Science Selection Exam Notes
Science Selection Exam Notes
What is a fossil?
Fossils are the preserved evidence in rocks or soils of organisms that once
existed on Earth. Palaeontology is the study of past life, especially fossils.
Palaeontologists are scientists who reconstruct past environments using fossils
and geology.
The Fossil Record
Lists all the species of living organisms that have been found as fossils, their
location and relative age. This record can be thought of as the Earth’s timeline.
The soft parts of organisms decay much faster than the hard parts and so it is
extremely rare for soft parts to be preserved. Hard objects such as skeletons,
shells, teeth and wood are most commonly found as fossils. Hence fossils of
dinosaurs, crabs and trees are more likely to be found than fossils for slugs.
Fossil Formation
1. Ammonite dies and falls to the bottom of the sea. It’s covered by
sediments and protected from being eaten. Soft parts decay, leaving
only the shell.
2. More sediment covers and squeezes the shell. Shell may remain or be
replaced with minerals, which seep into solution before shell dissolves.
3. Movements in crust may thrust the layer of sedimentary rock upwards.
4. Weathering and erosion may wear away some part of the rock, exposing
the fossil.
Types of Fossils
Many types of fossils can occur due to the different ways in which they form.
Types of organisms also affect what type of fossil it will become. Fossils can be
classified in different ways, including:
- Original
- Replacement
- Carbon film
- Indirect
Original Fossils
Original fossils form when a part of the organism is preserved, with its
chemical composition being about the same as it was when it was living.
Original fossils commonly include shelled sea creatures and vertebrates.
Replacement Fossils
A replacement fossil forms when a part of the organism is chemically changed
into another mineral. This takes a long time to happen so most of these fossils
date back to over 60 million years. If the material being replaced and fossilised
is wood, then scientists refer to the wood as being petrified.
Carbon Film Fossils
Carbon film fossils occur when the dead body partially decays and leaves a
thin black deposit of carbon.
Indirect Fossils
Indirect fossils (trace fossils) are not part of the organism itself, but instead,
preserved remains of things such as imprints of the body, burrows and
fossilised dung (corpolites). A mould is usually an imprint left in the rock,
showing the outside of an organism. A mould is a ‘negative image’, meaning
that it is space when there is no body. It is possible to have a mould of the
inside of an organism. This is referred to as an internal mould. A cast forms
when an organism in rock decomposes and the space in the rock fills with soil
and turns to rock. This leaves a copy of the outside of the organism in a solid
piece of rock. This is a positive image and is a 3D model of what the organism
looked like while it was alive.
Index Fossil Criteria
To be used as an index fossil, the species must:
- Have been fairly widespread
- Have lived in a narrow period of time
- Haven been abundant
- Be easy to identify
Index fossils allow rock layers in different locations to be compared and dated
(stratigraphy).
Two excellent examples of index fossils are trilobites and ammonites.
Fluorine Analysis
Fluorine dating is another relative dating method. It compares the amounts of
fluorine in different bones found in the same rock. Bones absorb fluorine from
the water in the surrounding rock. It happens at a slow rate and depends on
how much is in the water surrounding the bone.
Absolute Dating
Radioactive elements decay at a known rate, so they are used to date fossils
and objects from long ago. This dating method is much more reliable than
relative dating, as it gives scientists an estimated age. This decay allows
scientists to estimate how long ago the rock was laid down. From a decay
curve, the element’s half-life can be estimated.
Tree Rings
Using tree rings is another useful method of absolute dating for dating wood.
This method can give a date to several thousand years ago. Tree ring dating
involves counting growth rings in the woody trunks of trees.
Creating a Time Scale
Palaeontologists have constructed the geological time scale which shows past
life and geology found in strata around the world.
Relative Dates
Geological time scale was constructed by combining relative and absolute
dates. Stratigraphy and index fossils of many different plants and animals
showed that a particular time period covered by a set of fossils was a
geological period.
Absolute Dates
Development of techniques such as radioactive carbon dating allowed
palaeontologists for the first time to calculate the actual age of each index
fossil and rocks they were found in. These dates were added to the fossil
sequence. The combined information from both became the geological time
scale. It represents time all the way back since Earth’s formation 4.5 billion
years ago.
The Earliest Organisms
Despite the lack of fossil evidence, palaeontologists concluded that the first
forms of life on Earth were single-celled organisms (bacteria). All the oldest
fossils found have been from the oceans, suggesting life began there. Most
ancient organisms for which there are fossil records were cyanobacteria. They
lived in shallow waters of early seas, where they formed stromatolites.
Vertebrate Fossil History
Vertebrates are animals with a bony inner skeleton and include fish,
amphibians, reptiles, birds and mammals. The earliest known vertebrate
ancestors were primitive fish from the Cambrian era, dated back to 525 million
years ago.
Moving from Water to Land
Life started to spread from sea to land. Insects and vertebrates followed soon
after.
Lobe-Finned Fish
Palaeontologists are fairly sure that the lobe-finned fish are the ancestors of
the group of life forms that finally made the move to land.
Land Vertebrates
The first land vertebrates in the fossil record were amphibian ancestors. They
were the first of the tetrapods. Living tetrapods are now classified into
amphibians, reptiles, birds and mammals.
Birds
Bird-like animals appear in the Jurassic period around 200 million years ago.
The oldest true birds date from about 110 million years ago. Birds shared
many features with a small group of dinosaurs called theropods.
Mammals
The earliest mammal-like fossils appeared in the Triassic period, 190 million
years ago.
Glossary Terms - Chapter 2
Carbon film fossil: When the dead body partially decays and leaves a thin
black deposit of carbon.
Cast: When an organism in rock decomposes and the space in the rock fills with
soil that turns to rock.
Ediacaran period: Time period on the geological time scale when complex life
forms were developing.
Fossil record: A list showing the classification of all the species that have been
found as fossils.
Fossils: The preserved evidence in rocks or soils of organisms that were once
alive.
Indirect fossils: Preserved remains of things such as imprints of the body,
fossilised dung and burrows.
Mould: An imprint of the outside of the body in rock.
Original fossils: When a part of the organism such as a skeleton is preserved
and remains in its original form.
Palaeontologist: Scientist who studies prehistoric life.
Palaeontology: The study of prehistoric life.
Petrified: When wood is replaced by minerals and fossilised.
Replacement fossil: When a part of the organism is changed into another
mineral.
Absolute dating: A way of determining the actual age of rocks and fossils.
Fluorine dating: Finding a relative age for two bones from the same area by
comparing the amount of fluorine in them.
Half-life: The time it takes for half of a radioactive sample to decay.
Index fossil: Fossils that can be used to compare the relative age of rock strata
in different locations.
Isotope: Different forms of the same element with different numbers of
neutrons, and so different atomic masses.
Relative dating: Comparing the age of one fossil or rock against another to see
if one is older or younger than the other.
Strata: Layers of sedimentary rock.
Stratigraphy: Comparing strata in different locations to determine their relative
ages.
Tree ring dating: Counting growth rings in the woody trunks of trees to find
their age.
Archaeopteryx: Bird-like dinosaur that had feathers.
Coelacanths: Ancient group of fish related to the lobe-finned fish ancestors of
the amphibians.
Ectothermic: Depending on surroundings for warmth.
Endothermic: Able to control body temperature.
Geological time scale: A scale showing the history of life and geology.
Ichthyostega: Early amphibians which were the first of the group called
tetrapods.
Lobe-finned fish: Fish with bones in their fins similar to land animals.
Lungfish: Relatives of the lobe-finned fish that made the move from water to
land.
Primates: Orders of mammals to which humans belong.
Stromatolite: Circular rocky structures thought to be the earliest evidence of
living organisms called the cyanobacteria.
Tetrapods: Land animals with four limbs. Living tetrapods are now classified as
amphibians, reptiles, birds and mammals.
Theropods: A dinosaur group closely related to birds and from which birds
probably developed.
Measuring Speed
There are various ways to measure speed, for instance -
· Fixed speed uses 2 electronic sensors- travelling over the first sensor is
timed to travel over the second sensor. Speed of a car can then be determined.
Light gates used for sporting events- skiing. Uses a sensor to trigger an
electronic timing mechanism when an object breaks through the sensor.
· Multiflash photograph shows diff. stages in a motion. The spacing
between each image gives some idea of speed.
Increase in spacing shows acceleration.
· A ticker timer is another device that can
be used to measure speed. When the timer is
attached to an object moving in a straight line,
dots record its motion.
Forms of Energy
· Energy is required to make things happen. Energy is needed whenever
something moves.
· There are many types of energy, such as kinetic, sound, light, heat and
electrical. Objects that have the potential to use energy possess potential
energy.
· Energy can be passed or transferred from one object to another.
· Energy can also be changed or transformed from one form to another.
Kinetic Energy
· The energy of a moving object is called kinetic energy. The amount of kinetic
energy an object has depends on its mass and speed.
· If an object’s mass doubles, its kinetic energy doubles too. However, if an
object’s speed doubles, its kinetic energy increases by a factor of four.
Potential Energy
Potential energy is energy that an object has because of its position or
structure. Potential energy is also called stored energy.
Gravitational Potential Energy
· An object positioned above the ground has gravitational potential energy.
· An object positioned high above the ground has greater gravitational
potential energy than the same object found closer to the ground.
· The greater the mass of an object, the greater its gravitational potential
energy would be.
Elastic Potential Energy
· A stretched or compressed spring has elastic potential energy.
· This energy is converted into kinetic energy when the spring is released and
returns to its original shape.
Conservation of Energy
The law of conservation of energy states that
energy may be transferred from one object to
another, but it is never created or destroyed.
Energy Efficiency
Although energy is always conserved in an
energy transfer, a little energy is usually “lost”
because it changes into non-useful forms such
as heat and sound. For example:
Chapter 6
- Global Systems
6.1- Earth’s Spheres
Vocab/Unit Glossary
Atmosphere: The layer of gases surrounding the planet.
Biosphere: All living things on Earth.
Carbon cycle: The process by which carbon is recycled through the soil, water,
living things and the atmosphere.
Denitrifying bacteria: Bacteria that convert nitrates back into gaseous nitrogen
(N2), which is then released back into the atmosphere.
Fossil fuels: Fuels that contain the carbon of plants and animals that died and
were preserved millions of years ago.
Fossils: The preserved remains of once living organisms.
Hydrosphere: All the liquid water on Earth’s surface.
Liquefaction: A process in which soils lose their strength and behave as a
liquid.
Lithosphere: The landmasses on Earth.
Nitrogen cycle: The process through which nitrogen cycles between the living
and non-living environments.
Nitrogen-fixing bacteria: Bacteria that absorb nitrogen from the air and
convert it into ammonia and then into nitrates.
Photosynthesis: Process by which green plants and some other organisms use
sunlight to synthesise glucose from carbon dioxide and water; it generally
involves the green pigment chlorophyll and generates oxygen as a by-product.
Respiration: Process occurring within living cells by which chemical energy is
released in a series of metabolic steps involving the consumption of oxygen
and the release of carbon dioxide and water.
Sustainable ecosystems: Ecosystems that are diverse and provide for the needs
of the organisms that live there.
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The Biosphere
The biosphere includes all parts of the Earth’s surface and atmosphere where
living things exist. It is the sum of all Earth’s ecosystems. It’s where the other
spheres of Earth interact:
- The land (lithosphere) interacts with the water (hydrosphere).
- The land interacts with the air (atmosphere).
- Living things interact with the land, water and air.
Natural Changes
Major natural events such as earthquakes, volcanic eruptions and tropical
cyclones have shaped Earth. These natural events influence the atmosphere,
lithosphere and hydrosphere. They also cause the different spheres to interact
in different ways.
Earthquakes
Depending on their severity, earthquakes may cause parts of the lithosphere to
move apart, move together, rise or subside (drop). This movement may cause
large cracks to appear or land to increase in height. The movement may cause
landslides or mudslides. Landslides and mudslides tear down forests and any
other vegetation in their path. Earthquakes may also cause liquefaction, which
is when saturated sandy soils lose their structure and behave as a liquid.
In saturated soils, water fills the spaces between the particles. When an
earthquake compresses the soil, it puts the water in it under pressure. This
causes the water to squeeze out from between the particles, large quantities
of water/soil bubble up through the layers and flow over the surface like a
liquid.
Earthquakes have little effect on the atmosphere, however have significant
effects on the hydrosphere. They can cause tsunamis if they happen out at sea.
Earthquakes on land can:
- Change the course of rivers
- Cause landslides and rock falls that block rivers, creating new lakes
- Destroy dams, releasing large amounts of water in a huge flood down a
valley.
A mudslide is mud or other material that’s fallen down a hillside. A landslide
is the collapse of earth or rocks from a mountain or cliff.
Tsunamis
The 2011 Japanese tsunami was the effect of an underwater earthquake that
caused a huge shift in tectonic plates in the Pacific Ocean. Since that
catastrophic event, Pacific Nations have updated their tsunami warning
systems and have contingency plans in place. This involves computer
modelling of Earth’s crust and using it to predict tsunami severity.
Volcanic Eruptions
Volcanic eruptions have short term and long term effects on the atmosphere
and environment. Short term effects include:
- Sending large ash clouds into the atmosphere, causing heavy rain and
spectacular lighting. Toxic gases that are released may cause acid rain.
Sometimes, rain occurs because the ash particles allow water vapour to
condense around them and form rain droplets. The probable cause of the
lightning is the collision of ash and air particles that become charged and are
then forced apart. Some areas of the atmosphere become negatively charged
while others become positively charged. When the difference in charge and the
voltage it creates becomes high enough, a flow of electric charge occurs. This is
lightning.
Long term effects of volcanic eruptions include:
- The clouds of ash in the atmosphere reduce the amount of sunlight
reaching the surface, which has a cooling effect on Earth, killing crops
and livestock.
- It has an impact on the biosphere, as it may burn vegetation.
- It could form new land, but it would be too hot, so seeds and pores
would take many years to germinate.
- Toxic gases and ash suffocate organisms.
Despite the multitude of impacts of volcanic eruptions, many people choose to
live near volcanoes, as volcanic soil is nutrient-rich and fertile due to the
minerals released from the eruption. It is ideal for growing crops.
Tropical Cyclones
Tropical cyclones are caused by intense low pressure atmospheric systems that
develop in the warm tropics when sea surface temperatures are above 26.5
degrees C. Evaporation above the warm water causes clouds to form, and the
low air pressure causes the clouds to spiral upwards forming very large and
high clouds. These spirals can become very destructive. Tropical cyclones
produce very heavy rain and wind speed of 63 km/h to more than 200 km/h.
Heavy rainfall associated with tropical cyclones continues after the tropical
cyclone has moved inland and decayed. The rain causes rivers to flood and the
effects extend far beyond the area of the cyclone.
Impacts of cyclones can include storm surges, floods, torrential rain, erosion of
land and waterways, blocked rivers, habitat destruction and more.
A storm surge is when the tide level of the sea increases due to winds and low
pressure systems.
Nitrogen Cycle
The nitrogen cycle is an important natural cycle for living things, as nitrogen is
an important element in proteins. Air is 78% nitrogen, but most living things
can’t use it in the form of gas. Plants use nitrogen compounds from the soil.
Animals are consumers that obtain their nitrogen by eating plants or other
animals. Some bacteria, such as decomposers and nitrogen-fixing bacteria,
make nitrogen available to other living things. They do this by converting it
into ammonia and then intrates that plants can use. Other bacteria, known as
denitrifying bacteria convert nitrates back into gaseous nitrogen (N2). This is
then released back into the atmosphere.
- Nitrification is the process by which ammonium (NH4+) or ammonia (NH3)
is oxidised into nitrite (NO2-) and nitrates (NO3-).
- Nitrifying bacteria convert ammonia to nitrates in the soil.
- Nitrogen fixing bacteria convert nitrogen gas into nitrates in the soil or
root nodules.
- Denitrifying bacteria convert nitrates into nitrogen gas (N2).
- Denitrification is the reverse process of nitrification. Nitrates are reduced
to nitrates, then nitrites, then nitrogen gas and ammonia.
- Legumes are a group of plants with root nodules.
Steps of Nitrogen Cycle
1. Nitrogen fixing bacteria absorb nitrogen gas from the air in the soil and
make it into ammonia (NH3).
2. Nitrifying bacteria then convert the ammonia into nitrates. This process
is called nitrification.
3. Other species of bacteria change the ammonia into chemicals called
nitrites and then into nitrates.
4. Nitrates are absorbed by plants through the roots and are used to
construct protein and other compounds.
5. Animals consume plants, take in nitrogen to construct proteins and
other compounds that become part of the animal.
6. Some nitrates
that aren’t
absorbed by
plants can be
turned back into
atmospheric
nitrogen. This is
denitrification.
Carbon Cycle
The carbon cycle is
essential for life on
Earth. Carbon is found in all living things, and in their dead bodies and wastes.
It is part of the carbohydrates, fats, proteins, vitamins and DNA found in cells,
tissues and organs. Carbon is also found in the atmosphere as carbon dioxide
gas (CO2).
Carbon dioxide is used in photosynthesis when plants combine it with the
hydrogen from water to form glucose.
Organic means something contains carbon.
Fossil Fuels
Fossils are the preserved remains of once lying organisms. Fossil fuels such as
coal and oil contain carbon of dead plants and animals preserved over
millions of years. Burning fossil fuels releases carbon back into the carbon
cycle.
The general chemical formula for complete combustion is CxHy + O2 → CO2 +
H2O. The word equation is hydrocarbon + oxygen → carbon dioxide + water.
The general chemical formula for incomplete combustion is CxHy + O2 → CO +
H2O or CxHy + O2 → C + H2O. The word equations are hydrocarbon + oxygen →
carbon monoxide + water, or hydrocarbon + oxygen → carbon + water.
Long-Term Stores of Carbon
Carbon is stored in many places and forms across Earth. It is stored in fossil
fuels, rainforest trees, sediments and much more. Calcium carbonate (CaCO3)
or limestone is the oldest and largest long-term store of carbon on Earth.
Limestone is a sedimentary rock usually made from the shells of molluscs and
other marine organisms.
Water Cycle
The water on Earth is continuously recycled in the water cycle.
1. The evaporation process is driven by the sun. AS the sun interacts with
water on the surface of the ocean, water becomes water vapour.
2. Condensation causes water vapour to become water droplets to form
clouds.
3. Precipitation describes any liquid or solid water that falls to the Earth as
a result of condensation in the atmosphere.
4. Liquid water moves across the land in a variety of ways. Water runs off
mountain surfaces and collects in rivers and oceans.
5. Oceans and lakes collect water that has fallen as a result of
precipitation or that is a result of surface runoff.
6. Transpiration is the process of water vapour being released from plants
and soil. Plants release water vapour through microscopic pores called
stomata.
Proton +1 1
Neutron 0 1
Electron -1 1/1800
Electron Shells
First electron shell is closest to the nucleus and so the attraction between the
nucleus and the first-shell electrons is the strongest. This is the lowest energy
level for electrons. Electrons in the outer shell have the highest energy.
Electron Configuration
Electron configuration shows how the electrons are arranged in the shells of
an atom when it is in its grouped state. The below image shows the electron
configuration for the first 20 elements.
Elements
Atoms are the smallest unit of an element and each element is made up of
atoms that are the same. The atoms have the same number of protons in the
nuclei and therefore the same number of electrons around them.
The number of protons in the nucleus determines the element to which the
atom belongs. The chemical formula of a compound tells you what elements
make it up and in what proportions. H2O is made up of two hydrogen atoms
and one oxygen atom.
Compounds
Compounds are also considered to be pure substances. However, their building
blocks are made up of two or more different types of atom.
Atoms are chemically bonded together by chemical reactions that lose or gain
or share electrons. Compounds have very different properties to the elements
that make them up.
Molecules and Lattices
Atoms don’t normally exist by themselves but exist in molecules or crystal
lattices. Molecules are small groups of bonded atoms. In a crystal lattice,
atoms keep bonding together to make large structures.
Atomic Number
The number of protons in the nucleus is known as the atomic number. Atomic
number = number of protons.
Mass Number
The total number of particles in the nucleus (protons and neutrons) of an atom
is called its mass number. Mass number = protons + neutrons in nucleus
Isotopes
Atoms belonging to the
same element always have
the same number of
protons in their nuclei and
same atomic number.
However they can have
different numbers of neutrons. This gives the atoms different mass numbers
(isotopes).
Arranging the Elements
The periodic table lists all of the known elements in order of increasing atomic
number. The periodic table lists the elements according to their atomic number
but it also arranges them in rows and columns. The rows are called periods
and are numbered from 1-7. The columns are called groups, numbered 1-18.
The arrangements of the periodic table into columns and rows places elements
with similar physical and chemical properties in the same group. A group is a
column in the periodic table but can be thought of as a set of elements that
act the same. Periodic table has three special blocks of elements known as
transition metals, lanthanides and actinides.
Group 1: Alkali Metals
Group 1 elements form +1 ions. They are far too reactive to be found naturally
in pure form. They have typical metallic properties and display similar extreme
chemical behaviour. Lithium, sodium and potassium are less dense than water,
which allows them to float on it. They all react with chlorine to form white
salts.
All alkali metals react violently with water, producing an alkaline or basic
solution and hydrogen gas, which sometimes ignites due to the heat products.
Group 2: Alkaline Earth Metals
Group 2 elements are alkaline earth metals. They are all metals and all act in
a similar (slightly less reactive) way to group 1 elements. When they react,
they form +2 ions. They are shiny, silvery-white and have low melting and
boiling points.
Group 14
ELements of group 14 display a wide range of properties. The group begins
with non-metal carbon, moves through the metalloids silicon and germanium
and finishes with the metallic elements tin and lead.
Pure carbon exists in several different forms (allotropes), the most common
being amorphous carbon, diamond, graphite and buckyball.
An allotrope is the property of some chemical elements to exist in two or more
different forms.
Substances that have carbon skeletons are known as organic substances and
their molecules are organic molecules.
Group 17: Halogens
Atoms of halogens form ions with a charge of -1 and are not found in nature
in pure form, but are found in various types of sea salts. As you move down
the group, the elements become larger and less reactive. Halogens are all
diatomic, and produce coloured and poisonous vapours.
Group 18: Noble gases
Noble gases are also known as inert gases. They are all colourless and occur
naturally in the atmosphere. Distillation is used to separate them from liquid
air. They are incredibly stable, only reacting under rare and extreme conditions.
Helium is less dense than air. As you move down group 18, the noble gases
become progressively denser and this makes them heavier.
Transition Metals
Groups 3-12 are all metals and include many colourful, useful and valuable
elements. Transition metals have very similar properties, and they all tend to
have high melting and boiling points and are all relatively hard.
Predicting Chemical Equations
ELements of the same group tend to react in very similar ways so a balanced
chemical equation for one element can be used to predict the reactions for
other elements in the group.
Chemical Equations
Chemical equations describe what happens in a chemical reaction.
Reactants → Products (Arrow means rearrange to form)
Word Equations
Replacing reactants and products with the chemical name of each substance
gives you a word equation. For example:
Calcium carbonate + sulfuric acid → calcium sulphate + water + carbon dioxide
gas
Exothermic and Endothermic Reaction
Chemical reactions that release energy in the form of heat or light are referred
to as exothermic. Exothermic reactions are referred to as flames, explosions or
fireworks. For example, octane in petrol explodes, releasing energy as heat
and a flash of light. The word equation for this reaction is:
Octane + oxygen gas → Carbon dioxide + water vapour + energy
2C8H18 + 25O2 → 16CO2 + 18H2O + Energy
Chemical reactions that absorb energy are called endothermic. They usually
feel cold as they absorb heat energy from their surroundings.
Reactions with Oxygen
Reactions that have oxygen as one of the reactants tend to be exothermic.
These reactions have oxygen as one of the reactants. They are:
- Combustion
- Respiration
- Corrosion
Combustion Reactions
Combustion describes any chemical reaction in which substances burn in
oxygen gas to produce light and heat. Hydrogen fuel cells release energy
because of the combustion reaction with oxygen, which produces water vapour.
Hydrogen gas + Oxygen Gas → Water Vapour
2H2 + O2 → 2H2O
Very reactive metals such as sodium and magnesium can also combust in
oxygen. When magnesium is burnt, it combines with the oxygen in the air to
produce magnesium oxide.
2Mg + O2 → 2MgO
Combustion is a limited oxygen supply is incomplete combustion.
Butane + Oxygen → Carbon Monoxide + Water
2C4H10 + 9O2 → 8CO + 10H2O
Respiration
Respiration is a chemical reaction that goes on inside cells of all living things.
It involves the combination of glucose with oxygen to produce carbon dioxide
and water. Respiration is a slow process compared to combustion.
Corrosion
Most metals will combine with oxygen gas in the air to form metal oxides.
Metal + Oxygen → Metal oxide
The most common example of corrosion is the rusting of iron and its alloy,
steel. Corrosion reactions are exothermic.
Iron + Oxygen → Iron (iii) oxide
4Fe + 3O2 → 2Fe2O3
Decomposition Reactions
Decomposition reactions are reactions in which one reactant breaks apart to
form several products. The reactant is said to decompose. The general word
equation for decomposition reaction is as follows:
XY → X + Y
An everyday example of such a reaction is the chemical reaction which puts the
fizz in soft drinks. When carbonic acid decomposes, it forms water and bubbles
of carbon dioxide gas. The carbon dioxide gas remains dissolved in the drink
until the drink is removed. The chemical and word equation for this equation is:
Carbonic acid → Water + Carbon dioxide gas
H2CO3 → H2O + CO2
Some substances will only decompose when heated. This is known as thermal
decomposition. Metal carbonates and metal hydrogen carbonates both
undergo thermal decomposition when heated. For example when sodium
hydrogen carbonate is heated above 50 degrees C, it decomposes to form
sodium carbonate, carbon dioxide and water. The equation is:
Sodium hydrogen carbonate → Sodium carbonate + carbon dioxide + water
2NaHCO3 → Na2CO3 + CO2 + H2O
Thermal decomposition of sodium azide (NaN3) is a chemical reaction which
inflated vehicle airbags. When heated, it decomposes into sodium metal and
nitrogen gas. The equation is:
Sodium azide → sodium + nitrogen gas
2NaN3 → 2Na + 3N2
100 grams of sodium azide can produce around 56 litres of nitrogen gas in
under 0.03 seconds. This reaction rapidly inflates the airbag in the event of a
collision.
Decomposition Reactions
Combination reactions occur when two reactants combine to form a single
product. The general equation for a combination reaction can be written as:
X + Y → XY
An example is the creation of hydrogen chloride gas, which is then processed
to create hydrochloric acid. The equation is:
Hydrogen gas + Chlorine gas → Hydrogen chloride gas
H2 + Cl2 → 2HCl
Precipitation Reactions
Occasionally when two clear solutions are mixed together, they react to form
an insoluble solid. The solid is said to precipitate out of the solution. These
types of reactions are known as precipitation reactions.
Solubility
A precipitation reaction occurs when two soluble reactants combine to form an
insoluble product, which is the precipitate. A substance is said to be soluble if
it can dissolve. In precipitation reactions particles from two soluble compounds
mix together and some stick together to form an insoluble solid. The solid
precipitates out of the solution, making it murky. Usually, the solution clears as
the precipitate settles on the bottom.
Ionic Compounds
Cations are atoms that have lost electrons and thus have a positive charge.
Anions are atoms that have gained electrons and thus have a negative charge.
When ionic compounds dissolve, the cations and the anions break away from
the crystal lattice and spread evenly throughout the solvent.
The name of an ionic compound is simply the name of the cation followed by
the name of the anion. In the case where an atom can form more than one
type of ion, a Roman numeral is included in the name of the compound to
indicate the cation’s charge.
Ionic compounds have no overall charge, and are always charge neutral.
Hence the total charge on the cations balances the total charge on the anions.
Polyatomic ions are ions with more than one atom.
Solubility Table
Scientists use the solubility rules to predict if a precipitation reaction will occur
when two ionic solutions are mixed. Below is an example of a solubility table.
Using solubility rules, it’s
possible to predict what
happens when two ionic
solutions are mixed.
An example is below:
Potassium chloride solution +
silver nitrate solution →
potassium nitrate solution +
silver chloride solid
KCl + AgNO3 → KNO3 + AgCl
Acid Reactions
Another method of classifying
chemical reactions is based
on the type of reactants used
in the chemical reactions.
Acids are a common type of
reactant used in everyday
situations. There are several
types of chemical reactions
that use acids, including
neutralisation reactions,
acid-metal reactions and
acid-carbonate reactions.
Neutralisation Reactions
Neutralisation reactions occur
when an acid reacts with a
base. Examples of acids
include sulfuric acid (H2SO4), hydrochloric acid (HCl) and nitric acid (HNO3),
citric acid (C6H8O7), lactic acid (C3H6O3) and acetic acid (CH3COOH). Examples of
bases are sodium hydroxide (NaOH) and ammonia.
When an acid and base mix, they can neutralise each other. This is because the
hydrogen atoms (H+) from the acid combine with hydroxide ions (OH-) from the
base to form water (H2O), which is neutral. The general equation is:
Acid + base → salt + water
The term salt refers to ionic compounds that are produced through a chemical
reaction with an acid. An example is the following reaction:
The hydrogen ions from the sulfuric acid combine with the hydroxide ions to
form water molecules. This leaves the magnesium and sulphate ions. This is
the remaining salt, which is magnesium sulphate.
Heartburn is caused by an excess of acid in the stomach. It can be controlled
by a neutralisation reaction. Antacids are essentially bases in solid or liquid
form that neutralise the excess acid. This is why they relieve heartburn.
Acid-Metal Reactions
Acids react with metals to produce a salt and hydrogen gas. The general
equation for this type of reaction is:
- Study the second half of chapter 6.3 and 6.4 on your own
(sorry, it was just too much content for me).
- Practise lots of ‘explain’ and ‘describe’ questions, as the
selection exam is going to have a lot of those.
- Make sure you know Chapters 1,2 and 3 very well, as a large
chunk of the exam will be based around that, and you will get
3-5 mark questions about natural selection and evolution and
other biology related concepts, so make sure you practise
questions, and know the content very well.
- Know your scientific skills like the back of your hand, and
know validity, reliability and accuracy very well. Also, revise
other skills, such as writing up methods, aims, hypotheses,
drawing and reading tables, graphing and reading graphs, etc.
And make sure you use rulers for all diagrams, and use pencil
for all diagrams as well.
- Make sure you know your chemistry well, such as chemical
reactions, compounds, naming, solubility and precipitates,
factors affecting reaction rates (with explanations) and nuclear
chemistry (alpha, beta and gamma decay + nuclear chemistry
reactions).
- You will get questions about global systems, such as
questions about the carbon and water cycle, and the impacts
of global warming, etc, so go over global systems well.
- For all questions, answer with thorough detail, as it’s always
better to be safe than sorry.
- The science selection exam will be very application based, so
you need to know how to apply your knowledge. It’s not merely
vomiting out memorised things onto the page, you have to
know what you’re writing or doing, and why you’re doing it.