GUIDED REVISION ENTHUSIAST & LEADER

Target : JEE(Main + Advanced) - 2019 COURSE

INORGANIC CHEMISTRY
GUIDED REVISION PLAN-SCORE ADVANCED
Question Bank # 05 [Topic : Salt Analysis]
Only Single Correct :
1. Which of the following reaction produce colourless and odourless gas :-
(A) S2O3–2 + dil. H2SO4 (B) Zn + Conc. H2SO4
(C) Zn + dil. HCl (D) Cu + conc. HNO3
2. When the soda extract containing thiosulphate ion treated with excess of AgNO3 solution followed by boiling,
then.
(A) White precipitate is formed (B) Black precipitate is formed
(C) brown precipitate is formed (D) No ppt precipitate is formed
3. Anion that can not decolorise acidic solution of KMnO4
(A) HSO3– (B) HSO3– (C) SO32– (D) All of the above
4. CO3 + 2HCl(dil) ® Gas + solution
2–

Resulting gas produces salt when passed in -

(A) NaOH solution (B) NH4OH solution (C) Lime water (D) All of the above
5. On addition of conc.H2SO4 to the BaC2O4 suspension, the gas(es) liberated is/are
(A) CO only (B) (CO + CO2) only (C) CO2 only (D) SO2
More than may be Correct :
6. Which of the following radical(s) when reacts with conc. H2SO4 give brown colour gas :-
–
(A) NO3– (B) CO32– (C) Br– (D) I
7. Mn2+ solution ¾¾¾¾
Re agent 'A '
® MnO4–.
In the above conversion, the reagent 'A' may be
(A) Pb2O3 + conc. HNO3 (B) K2S2O8 / H+ solution
(C) (NH4)2S2O8 / H+ soltuion (D) K2SO4 solution
8. Which of the following anions is/are identified by dil. H2SO4 ?
(A) S2– (B) C2O42– (C) NO3– (D) S2O32–
9. Which of the following cations form ppt. with K4[Fe(CN)6]
(A) Zn2+ (B) Cu2+ (C) Cd2+ (D) Al3+
10. Select the correct statements -
(A) The sodium hydrogen carbonate of the alkali metal are soluble in water, but are less soluble than the
corresponding carbonate.
(B) Solution of carbonate forms reddish brown pptn of basic mercury(II) carbonate (3HgO.HgCO3) when
react with Mercury(II) chloride
(C) When AgNO3 react with sulphite ion no visible change occurs initially because of the formation of soluble
sulphitoargentate ion.
(D) On standing the precipitate BaSO3 is slowly oxidised to the sulphate.
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 GUIDED REVISION ENTHUSIAST & LEADER
Target : JEE(Main + Advanced) - 2019 COURSE
Comprehension Type :
Passage for Q.11 to Q.12
Consider the following reaction(s)
A (s) B (s) + C (g) + D(g) + E (v)
(Pale green) (Brown)

KMnO4/H
+
– Anhydrous CuSO4
MnO4 is decolorized F
(Blue solid)

NaNO2 + dil.H2 SO4

(A)aq. ¾¾¾¾¾¾¾¾ ® unstable brown compound (G)
¾

(m = 15 B.M. )
11. Sum of oxidation state of the central atom in C(g) and D(g) is :-
(A) 6 (B) 10 (C) 8 (D) 4
12. Select INCORRECT statement about compound 'F' :-
(A) It absorb orange-red light for d-d transition
(B) 4 water molecules are directly bonded with each Cu+2
(C) It is paramagnetic
(D) It's m = 8 B.M.
Passage for Q.13 to Q.15
(G) is a greenish yellow gas, moderately soluble in water and produce solution(S). Solution(S) produce
brown layer(L) when treated with CCl4 and KBr (aq.).
13. Gas(G) is produced when -
(A) NaBr + conc. H2SO4 is heated (B) KCl(aq.) + Br2
(C) NaNO3 + conc. H2SO4 is heated (D) KCl + MnO2 + conc. H2SO4 is heated
14. No. of s bonds and magnetic nature of gas(G) is -
(A) one, diamagnetic respectively (B) two, diamagnetic respectively
(C) one, paramagnetic respectively (D) two, paramagnetic respectively
15. Brown layer (L) is produced due to.
(A) oxidation of KBr (B) reduction of KBr
(C) oxidation of CCl4 (D) reduction of CCl4
Paragraph for Q.16 to Q.17

boil KCN FeCl3

(A) + Sulphur (B) (D) (E)
strong
alkaline Blood red
dil.HCl solution complex
–2 +
Cr2O7 /H
Sulphur + (C) green colour

16. When excess AgNO3 react with (B) then ppt of (X) is formed which is converted to (Y) on standing.
Identify the colour of (X)
(A) Black (B) Green (C) Yellow (D) White
17. Which of the following anion is present in complex (E) –
1 1
2– 2–
(A) C N (B) SO3 (C) S CN (D) CO3

2
E
 GUIDED REVISION ENTHUSIAST & LEADER
Target : JEE(Main + Advanced) - 2019 COURSE

MATRIX MATCH
18. Match the column :
Column-I Column-I
Cation in solution Correct characteristics when no
where excess reagent is used
(A) Ag+ and Pb2+ (P) can be distinguished by Na2HPO4 solution
(B) Zn2+ and Mg2+ (Q) can be distinguished by dil.HCl
(C) Pb2+ and Hg22+ (R) can be distinguished by KI solution
(D) Pb2+ and Fe3+ (S) can be distinguished by NaOH solution
(T) can not be distinguished by NH4OH solution
19. Match the column
Column-I Column-II
(A) Cu2+ (P) Produces soluble complex with excess of KCN
without any change of oxidation state of metal ions
(B) Fe3+ (Q) Produces coloured soluble complex with excess KCN
(C) Cd2+ (R) Produces no ppt with excess of KI
(D) Ag+ (S) Produces coloured ppt with NaOH
(T) Produces colourless soluble complex with excess of
NH4OH solution
Integer Type :
20. How many of the following cations gives ppt with H2S in acidic solution :-
Zn2+ , Cu2+ , Ni2+ , Sr2+ , Al3+ , Bi3+ , Sn2+ , Pb2+
21. Number of radicals which produce colour on flame
Na + , Mg2+ , Al3+ , BO33– , Ba2+ , Li+

® Violet complex ¾¾¾¾® Greensolution

On standing
22. Salt of iron ¾¾¾¾
Na 2S2 O3
(X) (Y) (Z)

Write oxidation number of Fe in (X) as first digit, (Y) as second digit, (Z) as third digit in OMR.
(eg. if your answer is x = 3, y = 4 and z = 5 then you have to fill 345 in OMR)
23. Number of halide ion (given below) which change their oxidation number on heating with
MnO2 + conc.H2SO4.

F – ,Cl – ,Br – ,I–

24. How many of the following reactions produce blue colouration or blue ppt.

(i) CuSO4 solution ¾¾¾NH 3

¾
in excess
®

(ii) CuSO4 solution ¾¾¾¾¾

K 4 [ Fe(CN)6 ]
®

(iii) NiCl2 solution ¾¾¾¾

ExcessNH3
®
(iv) FeSO4 solution ¾¾¾¾¾
K 3 [Fe(CN) 6 ]
®
+
Na2CrO4 soltuion ¾¾¾¾¾¾¾¾¾ ®
H 2O 2 / H
(v) In presence of organicsolvent Et 2O

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