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Safety data sheet

acc. to 1907/2006/EC, Article 31 (REACH), 1272/2008/EC (CLP) and 453/2010/EC

Printing date 27.01.2015 Version number 1 Revision: 26.01.2015

* SECTION 1: Identification of the substance/mixture and of the company/undertaking

. 1.1 Product identifier
. Trade name Cetamine G830
Article number: 48398
. Article number: 48398
. 1.2 Relevant identified uses of the substance or mixture and uses advised against
No further relevant information available.
. Application of the substance / the mixture
Formulation additive
Water treatment
Water conditioner
Corrosion inhibitors
. 1.3 Details of the supplier of the safety data sheet
. Manufacturer/Supplier:
Kurita Europe APW GmbH www.kurita.eu
Giulinistraße 2 Tel: +49 621 5709-3000
D-67065 Ludwigshafen Fax: +49 621 5709-6452
. Information:
[email protected]
. 1.4 Emergency telephone number: Tel.: +49 621 / 5709-112

SECTION 2: Hazards identification

. 2.1 Classification of the substance or mixture
. Classification according to Regulation (EC) No 1272/2008
STOT RE 2 H373 May cause damage to organs through prolonged or repeated exposure. Route of exposure:
Oral.
Skin Corr. 1A H314 Causes severe skin burns and eye damage.
Eye Dam. 1 H318 Causes serious eye damage.
Aquatic Acute 1 H400 Very toxic to aquatic life.
Aquatic Chronic 2 H411 Toxic to aquatic life with long lasting effects.
. Classification according to Directive 67/548/EEC or Directive 1999/45/EC
C; Corrosive
R34: Causes burns.
Xn; Harmful
R48/22: Harmful: danger of serious damage to health by prolonged exposure if swallowed.
Xi; Irritant
R37: Irritating to respiratory system.
N; Dangerous for the environment
R50/53: Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
. Classification system:
The classification is in line with current EC lists. It is expanded, however, by information from technical literature and by
information furnished by supplier companies.
. 2.2 Label elements
. Labelling according to Regulation (EC) No 1272/2008
The product is classified and labelled according to the CLP regulation.
(Contd. on page 2)
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acc. to 1907/2006/EC, Article 31 (REACH), 1272/2008/EC (CLP) and 453/2010/EC

Printing date 27.01.2015 Version number 1 Revision: 26.01.2015

Trade name Cetamine G830

Article number: 48398

(Contd. of page 1)
. Hazard pictograms

GHS05 GHS08 GHS09

. Signal word Danger

. Hazard-determining components of labelling:
2-aminoethanol
(Z)-N-9-octadecenylpropane-1,3-diamine
2-diethylaminoethanol
fatty alkylamine, ethoxylated
. Hazard statements
H314 Causes severe skin burns and eye damage.
H373 May cause damage to organs through prolonged or repeated exposure. Route of exposure: Oral.
H400 Very toxic to aquatic life.
H411 Toxic to aquatic life with long lasting effects.
. Precautionary statements
P260 Do not breathe mist/vapours/spray.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/
shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER/doctor.
P301+P330+P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting.

SECTION 3: Composition/information on ingredients

. 3.2 Chemical characterisation: Mixtures
. Description: Alkanolamines in water.
. Dangerous components:
CAS: 3710-84-7 N,N-diethylhydroxylamine 3-<10%
EINECS: 223-055-4 Xn R20/21; Xi R37; N R51/53
Reg.nr.: 01-2119962470-39-xxxx R10
Flam. Liq. 3, H226; Aquatic Chronic 2, H411; Acute Tox. 4, H312; Acute Tox.
4, H332; STOT SE 3, H335
CAS: 141-43-5 2-aminoethanol 3-<5%
EINECS: 205-483-3 C R34; Xn R20/21/22
Index number: 603-030-00-8 Skin Corr. 1B, H314; Acute Tox. 4, H302; Acute Tox. 4, H312; Acute Tox. 4,
Reg.nr.: 01-2119486455-28-xxxx H332; STOT SE 3, H335; Aquatic Chronic 3, H412
CAS: 7173-62-8 (Z)-N-9-octadecenylpropane-1,3-diamine 3-<5%
EINECS: 230-528-9 T R48/25; C R35; Xn R22; N R50
Reg.nr.: 01-2119487002-46-xxxx STOT RE 1, H372; Skin Corr. 1A, H314; Aquatic Acute 1, H400; Aquatic
Chronic 1, H410; Acute Tox. 4, H302
(Contd. on page 3)
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acc. to 1907/2006/EC, Article 31 (REACH), 1272/2008/EC (CLP) and 453/2010/EC

Printing date 27.01.2015 Version number 1 Revision: 26.01.2015

Trade name Cetamine G830

Article number: 48398

(Contd. of page 2)
CAS: 100-37-8 2-diethylaminoethanol 3-<5%
EINECS: 202-845-2 C R34; Xn R20/21/22
Index number: 603-048-00-6 R10
Reg.nr.: 01-2119488937-14-xxxx Flam. Liq. 3, H226; Acute Tox. 3, H311; Acute Tox. 3, H331; Skin Corr. 1B,
H314; Acute Tox. 4, H302
CAS: 61791-26-2 fatty alkylamine, ethoxylated 1-<2.5%
Xn R22; Xi R41; N R50
Eye Dam. 1, H318; Aquatic Acute 1, H400; Acute Tox. 4, H302
. SVHC No
. Additional information For the wording of the listed risk phrases refer to section 16.

SECTION 4: First aid measures

. 4.1 Description of first aid measures
. General information Instantly remove any clothing soiled by the product.
. After inhalation : In case of unconsciousness bring patient into stable side position for transport.
. After skin contact :
Seek medical treatment.
Immediately wash with soap and water and rinse thoroughly.
. After eye contact :
Call a doctor immediately.
Rinse opened eye for 15 minutes under running water. Then consult doctor.
. After swallowing :
Rinse out mouth and then drink plenty of water (approx. 500 ml).
Drink copious amounts of water (app. 500 ml) and provide fresh air. Instantly call for doctor.
. 4.2 Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section 2) and / or in section 11.
Further important symptoms and effects are so far not known.
Ingestion causes pain, burns, abdominal pain, possible general impact (shock).
Splashes cause strong tearing, pain, may cause permanent visual impairment.
. 4.3 Indication of any immediate medical attention and special treatment needed
If swallowed, gastric irrigation
No specific antidot is known. Treatment of the symptoms.

SECTION 5: Firefighting measures

. 5.1 Extinguishing media
. Suitable extinguishing agents
Use fire fighting measures that suit the environment.
CO2, extinguishing powder or water jet. Fight larger fires with foam.
. 5.2 Special hazards arising from the substance or mixture
Fire can cause release of :
Carbon monoxide (CO)
Nitrogen oxides (NOx)
. 5.3 Advice for firefighters
. Protective equipment:
Wear full protective suit.
Wear alkaline resistant protective clothing.
Put on breathing apparatus.
. Additional information
Cool endangered containers with water spray jet.
(Contd. on page 4)
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Printing date 27.01.2015 Version number 1 Revision: 26.01.2015

Trade name Cetamine G830

Article number: 48398

(Contd. of page 3)
Collect contaminated fire fighting water separately. It must not enter drains.

SECTION 6: Accidental release measures

. 6.1 Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
. 6.2 Environmental precautions:
Do not allow concentrated solutions to enter drainage system, surface or ground water.
. 6.3 Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders).
Use neutralising agent.
Dispose of contaminated material as waste according to section 13.
. 6.4 Reference to other sections
See section 7 for information on safe handling
See section 8 for information on personal protection equipment.

SECTION 7: Handling and storage

. 7.1 Precautions for safe handling
Keep containers tightly sealed.
Ensure good ventilation/exhaustion at the workplace.
. Information about protection against explosions and fires: No special measures required.
. 7.2 Conditions for safe storage, including any incompatibilities
. Storage
. Requirements to be met by storerooms and containers:
Store only in the original container.
Provide alkali-resistant floor.
Use polyolefine containers.
Unsuitable materials: steel, light- and brass alloys
Provide floor trough without outlet.
. Information about storage in one common storage facility:
Do not store together with acids.
Store away from oxidising agents.
Store away from reducing agents.
. Further information about storage conditions:
Keep container tightly sealed.
Store container in a well ventilated position.
Protect from frost.
Product quality requires storage between 5 °C and 40 °C.
. 7.3 Specific end use(s) No further relevant information available.
(Contd. on page 5)
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Printing date 27.01.2015 Version number 1 Revision: 26.01.2015

Trade name Cetamine G830

Article number: 48398

(Contd. of page 4)

SECTION 8: Exposure controls/personal protection

. 8.1 Control parameters
. Components with critical values that require monitoring at the workplace:
141-43-5 2-aminoethanol
WEL (Great Britain) Short-term value: 7.6 mg/m³, 3 ppm
Long-term value: 2.5 mg/m³, 1 ppm
Sk
IOELV (European Union) Short-term value: 7.6 mg/m³, 3 ppm
Long-term value: 2.5 mg/m³, 1 ppm
Skin
. DNELs
3710-84-7 N,N-diethylhydroxylamine
Oral General population 0.13 mg/kg bw/day (long-term exposure, systemic effects)
Dermal Worker 0.26 mg/kg bw/day (long-term exposure, systemic effects)
4.7 mg/kg bw/day (short term exposure, systemic effects)
Inhalative General population 0.65 mg/m3 (long-term exposure, systemic effects)
Worker 2.92 mg/m3 (long-term exposure, local effect)
3.65 mg/m3 (long-term exposure, systemic effects)
8.76 mg/m3 (short term exposure, local effects)
45.6 mg/m3 (short term exposure, systemic effects)
7173-62-8 (Z)-N-9-octadecenylpropane-1,3-diamine
Dermal Worker 0.01 mg/kg bw/day (long-term exposure, systemic effects)
Inhalative Worker 0.035 mg/m3 (long-term exposure, systemic effects)
. PNECs
3710-84-7 N,N-diethylhydroxylamine
Sediment 0.0652 mg/kg (fresh water)
0.00652 mg/kg (sea water)
Sewage treatment 10 mg/L (sewage-treatment plant)
Soil 0.0082 mg/kg (soil)
Water 0.0082 mg/L (fresh water)
0.00082 mg/L (sea water)
0.082 mg/L (intermittent release)
7173-62-8 (Z)-N-9-octadecenylpropane-1,3-diamine
Sediment 0.22 mg/kg (fresh water)
0.022 mg/kg (sea water)
Sewage treatment 0.251 mg/L (sewage-treatment plant)
Soil 10 mg/kg (soil)
Water 0.01 mg/L (fresh water)
0.001 mg/L (sea water)
0.0029 mg/L (intermittent release)
. Additional information: The lists that were valid during compilation were used as a basis.
(Contd. on page 6)
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Trade name Cetamine G830

Article number: 48398

(Contd. of page 5)

. 8.2 Exposure controls

. Personal protective equipment
. General protective and hygienic measures
The usual precautionary measures should be adhered to in handling the chemicals.
Keep away from foodstuffs, beverages and food.
Instantly remove any soiled and impregnated garments.
Wash hands during breaks and at the end of the work.
Avoid contact with the eyes and skin.
. Breathing equipment:
Use breathing protection in case of insufficient ventilation.
Use breathing protection only when aerosol or mist is formed.
In case of brief exposure or low pollution use breathing filter apparatus. In case of intensive or longer exposure use
breathing apparatus that is independent of circulating air.
Short term filter device: ABEK-filter
Filter type K, green, for organic, basic amines.
. Protection of hands:
Protective gloves:
In case of spray contact at least protection index 2 recommended, according to more than 30 min. penetration time (EN
374).
Layer thickness of gloves at least: 0.4 mm
In case of prolonged and intensive contact protection index 6 recommended, according to more than 480 min.
penetration time (EN 374).
Layer thickness of gloves at least: 0.7 mm
. Material of gloves
Butyl rubber, BR
Fluorocarbon rubber (Viton)
Nitrile rubber, NBR
Natural rubber, NR
Chloroprene rubber, CR
Neoprene gloves
. Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed.
. Not suitable are gloves made of the following materials: Leather gloves
. Eye protection: Tightly sealed safety glasses (DIN 58211, EN 166)
. Body protection: Alkaline resistant protective clothing

SECTION 9: Physical and chemical properties

. 9.1 Information on basic physical and chemical properties
. General Information
. Appearance:
Form: Fluid
Colour: Yellowish
Cloudy
. Smell: Amine-like
. Odour threshold: not determined
. pH-value at 20 °C: ca. 12.1 (100 %)
. Change in condition
Melting point/Melting range: not determined
Boiling point/Boiling range: Not determined
(Contd. on page 7)
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Trade name Cetamine G830

Article number: 48398

(Contd. of page 6)

. Flash point: > 61 °C

. Inflammability (solid, gaseous) not applicable
. Ignition temperature: not determined
. Decomposition temperature: not determined
. Self-inflammability: Product is not selfigniting.
. Danger of explosion: Product is not explosive.
. Critical values for explosion:
Lower: Not determined.
Upper: Not determined.
. Oxidising properties none
. Steam pressure at 20 °C: ca. 23 hPa
. Density at 20 °C ca.1.0 g/cm3
. Evaporation rate not determined
. Solubility in / Miscibility with
Water: Fully miscible
. Partition coefficient (n-octanol/water): not determined
. Viscosity:
dynamic: not determined
. 9.2 Other information No further relevant information available.

SECTION 10: Stability and reactivity

. 10.1 Reactivity No hazardous reactions when stored and handled according to instructions.
. 10.2 Chemical stability
. Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
. 10.3 Possibility of hazardous reactions
Corrosive action on metals
Reacts with acids
. 10.4 Conditions to avoid No further relevant information available.
. 10.5 Incompatible materials: May react vigorously with strong acids.
. 10.6 Hazardous decomposition products:
No dangerous decomposition products known
Danger of toxic pyrolysis products

* SECTION 11: Toxicological information

. 11.1 Information on toxicological effects
. Acute toxicity:
. LD/LC50 values that are relevant for classification:
3710-84-7 N,N-diethylhydroxylamine
Oral LD50 2190 mg/kg (rat)
Dermal LD50 1300 mg/kg (rabbit)
Inhalative LC50 (4 h) 11.4 mg/L (rat) (OECD 403; 3140 ppm (vapour))
(Contd. on page 8)
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Trade name Cetamine G830

Article number: 48398

(Contd. of page 7)
7173-62-8 (Z)-N-9-octadecenylpropane-1,3-diamine
Oral LD50 500 mg/kg (rat)
. Components Type Value Species
Product ATEmix oral > 5000 mg/kg
Product ATEmix dermal > 5000 mg/kg
Product ATEmix inhaled > 20 mg/L, 4h
. Primary irritant effect:
. on the skin: Caustic effect on skin and mucous membranes.
. on the eye: Strong caustic effect.
. Additional toxicological information:
Hazardous to the environment
Swallowing will lead to a strong caustic effect on mouth and throat and to the danger of perforation of esophagus and
stomach.
. Sensitisation No sensitizing effect known.
. Repeated dose toxicity
7173-62-8 (Z)-N-9-octadecenylpropane-1,3-diamine
Oral NOAEL, systemic toxicity 0.4 mg/kg bw/day (rat) (per day, subchronic)
. CMR effects (carcinogenity, mutagenicity and toxicity for reproduction) No further relevant information available.

* SECTION 12: Ecological information

. 12.1 Toxicity
. Aquatic toxicity:
3710-84-7 N,N-diethylhydroxylamine
EC50 (48 h) 8.2 mg/L (daphnia magna) (OECD 202)
EC50 (72 h) > 101 mg/L (Pseudokirchneriella subcapitata) (OECD 201)
LC50 (96 h) > 134 mg/L (Pimephales promelas) (OECD 203)
NOEC 134 mg/L (Pimephales promelas)
100 mg/L (activated sludge) (28 d)
7173-62-8 (Z)-N-9-octadecenylpropane-1,3-diamine
EC50 25.1 mg/L (activated sludge)
EC50 (48 h) 0.013 - 0.025 mg/L (daphnia magna) (OECD 202)
EC50 (72 h) > 0.01 - 0.1 mg/L (desmodesmus subspicatus) (OECD 201)
LC50 (96 h) 0.148 mg/L (Brachydanio rerio) (OECD 203)
M-factor 10 (acute)
NOEC > 0.001 - 0.01 mg/L (daphnia magna) (OECD 211, 21 d)
. 12.2 Persistence and degradability A part of the components is not easily biodegradable.
. Other information: Easy elimination possible by flocculation or adsorption by sludge.
. 12.3 Bioaccumulative potential No further relevant information available.
. 12.4 Mobility in soil No further relevant information available.
. Additional ecological information:
. General notes:
The product may not be released into the aquatic environment without preliminary treatments (biological purification
plant).
Water danger class 3 (Self-assessment): extremely hazardous for water.
Do not allow product to reach ground water, water bodies or sewage system, even in small quantities.
Danger to drinking water if even extremely small quantities leak into soil.
(Contd. on page 9)
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Trade name Cetamine G830

Article number: 48398

(Contd. of page 8)
. 12.5 Results of PBT and vPvB assessment
. PBT: Not applicable.
. vPvB: Not applicable.
. 12.6 Other adverse effects No further relevant information available.

SECTION 13: Disposal considerations

. 13.1 Waste treatment methods
. Recommendation
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
Must be specially treated in adherence to official regulations.
. European waste catalogue
16 03 05* organic wastes containing dangerous substances
. Uncleaned packaging:
. Recommendation:
Empty contaminated packagings thoroughly. They can be recycled after thorough and proper cleaning.
Packagings that cannot be cleaned are to be disposed of in the same manner as the product.
Dispose of packaging according to regulations on the disposal of packagings.
. Recommended cleaning agent: Water, if necessary with cleaning agent.

SECTION 14: Transport information

. 14.1 UN-Number
. ADR, IMDG, IATA UN2735
. 14.2 UN proper shipping name
. ADR 2735 AMINES, LIQUID, CORROSIVE, N.O.S. (N,N-
diethylhydroxylamine, (Z)-N-9-octadecenylpropane-1,3-diamine),
ENVIRONMENTALLY HAZARDOUS
. IMDG AMINES, LIQUID, CORROSIVE, N.O.S. (N,N-diethylhydroxylamine,
(Z)-N-9-octadecenylpropane-1,3-diamine), MARINE POLLUTANT
. IATA AMINES, LIQUID, CORROSIVE, N.O.S. (N,N-diethylhydroxylamine,
(Z)-N-9-octadecenylpropane-1,3-diamine)
. 14.3 Transport hazard class(es)
. ADR

. Class 8 (C7) Corrosive substances.

. Label 8
. IMDG

. Class 8 Corrosive substances.

(Contd. on page 10)
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Trade name Cetamine G830

Article number: 48398

(Contd. of page 9)
. Label 8
. IATA

. Class 8 Corrosive substances.

. Label 8
. 14.4 Packing group
. ADR, IMDG, IATA III
. 14.5 Environmental hazards: Product contains environmentally hazardous substances: (Z)-N-9-
octadecenylpropane-1,3-diamine, N,N-diethylhydroxylamine
. Marine pollutant: Yes (P)
Symbol (fish and tree)
. Special marking (ADR): Symbol (fish and tree)
. 14.6 Special precautions for user Warning: Corrosive substances.
. Kemler Number: 80
. EMS Number: F-A,S-B
. Segregation groups Alkalis
. 14.7 Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not applicable.
. Transport/Additional information: Frost protected transport has to be guaranteed.
. ADR
. Limited quantities (LQ) 5L
. Transport category 3
. Tunnel restriction code E
. UN "Model Regulation": UN2735, AMINES, LIQUID, CORROSIVE, N.O.S. (N,N-
diethylhydroxylamine, (Z)-N-9-octadecenylpropane-1,3-diamine),
ENVIRONMENTALLY HAZARDOUS, 8, III

SECTION 15: Regulatory information

. 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
. National regulations
. Information about limitation of use: Employment restrictions concerning young persons must be observed.
. 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

SECTION 16: Other information

These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product
features and shall not establish a legally valid contractual relationship.
. Relevant phrases
H226 Flammable liquid and vapour.
H302 Harmful if swallowed.
H311 Toxic in contact with skin.
H312 Harmful in contact with skin.
H314 Causes severe skin burns and eye damage.
H318 Causes serious eye damage.
(Contd. on page 11)
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Article number: 48398

(Contd. of page 10)

H331 Toxic if inhaled.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H372 Causes damage to organs through prolonged or repeated exposure.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H411 Toxic to aquatic life with long lasting effects.
H412 Harmful to aquatic life with long lasting effects.
R10 Flammable.
R20/21 Harmful by inhalation and in contact with skin.
R20/21/22 Harmful by inhalation, in contact with skin and if swallowed.
R22 Harmful if swallowed.
R34 Causes burns.
R35 Causes severe burns.
R37 Irritating to respiratory system.
R41 Risk of serious damage to eyes.
R48/25 Toxic: danger of serious damage to health by prolonged exposure if swallowed.
R50 Very toxic to aquatic organisms.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
. Department issuing data specification sheet: Product Safety and Regulatory Affairs
. Contact: [email protected]
. Abbreviations and acronyms:
RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning the International
Transport of Dangerous Goods by Rail)
ICAO: International Civil Aviation Organisation
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of
Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
P: Marine Pollutant
GHS: Globally Harmonised System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
DNEL: Derived No-Effect Level (REACH)
PNEC: Predicted No-Effect Concentration (REACH)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
Flam. Liq. 3: Flammable liquids, Hazard Category 3
Acute Tox. 3: Acute toxicity, Hazard Category 3
Acute Tox. 4: Acute toxicity, Hazard Category 4
Skin Corr. 1A: Skin corrosion/irritation, Hazard Category 1A
Skin Corr. 1B: Skin corrosion/irritation, Hazard Category 1B
Eye Dam. 1: Serious eye damage/eye irritation, Hazard Category 1
STOT SE 3: Specific target organ toxicity - Single exposure, Hazard Category 3
STOT RE 1: Specific target organ toxicity - Repeated exposure, Hazard Category 1
STOT RE 2: Specific target organ toxicity - Repeated exposure, Hazard Category 2
Aquatic Acute 1: Hazardous to the aquatic environment - AcuteHazard, Category 1
Aquatic Chronic 1: Hazardous to the aquatic environment - Chronic Hazard, Category 1
Aquatic Chronic 2: Hazardous to the aquatic environment - Chronic Hazard, Category 2
Aquatic Chronic 3: Hazardous to the aquatic environment - Chronic Hazard, Category 3
. Sources: source ECHA: European Chemicals Agency, http://echa.europa.eu/
. * Data compared to the previous version altered.
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