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Paint, Spray Aerosol (Bosny)

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Jordan Talaban
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2K views13 pages

Paint, Spray Aerosol (Bosny)

Uploaded by

Jordan Talaban
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF or read online on Scribd
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@ Bsn Safety Data Sheet ___ According to 1907/2006/EC (REACH).1272/2008EC (CLP) and GHS —__ 1 identification 1.1 Product identifier ‘Trade name: Article number: 1.2 Relevant identified use of the substance or mixture and uses advised a Application of the substance / the mixture Spray Paint 1.3 Details of the supplier of the Safety Data Sheet Manufacturer/Sup R.J.LONDON CHEMICAL INDUSTRIES CO.,LTD Further information obtainable from Technical Department "1 Enfigrgjeney telephone number (B82y STRUTS ext 18H = 2 Hazard(s) identification 2.4 Classification of the substance or mixture. Classification according to Regulation (EC) No. 1272/2008 (CLP) S GHS 04 gas cylinder Press.Gas -H280 Contains gas under pressure; may explode if heated. ® GHS02 Flame 1 Aerosol | H222—H229 Extremely flammable aerosol. Pressurized container. May burst if heated, a (GHS07 Exclamation Acute Tox.4 302, H312,H332 Harmful if swallowed., Harmful in contact with skin., Harmful if inhaled. ‘Skin init. 2 315 Causes skin irritation. Eye iit. 2 H319 Causes serious eye irritation STOTSE3 336 May cause drowsiness or dizziness. 2.2 Label elements GHS label elements ‘The product is classified and labeled according to the Globally Harmonized System (GHS). MSDS GHS 100% Acrylic spray RO1-260315 Hazard plctograms g ® Q ‘Gignel word Weming! Pressurized container + Hazard.determining components of Iabeling : Pressurleed container : protect from sunlight and do not expose to Lemmperetures exceeding 60 *0, Do not pierce or burn, even after use. Do not spray ona waked fame or any incandescent materia Hazard statements H280 Contain. gas under pressure; may explode it heated. 1222-1229 Extremely flammable aerosol. Pressurized container: May burst if heated. 11302. Harmful if swallowed, 1312. Harmful in contact with skin H318 Causes skin inilation. H319 Causes serious eye initation. 1332. Harmful i inhaled H336_ May catise drowsiness or dizziness. Precautionary statements 102 Keep out of reach of chiléren P103 Read Label before use. P210 Keep away from heal/sperks/open flames/hot surfaces. - No smoking. 211. Do not spray on an open flame or other ignition source, 251 Pressurized container: Do not pierce or bum, even after use. 260 Do not breathe mistivapors spray. P262 Do not get in eyes, on skin, or on clothing, 271 Use outdoors or in a well-ventilated area. P281_Use personal protective equipment as required. P3021P362 If on skin: Wash with plenty of water. P305+P336+P351 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact Lenses, if present and easy to do. Continue rinsing. P308+P313 IF exposed or concemed: Get medical advice/attention. P403+P233 Store in a well-ventilated place. Keep container tighily closed P405 Store locked up. P410+P412 Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F 501 Dispose of contents/container in accordance with localegional/nationalinternational regulations. 2.3 Other hazards Results of PBT and vPVB assessment PBT: Not applicable, ‘vPvB: Not applicable 3 Composition/information on ingredients 3.4 Chemical characterization: Mixtures 3.2 Description: Mixture of the substances listed below with nonhazardous additions. MSDS GHS 100% Acrylic spray RO1-260315 ~ Dangerous components: CAS No, Ingredients | “Aeetene———— as @ Frau. big 2, 4226 press. cas, 1280 10-45 Additional information : For the wording of the listed phases refer to section 16 MSDS GHS 100% Acrylic spray R01-260315 Domne nduce vomiting: immediately eall for medics help: ———————- 4 First-aid measures 4A Description of first ald measures General information: lake affected persons out into the fresh air. Aftor inhalation: Supply fresh air; coneult doctor in caee of complaints. Provide oxygen treatmant if affected nereon has difficulty breathing. In case of irregular breathing or respiratory arrest provide artificial respiration, In caeo of unconecioueness place pationt stably in eido poston for transportation. After skin contact: nnmediately wash with water and soap and nee thoroughly. If skin irritation continues, consult a doctor. After eye contact: Remove contact lenses if worn Rinse opened eye for several minutes under running water. If symptoms persist, consulta doctor. After swallowing: Unlikely route of exposure, Rinse out mouth and then drink plenty of water. ‘4.2 Most important symptoms and effects, both acute a Headache Dizziness Nausea ‘Gastric or intestinal disorders when ingested. Breathing difficulty Allergic reactions Coughing Irritant to skin and mucous membranes. Slight initant effect on eyes. Disorientation Danger Danger of impaired breathing, ‘Vapours may cause drowsiness and dizziness. Danger of disturbed cardiac rhythm. Danger of pulmonary edema. Repeated exposure may cause skin dryness or cracking Danger ot setious darnayo to heal by prolonged exposure. 4.3 Indication of any immediate medical attention and sp If swallowed, gastic irigation with added, activated carbon. Itnecessary oxygen respiration treatment. Medical supervision for at least 48 hours, If swallowed or in case of vomiting, danger of entering the lungs. ‘Treat skin and mucous membrane with antihistamine and corticold preparations. 5 Fire-fighting measures 5.1 Extinguishing media Suitable extinguishing agents: C02, extinguishing powder or sand. Fight larger fires with water spray or alcohol resistant foain, For safety reasons unsuitable extinguishing agents: Water stream. 5.2 Special hazards arising from the substance or mixture Danger of receptacles bursting because of high vapor pressure if heated Formation of toxic gases is possible during heating or in case offre. 5.3 Advice for firefighters device. Wear fully protective sut MSDS GHS 100% Acrylic spray RO1-260315 Additional information Eliminate all ignition sources if safe to do so. 6 Accidental release measures ‘Wear protective equipinent Keep unprotected prisons away Ensuire adequate ventilation. Keep away from Ignition sources, 6.2 Environmental precautions: Do not allow to enter sewers/ surface or ground water. 6.3 Methods and material for containment and cleaning up: Allow to evaporate. Dispose contaminated material as waste according to item 13. Ensure adequate ventilation. Send for recovery or disposal in suitable receptacles. 6.4 Reference to other sections ‘See Section 7 for information on safe handling. ‘See Section 8 for information on personal protection equipment. ‘See Section 13 for disposal information 7 Handling and storage 7.4 Precautions for safe handling Keep away from heat and direct suniight. Use only in well ventilated areas, Information about protection against explosions and fires: Do not spray onto @ naked flame or any Incandescent material Keep ignition sources away Do not smoke. 7.2 Conkitions for safe storage, including any incompatibilties, Storage: Protect against electrostatic charges. Requirements to be met by storerooms and receptacles: Pressurized container : protect from sunlight and do not expose to temperature exceeding 0 °C. Provide ventilation for receptacies. ‘Avoid storage near extreme heat, ignition sources or open flame. « Information about storage In one common storage facility: Store eway from foodstuffs, ‘Store away from oxidizing agents. Further information about storage conditions: Store in a cool place. Heat wil increase pressure and may lead to the receptacle bursting. 7.3 Specific end use (s): Do not pierce or burn, even after use ‘8 Exposure controls/personal protection Additional information about design of technical systems: No further data; see item 7. 8.1 Control parameters MSDS GHS 100% Acrylic spray RO1-260315 Components with limit values that require monitoring at the workplace: Hazardous Ingredient (s) Type ppm mgim® ‘Source Aeatone wa [1800] 360] Aco Xylene wa 100 ast AccIH Propane, Butane TWA 1000 - ACGIIT butyl Acetate TWA 200 6s acciH Ethyl Acstate WA 400 : AcolH 2-Butoxyethancl Twa 20 : cell 8.2 Exposure controls : Personal protective equipment: General protective and hygienic measures: ‘The usual precautionary measures for handling chemicals should be followed. Keep away from foodstuffs, beverages and feed. Wash hands boforo broaks and at the end of work. Do not inhale gases / fumes / aerosols. Avoid contact with the eyes and skin. Breathing equipment: Suitable respiratory protective device recommended. For spils, respiratory protection may be advisable Use suitable respiratory protective device in case of insufficient ventilation NIOSH or EN approved organic vapor respirator equipped with a dus/mist prefiter should be used. Protoction of hands: ‘The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation Material of gloves ‘The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior lo the application. + Panatration time of glove material “The exact break through time has to be found out by the manufacturer of the protective gloves and has tobe observed. MSDS GHS 100% Acrylic spray RO1-260315 Eyo protection: © Physical and chemical properties. 9.1 Information on basic physical and chemical properties General information Appearance: Aerosol According to product catalogue Characteristic + Odor threshold: Not determined, ~ Change in condition Melting pointMetting range: Undetermined. Bolling point/Bolling rang Not applicable. + Auto-ignition temperature: Not determined, + Flash point <0°C (< 82°F) - Decomposition tomporature: Not determined. + Auto igniting: Product is not self-igniting. + Danger of explosion: Product is not explosive. However, formation of + Explosion limits: Lower: Upper: = Vapor pressure at 21 * + Density at 21 °C (70 + Relative donsity: - Vapor density: Evaporation rate ‘Solubility in / Miscibility with Water: Partition coefficient (n-octanoliwater): Viscosity: Solvent content: ‘VOC content ‘9.2 Other information: ‘explosive air! vapor mixtures are possible. Not determined. Not determined ~ 8000 hPa. ~0.87 gfom* Not determined. >1 (Air=1) Nat applicable, miscible, Not determined. Not determined. Not determined. >80% No further relevant information available. MSDS GHS 100% Acrylic spray RO1-260315, 10 Stability and reactivity 10.1 Reactivity 10.2 Chemical stability a ~—“eTtrermal decomposition f conditions to tbe avotded: No decomposition ifused und sloted according lo epeciications. Danger of receptacles bursting because of high vapor pressure if heated. 10.3 Possibility of hazardous reactions Can from explosive mixtures in air if heated above flash point and/or when sprayed or atomized Extremely flammable aercsl Toxic fumes may be released If ieated above the decomposition palit Danger of raceptacies bursting bacauro of high vapor prossuro if heated. 10.4 Conditions to avoid Keep away from heat and direct sunlight. ‘Keep ignition sources away Do not smoke. Store away from o} agents 10.6 Hazardous decomposition products: Decomposition may produce carbon monoxide and carbon dioxide, hydrogen chloride, and chlorine gas. 11 Toxicological information Information on toxicological effects Acute toxicity: + LD/LC50 values that are relevant for classification: é = ‘Acetone _ Oral L050 5800_maikg (rat) Dermal L050 20000 mgikg (rabbi) ————_—| Xylene oe Oral 1050 4300 mgkg (rat) = Dermal L050 | 2000 mavka (rabbit) n-Butyl Acetate ins ‘Oral (050 7250 ma/kg (rat) Dermal L050 ‘220 malkg (rabbit) Ethyl Acetate ‘Oral 1050 > 5000 maikg (rat) Dermal L050 318 _ gikg (rabbit) 2-Butoxyethanol 2 ‘Oral 1050 = 3300-2000 mgikg (rat) Dermal L060 = 60-200 mg/kg (rabbit) [Propane + Butane 7 7 ipso 226 mglkg (rat) L050 682 mg/kg (ret) Inhalative Lesorh 2770 ppm (mouse) + Primary irritant effec On the skin: irtant to skin and mucous membranes. On the eye: Moderate iritant effect on eyes. On the respiratory : Initant to respiratory system. MSDS GHS 100% Acrylic spray RO1-260315 ‘Sensitization: No sensitizing effects known. + Additional toxicological information: ‘The product shows the following dangers according to internally approved calculation methods for ‘eparallons. tritant _ Inhalation of concentrated vapors. as well as oral intake. will jead to. anaasthasiaslike conditions and. headache, dizziness, ote. ‘Vapours havo narcotic offect, 412 Ecological InformationToxicity 121 Toxleny C50 (24n) | > 175 mg/l (bacteria) Ec50/48h | 3.82 mgil (daphnia magna/Wasserfioh) EC50/72h _| 4.7 mgil (Pseudokirchnorielia subcapitata) TC50/96h | 7.6 mgll (oncomynchus mykiss / Regenbogenforelle) 412.2 Persistence and degradability No further relevant information available. 12.3 Bioaccumulative potential No further relevant information available. 12.4 Mobility in soil No further relevant information available, Additional ecological information: “General notes: ‘Avoid transfer into the environment. Do not allow product to reach ground water, water course or sewage system. ‘Dangor to drinking wator if even, small quantities leak into the ground. 12.6 Results of PBT and vPvB assessment PBT: Not applicable. +: vPVB: Not applicable, 12.6 Other adverse effects No further relevant information available. 13 Disposal considerations 13.4 Waste treatment methods - Recommendation: The user of this material has the responsibilty to dispose of unused material, residues and containers in compliance with all relevant local, state and federal laws and regulations regarding treatment, storage end disposal for hazardous and nonhazardous wastes. Residual materials should be treated as hazardous, Uncleaned packagings: - Recommendation: Disposal must be made according to official regulations. 14 Transport information 14.1 UN-Number DOT, ADR, IMNG, IATA UN1950 MSDS GHS 100% Acrylic spray R01-260315 414.2 UN proper shipping name ~ v than 30 kg (66 lb) and inner packagings less than +L (0:3gal),— pot Aros, fabs ‘ADR 1060 AEROSLS, flammable IMDG ‘AEROSOLS “ATA AEROSOLS, flammable por e + Class + Label ADR. e + Class 2.5 F Gases + Label at + Class + Label pe IATA e + Class + Label Packing group - DOT, ADR, IMDG, IATA u Environmental hazards: Sees aaa as No " Spectal precautions for user TransporvAdltional information: Waring : Gases 16 Regulatory information 184 Safety, health and environmental regulations/legistation specific for the substance or mixture ‘This product has been classified in accordance with hazard criteria of the controlled products Regulations and the SDS contains all the information required by the controlled products regulations. 16.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out. MSDS GHS 100% Acrylic spray RO1-260315 16 Other information This information is based on our present knowledge. Ilowever, this shall not constilule a guarantee for ‘any specific product features and shall not establish a legally valid contractual relationship. “The information contained herein hat been obtained as tho result of testing and development work carried out by us. However, this product can be put to numerous uses under widely varying circumstances and conditions and accordingly we do not guarantee the accuracy of the contents of the statements contained herein, and in particular, we do not warrant that this product is. suitable for ‘any particular use. We shall not be liable in any way whatsoever to any person who relies upon the statements contained herein without taking sufficient steps to ensure in advance that the product is Suitable for this particular purpose, production, conditions and/or use" MSDS GHS 100% Acrylic spray RO1-260315 MSDS GHS 100% Acrylic spray RO1-260315 Printing date 23/03/2015, Reviewed on 23/03/2015 MSDS GHS Chrome spray R01-230315

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