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Practical Wet Test For Basic Radical 1+2

This document summarizes the analysis of cation groups using wet chemical tests. It describes 7 groups of cations - Group 0 (NH4), Group I (Pb, Ag), Group II (Pb, Cu), Group III (Fe), Group IV (Ni, Mn, Zn), Group V (Ba, Ca, Sr), and Group VI (Mg). For each group, it lists the reagents used to identify the cations and any precipitates formed. Confirmatory tests are also described to verify the identity of the cations in each group. The document provides details of the procedures, chemical reactions, and observations for analyzing samples to determine which cation group is present.

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0% found this document useful (0 votes)
1K views8 pages

Practical Wet Test For Basic Radical 1+2

This document summarizes the analysis of cation groups using wet chemical tests. It describes 7 groups of cations - Group 0 (NH4), Group I (Pb, Ag), Group II (Pb, Cu), Group III (Fe), Group IV (Ni, Mn, Zn), Group V (Ba, Ca, Sr), and Group VI (Mg). For each group, it lists the reagents used to identify the cations and any precipitates formed. Confirmatory tests are also described to verify the identity of the cations in each group. The document provides details of the procedures, chemical reactions, and observations for analyzing samples to determine which cation group is present.

Uploaded by

psyxs4tsv9
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© © All Rights Reserved
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Date:

Pago:29

WET JETS FOR BASIC RADICALS (CATION&


hcohonallen praeliminau tesks, is finall detek2d
ond conimmad tzouan gustecmaieonglugidinvolving
uAot tests..Fox qualtahivë anoysiscoing an
clasgikied as:
Caions
GToOup zera NH4
Pb2
Garoup I-
Pb Cu2
Gzsa up 1 Fe3t
Grsoup lo2,Ni2, Mn2 Zn
Cnoup N Ba2 9 Ca2
Ma2
Taxoup VL
Ha sep0xatiom_Of coian inta vaxiau& qOUp by
moking u&e of Ruitable Seaqentag (knõuwn 03 qsoup
neaagn is bosed an diffexonce inchamical prsopexheg
of ahons.
Gzaup Gsoup COgent Coions Fosm in which
cahonsoxa
peipitakd
No
zeO
Group I Dilute HC P2 ChlosidS
Dato

Phea30

GTGOUp Grsoup TeOgent CoJions Foom inuwhich


cohang axa
psecipitakd
axoup II HSinpmesenceof dilue HCI Ph2" C Sulplid
GrEOLp ILNH OH in tho presenco OF Fe3, A3 Hudrozide
NHC
arsoup IV HS mtho poesence oF NiMn2t Sulphides
NH4OH Zn2 Co
GTODp NHy, CO in presencL Of o Bas{Loxbanok3
NH4OH
|Croup VT No Ma

ANALYSLS OE GnROUP I (SILVER GROUP)


amp eagent fx miaQKOLp i 2 tdil. hudrochlonic ouid.
Itincludes Ph Aa and
Psocoduo
T th igina scluhonadd dil HCL,4Fa white
preripikak ie femed, frgtqKoup (PK*)iaprSe&ent
a Files and u0h te pptith distiled cater
and ezoming as tolot uing
Boil tho white psecipita with 5-10mloP oate
Poecipitae digsolvesDivido the <oluhion. lanMmahom
4. Coolamo_pautOF coluion undox tap Whiie custa 00ine
ppi80paHalke
2 PaBaLium_iadida keatTo tho eecmd pant add
KI 30lohm qellau ppt
3. Poiasium chuomnahe test A thirdpOnt,Qadd
K,C0e 90lution=ueQDQuupp
CONELRMATORY EST
On c0oling, pecipitotes eeitlo daun 0s PbCl, is
Lo soluble in cald uwake.
ANALYSIS OF CnROUP L (COPpER GROUP)
raOup Raaent £as t a asOup is Hgas in proeenco of
dil. HCI
Black ppt. (Pb x u2
Hent tho blockpptwith minimum quantity (12m) Of50
HNO, Ppt dissolves. to onn patt Oftho obave golution,
Odd dil. H, So and olcohal
White Ppt. (Ph2) No uwhie ppt
lo eutafE tho galutHom odd
NH20Hin exco28
ConHimaaiom
Digeolye ppkin hot ammaNIumBlu0_colouxOd golution
ocatate soluhion. CCu2
ConEimmabion
Det

A Pot.agsium iadido Hest_ A Potnssiim fernocyanid


Hegt
Tbm poxtadd KT 20lution. To one pont of blug solutiam
Yellouppt. is faamod thatcanodd acaHc acid apd pot
be dissolvedin boiliaauooLond-auiumferxadiantde
on cooling ecugtoize Solutian, Chocalak bmun
ppti formadd
2 btasium_ehMOmale test 2. Potassium iodida lest
6onath pOHF add pabossium o ootho partadd acoic
chaomate solution.Yellar ppllaid and pgkausium iodida
fnmnod wkich dissalyes insclution Auhide ppt is
NaOtl ealution faranagd in braun colouud
salutian.

ANAL Yig AF (nROUP T IRON GGROUP)


ooupeagent Xx Mig asoup ig NH4CH im paeiencg af
NH4CL
RraCedLe
Takeabout 5 mOf onqinol salutiom and add 45 dops
Of coe, nitzic ocid. Boil it and add 2q0f s0lid
NH4CLBoilagain and cool ho colution dnden tap
wakhAdd ezcoS QE ammmiuN udgozido ond shake.
A ppt shouss ho pe2ence of catim af Cusoup 11l.
Filte pp, usa3h umith olk and naBe to colCu
OP tho pecipitak
JRS
Chamical Reochions involved in onalusis of Gtroup
Alwminium CA3)ootoss ondliod orhulowzb
A. Lake test

AllOH)st 3H CI AlCl+3H, O diasoloHon

c b AClgt 3NH4OH 3NH,C AIOH) J


Blu colawadosbs
sA.osloe 29ioezihGfths ppt.2
. orhufo2 0oV

(003 0 ) t uoao0212kra

qorb
no oe
Dte:
Pe:33
Fe3t(Reddish bsouwn ppt.2_ A13 (White ppt:2
Digsalve ppt. indil HCLond
divide the aoluhan
Confimaian ComimaHon
Pahassium fenrocuanide test |4.lake kest
loone paNt add potassiuomDigsale ppt in dil HCland
fenyocuanide Paggian bluo ladd tuoo dsops of hluo
Lobueahon litmus soluion.Add
NHA OH dropuwise il1 blua
colou develops. Blue ppt.
floaing
2. fotassium sulphocanido test
b ha seand partadd
pchassium ulphocuanid.Blood
ed colcLtohon

ANAYSIS OF CROUP T (ZINC CROUP)

POcoduKe
Use h am ammonlacol golulianof thind Qsaup fa
th foith qsoup fosst S qas thaough the toluion.
Afpp ig fiarmed,poP&encA or radimlof qonup V
igindicoltd Filten ho Pptand woah * with1
waenNote in colouto ppt
Dt:

Back ppt (Co2 or N25|BufeLFlesh> DuQN white


Obseve tha colau of oniqinal saltLcoloLXLd pptlppt 2

4 saltispunple_or deop violet in Mn


Mn2+
colou pex{omm cornipaolom tesk
Fors Co2 ond ifitis oneenich
peos con timaomy tezt tor
N ith oniqinal edluhian-
Canimaion of o onhimahonCf onhimaianoflbr:tht-to_
N:2 Mn2 onfinmohen |
Of Zn2
1.Potas8ium niEritela Dimnthsloluakini 1.cdium- u Sodiumn
test tegt kus0zide -Ba, udozide
la.an paxEof Add NaOH_ Add sodium |
salshanOdd solutian Qdd &aluian &hakelhudxoxide
ommaniun kudsozidmpaaniumm Aite ppt soluhion
n nuholié malhydnazida solbk-lig fomad. Addl.dsopwise.A
soluhon.Add onan lendrapd Br attn to uhite pptis
ocaic acid anda lof dimoth wnite pptAHkrmid.Add
ugtalof QlLyauime Huns bla.ck moxe_of NaOH_
potasgium nitik Baightrose redLox bxown. whik ppt.
awm.Auelloo ppE. ieobBoined| dissolves
Ppt:i facrasd
Dete
:35

ANALYR3 OF GIROUP VI (MAGINESIUM GIROUP)


Ammomivm_phosplate teat
D a patof tho oioinal salution ,add same.
colid NH4C ond NH4OH n gliaht ezcoaghon_ada
oamomniym phogphate 80luhonan eHOrh tho sides
OF ho Hegt the titn o qlagKOd.
2
A uwhitH ppt. Con fims Mq

(N t R 2

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