This document discusses the history and properties of metallic materials used in metal structures for rehabilitation projects. It describes the evolution of materials from cast iron and wrought iron in the late 18th century to modern steels. Key developments include the emergence of steelmaking processes in the late 19th century and the increasing weldability of steels from the 1930s onward. The document outlines the characteristic properties of different iron alloys and steels over time that should be considered for repair work.
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Rehabilitation of Steel Structures C1
This document discusses the history and properties of metallic materials used in metal structures for rehabilitation projects. It describes the evolution of materials from cast iron and wrought iron in the late 18th century to modern steels. Key developments include the emergence of steelmaking processes in the late 19th century and the increasing weldability of steels from the 1930s onward. The document outlines the characteristic properties of different iron alloys and steels over time that should be considered for repair work.
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REHABILITATION
(REPAIR AND RENOVATION)
METAL STRUCTURES
Dr. ing. Dragos Voiculescu
1. INTRODUCTION
In general, traditional building techniques and methods
are used for repair and renovation, but they must take into account the specificities of the metallic materials over time.
The methods for preparation of metallic materials and
the assembly techniques have evolved according to the industrial development. It is therefore necessary to carry out repair work in good knowledge of the material properties, modes of assembly and design rules used in the time of the construction erection. Particularly, the metallic materials have been subjected to important developments. Thus, the use of cast irons, wrought irons and steels, shows very different characteristics. Even the evolution of steels, from the early twentieth century, also shows very variable material characteristics and behaviors that should be considered in all repair projects. The most important development for steel is the weldability which gradually emerged from the 1930’s, along with the development of welding techniques and research on the metallurgical aspects of steel weldability. 2. HISTORY OF MATERIALS IN METAL STRUCTURES After the masonry and wood, metallic materials were used for construction from the late eighteenth century.
Three iron-based alloys, cast iron, wrought iron and
steel, will define the main periods of construction for metal structures. 2.1. REMINDERS OF METALURGY
Depending on the temperature, pure iron has
different crystallographic network forms.
From a CC-centered cubic crystallographic network (α
iron or ferrite) at low temperature, iron is transformed into a CFC-centered faces cubic crystallographic network (γ iron or austenite) at 912 °C and then recover a centered cubic crystallographic network at high temperatures centered before the transformation solid - liquid. The properties of the iron-carbon alloys are characterized in the phase diagram as a function of the chemical composition and their preparation process (thermal cycles).
The phase diagram Fe-C presents the areas of
solubility of carbon in the iron at different temperatures and the levels of allotropic transformations. The simplified diagram shown below is established under conditions of slow heating and slow cooling. 2.2. THE PROPERTIES OF METALLIC MATERIALS
a) The tensile test is the most classical mechanical
test procedure which is fully normalized (EN 10002).
On a effort-deformation diagram, the classical
characteristics measured are: – The yield strength of steel Re successively expressed in kg/mm2 then MPa or N/mm2. – The maximum tensile load Rm or breaking load successively expressed in kg/mm2 then MPa or N/mm2. – The elongation expressed in %. b) The impact test characterizes the energy absorbed by breaking a notched specimen (EN 10045).
This test carried out at different temperatures
allows the classification of grades of steel and represents a brittle fracture risk characterization and weldability of the material.
First performed on U-notched test specimens,
and expressed in J/cm2, this test is done today on V-notched test specimens and is expressed in joules. 2.3. THE EMPLOYED MATERIALS
At the end of the eighteenth century, the
industrial methods for manufacturing iron alloys, allowed the development of cast iron alloys, with a carbon content of about 3%, and mediocre characteristics, which favored the production of structures operating in compression inspired from masonry structures - arched structures. From 1820, the development of the industrial techniques allowed the fabrication of wrought iron (fier forjat), having an improved tensile strength, that could be used for the construction of metalic girders.
The second half of the nineteenth century will be
marked by the appearance of steelmaking processes; Bessemer process (1856), Siemens-Martin (1865) and Thomas (1877), will allow the production of large quantities of material. Thanks to its mechanical properties, primarily its high strength, steel will totally replace the early twentieth century cast iron and wrought iron in bridge construction. 2.3.1. The cast iron
Cast iron was used in many bridges in the XIX-th century, but most of the works had a limited life span.
The cast is a fragile material, with low tensile strength as
evidenced by the characteristics found for the products of that era: – Carbon: 3 à 3,5 % – Silicium: 2 à 3,5 % – Elasticity limit: 50 à 100 N/mm2 – Tensile strength: 100 à 180 N/mm2 The first cast iron bridge was built across the Severn at Coalbrookdale in England in 1779 2.3.2. Wrought iron
Wrought iron was obtained by puddling from
liquid melted introduced into a reverberatory furnace and mixed with oxidant additions.
After melting, the metal was cleaned: this
operation was realised by stirring of the bath of metal; this was followed by a decarburization phase in oxidative atmosphere at a temperature below the melting temperature of iron. A worker mixing melted iron with oxidant additions • Reverberatory furnace used for puddling: A : Hole ; B : Refractory clay ; C : Tie rods ; D : Grating ; E : Work door ; F : Laboratory opening ; G : Maintenance plate ; H : Stone Wrought iron thus obtained has, according to various bibliographies of the time, an approximate chemical composition : – carbon : 0,01 %, – manganese : 0,02 %, – phosphorus : 0,2 %, – sulfur : 0,05 %, – silicium : 0,2 %. The mechanical characteristics of these irons are heterogeneous with the following values : – elasticity limit (E) : 230 to 300 N/mm2 (measured on existing works, bibliography gives lower values 170 N/mm2), – breaking load(R) : 260 to 400 N/mm2, – elongation (A) : 10 to 20 % (in the rolling direction) : almost zero (in the transverse direction). 2.3.3. The old steels
Construction steels are iron-carbon alloys with the carbon
contents variable, depending on the mode of fabrication and the desired grade.
Other elements are present because they could not be
eliminated in the preparation; some are harmful, such as phosphorus, sulfur, nitrogen.
The main chemical elements used to characterize the
fabrication method are nitrogen, nickel, chromium, copper, phosphorus, sulfur. Phosphorus is an embrittling element, it strongly decreases the resilience of rough rolled products. The drop of resilience is especially pronounced beyond 0.07% phosphorus
The effect of these impurities justifies extreme
caution before hiring a repair on ancient metals and make necessary to obtain good knowledge of the materials used. 2.3.4. Modern steels
"Modern steels" correspond to weldable
steels grades have been the subject of standardization.
They are generally prepared by processes with
oxygen and the grades obtained do not present difficulties in welding The processes developed with oxygen, without external heat, derived from the Bessemer process. After loading materials (lime, scrap metal and cast iron), oxygen insufflation can be done in different ways : – through the spout of the converter, using a metal- water cooled lance: oxygen is blown to the surface of the liquid bath (LD processes, OLP, Kaldo); – through nozzles arranged in the converter bottom: oxygen is then blown through the melt (recent processes OBM, LWS). To increase the strength of sheets, steelmakers have two ways : – raise the carbon and silicium content to increase the hardness; – increasing the hardenability (duritatea) of steel to obtain a finer structure, by adding manganese for example.
But this development has been done to the
detriment of weldability (cold cracking risk) and toughness of the metal and steelmakers had to use other means to change the characteristics of steel. • For steels with improved resistance to atmospheric corrosion Improved atmospheric corrosion resistance steels or autopatinables are protecting themselves against corrosion by forming an oxide layer on their surface. These are steels are containing a low percentage of copper (about 1%). They are better known under their brand name, such as Corten, Indaten, Diweten. The protection is achieved when the product is exposed alternately to a dry and wet atmosphere and a dark brown oxide layer, also called patina was formed. This oxide layer is relatively resistant and waterproof. It therefore constitutes an obstacle to corrosion, that can no longer continue in depth. The use of this type of steel is not recommended in aggressive media and for construction in permanent contact with water or condensed moisture.
It should also be very careful to avoid any possibility of water
retention which would ultimately cause an alteration of the material.
Furthermore, the protective layer, which can last several
years, is accompanied by a clearance of rust that can dirty the non-ferrous parts of construction. It will therefore be necessary to collect all the runoff water that have been in contact with the weathering steel. • Cast steel case In case of foundry cast steel, the pieces are obtained directly by solidification of the liquid metal in impressions (or molds) which reproduce as faithfully as possible the final shape and size of the elements.
This practice is technically and economically attractive
because it eliminates costly secondary machining operations, and it will keep gross casting skin which generally has a fine microstructure favorable to the good performance of service. The use of cast steel for various parts, such as: bearing elements, beams ... may present elevated carbon content, so any work on this type of material requires metallurgical characterization. 2.4. DIMENSIONAL DEVELOPMENTS The cast iron of the first metallic structures was in the form of castings according to the drawings of engineers and architects.
Wrought iron successor comes either in the form of
molded elements but as plates, rods, profiles, in shapes and sizes offered by steelmakers. The construction is a combination of rolled or forged parts assembled by ordinary bolts, and especially by rivets. Part dimensions are quite low. Achievable sheet in 1830, for example, had thicknesses between 3 and 20 mm, widths which did not exceed 500 mm and lengths limited to 1000 millimeters. In bridge construction, the thicknesses used are of the order of 10 - 12 mm. With the advent of steel, produced thicknesses amount to 65 mm and lengths go up to 4 meters. The evolution of the steel equipment and the growing needs of the industry (boiler making, shipbuilding) will advance very rapidly these numbers.
Between 1870 and 1890, in sheet metal production,
the weight passes 12 then 30 tonnes and the lengths of 5 then 10 meters, while the thicknesses and maximum widths achievable are established respectively at 300/400 mm and 3 m. The profiled sheets are long sheets whose width varies in the longitudinal direction and which, in the bridge construction, allow better approximation of the ideal profile dictated by the distribution of the bending moment. Among the feasible profiles, the most common are :
Forging - Manual of Practical Instruction in Hand Forging of Wrought Iron, Machine Steel and Tool Steel; Drop Forging; and Heat Treatment of Steel, Including Annealing, Hardening and Tempering
Heat-Treatment of Steel: A Comprehensive Treatise on the Hardening, Tempering, Annealing and Casehardening of Various Kinds of Steel: Including High-speed, High-Carbon, Alloy and Low Carbon Steels, Together with Chapters on Heat-Treating Furnaces and on Hardness Testing