Steel - Wikipedia
Steel - Wikipedia
Steel is an alloy of iron and carbon with improved strength and fracture resistance compared to other forms
of iron. Many other elements may be present or added. Stainless steels, which are resistant to corrosion and
oxidation, typically need an additional 11% chromium. Because of its high tensile strength and low cost, steel
is used in buildings, infrastructure, tools, ships, trains, cars, bicycles, machines, electrical appliances,
furniture, and weapons.
Iron is the base metal of steel. Depending on the temperature, it can take two crystalline forms (allotropic
forms): body-centred cubic and face-centred cubic. The interaction of the allotropes of iron with the alloying
elements, primarily carbon, gives steel and cast iron their range of unique properties. In pure iron, the crystal
structure has relatively little resistance to the iron atoms slipping past one another, and so pure iron is quite
ductile, or soft and easily formed. In steel, small amounts of carbon, other elements, and inclusions within the
iron act as hardening agents that prevent the movement of dislocations.
The carbon in typical steel alloys may contribute up to 2.14% of its weight. Varying the amount of carbon and
many other alloying elements, as well as controlling their chemical and physical makeup in the final steel
(either as solute elements, or as precipitated phases), impedes the movement of the dislocations that make
pure iron ductile, and thus controls and enhances its qualities. These qualities include the hardness,
quenching behaviour, need for annealing, tempering behaviour, yield strength, and tensile strength of the
resulting steel. The increase in steel's strength compared to pure iron is possible only by reducing iron's
ductility.
Steel was produced in bloomery furnaces for thousands of years, but its large-scale, industrial use began only
after more efficient production methods were devised in the 17th century, with the introduction of the blast
furnace and production of crucible steel. This was followed by the Bessemer process in England in the mid-
19th century, and then by the open-hearth furnace. With the invention of the Bessemer process, a new era of
mass-produced steel began. Mild steel replaced wrought iron. The German states saw major steel prowess
over Europe in the 19th century,[1] and the American steel production industry was manufactured in cities
such as Pittsburgh and Cleveland until the late 20th century.
Further refinements in the process, such as basic oxygen steelmaking (BOS), largely replaced earlier methods
by further lowering the cost of production and increasing the quality of the final product. Today, steel is one
of the most commonly manufactured materials in the world, with more than 1.6 billion tons produced
annually. Modern steel is generally identified by various grades defined by assorted standards organisations.
The modern steel industry is one of the largest manufacturing industries in the world, but also one of the
most energy and greenhouse gas emission intense industries, contributing 8% of global emissions.[2]
However, steel is also very reusable: it is one of the world's most-recycled materials, with a recycling rate of
over 60% globally.[3]
The carbon content of steel is between 0.02% and 2.14% by weight for plain carbon steel (iron-carbon alloys).
Too little carbon content leaves (pure) iron quite soft, ductile, and weak. Carbon contents higher than those of
steel make a brittle alloy commonly called pig iron. Alloy steel is steel to which other alloying elements have
been intentionally added to modify the characteristics of steel. Common alloying elements include:
manganese, nickel, chromium, molybdenum, boron, titanium,
vanadium, tungsten, cobalt, and niobium.[5] Additional elements, most
frequently considered undesirable, are also important in steel:
phosphorus, sulfur, silicon, and traces of oxygen, nitrogen, and copper.
Plain carbon-iron alloys with a higher than 2.1% carbon content are
known as cast iron. With modern steelmaking techniques such as
powder metal forming, it is possible to make very high-carbon (and
other alloy material) steels, but such are not common. Cast iron is not
malleable even when hot, but it can be formed by casting as it has a
lower melting point than steel and good castability properties.[5]
Certain compositions of cast iron, while retaining the economies of
melting and casting, can be heat treated after casting to make
malleable iron or ductile iron objects. Steel is distinguishable from
wrought iron (now largely obsolete), which may contain a small
amount of carbon but large amounts of slag.
The steel cable of a colliery winding
Material properties tower
To inhibit corrosion, at least 11% chromium can be added to steel so that a hard oxide forms on the metal
surface; this is known as stainless steel. Tungsten slows the formation of cementite, keeping carbon in the
iron matrix and allowing martensite to preferentially form at slower quench rates, resulting in high-speed
steel. The addition of lead and sulfur decrease grain size, thereby making the steel easier to turn, but also
more brittle and prone to corrosion. Such alloys are nevertheless frequently used for components such as
nuts, bolts, and washers in applications where toughness and corrosion resistance are not paramount. For the
most part, however, p-block elements such as sulfur, nitrogen, phosphorus, and lead are considered
contaminants that make steel more brittle and are therefore removed from steel during the melting
processing.[7]
Properties
When steels with exactly 0.8% carbon (known as a eutectoid steel), are cooled, the austenitic phase (FCC) of
the mixture attempts to revert to the ferrite phase (BCC). The carbon no longer fits within the FCC austenite
structure, resulting in an excess of carbon. One way for carbon to leave the austenite is for it to precipitate out
of solution as cementite, leaving behind a surrounding phase of BCC iron called ferrite with a small
percentage of carbon in solution. The two, ferrite and cementite, precipitate simultaneously producing a
layered structure called pearlite, named for its resemblance to mother of pearl. In a hypereutectoid
composition (greater than 0.8% carbon), the carbon will first precipitate out as large inclusions of cementite
at the austenite grain boundaries until the percentage of carbon in the grains has decreased to the eutectoid
composition (0.8% carbon), at which point the pearlite structure forms. For steels that have less than 0.8%
carbon (hypoeutectoid), ferrite will first form within the grains until the remaining composition rises to 0.8%
of carbon, at which point the pearlite structure will form. No large inclusions of cementite will form at the
boundaries in hypoeutectoid steel.[11] The above assumes that the cooling process is very slow, allowing
enough time for the carbon to migrate.
As the rate of cooling is increased the carbon will have less time to migrate to form carbide at the grain
boundaries but will have increasingly large amounts of pearlite of a finer and finer structure within the
grains; hence the carbide is more widely dispersed and acts to prevent slip of defects within those grains,
resulting in hardening of the steel. At the very high cooling rates produced by quenching, the carbon has no
time to migrate but is locked within the face-centred austenite and forms martensite. Martensite is a highly
strained and stressed, supersaturated form of carbon and iron and is exceedingly hard but brittle. Depending
on the carbon content, the martensitic phase takes different forms. Below 0.2% carbon, it takes on a ferrite
BCC crystal form, but at higher carbon content it takes a body-centred tetragonal (BCT) structure. There is no
thermal activation energy for the transformation from austenite to martensite. There is no compositional
change so the atoms generally retain their same neighbors.[12]
Martensite has a lower density (it expands during the cooling) than does austenite, so that the transformation
between them results in a change of volume. In this case, expansion occurs. Internal stresses from this
expansion generally take the form of compression on the crystals of martensite and tension on the remaining
ferrite, with a fair amount of shear on both constituents. If quenching is done improperly, the internal
stresses can cause a part to shatter as it cools. At the very least, they cause internal work hardening and other
microscopic imperfections. It is common for quench cracks to form when steel is water quenched, although
they may not always be visible.[13]
Heat treatment
There are many types of heat treating processes available to steel. The most common are annealing,
quenching, and tempering.
Annealing is the process of heating the steel to a sufficiently high temperature to relieve local internal
stresses. It does not create a general softening of the product but only locally relieves strains and stresses
locked up within the material. Annealing goes through three phases: recovery, recrystallization, and grain
growth. The temperature required to anneal a particular steel depends on the type of annealing to be achieved
and the alloying constituents.[14]
Quenching involves heating the steel to create the austenite phase then quenching it in water or oil. This
rapid cooling results in a hard but brittle martensitic structure.[12] The steel is then tempered, which is just a
specialized type of annealing, to reduce brittleness. In this application the annealing (tempering) process
transforms some of the martensite into cementite, or spheroidite and hence it reduces the internal stresses
and defects. The result is a more ductile and fracture-resistant steel.[15]
Production
When iron is smelted from its ore, it contains more carbon than is
desirable. To become steel, it must be reprocessed to reduce the carbon
to the correct amount, at which point other elements can be added. In
the past, steel facilities would cast the raw steel product into ingots
which would be stored until use in further refinement processes that
resulted in the finished product. In modern facilities, the initial
product is close to the final composition and is continuously cast into
long slabs, cut and shaped into bars and extrusions and heat treated to
produce a final product. Today, approximately 96% of steel is
continuously cast, while only 4% is produced as ingots.[16] Iron ore pellets used in the production
of steel
The ingots are then heated in a soaking pit and hot rolled into slabs,
billets, or blooms. Slabs are hot or cold rolled into sheet metal or
plates. Billets are hot or cold rolled into bars, rods, and wire. Blooms are hot or cold rolled into structural
steel, such as I-beams and rails. In modern steel mills these processes often occur in one assembly line, with
ore coming in and finished steel products coming out.[17] Sometimes after a steel's final rolling, it is heat
treated for strength; however, this is relatively rare.[18]
History
Ancient
Steel was known in antiquity and was produced in bloomeries and crucibles.[19][20]
The earliest known production of steel is seen in pieces of ironware excavated from an archaeological site in
Anatolia (Kaman-Kalehöyük) and are nearly 4,000 years old, dating from 1800 BC.[21][22] Horace identifies
steel weapons such as the falcata in the Iberian Peninsula, while Noric steel was used by the Roman
military.[23]
The reputation of Seric iron of India (wootz steel) grew considerably in the rest of the world.[20] Metal
production sites in Sri Lanka employed wind furnaces driven by the monsoon winds, capable of producing
high-carbon steel. Large-scale Wootz steel production in India using crucibles occurred by the sixth
century BC, the pioneering precursor to modern steel production and
metallurgy.[19][20]
The Chinese of the Warring States period (403–221 BC) had quench-
hardened steel,[24] while Chinese of the Han dynasty (202 BC—
AD 220) created steel by melting together wrought iron with cast iron,
thus producing a carbon-intermediate steel by the 1st
century AD.[25][26]
The manufacture of what came to be called Wootz, or Damascus steel, famous for its durability and ability to
hold an edge, may have been taken by the Arabs from Persia, who took it from India. It was originally created
from several different materials including various trace elements, apparently ultimately from the writings of
Zosimos of Panopolis. In 327 BC, Alexander the Great was rewarded by the defeated King Porus, not with
gold or silver but with 30 pounds of steel.[45] A recent study has speculated that carbon nanotubes were
included in its structure, which might explain some of its legendary qualities, though, given the technology of
that time, such qualities were produced by chance rather than by design.[46] Natural wind was used where the
soil containing iron was heated by the use of wood. The ancient Sinhalese managed to extract a ton of steel for
every 2 tons of soil,[42] a remarkable feat at the time. One such furnace was found in Samanalawewa and
archaeologists were able to produce steel as the ancients did.[42][47]
Crucible steel, formed by slowly heating and cooling pure iron and carbon (typically in the form of charcoal)
in a crucible, was produced in Merv by the 9th to 10th century AD.[35] In the 11th century, there is evidence of
the production of steel in Song China using two techniques: a "berganesque" method that produced inferior,
inhomogeneous steel, and a precursor to the modern Bessemer process that used partial decarburization via
repeated forging under a cold blast.[48]
Modern
Since the 17th century, the first step in European steel production has
been the smelting of iron ore into pig iron in a blast furnace.[49]
Originally employing charcoal, modern methods use coke, which has
proven more economical.[50][51][52]
In these processes, pig iron made from raw iron ore was refined (fined)
in a finery forge to produce bar iron, which was then used in steel-
making.[49]
The raw material for this process were bars of iron. During the 17th
century, it was realized that the best steel came from oregrounds iron A Bessemer converter in Sheffield,
of a region north of Stockholm, Sweden. This was still the usual raw England
material source in the 19th century, almost as long as the process was
used.[54][55]
Crucible steel is steel that has been melted in a crucible rather than having been forged, with the result that it
is more homogeneous. Most previous furnaces could not reach high enough temperatures to melt the steel.
The early modern crucible steel industry resulted from the invention of Benjamin Huntsman in the 1740s.
Blister steel (made as above) was melted in a crucible or in a furnace, and cast (usually) into ingots.[55][56]
Industry
The steel industry is often considered an indicator of economic
progress, because of the critical role played by steel in infrastructural
and overall economic development.[62] In 1980, there were more than
500,000 U.S. steelworkers. By 2000, the number of steelworkers had
fallen to 224,000.[63]
Recycling
Steel is one of the world's most-recycled materials, with a recycling rate of over 60% globally;[3] in the United
States alone, over 82,000,000 metric tons (81,000,000 long tons; 90,000,000 short tons) were recycled in
the year 2008, for an overall recycling rate of 83%.[71]
As more steel is produced than is scrapped, the amount of recycled raw materials is about 40% of the total of
steel produced - in 2016, 1,628,000,000 tonnes (1.602 × 109 long tons; 1.795 × 109 short tons) of crude steel
was produced globally, with 630,000,000 tonnes (620,000,000 long tons; 690,000,000 short tons)
recycled.[72]
Contemporary
Carbon
Carbon Steels are often galvanized, through hot-dip or electroplating in zinc for protection against rust.[77]
Alloy
Standards
Cor-Ten rust coating
Most of the more commonly used steel alloys are categorized into
various grades by standards organizations. For example, the Society of
Automotive Engineers has a series of grades defining many types of
steel.[82] The American Society for Testing and Materials has a separate set of standards, which define alloys
such as A36 steel, the most commonly used structural steel in the United States.[83] The JIS also defines a
series of steel grades that are being used extensively in Japan as well as in developing countries.
Uses
Iron and steel are used widely in the construction of roads, railways, other infrastructure, appliances, and
buildings. Most large modern structures, such as stadiums and skyscrapers, bridges, and airports, are
supported by a steel skeleton. Even those with a concrete structure employ steel for reinforcing. It sees
widespread use in major appliances and cars. Despite the growth in usage of aluminium, steel is still the main
material for car bodies. Steel is used in a variety of other construction materials, such as bolts, nails and
screws and other household products and cooking utensils.[84]
Other common applications include shipbuilding, pipelines, mining,
offshore construction, aerospace, white goods (e.g. washing machines),
heavy equipment such as bulldozers, office furniture, steel wool, tool,
and armour in the form of personal vests or vehicle armour (better
known as rolled homogeneous armour in this role).
Historical
With the advent of speedier and thriftier production methods, steel has
become easier to obtain and much cheaper. It has replaced wrought
iron for a multitude of purposes. However, the availability of plastics in
the latter part of the 20th century allowed these materials to replace
steel in some applications due to their lower fabrication cost and
weight.[85] Carbon fiber is replacing steel in some cost insensitive
applications such as sports equipment and high-end automobiles. A carbon steel knife
Long
As reinforcing bars and mesh in reinforced concrete
Railroad tracks
Structural steel in modern buildings and bridges
Wires
Input to reforging applications
Major appliances
Magnetic cores
The inside and outside body of automobiles, trains, and ships.
Weathering (COR-TEN)
Intermodal containers
Outdoor sculptures
Architecture
A steel pylon suspending overhead
power lines
Highliner train cars
Stainless
Cutlery
Rulers
Surgical instruments
Watches
Guns
Rail passenger vehicles
Tablets
Trash Cans A stainless steel gravy boat
Body piercing jewellery
Inexpensive rings
Components of spacecraft and space stations
Low-background
Steel manufactured after World War II became contaminated with radionuclides by nuclear weapons testing.
Low-background steel, steel manufactured prior to 1945, is used for certain radiation-sensitive applications
such as Geiger counters and radiation shielding.
See also
Bulat steel Rolling
Chemistry portal
Direct reduction Rolling mill
Carbon steel Rust Belt
Damascus steel Second Industrial Revolution
Galvanising Silicon steel
Global steel industry trends Steel abrasive
Iron in folklore Steel mill
Knife metal Tamahagane, used in Japanese
Machinability swords
Noric steel Tinplate
Pelletizing Toledo steel
Wootz steel
References
1. R., Allen. "(1979). International Competition in Iron and Steel, 1850-1913" (http://www.jstor.org/stable/212
0336). JSTOR. Cambridge university. JSTOR 2120336 (https://www.jstor.org/stable/2120336). Retrieved
November 13, 2020.
2. "Decarbonization in steel | McKinsey" (https://www.mckinsey.com/industries/metals-and-mining/our-insigh
ts/decarbonization-challenge-for-steel). www.mckinsey.com. Retrieved 2022-05-20.
3. Hartman, Roy A. (2009). "Recycling" (https://web.archive.org/web/20080414215636/http://encarta.msn.co
m/encyclopedia_761556346/Recycling.html). Encarta. Archived from the original (https://encarta.msn.co
m/encyclopedia_761556346/Recycling.html) on 2008-04-14.
4. Harper, Douglas. "steel" (https://www.etymonline.com/?term=steel). Online Etymology Dictionary.
5. Ashby, Michael F. & Jones, David R.H. (1992) [1986]. Engineering Materials 2 (with corrections ed.).
Oxford: Pergamon Press. ISBN 0-08-032532-7.
6. Smelting (https://www.britannica.com/technology/smelting). Encyclopædia Britannica. 2007.
7. "Alloying of Steels" (https://web.archive.org/web/20070221070822/http://www.materialsengineer.com/E-Al
loying-Steels.htm). Metallurgical Consultants. 2006-06-28. Archived from the original (http://materialsengi
neer.com/E-Alloying-Steels.htm) on 2007-02-21. Retrieved 2007-02-28.
8. Elert, Glenn. "Density of Steel" (http://hypertextbook.com/facts/2004/KarenSutherland.shtml). Retrieved
2009-04-23.
9. Sources differ on this value so it has been rounded to 2.1%, however the exact value is rather academic
because plain-carbon steel is very rarely made with this level of carbon. See:
Smith & Hashemi 2006, p. 363—2.08%.
Degarmo, Black & Kohser 2003, p. 75—2.11%.
Ashby & Jones 1992—2.14%.
10. Smith & Hashemi 2006, p. 363.
11. Smith & Hashemi 2006, pp. 365–372.
12. Smith & Hashemi 2006, pp. 373–378.
13. "Quench hardening of steel" (https://web.archive.org/web/20090217103241/http://steel.keytometals.com/
default.aspx?ID=CheckArticle&NM=12). keytometals.com. Archived from the original (http://steel.keytome
tals.com/default.aspx?ID=CheckArticle&NM=12) on 2009-02-17. Retrieved 2009-07-19.
14. Smith & Hashemi 2006, p. 249.
15. Smith & Hashemi 2006, p. 388.
16. Smith & Hashemi 2006, p. 361
17. Smith & Hashemi 2006, pp. 361–362.
18. Bugayev et al. 2001, p. 225
19. Davidson 1994, p. 20.
20. Srinivasan, S.; Ranganathan, S. (1994). "The Sword in Anglo-Saxon England: Its Archaeology and
Literature" (https://web.archive.org/web/20181119033451/http://materials.iisc.ernet.in/~wootz/heritage/W
OOTZ.htm). Bangalore: Department of Metallurgy, Indian Institute of Science. ISBN 0-85115-355-0.
Archived from the original (https://materials.iisc.ernet.in/~wootz/heritage/WOOTZ.htm) on 2018-11-19.
21. Akanuma, H. (2005). "The significance of the composition of excavated iron fragments taken from
Stratum III at the site of Kaman-Kalehöyük, Turkey". Anatolian Archaeological Studies. Tokyo: Japanese
Institute of Anatolian Archaeology. 14: 147–158.
22. "Ironware piece unearthed from Turkey found to be oldest steel" (https://web.archive.org/web/2009032911
1924/http://www.hindu.com/thehindu/holnus/001200903261611.htm). The Hindu. Chennai, India. 2009-
03-26. Archived from the original (http://www.hindu.com/thehindu/holnus/001200903261611.htm) on
2009-03-29. Retrieved 2022-08-13.
23. "Noricus ensis", Horace, Odes, i. 16.9
24. Wagner, Donald B. (1993). Iron and Steel in Ancient China: Second Impression, With Corrections. Leiden:
E.J. Brill. p. 243. ISBN 90-04-09632-9.
25. Needham, Joseph (1986). Science and Civilization in China: Volume 4, Part 3, Civil Engineering and
Nautics. Taipei: Caves Books, Ltd. p. 563.
26. Gernet, Jacques (1982). A History of Chinese Civilization. Cambridge: Cambridge University Press. p. 69.
ISBN 0-521-49781-7.
27. Schmidt, Peter; Avery, Donald (1978). "Complex Iron Smelting and Prehistoric Culture in Tanzania".
Science. 201 (4361): 1085–1089. Bibcode:1978Sci...201.1085S (https://ui.adsabs.harvard.edu/abs/1978
Sci...201.1085S). doi:10.1126/science.201.4361.1085 (https://doi.org/10.1126%2Fscience.201.4361.108
5). JSTOR 1746308 (https://www.jstor.org/stable/1746308). PMID 17830304 (https://pubmed.ncbi.nlm.ni
h.gov/17830304). S2CID 37926350 (https://api.semanticscholar.org/CorpusID:37926350).
28. Schmidt, Peter; Avery, Donald (1983). "More Evidence for an Advanced Prehistoric Iron Technology in
Africa". Journal of Field Archaeology. 10 (4): 421–434. doi:10.1179/009346983791504228 (https://doi.org/
10.1179%2F009346983791504228).
29. Schmidt, Peter (1978). Historical Archaeology: A Structural Approach in an African Culture. Westport, CT:
Greenwood Press.
30. Avery, Donald; Schmidt, Peter (1996). "Preheating: Practice or illusion". The Culture and Technology of
African Iron Production. Gainesville: University of Florida Press. pp. 267–276.
31. Schmidt, Peter (2019). "Science in Africa: A history of ingenuity and invention in African iron technology".
In Worger, W; Ambler, C; Achebe, N (eds.). A Companion to African History. Hoboken, NJ: Wiley
Blackwell. pp. 267–288.
32. Childs, S. Terry (1996). "Technological history and culture in western Tanzania". In Schmidt, P. (ed.). The
Culture and Technology of African Iron Production. Gainesville, FL: University of Florida Press.
33. Wilford, John Noble (1996-02-06). "Ancient Smelter Used Wind To Make High-Grade Steel" (https://www.
nytimes.com/1996/02/06/science/ancient-smelter-used-wind-to-make-high-grade-steel.html?n=Top%2FN
ews%2FScience%2FTopics%2FArchaeology%20and%20Anthropology). The New York Times.
34. Srinivasan, Sharada; Ranganathan, Srinivasa (2004). India's Legendary Wootz Steel: An Advanced
Material of the Ancient World (https://web.archive.org/web/20190211082829/http://materials.iisc.ernet.in/~
wootz/heritage/WOOTZ.htm). National Institute of Advanced Studies. OCLC 82439861 (https://www.world
cat.org/oclc/82439861). Archived from the original (http://materials.iisc.ernet.in/~wootz/heritage/WOOTZ.h
tm) on 2019-02-11. Retrieved 2014-12-05.
35. Feuerbach, Ann (2005). "An investigation of the varied technology found in swords, sabres and blades
from the Russian Northern Caucasus" (https://web.archive.org/web/20110430044256/https://www.es.ucl.a
c.uk/iams/jour_25/iams25_Feuerbach.pdf) (PDF). IAMS. 25: 27–43 (p. 29). Archived from the original (htt
ps://www.es.ucl.ac.uk/iams/jour_25/iams25_Feuerbach.pdf) (PDF) on 2011-04-30.
36. Srinivasan, Sharada (1994). "Wootz crucible steel: a newly discovered production site in South India" (htt
ps://doi.org/10.5334%2Fpia.60). Papers from the Institute of Archaeology. 5: 49–59. doi:10.5334/pia.60 (h
ttps://doi.org/10.5334%2Fpia.60).
37. Hobbies – Volume 68, Issue 5 – p. 45. Lightner Publishing Company (1963)
38. Mahathevan, Iravatham (24 June 2010). "An epigraphic perspective on the antiquity of Tamil" (https://web.
archive.org/web/20100701211040/http://www.hindu.com/2010/06/24/stories/2010062451701100.htm).
The Hindu. Archived from the original (http://www.hindu.com/2010/06/24/stories/2010062451701100.htm)
on 1 July 2010. Retrieved 31 October 2010.
39. Ragupathy, P (28 June 2010). "Tissamaharama potsherd evidences ordinary early Tamils among
population" (http://www.tamilnet.com/art.html?catid=79&artid=32303). Tamilnet. Retrieved 31 October
2010.
40. Needham, Joseph (1986). Science and Civilization in China: Volume 4, Part 1, Civil Engineering and
Nautics (https://web.archive.org/web/20170703010030/https://monoskop.org/images/7/70/Needham_Jos
eph_Science_and_Civilisation_in_China_Vol_4-1_Physics_and_Physical_Technology_Physics.pdf)
(PDF). Taipei: Caves Books, Ltd. p. 282. ISBN 0-521-05802-3. Archived from the original (https://monosk
op.org/images/7/70/Needham_Joseph_Science_and_Civilisation_in_China_Vol_4-1_Physics_and_Physi
cal_Technology_Physics.pdf) (PDF) on 2017-07-03. Retrieved 2017-08-04.
41. Manning, Charlotte Speir. Ancient and Mediæval India. Volume 2 (https://books.google.com/books?id=nm
ESJR3a0RYC&pg=PA365). ISBN 978-0-543-92943-3.
42. Juleff, G. (1996). "An ancient wind powered iron smelting technology in Sri Lanka". Nature. 379 (3): 60–
63. Bibcode:1996Natur.379...60J (https://ui.adsabs.harvard.edu/abs/1996Natur.379...60J).
doi:10.1038/379060a0 (https://doi.org/10.1038%2F379060a0). S2CID 205026185 (https://api.semanticsc
holar.org/CorpusID:205026185).
43. Coghlan, Herbert Henery. (1977). Notes on prehistoric and early iron in the Old World. Oxprint. pp. 99–
100
44. Manning, Charlotte Speir. Ancient and Medieval India. Volume 2 (https://books.google.com/books?id=nm
ESJR3a0RYC&pg=PA365). ISBN 978-0-543-92943-3.
45. The Story of Civilization, Our Oriental Heritage (https://archive.org/details/storyofcivilizat035369mbp).
Simon and Schuster. 1935. p. 539 (https://archive.org/details/storyofcivilizat035369mbp/page/n642).
ISBN 0-671-54800-X. Retrieved 4 March 2017.
46. Sanderson, Katharine (2006-11-15). "Sharpest cut from nanotube sword" (https://doi.org/10.1038%2Fnew
s061113-11). Nature News. doi:10.1038/news061113-11 (https://doi.org/10.1038%2Fnews061113-11).
S2CID 136774602 (https://api.semanticscholar.org/CorpusID:136774602).
47. Wayman, M.L. & Juleff, G. (1999). "Crucible Steelmaking in Sri Lanka". Historical Metallurgy. 33 (1): 26.
48. Hartwell, Robert (1966). "Markets, Technology and the Structure of Enterprise in the Development of the
Eleventh Century Chinese Iron and Steel Industry". Journal of Economic History. 26: 53–54.
doi:10.1017/S0022050700061842 (https://doi.org/10.1017%2FS0022050700061842). S2CID 154556274
(https://api.semanticscholar.org/CorpusID:154556274).
49. Tylecote, R.F. (1992) A history of metallurgy 2nd ed., Institute of Materials, London. pp. 95–99 and 102–
105. ISBN 0-901462-88-8.
50. Raistrick, A. (1953) A Dynasty of Ironfounders.
51. Hyde, C.K. (1977) Technological Change and the British iron industry. Princeton
52. Trinder, B. (2000) The Industrial Revolution in Shropshire. Chichester.
53. Barraclough 1984, pp. 48–52.
54. King, P.W. (2003). "The Cartel in Oregrounds Iron: trading in the raw material for steel during the
eighteenth century". Journal of Industrial History. 6 (1): 25–49.
55. "Iron and steel industry". Encyclopædia Britannica. 2007.
56. Barraclough, K.C. (1984) Steel before Bessemer: II Crucible Steel: the growth of technology. The Metals
Society, London.
57. Swank, James Moore (1892). History of the Manufacture of Iron in All Ages. Burt Franklin Publisher.
ISBN 0-8337-3463-6.
58. Bessemer process (https://www.britannica.com/technology/Bessemer-process). Vol. 2. Encyclopædia
Britannica. 2005. p. 168.
59. Sherman, Zander (4 September 2019). "How my great-grandfather's Dofasco steel empire rose and fell,
and his descendants with it" (https://www.theglobeandmail.com/business/rob-magazine/article-how-my-gr
eat-grandfathers-dofasco-steel-empire-rose-and-fell-and-his/). The Globe and Mail Inc.
60. Basic oxygen process. Encyclopædia Britannica. 2007.
61. Fruehan & Wakelin 1998, pp. 48–52.
62. "Steel Industry" (https://web.archive.org/web/20090618230340/http://bx.businessweek.com/steel-industr
y/). Archived from the original (http://bx.businessweek.com/steel-industry/) on 2009-06-18. Retrieved
2009-07-12.
63. "Congressional Record V. 148, Pt. 4, April 11, 2002 to April 24, 2002 (https://books.google.com/books?id=
iOgfSDKecCcC&pg=PA4557)". United States Government Printing Office.
64. Chopra, Anuj (February 12, 2007). "India's steel industry steps onto world stage" (http://csmonitor.com/20
07/0212/p07s02-wosc.html). Cristian Science Monitor. Retrieved 2009-07-12.
65. "Worldsteel | World crude steel output decreases by -2.8% in 2015" (https://web.archive.org/web/2017020
2084313/http://www.worldsteel.org/media-centre/Press-releases/2016/--World-crude-steel-output-decreas
es-by--2.8--in-2015.html). Archived from the original (https://www.worldsteel.org/media-centre/press-relea
ses/2016/--World-crude-steel-output-decreases-by--2.8--in-2015.html) on 2017-02-02. Retrieved
2016-12-26.
66. "Top Steelmakers in 2017" (https://web.archive.org/web/20180823005844/https://www.worldsteel.org/en/d
am/jcr:1a0978ce-d387-4ce9-8d1b-5f929f343ac1/2017_2016+top+steel+producers_Extended+list.pdf)
(PDF). World Steel Association. Archived from the original (https://www.worldsteel.org/en/dam/jcr:1a0978
ce-d387-4ce9-8d1b-5f929f343ac1/2017_2016+top+steel+producers_Extended+list.pdf) (PDF) on August
23, 2018. Retrieved August 22, 2018.
67. "Long-term planning needed to meet steel demand" (https://www.webcitation.org/5twr3Sstf?url=http://ww
w.hellenicshippingnews.com/index.php?option=com_content&task=view&id=1576&Itemid=46). The
News. 2008-03-01. Archived from the original (http://www.hellenicshippingnews.com/index.php?option=co
m_content&task=view&id=1576&Itemid=46) on 2010-11-02. Retrieved 2010-11-02.
68. Rossi, Marcello (2022-08-04). "The Race to Remake the $2.5 Trillion Steel Industry With Green Steel" (htt
ps://singularityhub.com/2022/08/04/the-race-to-remake-the-2-5-trillion-steel-industry-with-green-steel/).
Singularity Hub. Retrieved 2022-08-06.
69. "Global Steel Industry's GHG Emissions" (https://www.globalefficiencyintel.com/new-blog/2021/global-ste
el-industrys-ghg-emissions). Global Efficiency Intelligence. 6 January 2021. Retrieved 2022-08-06.
70. Uchitelle, Louis (2009-01-01). "Steel Industry, in Slump, Looks to Federal Stimulus" (https://www.nytimes.
com/2009/01/02/business/02steel.html?_r=1&partner=permalink&exprod=permalink). The New York
Times. Retrieved 2009-07-19.
71. Fenton, Michael D (2008). "Iron and Steel Scrap". In United States Geological Survey (ed.). Minerals
Yearbook 2008, Volume 1: Metals and Minerals. Government Printing Office. ISBN 978-1-4113-3015-3.
72. The World Steel Association (2018-03-01). "Steel and raw materials" (https://www.worldsteel.org/en/dam/j
cr:16ad9bcd-dbf5-449f-b42c-b220952767bf/fact_raw%2520materials_2018.pdf) (PDF).
73. "High strength low alloy steels" (http://resources.schoolscience.co.uk/Corus/16plus/steelch3pg1.html).
Schoolscience.co.uk. Retrieved 2007-08-14.
74. "Dual-phase steel" (https://web.archive.org/web/20110525170931/http://www.intota.com/experts.asp?strS
earchType=all&strQuery=dual%2Dphase+steel). Intota Expert Knowledge Services. Archived from the
original (http://www.intota.com/experts.asp?strSearchType=all&strQuery=dual%2Dphase+steel) on 2011-
05-25. Retrieved 2007-03-01.
75. Werner, Ewald. "Transformation Induced Plasticity in low alloyed TRIP-steels and microstructure
response to a complex stress history" (https://web.archive.org/web/20071223184922/http://www.wkm.mw.
tum.de/Forschung/projekte_html/transtrip.html). Archived from the original (https://www.wkm.mw.tum.de/F
orschung/projekte_html/transtrip.html) on December 23, 2007. Retrieved 2007-03-01.
76. Mirko, Centi; Saliceti Stefano. "Transformation Induced Plasticity (TRIP), Twinning Induced Plasticity
(TWIP) and Dual-Phase (DP) Steels" (https://web.archive.org/web/20080307200557/http://www.dimet.uni
ge.it/resta/studenti/2002/27839/26/TWIP%2CTRIPandDualphase%20mirko.doc). Tampere University of
Technology. Archived from the original (http://www.dimet.unige.it/resta/studenti/2002/27839/26/TWIP,TRIP
andDualphase%20mirko.doc) on 2008-03-07. Retrieved 2007-03-01.
77. Galvanic protection. Encyclopædia Britannica. 2007.
78. "Steel Glossary" (http://steel.org). American Iron and Steel Institute (AISI). Retrieved 2006-07-30.
79. "Steel Interchange" (https://web.archive.org/web/20071222180444/http://aisc.org/MSCTemplate.cfm?Sect
ion=Steel_Interchange2&Template=%2FCustomSource%2FFaq%2FSteelInterchange.cfm&FaqID=2311).
American Institute of Steel Construction Inc. (AISC). Archived from the original (http://aisc.org/MSCTempl
ate.cfm?Section=Steel_Interchange2&Template=/CustomSource/Faq/SteelInterchange.cfm&FaqID=231
1) on 2007-12-22. Retrieved 2007-02-28.
80. "Properties of Maraging Steels" (https://web.archive.org/web/20090225211327/http://steel.keytometals.co
m/default.aspx?ID=CheckArticle&NM=103). Archived from the original (http://steel.keytometals.com/defau
lt.aspx?ID=CheckArticle&NM=103) on 2009-02-25. Retrieved 2009-07-19.
81. Tweedale, Geoffrey, ed. (1987). Sheffield Steel and America: A Century of Commercial and Technological
Independence. Cambridge University Press. pp. 57–62.
82. Bringas, John E. (2004). Handbook of Comparative World Steel Standards: Third Edition (https://web.arc
hive.org/web/20070127135646/http://www.astm.org/BOOKSTORE/PUBS/DS67B_SampleChapter.pdf)
(PDF) (3rd. ed.). ASTM International. p. 14. ISBN 0-8031-3362-6. Archived from the original (http://astm.o
rg/BOOKSTORE/PUBS/DS67B_SampleChapter.pdf) (PDF) on 2007-01-27.
83. Steel Construction Manual, 8th Edition, second revised edition, American Institute of Steel Construction,
1986, ch. 1 pp. 1–5
84. Ochshorn, Jonathan (2002-06-11). "Steel in 20th Century Architecture" (http://www.ochshorndesign.com/c
ornell/writings/steel.html). Encyclopedia of Twentieth Century Architecture. Retrieved 2010-04-26.
85. Venables, John D.; Girifalco, Louis A.; Patel, C. Kumar N.; McCullough, R.L.; Marchant, Roger Eric;
Kukich, Diane S. (2007). Materials science (https://www.britannica.com/technology/materials-science).
Encyclopædia Britannica.
Bibliography
Ashby, Michael F.; Jones, David Rayner Hunkin (1992). An introduction to microstructures, processing
and design. Butterworth-Heinemann.
Barraclough, K. C. (1984). Steel before Bessemer: I Blister Steel: the birth of an industry. London: The
Metals Society.
Bugayev, K.; Konovalov, Y.; Bychkov, Y.; Tretyakov, E.; Savin, Ivan V. (2001). Iron and Steel Production (h
ttps://books.google.com/books?id=MJdIVtmwuUsC). The Minerva Group, Inc. ISBN 978-0-89499-109-7.
Davidson, H. R. Ellis (1994). The Sword in Anglo-Saxon England: Its Archaeology and Literature.
Woodbridge, Suffolk, UK: Boydell Press. ISBN 0-85115-355-0.
Degarmo, E. Paul; Black, J T.; Kohser, Ronald A. (2003). Materials and Processes in Manufacturing
(9th ed.). Wiley. ISBN 0-471-65653-4.
Fruehan, R. J.; Wakelin, David H. (1998). The Making, Shaping, and Treating of Steel (11th ed.).
Pittsburgh, PA: AISE Steel Foundation. ISBN 0-930767-03-9.
Verein Deutscher Eisenhüttenleute (Ed.). Steel – A Handbook for Materials Research and Engineering,
Volume 1: Fundamentals. Springer-Verlag Berlin, Heidelberg and Verlag Stahleisen, Düsseldorf 1992,
737 p. ISBN 3-540-52968-3, 3-514-00377-7.
Verein Deutscher Eisenhüttenleute (Ed.). Steel – A Handbook for Materials Research and Engineering,
Volume 2: Applications. Springer-Verlag Berlin, Heidelberg and Verlag Stahleisen, Düsseldorf 1993, 839
pages, ISBN 3-540-54075-X, 3-514-00378-5.
Smith, William F.; Hashemi, Javad (2006). Foundations of Materials Science and Engineering (4th ed.).
McGraw-Hill. ISBN 0-07-295358-6.
Further reading
Mark Reutter, Making Steel: Sparrows Point and the Rise and Ruin of American Industrial Might (https://b
ooks.google.com/books?id=bdkUfDoY24QC). University of Illinois Press, 2005.
Duncan Burn, The Economic History of Steelmaking, 1867–1939: A Study in Competition (http://questia.c
om/PM.qst?a=o&d=3914930). Cambridge University Press, 1961.
Harukiyu Hasegawa, The Steel Industry in Japan: A Comparison with Britain (http://questia.com/PM.qst?a
=o&d=108742046). Routledge, 1996.
J.C. Carr and W. Taplin, History of the British Steel Industry (http://questia.com/PM.qst?a=o&d=808791).
Harvard University Press, 1962.
H. Lee Scamehorn, Mill & Mine: The Cf&I in the Twentieth Century (http://questia.com/PM.qst?a=o&d=94
821694). University of Nebraska Press, 1992.
Warren, Kenneth, Big Steel: The First Century of the United States Steel Corporation, 1901–2001 (http://e
h.net/bookreviews/library/0558). University of Pittsburgh Press, 2001.
External links
Official website (http://www.worldsteel.org/) of the World Steel Association (worldsteel)
steeluniversity.org (http://steeluniversity.org/): Online steel education resources, an initiative of World
Steel Association
Metallurgy for the Non-Metallurgist (https://books.google.com/books?id=brpx-LtdCLYC&pg=PA26) from
the American Society for Metals
MATDAT Database of Properties of Unalloyed, Low-Alloy and High-Alloy Steels (http://www.matdat.com)
– obtained from published results of material testing