Sarada Educational Institutions

SR CHEMISTRY-9
27 Sep 2022

0
5) The freezing point of benzene decreases by 0.45 C when
1) Which of the following is an example of "Homogenous"
0.2 g of acid is added to 20 g of benzene. If acetic acid
mixture
associates to from a dimer in benzene, percentage
(1) Colloids association of acetic acid in benzene will be :
(2) Suspensions (Kf for benzene = 5.12 K kg mol−1 )
(3) True solutions (1) 74.6%
(4) None of these (2) 94.6%

2) The characteristic property of solution is (3) 64.6%

a) formation of solution is physical change (4) 80.4%

b) solute and solvent in the solution can be separated by
6) The boiling point elevation constant for toluene is 3.32 K kg
filtration o
mol
−1
. The normal boiling point of toluene is 110.7 C . The
c) solute and solvent in the solution can be separated by
enthalpy of vaporization of the toluene would be nearly:
decantation
(1) 17.0kJ mol−1
d) solution can be represented with a chemical formula
(1) a, b (2) 34.0kJ mol−1

(2) a (3) 51.kJ mol−1

(3) b, d (4) 68.0 kJ mol−1

(4) c, d 7) 60 g of urea is dissolved in 1100 gr of solution. to keep

ΔTf

kf

3) Two open beakers one containing a solvent and the other as 1 mole/kg, weight of water separated in the form of ice is
containing a mixture of that solvent with a non volatile solute (1) 60 g
are together sealed in a container. Over time - (2) 40 g
(1) The volume of the solution does not change and the (3) 20 g
volume of the solvent decreases
(4) 80 g
(2) The volume of the solution decrease and the volume of
0

the solvent increases 8) An aqueous solution containing 1g of urea boils at 100.25 C

. The aqueous solution containing 3 g of glucose in the same

(3) The volume of the solution increase and the volume of
volume will boil at (Molecular weight of urea and glucose are
the solvent decreases
60 and 180 respectively)
(4) The volume of the solution and the solvent does not
o
(1) 100.75 C
change
o
(2) 100.5 C
4) Solubility of four ionic salts S1 , S2 , S3 and S4 are plotted o
(3) 100.25 C
against temperature in Kelvin. Which of the salts will form o
(4) 100 C
exothermic solution
0
9) CO(g) is dissolved in H2 O at 30 C and 0.020 atm. Henry’s
law constant for this system is 6.20 × 10
4
atm . Thus, mole
fraction of CO(g) is
−7
(1) 1.72 × 10

−7
(2) 3.22 × 10

(3) 0.99
(1) S1

(4) 0.01
(2) S2

(3) S3 10) A solution is prepared by adding 2g of glucose into 18 g of

(4) S4
water. Calculate the mass percent of the glucose.
(1) 20 %
(2) 10 %
 (3) 12.5 % 17) The freezing point of a solution containing 0.2 g of acetic
acid in 20.0 g benzene is lowered by 0.45℃. The degree of
(4) 10.5 %
association of acetic acid in benzene is (Assume acetic acid
11) Two elements A and B form compounds of formula AB2 dimerises in benzene and Kf for benzene = 5.12 K kg
and AB4 . When dissolved in 20.0 g of benzene 1.0 g of mol
−1
) Mobserved of acetic acid = 113.78
AB2 lowers F.pt. by 2.3 C
0
whereas 1.0g of AB4 lowers (1) 94.5%
F.pt. by 0
1.3 C . The Kf for benzene is 5.4. The atomic
(2) 54.9%
masses of A and B respectively are
(3) 78.2%
(1) 27, 45
(4) 100%
(2) 42, 52
(3) 42, 25 18) A 0.004 M solution of N a2 SO4 is isotonic with a 0.010 M
solution of glucose at same temperature. The apparent
(4) 48, 52
degree of dissociation of N a2 SO4 is
12) The van't Hoff factor for 0.1 M Barium nitrate is 2.74. The (1) 0.25
percentage of dissociation of barium nitrate is
(2) 0.5
(1) 91.3 %
(3) 0.75
(2) 87 %
(4) 0.85
(3) 100 %
19) The vapour pressures of pure liquids A and B are 400 and
(4) 74 %
600 mmHg, respectively at 298 K. On mixing the two
13) Which of the following is a Homogeneous mixture liquids, the sum of their initial volumes is equal to the
(1) Oxygen and hydrogen volume of the final mixture. The mole fraction of liquid B is
(2) Complex mixture of ink 0.5 in the mixture. The vapour pressure of the final solution,
the mole fractions of components A and B in vapour phase,
(3) Petrol + Water
respectively are
(4) Water + Mercury
(1) 500 mmHg, 0.4, 0.6
14) A molecule M associates in a given solvent according to the (2) 450 mmHg, 0.4, 0.6
equation M → (M ) . For a certain concentration of M,
n
(3) 500 mmHg, 0.5, 0.5
the van’t Hoff factor was found to be 0.9 and the fraction of
(4) 450 mmHg, 0.5, 0.5
molecules associated was 0.2. The value of n is
(1) 3 20) A Current of dry air was first passed through the bulb

(2) 5 containing solution of 'A' in water and then through the bulb
containing pure water. The loss in mass of a solution bulb is
(3) 2
1.92g gm Where as that in pure water bulb is 0.08g, then
(4) 4
mole fraction of 'A' is
15) How many grams of CO2 gas dissolved in a 1 lt bottle of (1) 0.86
carbonated water if the manufacturer uses a pressure of 2.4 (2) 0.2
atmosphere in the bottling process at 25 C
0
Given KH of
(3) 0.96
CO2 water = 29.76atm/mole/l at 250 C
(4) 0.04
(1) 3.54
(2) 4.2 21) The normal boiling point of water is 373 K. Vapour pressure
of water at temperature T is 19 mm Hg. If enthalpy of
(3) 3.1
vaporization is 40.67 kJ/mol, then temperature T would be
(4) 2.5 −1 −1
(U se : log 2 = 0.3, R : 8.3J K , mol )

16) Given at 350 K p

o
= 300 torr and p
o
= 800 torr, the (Note : The answer should be K)
A B

composition of the mixture having a normal boiling point of

22) The density of 2 M solution of acetic acid (Mol. wt.60) is
350 K is
1.02 gml−1 . The molality of the solutions
(1) XA = 0.08

23) Insulin (C2 H10 O5 )n is dissolved in a suitable solvent and

(2) XA = 0.06
the osmotic pressure π(atm) of solutions of various
(3) XA = 0.04
concentrations (g / ml) C is measured at 20°C. The slope of
(4) XA = 0.02
a plot of π against ‘C’ is found to be 4.65 × 10
−3
.
Molecular weight of insulin is
(Note : The answer should be g)
24) 20 ml of 0.02 M KM nO4 was required to completely 25) The specific gravity of H2 SO4 is 1.8 g/cc and this solution
oxidise 10 ml of oxalic acid solution. What is the molarity of is found to contain 98% H2 SO4 by weight. 10 cc of this
the oxalic acid solution ? solution is mixed with 350 cc of pure water. 25 ml of this dil.
(Note : The answer should be M) H2 SO4 solution nutralises 500 ml of N aOH solution.
Then the P H
of N aOH solution is
 SR CHEMISTRY-9
27 Sep 2022
Classrooms: 2022 SR NIT G5

1) 3 2) 2 3) 3 4) 4 5) 2 6) 2 7) 2 8) 3 9) 2 10) 2 11) 1 12) 2 13) 1 14) 3

15) 1 16) 1 17) 1 18) 3 19) 1 20) 4 21) 291.4 22) 2.22 23) 5620000.0 24) 0.1 25) 12.699

Solution :- 6)
2
RT0 × M1
1) Kb =
True solutions are example of Homogeneous ΔHvap × 1000
2
mixture. RT0 × M1
ΔHvap =
1000 × Kb
2
2) 8.314 × (383.7) × 92
+ − + − =
Na Cl (s) + aq → N a (aq) Cl (aq)
1000 × Kb

A liquid has empty spaces upon dissolution = 34KJ /mn

solute particles enter these spaces. If the solvent

it removed. The solute separates out as the 7)
molarity = 1
solid. Dissolution of a solute is a physical
60 1000
change. ⇒ ×
wsolvent
= 1
60

⇒ wsolvent = 1000g
3)
The pure solvent solution will try to maintain ⇒ Given weight of solution=1100g

higher vapour pressure in the sealed container Given weight of solute=60g

and in return the solvent vapour molecules will Given weight of solvent=1040g
condense in the solution of non-volatile solute as ∴ Amount of solvent seperated as ice=1040-
it maintains an equilibrium with lower vapour 1000
pressure. (Lowering of vapour pressure is =40g

observed when a non volatile solute is mixed in a

8)
volatile solvent) o
1000
Tb − T = Kb × n ×
This will eventually lead to increase in the b
w solvent

volume of solution and decrease in the volume of Here, Tb o

, Kb & w solvent all are constants
solvent. Tb ∝ n

3 1
n Glucose= =
4) 180 60

ΔHsol = −ve n urea=1/60

As temperature increases, solubility decreases ∴ nurea = nglu cos e then Tb of urea= Tb of
incase of 's4 ' glucose

5) 9)
From data ΔT f = i × Kf × m PCO = KH × xCO
0.2 1000
0.45 = i × 5.12 × × 0.02
−7
60 20 xCO = = 3.22 × 10
1 4
0.45 = i × 5.12 × 6.2 × 10
6

0.45 = i × 5.12 × 0.166

10)
0.45 = i × 0.85 2
% (w/w) = × 100
i = 0.529 2 + 18
2
for association in Benzene = × 100
20
2CH3 COOH ⇌ (CH3 COOH )
2
= 10%
α
i = 1 −
2
α
0.529 = 1 −
2

α = 0.945 f of degree of association = 94.5

11) 18)
case 1: cal of M wt of AB2: Isotonic
W2 1000 N a2 SO4 glucose
ΔT f = kf × ×
M2 wt (g)
c1 × i = c2
1 1000
c2 0.01
2.3 = 5.4 × ×
20 i = = = 2.5
M2
c1 0.004
∴ M2 (Mwt of AB2 ) = 117.4 g i − 1 2.5 − 1
α = = = 0.75
∴ A + 2B = 117.4 → (1) n − 1 3 − 1

case 2: cal of Mwt of AB4

W2 1000 19)
ΔT f = kf × × A and B forms ideal mixture
M2 wt (g)
0
PT = P XA + P
0
XB = 500mm of H8
M2 = (M wt of AB4 ) = 207.7 g A B
0
XA P
∴ A + 4B = 207.7 → (2) YA =
A

0
eq (1) and eq (2) 2B = 90 P
0
B
+ (P
A
− P
B
0
) XA

∴ B = 45 g (0.5 × 400)
=
sub 'B' value in eq (1) we get 600 − 200 × 0.5
200
A = 27.4 g = = 0.4
500

YB = 1 − YA = 1 − 0.4 = 0.6
12)
Degree of dissociation
i − 1 20)
α = Change of weight with water
n − 1 = mole fraction
2.74 − 1 Change of weight with solution
= = 0.87 0.8
3 − 1
= = 0.04
1.92
∴ % of dissociation = 87%
For Ba(N O3 )2 : n = 3
21)
The vapour pressure of a liquid increases with
13) increase of temperature according to the
Oxygen and hydrogen is a homogenous mixture
Clausius Clayperon equation.
both are mixed and same composition
p2 ΔH 1 1
log = ( − )
p1 2.3 × 8.3 T1 T2
14)
3
i − 1 760 40.67 × 10 1 1
For association ∝ =
1 log = ( − )
− 1 19 19.11 T1 373
n

1 0.9 − 1 1 T1 =291 K
− 1 = = −
n 0.2 2
1 1 1
= 1 − = 22)
n 2 2 2 M of Acetic acid solution means
2 moles of CH3 COOH present in 1000 ml of
15)
Since P = KH × Concentration
solution.
P 2.4 Weight of acetic acid=2×60=120g
∴ C = =
KH 29.76 weight of the solution=1000×1.02=1020 g,
= 0.0806 moles lt of CO2 weight of solute=1020-120=900 g
∴ Wt of CO2 = 0.0806 × 44 = 3.54 g 2 × 1000
∴ Molality= =2.22 m
900

16) (or)
0 0
Pt = P × XA + P × XB 1000 × M
A B
m =
At normal B.pt : Ptotal = 760 torr 1000 × d − M × GM wtof solute

1000 × 2
∴ 760 = 300.XA + 800 (1 − XA ) m =
1000 × 1.02 − 2 × 60
760 = 300.XA + 800 − 800XA
m =2.22 m
40
∴ XA = = 0.08
500

17)
0.2/60
M olality = = 0.166
0.02

ΔTf = i × Kf × molality;

0.45 = 512 × i × 0.1666

i = 0.5276

i = 1 − α + α/2. α = 0.945 or 94.5%

23) 25)
W 1000 d × % (w/w) × 10
π = C RT = × RT NH =
2 SO4
M V GEW
W 2
plot between π and (g/ml)
V 98 × 1.8 × 10
=
1000 × RT
49
Slope (m) =
M
∴ NH = 36
2 SO4
1000 × RT
∴ molecular weight (M) = case (1)
slope

1000 × 0.0821 × 293 N1 V1 = N2 V2

M =
−3 36 × 10 = N2 × 360
4.65 × 10
6
M = 5.17 × 10 gr N2 = 1

case (2)
24) H2 SO4 v/s N aOH
KM nO4 H2 C2 O4
(N1 V1 ) = (N2 V2 )
H2 SO4 N aOH
N1 = 0.02 × 5 = 0.1 N2 =?

1 × 25 = N2 × 500
V1 = 20ml V2 = 10ml
25
N1 V1 = N2 V2 N2 =
500
Since 0.1 × 2 /
0 = N2 × 1 /
0
= 5 × 10
−2

N2 = 0.2 N
= [OH
−
] [For NaOH ⇒ N = M]
Since N = Molarity × valency factor ∴ P
OH
= − log(5 × 10
−2
)
0.2 = M× 2
= 1.3
∴ MH 2 C 2 O2
=0.1, H
∴ P = 12.7