Safety Data Sheet in accordance with

Regulation (EU) No.453/2010

GENAPOL PF 20 Page 1(9)

Substance key: SXR024025 Revision Date: 27.03.2015

Version : 1 - 0 / ET Date of printing : 20.04.2015

SECTION 1: Identification of the substance/mixture and of the

company/undertaking
1.1. Product identifier
Trade name
GENAPOL PF 20
Material number: 102428
CAS number : 9003-11-6

1.2. Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses of the substance or mixture
Industry sector : Industrial Performance Chemicals
Type of use : Raw material for detergents
Dispersing agent
Wetting agent

1.3. Details of the supplier of the safety data sheet

Identification of the company
Clariant Produkte (Deutschland) GmbH

65926 Frankfurt am Main

Telephone no. : +49 69 305 18000
Information about the substance/mixture
Corp Product Stewardship
e-mail: [email protected]

1.4. Emergency telephone number

00800-5121 5121 (24 h)

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture
Classification according CLP regulation (Regulation (EC) No. 1272/2008, as amended)
The product is not classified as dangerous according to Regulation (EC) No. 1272/2008.
Not a hazardous substance or mixture.

2.2. Label elements

Labelling according CLP regulation (Regulation (EC) No. 1272/2008, as amended)
Not a hazardous substance or mixture., The product does not require classification and
labelling as hazardous according to CLP/GHS.

2.3. Other hazards

According to the present state of knowledge provided this product is handled correctly,there
is no danger to humans or the environment
Safety Data Sheet in accordance with
Regulation (EU) No.453/2010
GENAPOL PF 20 Page 2(9)

Substance key: SXR024025 Revision Date: 27.03.2015

Version : 1 - 0 / ET Date of printing : 20.04.2015

SECTION 3: Composition/information on ingredients

3.1. Substances
Chemical characterization
Polymerization product of ethylene oxide and propylene oxide
CAS number : 9003-11-6

SECTION 4: First aid measures

4.1. Description of first aid measures
General information
Remove/Take off immediately all contaminated clothing.
After inhalation
If inhaled, remove to fresh air.
Get medical advice/ attention.
After contact with skin
In case of contact, immediately flush skin with plenty of water.
After contact with eyes
In case of contact, immediately flush eyes with plenty of water for at least 15 minutes.
After ingestion
Get medical attention immediately.

4.2. Most important symptoms and effects, both acute and delayed
Symptoms
No symptoms known currently.
Hazards
No hazards known at this time.

4.3. Indication of any immediate medical attention and special treatment needed
Treatment
Treat symptomatically.

SECTION 5: Firefighting measures

5.1. Extinguishing media
Suitable extinguishing media
Water spray jet
Alcohol-resistant foam
Carbon dioxide (CO2)
Dry powder

5.2. Special hazards arising from the substance or mixture

Safety Data Sheet in accordance with
Regulation (EU) No.453/2010
GENAPOL PF 20 Page 3(9)

Substance key: SXR024025 Revision Date: 27.03.2015

Version : 1 - 0 / ET Date of printing : 20.04.2015

In case of fires, hazardous combustion gases are formed: Carbon monoxide (CO)
Carbon dioxide (CO2)

5.3. Advice for firefighters

Special protective equipment for firefighting
Self-contained breathing apparatus

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
Wear suitable protective equipment.

6.2. Environmental precautions

Do not allow to enter drains or waterways

6.3. Methods and material for containment and cleaning up

Pick up with absorbent material (eg sand, sawdust). Rinse away rest with water

6.4. Reference to other sections

Additional information
Information regarding Safe handling, see chapter 7.
For personal protection see section 8.
Information regarding Waste Disposal, see chapter 13.

SECTION 7: Handling and storage

7.1. Precautions for safe handling
Advice on safe handling
No special measures necessary if stored and handled as prescribed.
Hygiene measures
Wash hands before breaks and at the end of workday.
Use protective skin cream before handling the product.
Take off immediately all contaminated clothing and wash it before reuse.
Advice on protection against fire and explosion
Observe the general rules of industrial fire protection

7.2. Conditions for safe storage, including any incompatibilities

Further information on storage conditions
Keep containers tightly closed in a cool, well-ventilated place.
Handle and open container with care.

7.3. Specific end use(s)

No further recommendations.
Safety Data Sheet in accordance with
Regulation (EU) No.453/2010
GENAPOL PF 20 Page 4(9)

Substance key: SXR024025 Revision Date: 27.03.2015

Version : 1 - 0 / ET Date of printing : 20.04.2015

SECTION 8: Exposure controls/personal protection

8.1. Control parameters
Exposure limit values
Exposure limit values are not available.

DNEL/DMEL values
DNEL/DMEL values are not available.

PNEC values
PNEC values are not available.

8.2. Exposure controls

General protective measures
Avoid contact with skin and eyes.
Hand protection : Long-term exposure
Impervious butyl rubber gloves
Minimum breakthrough time / gloves : 480 min
Minimum thickness / gloves 0,7 mm
For short-term exposure (splash protection):
Nitrile rubber gloves.
Minimum breakthrough time / gloves : 30 min
Minimum thickness / gloves 0,4 mm
These types of protective gloves are offered by various
manufacturers. Please note the manufacturers´ detailed
statements, especially about the minimum thickness and the
minimum breakthrough time. Consider also the particular
working conditions under which the gloves are being used.
Eye protection : Safety glasses

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
Physical state : liquid
Form : Liquid
Particle size : : Not applicable
Colour : colourless to slightly yellow
Odour : characteristic

Odour threshold : not tested.

pH value : approx. 7 (20 °C, 10 g/l)
pour point : < -6 °C
Method : ISO 3016
Boiling point : > 360 °C
Method : Calculated by Syracuse.
Safety Data Sheet in accordance with
Regulation (EU) No.453/2010
GENAPOL PF 20 Page 5(9)

Substance key: SXR024025 Revision Date: 27.03.2015

Version : 1 - 0 / ET Date of printing : 20.04.2015

Flash point : > 250 °C

Method : DIN/ISO 2592 (open cup)
Evaporation rate : not tested.
Lower explosion limit : not tested.
Upper explosive limit : not tested.
Combustion number : Not applicable
Minimum ignition energy : not tested.
Vapour pressure : < 0,001 Pa (25 °C)
Method : Calculated by Syracuse.
Vapour density relative to air : not tested.
Solubility in water : approx. 10 g/l (20 °C)
soluble
Soluble in ... : fat
not tested.
Octanol/water partition Not applicable
coefficient (log Pow) :
Ignition temperature : not tested.
Self-ignition temperature : Not applicable
Thermal decomposition : > 350 °C (Heating rate : 3 K/min)
Source : Analogy
Viscosity (dynamic) : approx. 150 mPa.s (50 °C)
Method : DIN 53015
Viscosity (kinematic) : not tested.
Explosive properties : Explosive according to EU supply regulations : no data
available
Oxidizing properties : Not applicable

9.2. Other information

Density : approx. 1,02 g/cm3 (50 °C)
Method : DIN 51757
Bulk density : Not applicable

SECTION 10: Stability and reactivity

10.1. Reactivity
See section 10.3. "Possibility of hazardous reactions"

10.2. Chemical stability

Stable under normal conditions.
Safety Data Sheet in accordance with
Regulation (EU) No.453/2010
GENAPOL PF 20 Page 6(9)

Substance key: SXR024025 Revision Date: 27.03.2015

Version : 1 - 0 / ET Date of printing : 20.04.2015

10.3. Possibility of hazardous reactions

No dangerous reaction known under conditions of normal use.

10.4. Conditions to avoid

None known.

10.5. Incompatible materials

not known

10.6. Hazardous decomposition products

When handled and stored appropriately, no dangerous decomposition products are known

SECTION 11: Toxicological information

11.1. Information on toxicological effects
Information related to the product itself:
Acute oral toxicity : LD50 > 2.000 mg/kg (Rat)
Acute dermal toxicity : not tested.
Acute inhalation toxicity : not tested.
Irritant effect on skin : No skin irritation (Rabbit)
Source : CESIO
Irritant effect on eyes : No eye irritation (rabbit eye)
Source : CESIO
Sensitization : not tested.
Repeated dose toxicity: not tested.
Assessment of mutagenicity : No information available.
Assessment of No information available.
carcinogenicity :
Assessment of toxicity to No information available.
reproduction :
Assessment of teratogenicity : No information available.
Specific target organ toxicity not tested.
(STOT) - single exposure :
Specific target organ toxicity not tested.
(STOT) - repeated exposure :

SECTION 12: Ecological information

12.1. Toxicity
Information related to the product itself:
Safety Data Sheet in accordance with
Regulation (EU) No.453/2010
GENAPOL PF 20 Page 7(9)

Substance key: SXR024025 Revision Date: 27.03.2015

Version : 1 - 0 / ET Date of printing : 20.04.2015

Fish toxicity : LC0 > 500 mg/l (24 h, Poecilia reticulata (guppy))
Daphnia toxicity : not tested.
Algae toxicity : not tested.
Bacteria toxicity : EC50 > 1.000 mg/l
Method : OECD Test Guideline 209

12.2. Persistence and degradability

Information related to the product itself:
Biodegradability : > 99 % (28 d)
Method : OECD Test Guideline 301F
Chemical oxygen demand 2.050 mg/g
(COD) :

12.3. Bioaccumulative potential

Information related to the product itself:
Bioaccumulation: not tested.

12.4. Mobility in soil

Information related to the product itself:
Transport and distribution not tested.
between environmental
compartments :
Behaviour in environmental compartments
no data available

12.5. Results of PBT and vPvB assessment

Information related to the product itself:
no data available

12.6. Other adverse effects

Information related to the product itself:
Additional ecotoxicological remarks
no data available

SECTION 13: Disposal considerations

13.1. Waste treatment methods
Product
In accordance with local authority regulations, take to special waste incineration plant
Uncleaned packaging
Packaging that cannot be cleaned should be disposed of as product waste
Safety Data Sheet in accordance with
Regulation (EU) No.453/2010
GENAPOL PF 20 Page 8(9)

Substance key: SXR024025 Revision Date: 27.03.2015

Version : 1 - 0 / ET Date of printing : 20.04.2015

SECTION 14: Transport information

Section 14.1. to 14.5.
IATA not restricted
IMDG not restricted

14.6. Special precautions for user

See sections 6 to 8 of this Safety Data Sheet.

14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code (International
Bulk Chemicals Code)
No transport as bulk according IBC - Code.

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or
mixture
Other regulations
Apart from the data/regulations specified in this chapter, no further information is available
concerning safety, health and environmental protection.

15.2. Chemical safety assessment

No Chemical Safety Assessment (CSA) is yet available for the substance, or for the
component substances, contained in this product.

SECTION 16: Other information

Observe national and local legal requirements

Legend
ADN European Agreement concerning the International Carriage of Dangerous
Goods by Inland Waterways
ADR European Agreement concerning the International Carriage of Dangerous
Goods by Road
AOX Adsorbable organic bound halogens
CAS Chemical Abstracts Service
DMEL Derived Minimal Effect Level (genotoxic substances)
DNEL Derived No Effect Level
EC50 Half maximal effective concentration
GHS Globally Harmonized System
IATA International Air Transport Association
IMDG International Maritime Dangerous Goods
LC50 Lethal Concentration 50%
LD50 Lethal Dose 50%
MARPOL International Convention for the Prevention of Pollution From Ships
Safety Data Sheet in accordance with
Regulation (EU) No.453/2010
GENAPOL PF 20 Page 9(9)

Substance key: SXR024025 Revision Date: 27.03.2015

Version : 1 - 0 / ET Date of printing : 20.04.2015

NOAEC No Observed Adverse Effect Concentration

NOAEL No Observed Adverse Effect Level
NOEC Non Observed Effect Concentration
OEL Occupational Exposure Limit
PBT Persistent, Bioaccumulative, Toxic
PEC Predicted Environmental Concentration
PNEC Predicted No Effect Concentration
REACH Registration, Evaluation, Authorisation and Restriction of Chemicals
RID International Rule for Transport of Dangerous Substances by Railway
SVHC Substances of Very High Concern
vPvB very Persistent and very Bioaccumulative

This information corresponds to the present state of our knowledge and is intended as a general
description of our products and their possible applications. Clariant makes no warranties, express or
implied, as to the information's accuracy, adequacy, sufficiency or freedom from defect and assumes
no liability in connection with any use of this information. Any user of this product is responsible for
determining the suitability of Clariant's products for its particular application. Nothing included in this
information waives any of Clariant's General Terms and Conditions of Sale, which control unless it
agrees otherwise in writing. Any existing intellectual/industrial property rights must be observed. Due
to possible changes in our products and applicable national and international regulations and laws, the
status of our products could change. Material Safety Data Sheets providing safety precautions, that
should be observed when handling or storing Clariant products, are available upon request and are
provided in compliance with applicable law. You should obtain and review the applicable Material
Safety Data Sheet information before handling any of these products. For additional information,
please contact Clariant.