date of issue/Date of revision : 10/4/2022 Date of previous issue : 10/4/2022 Version : 1.04 2/10
Hardener 2750 20 kg

Section 4. First aid measures


Inhalation : No specific data.
Skin contact : No specific data.
Ingestion : No specific data.

Indication of immediate medical attention and special treatment needed, if necessary


Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
Specific treatments : No specific treatment.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It
may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.

See toxicological information (Section 11)

Section 5. Fire-fighting measures


Extinguishing media
Suitable extinguishing : Use an extinguishing agent suitable for the surrounding fire.
media
Unsuitable extinguishing : None known.
media

Specific hazards arising : No specific fire or explosion hazard.


from the chemical
Hazardous thermal : Decomposition products may include the following materials:
decomposition products nitrogen oxides
sulfur oxides
halogenated compounds
metal oxide/oxides

Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if
for fire-fighters there is a fire. No action shall be taken involving any personal risk or without
suitable training.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained
equipment for fire-fighters breathing apparatus (SCBA) with a full face-piece operated in positive pressure
mode.

Section 6. Accidental release measures


Personal precautions, protective equipment and emergency procedures
For non-emergency : No action shall be taken involving any personal risk or without suitable training.
personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Provide adequate
ventilation. Wear appropriate respirator when ventilation is inadequate. Put on
appropriate personal protective equipment.
For emergency responders : If specialized clothing is required to deal with the spillage, take note of any
information in Section 8 on suitable and unsuitable materials. See also the
information in "For non-emergency personnel".

Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways,
drains and sewers. Inform the relevant authorities if the product has caused
environmental pollution (sewers, waterways, soil or air).

Methods and materials for containment and cleaning up


Small spill : Move containers from spill area. Avoid dust generation. Using a vacuum with
HEPA filter will reduce dust dispersal. Place spilled material in a designated,
labeled waste container. Dispose of via a licensed waste disposal contractor.

Date of issue/Date of revision : 10/4/2022 Date of previous issue : 10/4/2022 Version : 1.04 3/10
Hardener 2750 20 kg

Section 6. Accidental release measures


Large spill : Move containers from spill area. Approach release from upwind. Prevent entry into
sewers, water courses, basements or confined areas. Avoid dust generation. Do
not dry sweep. Vacuum dust with equipment fitted with a HEPA filter and place in a
closed, labeled waste container. Dispose of via a licensed waste disposal
contractor. Note: see Section 1 for emergency contact information and Section 13
for waste disposal.

Section 7. Handling and storage


Precautions for safe handling
Protective measures : Put on appropriate personal protective equipment (see Section 8). Do not ingest.
Avoid contact with eyes, skin and clothing. Keep in the original container or an
approved alternative made from a compatible material, kept tightly closed when not
in use. Empty containers retain product residue and can be hazardous. Do not
reuse container.
Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is
occupational hygiene handled, stored and processed. Workers should wash hands and face before
eating, drinking and smoking. Remove contaminated clothing and protective
equipment before entering eating areas. See also Section 8 for additional
information on hygiene measures.

Conditions for safe storage, : Store in accordance with local regulations. Store in original container protected
including any from direct sunlight in a dry, cool and well-ventilated area, away from incompatible
incompatibilities materials (see Section 10) and food and drink. Keep container tightly closed and
sealed until ready for use. Containers that have been opened must be carefully
resealed and kept upright to prevent leakage. Do not store in unlabeled containers.
Use appropriate containment to avoid environmental contamination.

Section 8. Exposure controls/personal protection


Control parameters
Occupational exposure limits
Ingredient name Exposure limits
ammonium chloride ACGIH TLV (United States).
TWA: 10 mg/m³ 8 hours.
STEL: 20 mg/m³ 15 minutes.
ACGIH TLV (United States, 3/2015).
TWA: 10 mg/m³ 8 hours. Form: Fume
STEL: 20 mg/m³ 15 minutes. Form: Fume

Appropriate engineering : Good general ventilation should be sufficient to control worker exposure to airborne
controls contaminants.
Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure
controls they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process
equipment will be necessary to reduce emissions to acceptable levels.

Individual protection measures


Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and
safety showers are close to the workstation location.
Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn,
unless the assessment indicates a higher degree of protection: chemical splash
goggles.

Date of issue/Date of revision : 10/4/2022 Date of previous issue : 10/4/2022 Version : 1.04 4/10
Hardener 2750 20 kg

Section 8. Exposure controls/personal protection


Skin protection
Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should
be worn at all times when handling chemical products if a risk assessment indicates
this is necessary. Considering the parameters specified by the glove manufacturer,
check during use that the gloves are still retaining their protective properties. It
should be noted that the time to breakthrough for any glove material may be
different for different glove manufacturers. In the case of mixtures, consisting of
several substances, the protection time of the gloves cannot be accurately
estimated.
Body protection : Personal protective equipment for the body should be selected based on the task
being performed and the risks involved and should be approved by a specialist
before handling this product.
Other skin protection : Appropriate footwear and any additional skin protection measures should be
selected based on the task being performed and the risks involved and should be
approved by a specialist before handling this product.
Respiratory protection : Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.

Section 9. Physical and chemical properties


Appearance
Physical state : Solid.
Color : Not available.
Odor : Not available.
Odor threshold : Not available.
pH : Not applicable.
Melting point : Not available.
Boiling point : Not available.
Flash point : Not available.
Evaporation rate : Not tested
Flammability (solid, gas) : Not available.
Lower and upper explosive : Not applicable.
(flammable) limits
Vapor pressure : Not available.
Vapor density : Not available.
Density : 0.8 g/cm³
Solubility : Not tested
Partition coefficient: n- : Not tested
octanol/water
Auto-ignition temperature : Not available.
Decomposition temperature : Not tested
Viscosity : 3 - 7 Pa.s (BROOKFIELD LVT 4,60RPM) (25 °C)

Section 10. Stability and reactivity


Reactivity : No specific test data related to reactivity available for this product or its ingredients.

Chemical stability : The product is stable.

Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur.
reactions

Conditions to avoid : No specific data.


Date of issue/Date of revision : 10/4/2022 Date of previous issue : 10/4/2022 Version : 1.04 5/10
Hardener 2750 20 kg

Section 10. Stability and reactivity

Incompatible materials : No specific data.

Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products
products should not be produced.

Section 11. Toxicological information


Information on toxicological effects
Acute toxicity
Product/ingredient name Result Species Dose Exposure
ammonium chloride LD50 Oral Rat 1650 mg/kg -

Irritation/Corrosion
Product/ingredient name Result Species Score Exposure Observation
ammonium chloride Eyes - Mild irritant Rabbit - 24 hours 500 -
milligrams
Eyes - Severe irritant Rabbit - 100 -
milligrams
Sensitization
Not available.

Mutagenicity
Not available.

Carcinogenicity
Not available.

Reproductive toxicity
Not available.

Teratogenicity
Not available.

Specific target organ toxicity (single exposure)


Not available.

Specific target organ toxicity (repeated exposure)


Not available.

Aspiration hazard
Not available.

Information on the likely : Not available.


routes of exposure
Potential acute health effects
Eye contact : Causes serious eye irritation.
Inhalation : No known significant effects or critical hazards.
Skin contact : No known significant effects or critical hazards.
Ingestion : No known significant effects or critical hazards.

Symptoms related to the physical, chemical and toxicological characteristics


Eye contact : Adverse symptoms may include the following:
pain or irritation
watering
redness
Date of issue/Date of revision : 10/4/2022 Date of previous issue : 10/4/2022 Version : 1.04 6/10
Hardener 2750 20 kg

Section 11. Toxicological information


Inhalation : No specific data.
Skin contact : No specific data.
Ingestion : No specific data.

Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Long term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Potential chronic health effects
Not available.

General : No known significant effects or critical hazards.


Carcinogenicity : No known significant effects or critical hazards.
Mutagenicity : No known significant effects or critical hazards.
Teratogenicity : No known significant effects or critical hazards.
Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.

Numerical measures of toxicity


Acute toxicity estimates
Route ATE value
Oral 7382.6 mg/kg

Section 12. Ecological information


Toxicity
Product/ingredient name Result Species Exposure
ammonium chloride Acute EC50 0.07 mg/l Marine water Algae - Hormosira banksii - 72 hours
Gamete
Acute EC50 0.1 mg/l Fresh water Crustaceans - Cypris 48 hours
subglobosa
Acute LC50 390 µg/l Fresh water Daphnia - Daphnia magna - 48 hours
Young
Acute LC50 80 µg/l Fresh water Fish - Oncorhynchus mykiss 96 hours
Chronic EC10 0.03 mg/l Fresh water Daphnia - Daphnia obtusa 21 days
Chronic NOEC 0.6 mg/l Marine water Algae - Entomoneis punctulata - 72 hours
Exponential growth phase
Chronic NOEC 330 µg/l Fresh water Crustaceans - Crangonyx sp. - 21 days
Juvenile (Fledgling, Hatchling,
Weanling)
Chronic NOEC 0.006 mg/l Fresh water Fish - Ictalurus punctatus - Fry 30 days

Persistence and degradability


Not available.

Bioaccumulative potential

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Hardener 2750 20 kg

Section 12. Ecological information


Product/ingredient name LogPow BCF Potential
ammonium chloride -3.2 - low

Mobility in soil
Soil/water partition : Not available.
coefficient (KOC)

Other adverse effects : No known significant effects or critical hazards.

Section 13. Disposal considerations


Disposal methods : The generation of waste should be avoided or minimized wherever possible.
Disposal of this product, solutions and any by-products should at all times comply
with the requirements of environmental protection and waste disposal legislation
and any regional local authority requirements. Dispose of surplus and non-
recyclable products via a licensed waste disposal contractor. Waste should not be
disposed of untreated to the sewer unless fully compliant with the requirements of
all authorities with jurisdiction. Waste packaging should be recycled. Incineration or
landfill should only be considered when recycling is not feasible. This material and
its container must be disposed of in a safe way. Care should be taken when
handling emptied containers that have not been cleaned or rinsed out. Empty
containers or liners may retain some product residues. Avoid dispersal of spilled
material and runoff and contact with soil, waterways, drains and sewers.

Section 14. Transport information


UN IMDG IATA
UN number Not available. Not regulated. Not regulated.

UN proper Not available. Not available. Not available.


shipping name
Transport hazard Not available. Not available. Not available.
class(es)

Packing group - - -
Environmental No. No. No.
hazards
Additional - - The environmentally
information hazardous substance mark
may appear if required by
other transportation
regulations.

Special precautions for user : Transport within user’s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in
the event of an accident or spillage.

Transport in bulk according : Not available.


to Annex II of MARPOL and
the IBC Code

Date of issue/Date of revision : 10/4/2022 Date of previous issue : 10/4/2022 Version : 1.04 8/10
Hardener 2750 20 kg

Section 15. Regulatory information


Toxic classification (TCVN : 4
3164-79)
International regulations
Chemical Weapon Convention List Schedules I, II & III Chemicals
Not listed.

Montreal Protocol (Annexes A, B, C, E)


Not listed.

Stockholm Convention on Persistent Organic Pollutants


Not listed.

Rotterdam Convention on Prior Inform Consent (PIC)


Not listed.

UNECE Aarhus Protocol on POPs and Heavy Metals


Not listed.

International lists
National inventory
Australia : Not determined.
Canada : Not determined.
China : All components are listed or exempted.
Europe : Not determined.
Japan : Japan inventory (ENCS): Not determined.
Japan inventory (ISHL): Not determined.
Malaysia : Not determined.
New Zealand : Not determined.
Philippines : Not determined.
Republic of Korea : Not determined.
Taiwan : Not determined.
Turkey : Not determined.
United States : All components are listed or exempted.

Section 16. Other information


History
Date of printing : 10/4/2022
Date of issue/Date of : 10/4/2022
revision
Date of previous issue : 10/4/2022
Version : 1.04
Key to abbreviations : ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships,
1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations
Procedure used to derive the classification
Classification Justification
EYE IRRITATION - Category 2A Calculation method

Date of issue/Date of revision : 10/4/2022 Date of previous issue : 10/4/2022 Version : 1.04 9/10
Hardener 2750 20 kg

Section 16. Other information


References : Not available.
Indicates information that has changed from previously issued version.
Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above-
named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or
completeness of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may
present unknown hazards and should be used with caution. Although certain hazards are described herein,
we cannot guarantee that these are the only hazards that exist.

Date of issue/Date of revision : 10/4/2022 Date of previous issue : 10/4/2022 Version : 1.04 10/10

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