IJSO 2021 MCQ Solution Set
IJSO 2021 MCQ Solution Set
Constants
Acceleration due to gravity g = 9.8 ms-2
Specific heat of water is 4.2 kJ kg-1 K-1 and the density of water is 1000 kg m-3
Mechanical equivalent of heat = 4.18 Jcal-1
Answer: (a).
Explanation: At 12 and 6 O’ clock positions, the velocity of the observer sitting on the
merry-go-round with respect to the siren is zero, so no change in frequency.
At 9 O’clock position the observer is moving towards the source and 3 O’clock the
observer is moving away from the source. So the observer gets higher pitch at 9 O’clock
position and lower pitch at 3 O’clock position.
1
2. A light beam is travelling from vertically infinite region 1 to vertically infinite region 4 (refer to
figure). The refractive indexes in regions 1, 2, 3, 4 are 1.62, 1.60, 1.55, and 1.50, respectively.
The angle of incidence θ for which the beam just misses entering region 4 is
1.50
a) sin−1 �1.55�
1.50
b) sin−1 �1.62�
1.60
c) sin−1 �1.62�
1.55
d) sin−1 �1.60�
Ans.: (b)
1.50
Critical angle from region 3 to region 4: sin 𝜃𝜃𝑐𝑐 = 1.55
Applying Snell’s law in consecutive regions: 1.62 sin 𝜃𝜃 = 1.60 sin 𝛼𝛼 = 1.55 sin 𝜃𝜃𝑐𝑐
1.50
1.62 sin 𝜃𝜃 = 1.50 𝜃𝜃 = sin−1 1.62
2
3. In the following circuit, the current through the resistor
R (=2 Ω) is I Amperes. The value of I is
a) 0.5 A
b) 1.0 A
c) 1.8 A
d) 2.0 A
Ans.: b)
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4. Heater of an electric kettle is made of a wire of length L and diameter d. It takes 4 minutes to
raise the temperature of 0.5 kg of water by 40 K when connected to a line voltage source. This
heater is replaced by a new heater having two wires of the same material, each of length L
and diameter 2d. Which of the following options is correct regarding the time taken for
heating the same amount of water through the same temperature difference?
a) 4 minutes if wires are in series.
b) 2 minutes if wires are in parallel.
c) 1 minute if wires are in series.
d) 0.5 minute if wires are in parallel.
Ans.: d)
𝜌𝜌𝜌𝜌 4𝜌𝜌𝜌𝜌
Initial Resistance is 𝑅𝑅 = 𝜋𝜋𝑟𝑟 2 = 𝜋𝜋𝑑𝑑2
𝜌𝜌𝜌𝜌 𝜌𝜌𝜌𝜌 𝑅𝑅
When wires are changed resistance will be 𝑅𝑅 ʹ = 𝜋𝜋(2𝑟𝑟)2 = =
𝜋𝜋𝑑𝑑2 4
When wires are connected in series the resistance will be 2R’ = R/2
When wires are connected in parallel the resistance will be R’ /2= R/8
𝑉𝑉 2 𝐸𝐸 4
𝐸𝐸 = 𝑃𝑃𝑃𝑃𝑃𝑃𝑃𝑃𝑃𝑃 × 𝑡𝑡𝑡𝑡𝑡𝑡𝑡𝑡 = 𝑡𝑡 = 𝑅𝑅
𝑅𝑅 𝑉𝑉 2
When wires are connected in series the time required will be t = 2 minutes
When wires are connected in parallel the time required will be t = 0.5 minutes
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5. Consider a cannon ball of mass 200 kg is projected from cannon placed in front of Burj Khalifa
at angle of 60 degree with the horizontal with a velocity 100 km/hr during holy month of
Ramadan. The initial kinetic energy at the time of projection of the cannon ball is K. Then, its
kinetic energy at maximum height during its projection will be.
a) K
b) K/2
c) K/4
d) K/3
Ans.: c)
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6. A given ray of light suffers minimum deviation in an equilateral prism P. Additional prisms Q
and R of identical shape and of the same material as P are now added as shown in the figure.
The ray will now suffer
P R
a) Greater deviation.
b) Same deviation as before.
c) Total internal reflection.
d) No deviation.
Ans.: b)
As the incident ray is suffering minimum deviation, angle of incidence is equal to the
angle of emergence which should be the angle of incidence for the second prism as the
refracting surfaces are parallel.
Hence the ray will suffer minimum deviation in each prism and the final angle of
emergence will be equal to the initial angle of incidence.
Thus the ray will suffer same deviation as the case for a single prism.
7. When two mechanical waves meet in a small region of space, superposition of the two waves
takes place. This is known as interference of waves. Which of the following statements is false?
a) The resultant displacement of the two waves can be obtained by adding their individual
displacements.
b) The waves leaving the region carry less energy than the waves had before interference.
d) After leaving the region, the characteristics of the waves remain same as before
interference.
Ans.: b)
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8. While doing an experiment in physics laboratory, Mustafa connected
two coils (say coil 1 and coil 2) in series with a galvanometer and
dropped a magnet through the coils, as shown in the figure. He
noticed that there was no deflection in the galvanometer when the
magnet passed through coil 2 and observed a large deflection when it
passed through coil 1. He noticed that both coils are identical in shape,
size and material. Both had same number of turns and the speed with
which the magnet passed through each coil was nearly the same. He
concluded that
Ans.: d)
Windings in the coil B has been done in both the directions such that the no of turns in
clockwise direction is equal to the no. of turns in the anticlockwise direction.
Thus, the induced emfs produced in coil 2 are in opposite direction because of which
galvanometer does not show any deflection.
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9. A typical ping pong ball is dropped from a height of 1 m above a marble floor. The ball bounces
several times before it comes to rest. For every successive bounce, it loses 20% of its
maximum height. Fatima plotted two quantities that she observed in this phenomenon vs time
and the graphs are shown below. Identify the two quantities plotted on vertical axis vs time
along the horizontal axis.
time (S)
Ans.: b)
The velocity keeps on increasing linearly (-gt) with time until the ball hits the ground
then it reverses within a short time.
Kinetic energy is always positive and increases quadratic with velocity.
Time taken for each bounce is progressively shorter.
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10. Mercury is the fastest planet in the solar system moving with an average orbital speed of
47 km/s. The earth moves slower with an average orbital speed of 30 km/s. What is the
radius of mercury’s orbit around the Sun in astronomical units (nearly equal to the orbital
radius of earth)?
Solution (b)
𝑇𝑇 ∝ 𝑅𝑅 3/2 and also 𝑇𝑇=2𝜋𝜋R/𝑣𝑣 ⇒ 𝑣𝑣 ∝ (1/𝑅𝑅 1/2) ⇒ 𝑣𝑣1/𝑣𝑣2= (R2/ R1)1/2
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IJSO 2021 Chemistry MCQ Solution
Question 1
In a titration of acid mixture with base, the teacher prepared an acid mixture by mixing 4mL
of 4M HCl, 4mL of 18M H2SO4 and a certain volume of 4M HNO3, and then made up 3 L of
solution using distilled water. She used an aqueous solution of Sodium Carbonate
(Na2CO3.10H2O) as base for the titration, that was prepared by dissolving 2g of
(Na2CO3.10H2O) in water and diluting to 100 mL with distilled water. After performing the
titration, she observed that 15 mL of the acid mixture required 7.5 mL of Sodium Carbonate
solution for complete neutralisation. The amount of nitrate ions in the acid mixture is
a) 0.124 g
b) 3.1 g correct answer
c) 0.31 g
d) 1.24 g
Solution:
Let the volume of HNO3 acid be V mL.
Total equiv.of the acid mixture = [ (4 x V)+ (4 x 4) + (36 x 4) ]/1000
= (4V+ 16+144)/1000 = (4V+160) /1000
equiv.of acid in 15mL of this acid mixt. = [(160+ 4V)/1000 ] X 15 Eq.1
3000
Now Normality of Na2CO3.10H2O solution = (g/L)/ eq.wt.= 20/143
equiv. of 7.5mL of Na2CO3.10H2O solution = (20/143)X 7.5
1000
Thus equiv. of 15mL of acid mixt. = .equiv. of 7.5mL of Na2CO3.10H2O solution. Eq. 2
Alternate Solution:
Let the volume of HNO3 acid be V mL.
Total mmol of acid in mixture = (4X4) + (4X18)+ 4V
HCl H2SO4 HNO3
Question 2
UAE has vast reserves of limestone particularly in
the eastern and northern parts of the Emirates.
Jabel Hafeet Mountain is the part of Hajar
mountains and made of predominantly tertiary
sedimentary rock –Limestone. It is primarily
composed of Calcite which is chemically Calcium
carbonate. Calcite is used on a large scale as a
building material.
A mason was designing a pattern of transparent calcite tiles that were to be fixed in the
laboratory. He spread the tiles on the table to arrange different patterns. Accidently two
tiles from the pattern came loose and fell in a container having 100g of hydrochloric acid
solution. Each pure calcite tile weighs exactly 20g, and hydrochloric acid solution in the
container contains one tenth of its weight of pure acid. Assuming that both tiles dissolve
equally, what is the weight of each tile that remain undissolved?
a) 26.31 g
b) 13.15 g correct answer
c) 6.31g
d) 13.69 g
Solution:
Wt. of HCl taken = 100g. Wt. of pure acid in 100g of HCl solution = 100X0.1=10g
Question 3
The solid fuel in the booster stage of the space shuttle is a mixture of ammonium
perchlorate (NH4ClO4) and aluminium powder. On the ignition of this mixturethe products
obtained are solid aluminium oxide, gaseous hydrochloride, water, and nitrogen gas. Using
following data find out the standard enthalpy change at 298K for the reaction.
a) –9769 kJ
b) –9732.7 kJ correct answer
c) –8625.1 kJ
d) –8132.1 kJ
Solution:
ΔH = HP-HR
HR = 6(-295.3) = -1771.8
Solution:
Question 5
X ray diffraction studies show that an alkaline earth metal has a face centred cubic
structure with a unit cell width 0.197 nm. If the density of the metal is 1.55 g∙cm-3, the
number of atoms present in 40 g of the metal are:
a) 3.37 x 1024
b) 6.74 x 1024
c) 1.35 x 1025 correct answer
d) 2.70 x 10 25
Solution:
Volume of unit cell =( 0.197 x 10-9 m)3= (0.197 x 10-7cm)3= 7.65 x 10-24cm3
Volume of 40 g of metal= mass/density=40/1.55=25.81 cm3
Number of unit cells in this volume=25.81 / 7.65 x 10-24 = 3.37 x 1024
Number of atoms in this volume = 4[3.37 x 1024 ] =1.35 x 1025
Question 6
The graphs in the table below represent conductometric titrations. Choose the appropriate
entry/entries from graphs to match each of the entries in titrations. All entries in titrations
refer to aqueous solutions. (Hint: Conductance depends on number of ions as well as nature
of the ions).
Solution:
Question 7
When a l g piece of metal (Atomic Weight 89) was dropped into dilute sulphuric acid, a large
amount of gas was evolved. All the gas was collected and dried to remove moisture and was
found to occupy a volume of 378cm3 at STP. The resulting solution was electrolysed
between platinum electrodes using a current of 1A for a period of 15 minutes. The following
statements can be made about the above entire process:
Solution
22400 cm3 of hydrogen = 2 equivalents of hydrogen.
378 cm3 of hydrogen = 0.03375 equivalents of hydrogen.
Question 8
Ion exchange Resins are used to soften water. They contain sodium ions which get
exchanged with ‘hard’ ions like Ca2+ and Mg2+. Resins are not 100% efficient i.e. all sodium
ions present in the resin do not get exchanged at once and may need repeated passage of a
solution through the column to attain full efficiency.
Molecular formula of a commercial ion –exchange resin is C7H6SO3Na. A 100 cm3 solution
containing 0.3 mol L-1 of Mg2+ is passed through a column of ion exchange resin weighing
20g only once. What are the molarities of Mg2+ andNa+, respectively, in the solution
obtained after passing through the column, if the exchange efficiency is only 25 %.
a) 0.13 M and 0.26 M
b) 0.26 M and 0.17 M
c) 0.17M and 0.26 M correct answer
d) 0.21 M and 0.14 M
Solution:
Molar mass of the resin =193
2 molecules of the resin take up one Mg2+ ion.
386g of resin takes up 1mol of Mg2+ ions.
1g of the resin can take 2.59X 10-3mol of Mg2+
20g of the resin can take 51.8X 10-3mol of Mg2+ or 51.8 mmol
Exchange efficiency is only 25% 0.25 x 51.8 mmol of Mg2+ is exchanged = 12.95 m mol
of Mg2+is exchanged.
Initial amount of Mg2+ is 100 X 0.3 = 30 mmol
Amount exchanged = 12.95 mmol.
Amount left = 30-12.95= 17.05 mmol
Molarity= 17.05 / 100= 0.17 M
Question 9
The electrode reactions involved in the charging process of a lead storage battery are:
PbSO4+ 2 e → Pb + SO42-
PbSO4 + 2 H2O → PbO2 + SO42- + 4 H+ + 2 e
In a certain lead storage battery containing 2 L of aqueous sulphuric acid, the specific
gravity of the electrolyte was found to be 1.14 (20% H2SO4 by weight). This was
charged using average current of 1.67 A till the specific gravity rose to 1.28 (36.9%
H2SO4 by weight). What was the duration of the charging process?
a) 80 hours correct answer
b) 100 hours
c) 160 hours
d) 188 hours
Solution:
Overall rxn is 2 PbSO4 + 2 H2O Pb + PbO2 + 2 H2SO4
Hence in this rxn., .eq. wt of H2SO4 = mol wt = 98 (2 moles electrons for 2 mol H2SO4)
Before charging: (100/1.14) mL H2SO4 soln contains (20/98) eq of H2SO4
2000 mL soln = (20/98) x 2000 /(100/1.14) = 4.65 eq
After charging: 2000 mL = (36.9/98) x 2000 x ( 1.28/100) = 9.64 eq
Time required for charging = 4.99 x 96500 / 1.67 = 288344 sec = 80 hours
Question 10
Arrange the molecules H2O, H2S, BF3and NH3in order of their increasing dipole moment.
NH3 1.47
NH3 is pyramidal, N-H bond moment is larger than S-H bond moment
For studying the interactions between the organisms, the ecologist introduced a population of
a carnivorous fish (which feed only on other small fish) in the waterbody.
Which one of the following statements is the correct statement regarding the long term
consequence of this introduction?
Ans. c. [Explanation: Food webs are defined by their biomass. Biomass is the energy in
living organisms. Autotrophs, the producers in a food web, convert the sun's energy into
biomass. Biomass decreases with each higher trophic level. Because biomass decreases with
each trophic level, there are always more autotrophs than herbivores in a healthy food web.
There are more herbivores than carnivores. As a population of carnivorous fish is introduced
in the waterbody, the carnivorous fish will start feeding on the small fish (secondary
consumers). This will lead to a decline in the population of the secondary consumers. As the
population of secondary consumers declines, it will result in the population growth of the
herbivores because now there will be fewer small fish to feed on them. With the increase of
the herbivore population, the population of the autotrophs will decline because a greater
number of herbivores will be available to feed on them. Thus, the longtime consequence of
the introduction of tertiary consumer will lead to an increase in the Herbivore biomass and a
decrease in the Autotroph biomass.]
1
2.
Paramecium lives in pond water that is hypotonic to its cellular contents. However, the
Paramecium does not burst due to excess water uptake because of its contractile vacuole. The
vacuole collects fluids from a system of canals present in the cytoplasm. When full, the
vacuole and canals contract, expelling the fluid from the Paramecium.
In an experiment, the activity of contractile vacuole was monitored over time after placing
the Paramecium in a growth medium having an osmotic concentration (osmolarity) of 4
mosmol L-1 for 30 minutes and then shifted to a growth medium having an osmolarity of 24
mosmol L-1. Which one of the following graphs is a correct representation of the activity of
contractile vacuole in these two media?
2
3.
The pedigree above represents the inheritance of a genetic disorder. If the individuals marked
1 and 2 had a daughter, what is the probability that the daughter would show the disorder?
a. 1
b. 1/2
c. 2/3
d. 1/4
Ans.: b [The student has to first identify the mode of inheritance, which is X-linked recessive.
Individual 1 has the genotype XaY. Individual 2 is also a carrier XaX. The daughter will get
one X from the father that has the recessive allele and there is 50% chance of receiving the
recessive allele from the mother.]
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4.
Given below are schematic representations of chromosomes at Metaphase I of meiosis.
Which one of the following arrangement of chromosomes at the equatorial plane will
definitely ensure independent assortment of the genes ‘A’ and ‘B’ under normal meiotic
division?
The figures below depict the arrangement of alleles on the chromosomes and the alignment of
chromosomes at the equatorial plane.
a. hen chromosomes are arranged as shown and there is crossing over between genes A and
B.
b. hen 50% of the cells in meiosis have orientation I and 50% have orientation II.
c. hen 50% of the cells in meiosis have orientation I and 50% have orientation II.
Answer: b [If two genes are on different chromosomes they will always independently assort
and that is because of the two possible orientations. Option 1 is incorrect, as although this
will produce 4 kinds of gametes, all cells in meiosis will not undergo crossing over. Answer 3
is incorrect, as in metaphase I as there will be 2 chromatids per chromosomes. Answer 4 is
incorrect, as sister chromatids should have the same alleles.]
5
5.
The figure above represents two types of nephrons (labeled as A and B) observed in
mammals. Which one of the following statements regarding the nephrons is correct?
Ans. a Explanation: The main difference in the two types of nephron is the long Loop of
Henle in type B and its deeper extension into the renal medulla. The longer the loop an the
deeper its extends into the renal medulla, the greater the concentrating power of the nephron.
The loops of Henle are the longest and the urine is most hypertonic in desert dwellers such as
the kangaroo rat.
Statement b is incorrect as K+ ions are absorbed in the distal convulated tubule
Statement c is incorrect as type B nephron will absorb more sodium chloride
Statement d is incorrect as secretion of poisionous substances from bloof occurs in proximal
convulated tubule.
6
6
A small population of monkeys from Africa (Old World) are thought to have drifted to South
America (New World) on natural rafts about 40 million years ago. There were no monkeys in
the New World. On reaching South America, these monkeys bred and over time looked very
different from the monkeys in Africa. They formed new species.
1 – Old world monkeys
2- New world monkeys
Arrange the evolutionary processes that would lead to the formation of the new species.
a. Migration Adaptation Natural selection
b. Genetic drift Natural selection Adaptation
c. Natural selection Adaptation Genetic drift
d. Adaptation Genetic drift Natural selection
Ans. b [Migration refers to gene flow from one population to another. The founding
population of monkeys showed genetic drift and not migration, since no gene flow could
occur because of the absence of monkey populations in S. America. Hence 1 is wrong. 2 is
correct because the founding population formed by genetic drift, was acted upon by natural
selection over generations, which led to their adaptation to the new habitat. Natural selection
or adaptation will occur only after migration or genetic drift brings about an alteration in
allelic / gene frequencies, hence 3 and 4 are wrong. Ref:
https://www.britannica.com/science/evolution-scientific-theory/Genetic-drift]
7
7.
Ans. b [This experiment demonstrated the photosynthetic evolution of oxygen. The student
should first identify the non-random ditribution of the bacteria. This can then be correlated to
the physiological activity. Looking at the spectrum they have to arrive at the conclusion that
it is photosynthesis and this could involve oxygen liberation and thus the bacteria are aerobic]
8
8.
Filamentous cyanobacteria have special thick-walled structures called heterocysts that help in
nitrogen fixation. Nitrogen from the atmosphere is fixed by the enzyme nitrogenase present in
the heterocysts and converted to ammonia, using ATP as a source of energy. Nitrogenase is
very sensitive to inactivation by oxygen. Which of the following modifications will allow
heterocysts to effectively carry out nitrogen fixation?
a. High chlorophyll content
b. Lack of photosystem II activity
c. Enhanced CO2 fixation
d. Low respiratory rate
Ans: b [Photosystem ll is the site of oxygen evolution. Switching it off will reduce oxygen
levels and enable nitrogen fixation by nitrogenase. Chlorophyll content and CO2 fixation is
reduced and respiratory rate is high in heterocysts, so a, c and d are wrong]. Ref:
Cyanobacterial Heterocysts. Krithika Kumar et al. Cold Spring Harb Perspect Biol
2009;2:a000315)
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9
A phylogenetic tree is a diagram that depicts the lines of evolutionary descent of different
species, from a common ancestor. In the phylogenetic trees shown below, the evolutionary
descent of three organisms –Humans (1), Whale (2) and Sharks (3) has been depicted. Which
of the following phylogenetic trees correctly represents the relatedness between these three
organisms?
Ans. a [c and d are wrong because the shark is very different from whales or humans, since it
is a fish while the latter two are mammals. b is wrong because it shows that all three - sharks,
humans and whales have diversified from a common ancestor. a is correct because it shows
that whales and humans share a more recent common ancestry than they do with sharks.]
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10.
1- Interior species; 2- Edge species; 3- Sp-Y (bird); 4- Sp-X (reptile) 5- boundary zone; 6-
deep forest.
The figure depicts a forest area depicitng fauna living in deep forest or the boundary zone.
The different species may reside in specific niches. An ecological niche is defined as the sum
of its use of the biotic and abiotic resources in its environment.
Compare A and B and analyse the inferences given below:
i. A and B are examples of ecological succession.
ii. A and B are examples of habitat fragmentation.
iii. In B, interior habitat has shrunk while number of edge species increased.
iv. In B, there is an increase in both inner habitat and interior species.
v. In A and B, sp-X and sp-Y occupy different niches.
Ans: c
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