DPastulates of Quontum Mochanics :— 2 There am a no. of methed, callable bore development ¢}y gebaredingers ware equtcrtion to get the quantitative result Like ane ge > momentum , angalare momertcem , position , velocity cle. of o particle. Bul “in mocerch quanta mechanichy “the. | schmodi ngert wave equction is developecl ancl dhe above. cowl can bef obtained by use cercknin primciples collect os ostelatas of quan’ mechanics - postulate, crte :- | © for phi sical state of a system , jhe time clopendant wove functio? is meopreesented as WORE) Ie The wove Fenction rprssenks complete Knowledge on in yoremation ragarcling. the bohaviotws of particle . etre wave Rinckim Yat) most be well-behaveol 1.2. WC) dw, ey must be finite , continuct and single vatuesl * okt aes ok .% extended overt. the complete range of vartioldles upto © - Also the wave Fanclion ya, t) must be normalised. ie “pray = 4 (iE Wis rah) "0 ot tT pytavet CF Wis crmplon © fon. quorey, obsorwalole poctatates there & an opercature 2. all meosutable obserwade can be reopreaxented evs moth mati- -col opartkors . 24.1. The catkevian co-ordinate oporotor, 2. % give the position of parchclyy in those axes ane roprexentes] as a, 4 +2. TRYE oporcokore is to ba mulkiplt2cl by, same woe functio to get same wave function anol de, observable abstt “the position. eq -2 The lincaro momentum oparcator, CP) is represen tee] as P= hy oe a“ Pe, = ath 4 2 a 2r om =! Ox, xih Py - s ‘Scanned with CamScanner| rs ~~ \ sand) un > vie - thn vy =~ oe eg &-cthe no yp -BY = hy ox ez | a i es Toe Fuse opocafora are multipedl with the unve Runckion toget a " the 40me ieee Fanckion and ‘the vabut of Lineare momoftum | BY = (— ed +v)¥ . ort be s Pyra Aogalee ccomenkun operator, :— So the Hamiilenian opscakn contain 2oparcalon sichas | E We “knew that the angulas. momenta opexafor, of a Kinok’c enenyy? operates ancl potential oncrep/ opacatore & portide = the preoduck of ite Gineare momentum and radius, he. [fe oh ay 5 hee L= Pxre whote re = tacit grim z Pe Bincox. momenta 2 = L = Angalave % WOhere. a Ki oparators fav 3 Thus 5] = th Fyre ard P-E opocatee Boy 5 i = Sie lt he ysl, meataralte qpontities are eaat,1o | angtlars morentam oposcolor: of a particle, ali kif. | NRO Hemilfian cpercfors are possible evardidlate ant ans epesiertd ct ee ol axis pact + ° ; | L2=-ZPy+ye on yp, —zp, ‘fin oporafor. A is said to be Linear for 2 Fanckioms” | = 4(=% 2 2 “and ‘g? if the oparater: onthe um of 9, Ranckions | ar 32 )—=(-R &) | gues tase result ax the am of 2 nasalts obtainas| ley hy a2 9 | arreyiray uk the, saree cparakion on the 2 funckyons sepa - an (foe 5) | -zatelt és Steiflarciy the. [ACE+g) = AF +Ay il on. A, aly! can be fineor operators but taking, ae } equare of y~ ane, nan. Lirear, operators | ©)Heamitian Oparators +— | “Again an opocatore A will ba colttel ax Harcmition » | ' “pail, TF ik Ssakis fits the. follecvingy conditions :— 1 gas wee a, F Suppose Wi and Ws are te! kus Functions operating oven j The. ‘otal operator * abtaine ftom scheonidgor the two oporafore | wane equation callie ax “Hamiltonian Ch) to eo se, | hah! we. ys ew peaabons "(H). “Tue Aujde = fas horSee i ante devel from Scheodtnger’s cave. Runeffon 08 2g 213 enamine if GF te Horemition iF Yr @%and Ypesinn, ta a : 83 Sy + iain Ce wy =0 Ans + ey ee i 5 Se . | ove orm ev ~ Erm yy =9 s £ & (sina) dn fe Etat) dee ae {OF scone won carert yt oi |= fine (Gh et) de» rina foe = famx(-e%)de THoreehere s fan Herenilian operator 29:2 Shea ‘hak the apenator. 45 lore fanchion fea aw” 4 4a) = bz s Linear ov not . ainsi A [rey geo] aan bz") = ax™n + bn” 2 Age) = $ cr)= grads 2 Ar) = $oe) = nz 7 Soit fs Linea . oTe alicwerl values of an obserevable A in the operators eqpation; | Zw - The above equation t+ callool of igen value egpakion in which A capuynted a the sigen opecatoro . Yi meprsenk eign wove Funckion anol ai rapeecents vigen value. The a| i is the ofgen values ic valid if tae, Wy is well vchoyec} bel fury? ay 4 0 © SF ister ix ina stake of Y and there avtz mera observabla fore if then tes, enpeckarl avacaye maarercabiement of tne, Obynwalls of the operate Av it given ats aay = _Syaway Saytay The averea ition of a the w-ordiraly a oe teen aes veyton obey ; D ey = Sua van fury ay “The. mepected eran mamuntam Pre lof tee yam akoney the c-odinae ai ox ta given & 5 Ley 2 SY GER vax | futvda The. quanfurn machorvcal opercafoe, ceeerpenting) to obwrable orca emstructed by. wnikingy the duswical éapreion im tera of aa are eerultrcting toa! exprastion Yo the operators of aus 5 Classical variable & Quacturn ruchanical Opeaalans je o Classicak Quantum, | operates ie ariables | ariables Ps 2 | Wis mullipied by | ‘ vg | dst the dudvabive of Yount fo | Pe ig ‘fs taken and ‘then it is | mall pbiel with cy, | ae ar oe Y is mulfiptioad with x2, | gage [Te sind donivalive of | Pam Poe \ "Bae Y wiet. & is taken and then} | muliplied with > \ | tim)! ¢ |g Phe wave Function a | matttiptiad with +. BE é th 2. | Te dat donivabive of with Th | BE | taken ond then muttip'ecl "OF seme ith OREN Scanner Scanned with CamScanner- 1 fi = La i - f de ‘Broakie | Saaddinapr in 1926 made. car of daar © gliern rc en dadea | ave pation elzn tue? unuctairky pcp to | hectic aiotnbel bation fe elit os whrodinge 7 tru cqpation. Tha satabion ofy the eqpation qives the inforemdtion | obrak tne distribution in rpace an llowesl the aneeg4 lok | of the ‘| Ya devigmast-a clamteal was spain consi due thes particle nature, of pectreon . Ths, ant Ranckton ob particle roving olny re-ait (given by the mm) 5 Y = Axin 20% @ un Faulks on A = Amplitude. of wove, { Le disinibakion of panko. fyeom rwchess along rou Neo Aifoankialing the above equation with revpoct te oe we, ! 5 dy - Qe y Dir Sor ha ae Whores, | ay 2 = An pein Ine 2 ae | > ae 2 4n?y dat 4 > #8, + Any co This is the conve motion of a, parchicle chong “ean Considers ‘the notin of alec in 20- spate » then | equation wivee, @ dy 4 di d 2 art Ge ts +4 y¥-0—@ 7 VV Se y-0 _@ Bovis Pe 4 Ue AY, Loptat operat Fico, % e t' Brogli'es waue- en wo ened that 5 nl ie ps Sabostituting- the value of > i eqn @, we gat 5 oa AY ew 0 TTY 4 842 (mt i 7 . “ CS) 0 Bie tam (Fee Jay20 a fam 2 2 8 ¢C2ER) exes “0D We tensed that” 5 Total enancqy = ke + Pe PME Eqy' <2) Sabstitabinay this in qn @ oe pls vee Sm vy 07 Thu iy the Scheorcligart's wove vey on crovdinake anit . Sis a ond oredore stifountie agg and can alxo be arctan ei dy SE SY eM Evy =O dat t dye * dx 7 ofylialion of Suoacinpr's sou squatin $0 fect paride. tn 4D by :— yh puri: th staid 40 bo fut if potonbiol, ena mn pyeroprnarta in tha ox. A 1D boris a kind of Beery ont. one, astth co hail wall ob the too ands. P The: potanbial onteyy ofp tte porchile, inwidle, the by f ompol t 0 ie. v=O 2h aha walk & oukvide the wall the PE ts ogpal to oo . Lobe endo a porcidts such 98 2 fs cm ined in such 4D box and ts moving. dora) x dirastion upto a ditfanw ‘i a (PE) ‘than rtafurcns back - Lek 5 m= mom ob partic a= Segth of 30 tae i same yee ‘OF Scnned ith OREN Scanner Scanned with CamScannerSupper be ate ele. losin Leos. a cong stp + i the calliston he bale At a=0 ee Pas ma | wen 440 RXEO , Ve when 02% 2a,V=0 ; wiv’ beetying Schreacingere's wane espotion fyerca po! moving lang monet The oq” Ms Vs ae ce-w¥=0 —_@ das" Siw “hee parcicls is Minside. the bane, 40 'V? aby tne pathic, qual 40 0 Thus eq @ becomes 5 oe, + 80m py -0 ~ nn cy —_@ | In this patente Blame £ m are all I scant. RS |b 5 8rtm p = K> hE Thus Gr © brome ; de = ey | + ae + oY 2 | Tha edn eadiqoay and ale Afocenbial 247 | eee wr get 5 Artin Kx + Bros ee Wee wsenly the aclahion of pq @ bu it conditions . doin wah along "© onal ; SY = kaeske Hexinke, é 7 can = KC Asinket Breskx) —@ | A ‘the boundary eenditions when Z=0 > =O | putting sin ep ws gpk 5 F 0= —k*(nx0+8) 7-WB=0 cin 0 =O 7? 6-0 e Or4 ol Substttading this iq og” © on gt, tha ways, 2porion at 5 Wy =Aginkx —_@) ‘Apphiyeng Qed ‘owandacy undition , whan 02 &, Y=0 O= Ain kee Taal Ke = ne nt aS Ee! te Ciay arc D Sinw he parckicle. ia intide ‘the box , asi can't bt taken os Z2uto . Sh A iz taken os O then wit be 0 and Y? ail be eqnal fo naco which vs sok acceptabte Neco the 047 © becomes 5 Y= Asin OT w|—___@ “Tha ix the eave eqpotion of ‘the porcticle in, 41D box . breom Ua pqpctbion , it vo eae fo hay2a scion, off acceptable, wave hanchicn cercexpordiney ty n= 4,259. 1s knew that 5 K2 = ohm fAlse we howe 2 ma a 3 = nant Su2me tnt = a= >)e = met zi Fam Trish eguation o| of o partis in 1D bor The. ‘ae Pin Q of the partie must be nesmadis.2s} Oh ‘J yd = 2 2. J Ge mez)" da 22 > of ata om eet “OF Senne ith OREN Scanner Scanned with CamScanner2 Seco ome Ome dae 4 a eye (1-08 Baw’) cle = 4 [aie eae] 7 ye Ati, Af cn 2a dee 1 | > @ ray = £[ me a i 2 Oo r 2g A e-o)-t 7 dont - Pract pads Thus the wave, fanchioq becomes 5 | | Feo the ea of the Bas we Be spa te oer | rate quankttly % tha. pot ep re babe the | painks fF 0 given oma con Pave egal atecaay vata | set sy ea pe im 4D box can take up oueke ise Be ononyy i | qponkise| because h can hove values ay | Here the ‘nt has same a te ov thal o | principe quantum mo. in Bohn’ ar “haut me i a MLS by = PR the Xereo point annegy., n° 2,6, = Abr mo mae Ta te abo sons we geethak the parkids canathave weno enstyy. The min. petrible Litcon have > The caro point onary for porcfide is —b® is ceeeatend nay = 1 hich is otal cs Zar point mea des Tn orto erurgy 1s desingesl Dp bathe partis in 1D “box. as tho cnn at 'ma> that 5 ote anarcyy of particle i inversely, propercional fo thes didone bel toon jun prandasey « . ie. B gt s dp length A3e 4D box inc. then energy Lvel of the, 5 Tr joe cloucoates , 2 Gi The. and ae Ea) 4 times hes cmpacsdto S a eae RS Bees Newel te 4 haber 2 1¢ Yonaregey tov = > one waye function re “tha probabil noth 4 ber z Aifforcont values of- 'q’ once reprenented qrerhic 3 as follows 5 ate cet af hich the coe function wrO i cattesl © (vanaien ° vith ‘a') (Gautier (Cont. Bonet? "OF Senne ith OREN Scannercal representation it & conclueled tet, | @ Fuckide in. SD_box. -— La eee Fe the pewicle prt Yo lop ak thes uf” alts cin peclile haviey baie cond box. , ia we box howin Iho’ beeedth ©'b? ote (2 With iain yuo seni, teats ah te oe seme of nig ey a,b,c ara orseated “along the % ele. ome boca more unite ie. TL A= 2 the pi Since the porcticle i: buee 20 co-asdinated amy %s4r% » max. af Aplaces of the box. fe. yr is max. 2 place wip, ihe PC enyskore inside boy 14 zone cutride the box . aii | fore n=3 YD hor 2 Maxima, with 2 nods, is 00. 2 Than we pind hak ab highere evols “he perches The pebauing? byandarcy corditions, aru. wake present cutvide the box vee erce_ meres riper disttibut2o} inwcle +e box. sakishied wfth the porcticl, in 3D box , P\ De : a " = i te is \ i “oon he expression Foo db wrcenee away lly v =e and Y=6 yf particle ts he rewyp nls omuprsing toner &n=2 ea | G@ocxeasv-o heey ¢| | v=o Scanned with CamScanner puch. in AD box ane 024 2b, v=0 & Y=y i b ; ta~ foe nel or © 042 20, V=0% yey ¥ ra , Be o = The wave fenction of parcticle inthe foe M2 Gy = nthe | box can be reeprerented at, Yauys - Me Smo Tt can be reerolve tnt the 3-codinafes “™ A; DE aby = he “a a hh such ar Yr, Wy et = Fe) = te Cana) Winadatt, to: toes Frat B-cewdinates «ie. Pp @F apart, ia combined in 10 bey of tngth a, then okt é aid oman. when teias ee" Where 5 Ya the wane Fanefion of parcticle ateng* 2! anteim net. be Satgraudle i ‘ % clepends upon varcleuble %- eee ea ehs 2. qontum robe , Siok Mary, y & Yo ove. wowe peanctiens of- pareicle along, e YQ2 coeclinchen renxpectively ushich clependls upon the Sine the paride ts in dot quondam tebe ; a =A seo a is ih dhe. Sehtodingere vs wawe, equation not 2 z Ee J A=an (ae . ot as 842m -0 OP oie in 10 es dow 28 ode fy cr (gat apt Be aye tA Baye Ee —— wan es 7 sition taker | 2 . 2 2 ee Seo mattond, . = ee 7 (Set aet fea) +t En EG Wy. We =o) fai We know that AE = wy =-B* _ Ca2-n) . 2mae >" On sang) we gpk 5 = 7 2 a oe oe Wy oh + Me + Uaety oe , = Dye 2% z a) = Sh_. 3x6 0an10*T ani | fSima} Yy-Y2 =o —®) Smi® Ba am) foa73 % 40! sect + oe Be io ‘OF Scanned ith OREN ScannerTr —llUmrertrtt~™ Devidrgy re 04" by(Ue ty Ya) we gek 5! “Re wave function of parkiek, in 308% 5 oe a ee ee F Wx “dart % F te Tee Te Each of the Lib “hase toromy in the above, Ua is a Peanchion ome varciable Ao the total ara “B* can he arvithen ag 5 8 Be Ex + Ey tle 3 2@ ‘becomes + : This = Ty at ey BL Coa ec oF onenpy ling aici oan ai | § 7G. Gant Vy age 1H weg Bo bao MEN 2 oe tise + Haag att Cy. nyt he z 7 at “iy vay Ey Ste 1 Mag oo ae é “Fe above eq is valid teas the 3 harmg——@ Be. ete — sine Fmc™ nt (me 4 ae eget aopiation can bw Beg a Eig By Pas e -ht ( 3+ B+S) st dhe An TE “he box ssa. cube then a=b=C and the total We oat toe cli nce anergy > Ae 4 2m zm Extx =0-—@ = Pas Cote any ez) d' yy yy aye? im gO TIP the box is a cube “then @ this the ampramtion +f toads a y a a . a ma e. 7 ane “he ink of tha. parbicle i-e.tne, Cecuerh 4 ae te. energy when Nx = Ny =e =1 ie. C44, 1) 2 dee + glo srwcary lavels ona reapressentedl as (2,11 7 tits no © Cal Cle aehe arorguy dowels C2,119,CLa.5, Oty V2) are callesl aa de, genanate srereay levels. Te above ag wii, to tha parcticte in LD box. akong. ei th Yon rafpuallian con. 7 7 B Scan ssi in pola co-ordinates & on dh the alse wradie, 0p a j ee nee ee Fedak 16 ashe schoo swana, Spudbra ee ce J Bin( Mean) —® H-atom +o define the position sf alachen jnsicle atom, $ —. oe which is ayperdcal em ; more. preci q cecnalietie 4e Jee ¥a( t) —@ iat. meee ee Soca plese w-osdisaber X,Y, 2 e info-pslare co-abinaber «, © ‘The povition of a parchicls -/= in ( Nz rec i ® «f= vin (QE) —_@) in a ephrordcal’ vyvlami 15 hevt chepinad by the pala coordinates ‘instead of carctarian oranda. ‘OF scanned ith OREN Scannerx Le: re bo the radial dislance of a pt-‘P” From 0 Cdivlane of €0 firm “pu ruclowt) whores G2= 224 y242% Let; g = Angle between radial vasfors “OP? & =—aml $k i called as Zenith ang , A parpendialare PP! ix dawn om x¥— Plane such that OP makes on angi. > with x-cart . New we howe 5 (B= 2 > 2=2n0s 8 ——O Senillecly 5 cos S aT > we ccshrine —®©) and 5 fin= 4 _ og. renoaind @ resin @ > 7 Subvtibuhinay thee values of GY in. schondinger’s WEN toy cand Oh yolying/ we 3 F] 1 | o/,ay LL Bofen oot), ui BY ° EG oe)? ino 36 (6) sre Bq + Sn’m (e-v)¥ -5—@) = Tris pation is a obifarandiod oof etry? 3 voniates ig eee KQ The above 247 rane: ant, Yaron aah hawt) 2 vec tha « ae 7 vo ey 80) ep C2) reeds fsne Oe hen 2s) 7 ioe (% + find 2 sino (280) soca De ) 1035 MOL ae), SO > S08 dot x0) CUO” Hus ‘the wave jinelim “Yaye’ i 1ed napessanted 08 Yeerd « Ruchor Urc.6,g canbe weprerentea a 5 Yaad = Ko.87.b@) =? aK ate Roogery | 280 |__@ abe eo Rood (se }-® fasting Thue in ayn © we qe Wrow as 3 Rex) = Reda wove, fenton. 5 le} 6 cay are Angular, wonnt anckions 5 Now s BY = ee Peo) [2|-—e 5 ay g gh 4 hg Ger dw CBs} + ihe 38 lene pene ai + ae — Cs) + sringe-yy=0 iplyiney the abre exuation wlth Rr sin% we get 5 *Rupben(22e ints Bi cg > Se)* Hat CVI Rena Boy Heqy=O Dividing te abrre syeatin by Ree) ,8¢e) cor, we get s Se) Oe nai into 8 + Cuno Sem. Cé-v) -o i snp [ 20 fin 2. of 2) Ran 8 Oe} They 30 C28 A Ha So} @ nn 8 erin EN = bee ( ape ‘OF scanned wth OREN Scnner SatTT Sime LYS of the above, 2qn equal to RWS 5 Ging LHS = RNS 40 iis must hove a dedinite veolue his value bo Lak 5 LHS = RHS = > They e4M@ can now be written oy, ‘ + CE-V) = Brine =p @ ste 2. + (fan) + we. 3 2 ‘sine (30.0) 4. Snrmedit Sey 28. ( oD) +S by Rn o Pe 5 anf -1 2°*Oc0) - yg __ -® =" —& He Zao ( 28) =p—@® 5 Gq) 2d* a ano nd. a oh 2 ast. Fh “a Huth he 4/7) Be) ,we S 7 Bea sa + 1-0 ;_@) Ma “te 2 ins (a 20, 3 ame ne He am) « co) z & Tras, syuakion 4 calleel on angtitore cwoue! funchion. Here, Conte 4 consent alee ox ridgraic. quantum no. = It gy inyormakion abeuk the gua te adertakion off elector exit arcand the nuclour i magnalic field. whose solution is ; bn Tha equabion emfains one variable ee ule Avtar. ‘are Ffuncbion . By abigea est wech ay CHO. | @ Solufion of Deg) equation Nii We have “he aqation fee G9) From equatian @ 7th 2a at = Sd 4 yrs 7 Reng Oe Ser) 1 ae Be ane (2) ti Oey | 30% phe + BS eh (f-v)=nP =0 multiply, Atay @ beth sickle of 24 wegel 5 Diy the ag" by 8% gt Fhe 4 dey ur =2——O a. akery) nb ots) ) he equakion is similar to the wane eqnation fore a pauctide| 7G RO Se Ge * np fe) O8 (Se In a tox Tee sabubion of ds aquation is genes + Sota én Pq) = Asin MO + Bes MQ ——_@ a | Fore a solution -jo be accoptable ,it mugt be continusur, 2% A 2) + rer BV) eal Diese pad sople: vahingk for-Hse wateMn, dy bx! wieght thal ie i. ‘Ge ee) - bn ate, ee Sh, Gada lod, oe atl bers a — i = Ot Ir a @) Thus whan O=0.%m OO) 9 28cm © simiMar dy cohen = 2m then Ol) = Avin Marr +Be0s Maer ‘OF Scanned ith OREN ScannerNew the Randion depencls value of Me The Rencbion holds goed: 2. to ba vinglt Gehiadl {ER MeO own—ve : Thus 0, 41,2223 ‘and MR cate ox mageete °, Thus ue con so Og) depen upto'M The nighnal / wank aaltion of @ &s empraned ints, crxponendiak err 083 ign = cette them 3 C= acmsfank which moker ‘the @ narmallisee! & can 3 OF A tldakeel ot foots. “Applying nermalisesl eonaition we at *{ dee Sco) x = 4 ° : | of etintee iMag « por “ages | | Oe ar | se[o]"=4 sCarstoct=t oc | Fe eave farton can abe tan 5 se tim | Onto) = fe Ve | Whe H=0,t1,22 ..- ete | Fre Qep) fo ke dingte volues| ,it thotld have seme value after ong value of © rescbubion . Thuy the wave function on ‘now be written ox 5 = gi CO +9nr) > eimd - aim + 2nmry Were ‘q' is a whole no. & the prooluck am? mut be @ whole numbart « for Aion Volum of HA Goon ts given in Ane fottevira Nes i imo For. H-atom , cheg) = & eine 20 eo Salukin jes “8” funchion :— jutvolu Ooo. bio sae ee 0 —— 20) > Th a gi? wd +4—> 0110), ——> far °° = Ge —4—> 4.414) ——> ares = doting wore 5 0 Ye = sing 27 ht) —> he ote Le 2 OL eA ing Scanned with CamScanner Ve: bags the a4? bere Oca) from eq (A) a8 pellows 5 4 2 ci 30, 2, 2» emo Jo (259) - Woe 4 Poco) =o —D i Lek ; 2=cos@ 5 whose value voruics belueon +14 -1. Cubs reoplace, O¢0) by *P! which ik a Fenckion of <2”. Follcring % important relabionvhip decived ore written 24 pollots + Wz? =cst 8 = 4—siq™@ —_G) @ Nm; 2 . 9 oof .d2 a “367 30 “d= “35 = $f cine) 0 $e = exe) Thus; 98) _ ap a6 Se Caine)’ - — 28 sine @ 2706) _ a fae yaz Ber. oe (4 x 3) 2 = gh Se, bz/an 3 ae 36 doe 32 Jez + a naz 37006) | ee ge PoE OR ip > 3 Fe 88 “Cae solving. the 4st pach of efnty eS rigs tobe VO we gt 5 = 1. a cing 2c. Sing 08 28 "OF sexed ith OREN Scanner«ose sade 7; = tk ow a ee ee 1 2 ging 28m “Bis eqn is called ay Legendice ica, Polyynerniat nomial. Op uletog, the abe re sae on at. s08) Lagndne ae ace thes ah For Gear; | 2 a ‘ ; 1 ae Erma on) (“E 0) 4 sind © cam) = Ses or i ful corp i s see ed ( ts (+46 MHpmo}—at singe mi P 3 ptt att ae 2 sleet a. PEAT core is geven oF S Rite sey eI Sanne 2 acy Whuw 5% = 0056 | = ry = id 2] ‘i . pete momont ayiantam ne. z = + [ eno sy + Bop eo daind ] = fngutere, manana noha no. 3 eae ‘ Osean saat B O19) fox H- atoms is given as holler; 2 = Pe) , 50 oem 0 + aa! § “Aer sD ae Ormco) [eM coso | a = a2 A 41059 AOC) 0) [flop ed ae tt aa ditt sie. aA67 (Geom 2976) Ba 0) = he 5 = dP ae ay we dp a \ ele 6 aaah 7e 79 79% [0D oo] he j- Ud]. 7 SPE) oo[ 2 Ce 9-49) redeltap) | Ae MP) | s BSome Harmonre Oscrtator :— | 4 simple harmonic motion(SHH) cecttacl ax Vilaukion on oscitation ia dokined at pexiedie dévploamert of pasckice, olor are rate ie. the back & Ferd mation of a paschide he same. path. Thai Vibeational motion it a SHM. For a, ae it hos tixed time panel a ampit bad ex pendulum sai tarteuh avers wat Salt ada by 8 it cad | owe) Of Jong the tome path ‘3 also o al Simple. homenie ‘ot vino melee the atems bended arse cova inky iho" ocie Alena ala banal ova a ns & be charges) porciedically. Peed 3a Accoredinc to Heok’x laud ; the eestoaing, Fence och 0 packicls uban it is! displaced From its equilibrium pacitien thrown a distane 629 13 given os 5 = ky —@ = Fora constant a ne = displacement ve sign indiakes he rasoring perce i aleocugs acing eppile fo the displacement «Tre aq" forthe mnetion obs ‘A SHO Is given 08 5 x = Asin 2wvt ——@ The rastorcingy poren, f= =m ae _@ Now 3 a shes 2ept ard — Rea Asin Ie-Vt C2n9)> ACS - Arty? x —@ substiteting 24%@) in ® we geks Ps ies An®V*x) = Amq?v*2, —©® On plethiray « qroph Yeokuten petantiat energy ane Ae aie fe un ge aqgeaphis 7 Now , PE cae te qpiveh on 5 ve “fe diy vik Aue mmedae men LET ° = ad Sea ste "ene BE Inthe simarenes athe 8S pe eae 3 ren + ons Ce-v) ¥ =O "OF seme ith OREN Scanner Scanned with CamScannergt rb —@ wan ay we hs he +b athe abeve 24” by *b’ 5 ay Sem (C- AnvPmar Y=? ? “ap me f —@ 4 a butts wubsitete [Srme ar 5 qr @ om ‘oa. writen os 5 New ty ay _ lomty "nary 7° % Be Sat 4 ae _ ett my?g™ are if — beni et o\e yee 7 aq? b Sain CE — n2y*mx™)Y =O (overs x= gr) b A ° =O [ve ‘vl nh “he wlution of abo 047't!" must be baharcel aml it c00" be written a 5 Pres wn Mort Pe 2a" hin = 3% te = Gyt2jc7% whin Yo = ¥ = (aq) eM shen oP =F { om... — _ So i ts dae thak per Y to be wall behaved thes votu of 2 emus be beloatey te fermuba. ( 2941) igs Qc ngi whee qr e123 thus) & = Sw2mE / antmy . 2E ys pe See / Ae. Ts 5 Paes ve 9 2net) = (may Yrs 16 the fetal aner ef qpontam stebo of SHO. Ak n=O5 crereqey of SHO cs [E ho | “he devcoctacistic woue function of harmonic oseiVatore for whith 1-1,2,3 +» arte given inte graph whch v2 plotted belaeen qt Yim qe wuove bh re clear, tho fore awculere value oF 4g? , the amplitude} becomes xert0, P02. @ wae packet behowes Like a pastichi with fuzzy edger and aneciafes| coaye packet re bound only lin 9 tte imi diate neighbour hood of postide. 2 Rigit Rotatoe .medel of scolecbion oF diatom, mdacule :~ igid dow is a model bere chiatimi rrobeutes, Te consists’ of- two points messes m, and mz suparcatect bye Pret distane “R’ Te calorie mdecule / migtd coture vs reotatiney, about the anu Itty the bond orig hich passa threagh centre of mass. Lek 5 mys distane of pont mays m/ prom conte tty = dlivtene cf peiak mare tm, prom anhe, R= MAcy = total divfane, . "OF scxned wth onEN Scorer Scanned with CamScannerTr .. ee ee ee ee This otal distone cumaing + a. a ee emotes (okay te 2Ry-GR = thd -y2.) | ena if & falled ava tighd 7 Feotore The rekgtcl reotor vk ue ee rapreesentas} iq tarom of position us cn rcrnaor adel 7 operator, & Unear memanterm lore. Tk ts Conviiniont rotational srucqy The OE! ~o ure pelarc coed! nates in place of corckerian to sdve. C chetodt ldwe Pquation b ul 5 porsoned by the igi atom $ Prggere qpation by using. fellow? : ie equal 40 x00. Hee V=O paprantits 4 acl age 5 and ha arkiy cneregey peste % = resino cosh f 5 by it is KE, where CE a Mg sino sing S ie pie eet ale eae S $ (Res Rte ae © Ganpae —y #8 [etme j. Le =Tes ar 2 T= moment of jnortic Aanp = a 4 : Z W =angukar viclocit Wi Ps em & T= arr Fong ye 3s freanstyerenefi oy Freer , qs tu Pa ‘angele HY2 10 the fandtion oh Me ap weghs I actin oes mia fee th (sind & teste cso %) ee te af jreskio. of Rigi ty = it ( cos 2 | cetore Neo itt to clive nellenis reg a Hi (cer Fe tak tind) : 2 thy 2 eeprcion Qahyres dit oni i ») Cia Cer ime Sredtgrer Com Saree de cians te. C39 Cee tyets Ay ey wwe ft F Homettenian operuker/ = [she Se (eH) +, 3 J-@ ard A= 340 > PE operate eas. ‘ae ‘ smo Oe es; fag- 0 © bil ee Lce> emiesiNgs sien wri 1°, me Peangatare momenfan quan, spree, PL y-ey——* We toe hak 5 12 etl te Sutbibitubing, vole of Ch in eqn @ wa ats hous ag as ane tages, moma omy | 93 [aso WS) tre Sp ]TE SY ‘Than compmnanks ty, optralon, Yor are mepansniad aus | > EY te ag B (9%) 4 hey Be Joo -0 fae $A -24% =-ih (YS — 22 ply o i 2h ‘akc (48 2) erence congas suse eae din Betis Gie- sz ? [ane 5 #05) “See Spelt +9 O70 ‘OF scanned ith OREN Scannera a h> | Now s fat ecb gh = 2 ~ \ 3 ay *" Slope | [eds (oes) tae So ]** pr EvEO—S) 1 KE. of Rigkd cateder. Hors £7 & athe toto -ene KC 6 | t= moment of nection é ‘ Fr above wowe function P's a fanckion ob 2 cooadinehes Ou Dp. £0 te waue function now can beaten ag ; y= 90.) = Ele). Cem Hore the two fanckion, ara independent of cach other, tae varviakl 23 can he separcafes by the separation variable method Substituting Yas , P(e,g) above 94% woe gel; > Te 2 fuine-2 4 a 7 | ino 30 (soos) 4 SF F Joey | habs acre aD Ti op wacomes 5 2s 7 Lhe ds (0%) ply the 04” hy wnt S 2] 085 60) ten oh ta hare -¥n9-2-(aing 206) + Of6)_ Fe > deg). ¥n0-3-(ane- 28ce) + Re + Psin*®.O¢e).Pcg) =O Divinoy the above 29" Cy Do) weg ; | % M2 2 fing 2606) .1_ Phroy . 7a ho ah Lota oe ab. aOup 2 - by om ap (9 S89) +P O88 = “Eo aE 3m that yuakion we fird| that LHS. ctepencls en 6 & 6 ond bg using the matted of separcalion of vaxabtes. a: = Yen =0 ay =I +R SF ] 96) Fog Pemdagr® AHS aeporcls upon d- Sowe nae to separate 9, vonddll 1 osubttitule as 1. SMe) _ Se ' dao 1 do " ? gee “aon. 1 Ore > FO ym™heg) -0 —O Soe The genercal sdubion ‘ber the ame) 09" ‘8 3 Beg = No im] Whore 5 N= nermatixabion convlard epg “Ve 'Q)” varies Fream © to aan peli condition we yet 5 © deo). o"tg) Ad = 4 34 naire enim te = 4 DI rdgead SNE Wars PN* = ap 77 ean = fa | is cated magnehe 4 is similiar to the parctrle moving in at rung sadkaatro? west ib we pave’ yoesgond of 1g will be mopeaker as 5 Ir +h= Thus 5 eo) = become 5 a fp So dca) iE a Te follows the eapreesaion | gi So, acecosding 40 Euler ’s ceule ; Thun et 2T = ws Arm + isin Om = 1 New ; From ayn on a sy SIRE. 2 ser 2) ) 4B sinre = n> 7 66) 0& (ane oe ) 7 Sey 06 TM) where 5 m=O. £4, 2229- quantun Scanned with CamScanner ro. of than Gg Com+d). Then woe 24”, of pencontctt 2 gimd 1 ataCan+ 6) sine, 2 wine Se) ) pee O

TE fe tmportant te mote maki Im] 2 2 1-2. te wolua, ve HPs 4 [0C0r1) FA] Pew ~0 Bpayayseaninals be oe han “L!, mesauae if thee ae, ais value of [ra] > & ,Shan the valu of atotiabed Legendia, By Legenduc 24% we can Find cut the solution of © 24> | polynomial will pecoms eqpol te xO. fore conversion ,of @ e4% to Legenda: 247 we have to Thuy the @ eq” net bocomes 5 ake following subst tating as + non z Oe) = NL) fel yg —O (i= 24) AP) a da™ Scanned with CamScanner a) 1 = 105d 4 zattee jogres cmrO pp YL IS2e = HNO Whore 5 N (gm) = aga) oe @® da= -sinedd (Rar vem), u w Rea = 68) 7 Bs On wubdtitakings thy in or @® 5 2 _ doy, 00 ~ sing S - - fom 2 ae a © 30 = So .* Se “fae Vi a ee | = = 2 oe fe ee) a aye callte e B, On substi tubing these volursin egn@ we gek 3 Le eee ve ee ee ms Oand d, we hare, Ona) fe am Sha +(°- 25) P= —O ‘a ica gk the wreteepondingy mexpatkive, wave ? It will be ozactt Sengen dere, funchions . The total. wave Feanckion “of- raged notes 5 ay" ty B= LCL4). Now solution of Sengendor of) is ; Y¢0,6) = O(6)- ca), f fh pe ee 4 PM og = UE x an Px? —@ of[ Stet Carey“ pl (1 gine aa az (Cetin) Te) *| atr te dope. aed ae ae Tha is the total Wave fanckion for rudid remtore °. ‘a! 'm. is : where ty ee where Led bbe a) ah These burch 5] nf. EF catant oon ware Rencllon re. it must be well » Ht dy are alto oi lon ¢ = bohawed. CFinfle .Ctinusuy , ringl, values). THis is he noludion of Ragen dere Peigronial whore stubions | > Some of dha wane Functions of" Rigid rotor pes di arce. given, O8 5 volun of 2? ar afven as hatlows! ™ = ‘. ° Pe ae a ti When 2-0 5 4° 09,0) Aye Xyar one " 1 (324 L=4 5 (0,0) = Sing! Pa a)= x Ch 1) Tr 829 = & (923-32) haa stmt=0 5 #8 (0.9) = Verse a(t) = ge (2521 ~302743/) beg 5m +225 47 .g) =F LE sore? ‘OF scanned wth OnEN Scorer\ 5 Mle 4, Yr L080) = oe fou U2, Im) -0 5 WE (0.0) Ve (Geet) ob Regie reotutor colutater| 802 TE a fin onde’ Newdotal oneegy » as fellows :- av we have token; B= ACU) & BH Thus 3 L004 1) = SOA TE me gee WAC) pe 01203 an BQuonkun Mechanical Thaabment- fixe H-atom :— “Riz Uealom ie a mead chemteat swvtomn , SL has a ruckus ontainins ona protan and? one, & which shel nucleus in Sst orckit The H-atom Geeulake orcun' ea two partie sytem such as aproton & on o- The Sehradinguvs wane apotion fou y-atem nod con be wreitker 08 3 Ay=ey —O wait Lee. 409) The Hanglionian oparcotore CH) neces ww fo ba definite ovecty. The ob : “y'-atom cmsists of two KE foun ont fom prot (on) rucleos & another. hes & ga ects” Jo this there iso RE tocm ahich the force of othackton boekuoen ruckus & 2-. Thus uring tc the Sdhodinged” wae oyran be writlon as 5 7 Ay -ey 7G+0)y sey | Tha. PE cporcafore © is raprnenbed ar 5 | > 0 = Gy?) |? = | | Where Ze =ch ae rade arimie 2 box tle & 90 on. \ 4 7 =. Were Ie PE teem is —¥0 dut to forte of abiraction. bekueen, spvely changed ruclus & the 2~ The attraction terem lowers she oneegy © Home PC is —ve. Mew Scheodinger wave aq? joc H-ofem can be written as 5 tne mt Hy erie] ee Wore w=ey n —® free Bm, | Aner Wore se? = Oe, Oy * bez tage Pape —< de Ze (Ho, Yo Ze ane cartesian co-ondinakes of 2) qe 2. ee a hina Oxy Yq Oz (dorm 2m ara caxterian coronas ty = rcs me = mass of @ < ° leur ae to pcatem cents of two por 5 dy TE the H-atom move or tuch preem ont poink fo onohec thon its energey will bo catlecl os rans tational gnercqg « GF noregey of @- telakive 4o the nucleus ig . tecknenic er nergy Thos + [Etat = The. corerumpondiney wave Function bere thee fae kin of oneregy, will w Ve ber liane toy ae for. tabional cnensyy te Thus 3] = Ye. Ye | Substteking, tha e949 @ 5 decteonic + Etransiakional mh gt 2 ag gf 2e! (ie © eatm, MZ =e Verte ; =(E, +& ) ee —@O Thu eq” can ot be casi -( oar re arabed att josey tal has been seporcakco| ma Gea Ue. ger | TT ‘OF scanned with OREN Scanner Scanned with CamScannertwo le problem «4 te be eeducadl 40 Breer an tg have 0 define the coudnale of cankte of mam. Tho canker of mans ® the place of adorn where the whole mass is conantnated. Thus in the translational mation it & the conlee of mass thal moves, Now “tha co-adinafes oy cenkree of man oct Abbinad og Zam .Tha Xem , Yom & Zom cure Abad cy 5 Xem, Yom» Xun = %eMe +X Mn me +My Yom = Yeme + ¥aIMq ) Mg +My Zon 2 ZeMe+ Zan _ Meta Wa cevdinabes of cm are repeesented in tenms of tr co-mdinakes of nuckeus & o- along with theire rexpackive, Noy X,¥,2 ame the co-osdinater of e- relative to the nuidleus in one parctile septom . Whore $ X = Xe —Xn Y= Ye-7Yn fe Z=Ze-Z, Fi Taking. these 044 info connducaken , the Schovdingpe’ wore "eq" becomes informs of- reoduted mars a8 5 ae 7% bsg @ 2 ? ing Vo tN a Wen Vag, Wena 5M = Met My readussol mors Le GR Sian sey oe ds ty im Ve eg, Nat 3 Vays | | 3M vay ~ Me.my TES Toye = Laplacian oparatere in taunt of x,y and Zz, she modifizol og% row becomes =( C0 + &e ) We. Wy — @) > [a (+ Se) 2 Jen an OM A) 4 Bare =(Eo+ Ce Ye. —@ Dividing the whole 9m by Ye x He gan oft 5 Scanned with CamScanner SB ln fe abe Elite Bye He ene Deve Vege e — Se =Ee+& —@ Thus he Schreedingerc 4 wove sypabion is mees sopaeabed inte wave 00,7 auch” 08 5 (@) —h* yt 2 = & ore Tye Wem He + —@ @® aw y tH vy, wer _ -. # Hie gee ~ be @® ? > > 7 “Wis is fore electtanic motion of e- relative to the rclous The 29"@ is called a8 Schreodi Wave Eqyation fore translation al motion where canbree of mas ie movi ig. treonslalimat 24% fore H-atom C4"@ vs calteg d dleckwnie Schad Wewe, e9" for: H-atom. Ia electronic Scheeh neni wane, eapatton thi rade mast coma inthe 24% Grace oy ’s treomilatrena! une ea). sho. total mast comes, On solving the etichonic chao dinger: wove eq acer the ui wie Ye & the “reonalab ere Sdhreodin. Wave & fon giver us the votus of Ye oo The owt latimal’ Cohadingores Wave ayation V's mo ore Lun Sra So pertepaben particl i BB-bor Now we nave'to fied out the solution foe dlachconic. Schrockingp Wee Equation . ‘OF scanned ith OREN Scanner