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DPP Nomenclature

This document provides practice problems for IUPAC nomenclature. There are 26 multiple choice questions testing the ability to name organic compounds according to IUPAC rules and identify IUPAC names. An answer key is provided.

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gamishtag18
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329 views7 pages

DPP Nomenclature

This document provides practice problems for IUPAC nomenclature. There are 26 multiple choice questions testing the ability to name organic compounds according to IUPAC rules and identify IUPAC names. An answer key is provided.

Uploaded by

gamishtag18
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as PDF, TXT or read online on Scribd
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CHEMISTRY

DPP
DROOM PRACTICE PROBLEMS

IUPAC NOMENCLATURE NO. 01


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1. The hybrid state of C–atoms which are attached to single bond with each other in the
following structure are:
CH2=CH–CCH
2
(1) sp , sp (2) sp3, sp (3) sp2, sp2 (4) sp2, sp3

2. In compound HCC–CH2–CH=CH–CH3, the C2–C3 bond is the type of :-


(1) sp – sp2 (2) sp3 – sp3 (3) sp – sp3 (4) sp2 – sp2

3. In the hydrocarbon
CH3 – CH = CH – CH2 – C  CH
6 5 4 3 2 1
The state of hybridization of carbons 1, 3 and 5 are in the following sequence :-
(1) sp, sp2, sp3 (2) sp3, sp2, sp (3) sp2, sp, sp3 (4) sp, sp3, sp2

4. Which of the following molecules represents the order of hybridisation sp2, sp2, sp, sp from left
to right atoms?
(1) HCC–CCH (2) CH2=CH–CCH
(3) CH2=CH–CH=CH2 (4) CH3–CH=CH–CH3

5. Which is the correct representation of 1-chlorobut-2-ene?


(1) (2) Cl
Cl
Cl
(3) (4)
Cl

6. Indicate the IUPAC name of the compound shown below :


F

(1) 2-[1-fluoroethyl]pent-1-ene (2) 3-fluoro-2-propylbut-1-ene


(3) 2-fluoro-3-propylbut-3-ene (4) 2-fluoro-3-methylidenehexane
7. What is the IUPAC name of the compound shown below ?

(1) 5-ethyl-1-methyl cyclohexene (2) 1-methyl-3-ethyl cyclohexene


(3) 3-ethyl-1-methyl cyclohexene (4) 2-ethyl-4-methyl cyclohexene

8. Indicate the IUPAC name of the compound.


OH

NH2

(1) 2-amino cyclohexanol (2) 2-amino cyclohex-4-enol


(3) 6-amino cyclohex-3-enol (4) 2-hydroxy cyclohex-4-enamine

C2H5
9. What is the correct IUPAC name of the following compound?
CH3

(1) 1-ethyl-6-methylcyclohexene (2) 1-ethyl-3-methylcyclohex-2-ene


(3) 6-ethyl-1-methylcyclohexene (4) 1-methyl-6-ethylcyclohexene

O
||
10. CH3 – CH2–CH–C—OCH3
|
C2H5
(1) Methyl 2-ethylbutanoate (2) 1-methoxy-2-ethylbutanone
(3) 3-Methoxycarbonylpentane (4) 1-methoxy-2-ethylbutanal

Br Cl
| |
11. CH3 — CH2 — C — CH — CH2 — Cl
|
OH
(1) 3-Bromo-4, 5-dichloropentan-3-ol
(2) 3-Bromo-1, 2-dichloro-3-hydroxypentane
(3) 3-Bromo-1, 2-dichloropentan-3-ol
(4) 3-Bromo-4, 5-dichloro-3-hydroxypentane

CH3
|
12. CH2 = C — COOCH3

(1) Methyl-2-methylprop-1-en-3-oate (2) 2-Methoxycarbonylpropene


(3) 2-Methoxycarbonylprop-2-ene (4) Methyl-2-methylprop-2-enoate
13. The IUPAC name of is :

(1) 2–Ethyl–3–methyl–1–penten–4–yne
(2) 2–Ethyl–3–methyl–4–pentyne–1–ene
(3) 4–Ethyl–3–methyl–1–pentyn–4–ene
(4) 4–Ethyl–3–methyl–4–penten–1–yne

14. The IUPAC name of following compound is :


CH3 – CH= C – C  C – CH3
|
CH3

(1) 3–Methylhex–4–en–2–yne (2) 3–Methylhex–2–en–4–yne


(3) 4–Methylhex–4–en–4–yne (4) All are correct

15. The IUPAC name of is

(1) 3–Methyl–2–penten–4–yne (2) 3–Methyl–3–penten–1–yne


(3) 3–Methyl–4–pentyn–1–ene (4) 3–Methyl pentenyne

16. The IUPAC name of is :

(1) 3–Methyl cyclo–1–buten–2–ol (2) 4–Methyl cyclo–2–buten–1–ol


(3) 4–Methyl cyclo–1–buten–3–ol (4) 2–Methyl cyclo–3–buten–1–ol.

17.

IUPAC name is :
(1) 4-Ethyl-5-oxo pentanoic acid (2) 4-Ethyl-4-formyl butanoic acid
(3) 4-Formyl hexanoic acid (4) 4-Oxo hexanoic acid

18. has the IUPAC name :-

(1) 3–Chloro–1–ethyl–2–methyl cyclopentane


(2) 1–Chloro–3–ethyl–2–methyl cyclopentane
(3) 4–Chloro–1–ethyl–5–methyl cyclopentane
(4) 2–Chloro–5–ethyl–1–methyl cyclopentane
19. Which is the IUPAC name of Aspirin?
HO O
O CH3

(1) 2-carboxybenzenecarboxylate
(2) 2-Ethanoyloxy benzene carboxylic acid
(3) 2-Ethoxycarbonyl benzene carboxylic acid
(4) 2-carboxyphenylethanoate

20. What is the IUPAC name of the compound shown below?


O
C–OEt

NH2

(1) ethyl 3-amino benzene carboxylate (2) methyl 3-amino benzoate


(3) 3-amino benzene carboxylate (4) 3-ethoxy carbonyl benzenamine

21. The IUPAC name(s) of the following compound is (are) :

O2N CH3

(1) 4-methylnitrobenzene. (2) 4-nitrotoluene


(3) 1-methyl-4-nitrobenzene (4) 1-nitro-4-methylbenzene

22. The IUPAC name of is

(1) 2-Methoxy-4- nitro benzaldehyde (2) 4-Nitro -2-methoxy benzaldehyde


(3) 3-Methoxy-4-formyl nitro benzene (4) 2-formyl-4-nitro anisole

23. The IUPAC name of is :

(1) 2-Hydroxybenzenol (2) 1, 2-Dihydroxybenzene


(3) Benzene-1, 2-diol (4) 2-Hydroxyphenol

24. The IUPAC name of is :

(1) 3,4–Dihydroxy benzoic acid (2) 2,3–Dihydroxy benzoic acid


(3) 4–Carboxy–2–hydroxy phenol (4) 4–Carboxy benzene–1,2–diol
25. The IUPAC name for :

(1) 1-Chloro-2-nitro-4-methylbenzene (2) 1-Chloro-4-methyl-2-nitrobenzene


(3) 2-Chloro-1-nitro-5-methylbenzene (4) m-Nitro-p-chlorotoluene

26. Column I Column II


Br

(a) (p) 3-bromo-6-chloro cyclohexene

Cl
Br

(b) (q) 4-bromo-1-chloro cyclohexene

Cl
Br

(c) (r) 1-bromo-4-chloro cyclohexene

Cl
Br

(d) (s) 1-bromo-4-chloro cyclohexane

Cl

ANSWER KEY
1. (1) 2. (3) 3. (4) 4. (2) 5. (1)

6. (1) 7. (1) 8. (3) 9. (3) 10. (1)

11. (3) 12. (4) 13. (1) 14. (2) 15. (2)

16. (2) 17. (3) 18. (2) 19. (2) 20. (1)

21. (3) 22. (1) 23. (3) 24. (1) 25. (2)

26. (a) s, (b) q, (c) p (d) r

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