Pagdilao Act1
Pagdilao Act1
- Reversible process is a process, involving a system and its surroundings, whose direction can be
reversed by infinitesimal changes in some properties of the surroundings, such as pressure or
temperature.
Examples:
Freezing of water
If you keep water in the freezer for
some time, it transforms into ice. But as soon as you take it out of the freezer, it turns
into water again.
Boiling of water
If you boil water, it evaporates and becomes water vapor. When you cool this vapor
down, it turns back to water.
Folding of paper
Folding of a paper is a reversible change because paper can be unfolded to get it back.
Stretching of rubber band
If we stretch a rubber band with force of our hands, it undergoes a change and its length
increases. But, on releasing the force, the rubber band comes back to its original length.
Melting of wax
Melting of the wax is a reversible change because the shape of the wax can be obtained
by heating it.
- Irreversible arises frequently in thermodynamics. All complex natural processes are irreversible,
although a phase transition at the coexistence temperature is well approximated as reversible.
Examples:
Burning a piece of paper
When you burn a piece of paper, it turns to ash. It cannot become paper again.
Cooking an egg
Once we cook our eggs, we cannot uncook them. Therefore, cooking is an irreversible
change.
Rusting of iron
When water vapour comes in contact with the iron, they react. Therefore, iron rusts and
once this happens, we cannot reverse it.
Burning of candle
Burning of a candle is an irreversible change because once the candle melts, the wax
cannot be molded again.
Falling of leaves from a tree
Falling of leaves from a tree is irreversible process because we can't attach the leaves
again to tree. So falling of leaves process can’t be in its previous state so it is an
irreversible process.
The basic difference between reversible and irreversible processes is that in the reversible process the
system remains in thermodynamic equilibrium, while in the irreversible process the system does not
remain in thermodynamic equilibrium. A reversible process is one in which both the system and its
environment can return to exactly the states they were in by following the reverse path. While an
irreversible process is one in which the system and its environment cannot return together to exactly
the states that they were in.