1

A method of reducing food, food, medicine leaching toxic heavy

metals, improve food safety, environmental protection stabilizer and
preparation method
CN 105815757 A
Abstract
The present invention relates to a method of reducing food, food, medicine toxic
heavy metals in the leaching, enhance food safety, environmental stabilizers and
preparation method, by mixing raw materials in the following, phosphoric acid or
phosphate, acidity regulator and chloride. Stabilizers of the present invention is
directly added to foods, food, medicine, the brewing, cooking, or flavoring
process, i.e. before they enter the human tongue, parenteral, leaching reduces the
amount of dissolved heavy metals contained therein, even in acid strength than
the body or abnormal gastric acid environment such as acid rain 1N hydrochloric
acid solution may be difficult to break down heavy metal form, chemically
inactive form of the product, it is not easily absorbed by the body and to enhance
food safety and reduce its migration to the environment, diffusion and
transformation, enhance environmental protection and then go back to the food
chain to stop the heavy metals, reduce the degree of toxicity of heavy metals, has
a good prospect.
Claims(15)
1. A method for reducing food, food, medicine toxic heavy metals in
the leaching, enhance food safety, environmental stabilizing agent,
characterized in that: said stabilizer feed of phosphoric acid or
phosphates, chlorides and acidity regulators.
2. A method according to claim 1 for lowering of food, food, medicine
toxic heavy metals in the leaching, enhance food safety,
environmental stabilizing agent, wherein: said phosphate is tricalcium
phosphate, dihydrogen phosphate, calcium phosphate calcium
hydrogen pyrophosphate, sodium hexametaphosphate, sodium
trimetaphosphate, sodium tripolyphosphate, trisodium phosphate,
tripotassium phosphate, sodium dihydrogen phosphate, potassium
dihydrogen phosphate, disodium hydrogen phosphate, dipotassium
hydrogen phosphate, disodium dihydrogen pyrophosphate,
ammonium dihydrogen phosphate, diammonium hydrogen
phosphate, tetrapotassium pyrophosphate, trisodium monohydrogen
pyrophosphate, polyvinylidene potassium phosphate, acid
pyrophosphate, acidic sodium aluminum phosphate, magnesium
hydrogen phosphate, glycerol one or more of calcium phosphate,
ferric pyrophosphate, and casein phosphopeptide phosphate
containing food.
According to claim 2, wherein one of the reduced food, food, medicine toxic
heavy metals in the leaching, enhance food safety, environmental stabilizing
agent, wherein: said phosphate-containing food for the bone, bone soup
powder, one or more of fish meal.
1 according to one of the reduced food, food, medicine toxic heavy metals in the
leaching, enhance food safety, environmental stabilizers claim wherein: said pH
 2

adjusting agent is tricalcium phosphate, calcium dihydrogen phosphate,

sodium pyrophosphate, sodium trimetaphosphate, sodium
tripolyphosphate, trisodium phosphate, tripotassium phosphate,
sodium dihydrogen phosphate, potassium dihydrogen phosphate,
disodium hydrogen phosphate, dipotassium hydrogen phosphate,
disodium dihydrogen pyrophosphate, acid magnesium hydroxide,
magnesium phosphate tribasic, calcium sulfate, calcium hydroxide,
potassium hydroxide, magnesium hydroxide, lactic acid, calcium
lactate, sodium lactate, sodium carbonate, potassium carbonate,
potassium bicarbonate, sodium bicarbonate, sodium
sesquicarbonate, sodium acetate, sodium citrate, sodium citrate,
potassium citrate, one or several.
5. A method according to claim 1 for lowering of food, food, medicine toxic heavy
metals in the leaching, enhance food safety, environmental stabilizing agent,
wherein: said chloride is sodium chloride, potassium chloride, calcium
and magnesium in one or several.
6. A method according to claim 1 for lowering of food, food, medicine toxic heavy
metals in the leaching, enhance food safety, environmental stabilizing agent,
wherein: said starting material is mass percentage range: phosphoric acid or
phosphate billion. 5 to 90%; pH regulators from 0.5 to 65%; chloride
0.5 to 40%.
1 according to one of the reduced food, food, medicine toxic heavy metals in the
leaching, enhance food safety claim, green stabilizer, wherein: said material
further comprises a stabilizer comprising dietary fibers, pectin,
phlegmatic or rich, it can be made to increase probiotic food or processed
food, one or more food grade iron compound, an antioxidant, a thickener,
nutritional supplements, preservatives.
According to claim 7 for reducing the food, the food, the medicine of heavy metals
leaching toxicity, enhance food safety, environmental stabilizing agent, wherein:
said containing dietary fiber, gum, or abundant phlegm, can increasing
probiotic food fruits and vegetables, cereal grains, legumes, algae one
or more of food; containing dietary fiber, gum, or abundant phlegm,
probiotics can increase food is made by processing to health food
plants, fruits and vegetables, cereal grains, beans, milk, or algae, and
a housing shrimp, crab, insects is processed into raw material, one or
more flavorings or thickeners.
9. A member according to claim 7, wherein the reduction of food, the food, the
medicine toxic heavy metals leaching, enhance food safety, environmental
stabilizing agent, characterized in that: the food-grade iron compound is iron
oxide black, iron oxide red, ferrous sulfate, ferrous gluconate, ferric ammonium
citrate, ferrous fumarate, ferric citrate, ferrous citrate, ferrous lactate, high-heme
iron chloride, ferric pyrophosphate, iron porphyrins, ferrous glycine reduced
iron, sodium iron EDTA, carbonyl iron, ferrous carbonate, ferrous fumarate,
ferrous succinate, heme iron, electrolytic iron of one or more.
10. A method according to claim 7 for lowering of food, food, medicine toxic
heavy metals in the leaching, enhance food safety, environmental stabilizing
agent, wherein: the antioxidant is vitamin E, disodium edetate , edetate
 3

calcium disodium, sulfur dioxide, potassium metabisulfite, sodium

metabisulfite, sodium sulfite, sodium bisulfite, sodium sulfite low,
ascorbic acid, D- erythorbic acid and its sodium salt, sodium
ascorbate, calcium ascorbate, ascorbyl palmitate esters,
phospholipids, gallic acid propyl, licorice antioxidants, phytic acid,
sodium phytate, bamboo antioxidants, rosemary extract,
polyphenols, polyphenols palmitate, lipoic acid, L- methionine, one or
more of glutathione, cysteine, taurine.
11. A member according to claim 7, wherein the reduction of food, the food, the
medicine toxic heavy metals leaching, enhance food safety, environmental
stabilizing agent, wherein: the thickening agent is propylene glycol, tara gum,
acetate starch, sodium carboxymethyl starch, acid-treated starch, sodium starch
phosphate, aluminum starch octenyl succinate, oxidized starch, hydroxypropyl
oxidized starch, [beta] cyclodextrin, acacia gum, guar gum, carrageenan , Cassia
gum, gelatin, curdlan, pectin, locust bean gum, gum tenax, Abelmoschus gum,
xanthan gum, gum Artemisia, Tian Jing gum, flax seed gum, acacia gum, gellan
gum, agar , propylene glycol alginate, chitosan, deacetylated chitin, alginic acid,
sodium alginate, potassium, maltitol, lactitol, sorbitol, pullulan, soluble soybean
polysaccharide, tamarind seed gum, hydroxypropyl methyl cellulose, methyl
cellulose, sodium carboxymethyl cellulose, a polyglycerol fatty acid ester, distarch
phosphate, phosphated distarch phosphate, acetylated distarch phosphate,
acetylated distarch adipate one or more esters of
12. A method according to claim 7 for lowering of food, food, medicine toxic
heavy metals in the leaching, enhance food safety, environmental stabilizing
agent, characterized in that: the nutritional supplements of calcium
carbonate, calcium gluconate, citric acid calcium lactate, L- lactate,
calcium hydrogen phosphate, L- threonate, glycine, calcium
aspartate, calcium citrate, calcium malate, calcium acetate, calcium
chloride, tricalcium phosphate, vitamin Ε , calcium succinate,
calcium glycerophosphate, calcium oxide, calcium sulfate, bone meal,
sodium selenite, sodium selenate, selenoproteins, selenium-rich
edible mushroom powder, L- Se - methyl-selenocysteine, selenides
carrageenan, selenium enriched yeast, casein phosphopeptides,
calcium caseinate peptides, taurine, L- methionine, L- lysine, L-
carnitine, vitamin Bl, Β2, Β6, Β12, folic acid or a several.
13. A method according to claim 7 for lowering of food, food, medicine toxic
heavy metals in the leaching, enhance food safety, environmental stabilizing
agent, wherein: the preservative is potassium cinnamate, cinnamaldehyde,
ε_ poly lysine hydrochloride, ε_ polylysine, nisin, sodium diacetate,
sorbic acid and one or more of the potassium salt.
14. A method according to claim 1 for lowering of food, food, medicine toxic heavy
metals in the leaching, enhance food safety, environmental stabilizing agent,
wherein: said heavy metal is lead, cadmium, copper, arsenic and mercury in one
or several.
15. - reduced species of food, food, medicine toxic heavy metals in the leaching,
enhance food safety, environmentally friendly method of preparing a
stabilizer, comprising: a phosphoric acid or phosphate, chloride and
 4

acidity regulator for each starting material are accurate measurement scale,
after all fed into a mixer at ambient temperature and pressure uniformly stirred
and mixed, to obtain the package.
Description
A method of reducing food, food, medicine leaching toxic heavy metals, improve
food safety, environmental protection stabilizer and preparation method

FIELD

[0001] The present invention belongs to the technical field of food additives, in
particular, relates to a method of reducing food, food, medicine toxic heavy
metals in the leaching, enhance food safety, environmental stabilizers and
preparation method.

Background technique

[0002] of the people at the end of the food chain, the food chain of heavy metal
pollution on human health is a global issue of great concern. These heavy
metals into the human body, easy excretion, gradually accumulating,
tend to accumulate in the brain, kidney, immune system, when it
exceeds the body's physiological load, can cause physiological
function changes, resulting in acute and chronic diseases or long-
term hazards produced, comprising It may gradually form cancer
tissue and cause cancer, and would seriously interfere with human
health, normal function and even endanger human life. Such food safety
hazards have been badly serious threat to public security, and social stability, and
economic well-being of all countries, the situation is worrying.

[0003] However, today there is no universally accepted food grade products, also
no reports disclose a method or food grade products that can safely and
effectively reduce food cheap, leaching toxic heavy metals contained
in food concentration, about to dissolve, heavy metals in free form
into a stable product of a very poorly soluble and harmless, i.e.
decrease the biological effectiveness of their uptake including crops,
i.e. to reduce the toxicity of biological and heavy metal back stop the
food chain and to reduce or avoid transfer , enriched and amplified
spread of toxic or impact. Therefore, human beings will not be the last link in
the food chain effect of heavy metal pollution, but also may be due to enriched
and enlarged by the gastric acid decomposition Instead, start transmission.

[0004] China currently widespread soil contamination with heavy

metals, resulting in crops, herbal products, heavy metal content, and
thus contaminate the food chain. Chinese provinces and cities and more
frequent poisonous rice scandal caused by people from the mainland
continued Qiang Lie concern. Because rice and rice products are the
main food of the Chinese people, the product of "cadmium rice" made
as also affected rice noodles, rice cakes and so on. A US study at
 5

Columbia University School of Public Health showed that lead, cadmium,

mercury content immigrants came to New York in vivo China is much
higher than other ethnic groups. Chinese mainland immigrants blood lead
levels higher than other Asian immigrants 24.3%, 48.6% higher than New
York native, 35.4% higher cadmium content than other Asian
immigrants, 74% higher than the native New Yorker; mercury content
is 1.8 times that of other Asian immigrants 2.7 times New Yorkers.

[0005] The report analyzed that due to cadmium and lead can be
retained in the body for decades, so the new immigrants from China
cadmium and lead in the body can be determined mostly from China.
Report that this great relationship with their diet at the time of China. One reason
is that Chinese people have the habit of taking the medicine, and traditional
Chinese medicine contains large amounts of heavy metals, a more important
reason is the universal soil contaminated with heavy metals, and thus also the
crop contamination. But even taking strong measures to clean from now, once
the soil is contaminated, completely recovery time can take up to a thousand
years. However, the whole is not equal to the amount of heavy metals
in soil organisms, including humans and crops, the amount of
available absorption (bioavailability), the only water-soluble, readily
soluble (in case of acid decomposition) or free patterns in order to be
biological, such as crops root absorbed; these patterns move heavy
metals into the ground water via leaching action would endanger the
source of drinking water. Living environment has inevitably presence of
heavy metals, so there is no contaminated soil still contains small amounts of
heavy metals, even special geological factors concentration is
particularly high, and only the bioavailability (ie the degree of bio
absorption available) will be part of produce poison through the food
chain, such as crops, traditional Chinese medicine, affect human
health. Press Toxicology (composition) view, which poisons the low solubility
easily absorbed by the body and its toxicity is not easy to play. Poisons greater
solubility in water, and the shift of their toxicity can be greater, i.e.,
the affinity of the nervous system damage is large force. Poison does
not have a certain degree of water solubility is not easily absorbed
into the bloodstream. Can heavy metal bioavailability and move, not
only to its total mass is related to a greater extent decided by its form
of distribution, different forms have different Gan shift and solubility
as well as environmental and human health effects. General words,
"stabilizing the chemically modified" will dissolve, reduction of free heavy metal
to very poorly soluble mineral composition of the original structure in order to
reduce its biological effectiveness, toxicity simple and expeditious manner, can
effectively reduce crops, rice Heavy Metals absorption and improve the
quality of agricultural production and reducing heavy metals human
ingestion of heavy metals in the body can absorb opportunities or type
of material.
 6

[0006] 2014 Chinese invention patent CN102416396 B heavy metal to

provide a room temperature curing agent. The room temperature curing agent,
heavy metal percentage composition by weight: MgO 30.0% to 40.0% - 65.0%
55.0% potassium dihydrogen phosphate, 3.5% borax 5.0%, 0.1% to 0.5% of iron
oxide, silica, 0.1% to 0.5 %. It also provides a method of heavy metal
contaminants of heavy metals used in the curing. After room temperature curing
agent of the invention on heavy metal containing waste curing at normal
temperature, waste utilization can be achieved.

[0007] U.S. Patent No. 5202033 (Chowdhury, etc.) as shown in the use of
phosphate salts include sodium phosphate (including sodium dihydrogen
phosphate, disodium hydrogen phosphate, trisodium phosphate) and phosphoric
acid and an alkaline earth metal such as calcium or magnesium oxide waste
mixed reduce lead leaching of heavy metal.

[0008] U.S. Patent No. 5512702 (Ryan, etc.) using the calcium phosphate
compounds shown further in situ treatment of contaminated soil Pb method,
which is a solid material using a mixed phosphate of lead-contaminated soil.
Solid calcium phosphate materials include naturally occurring apatite, synthetic
hydroxyapatite, dibasic calcium phosphate, or phosphate rock.

[0009] Forrester U.S. Patent No. 7,736,291 and No. 7,530,939 discloses a
method of using powdered dicalcium phosphate dihydrate stabilized effectively
handle waste incineration fly ash, bottom slag and deodorizing effect
significantly.

Method [0010] Another U.S. Patent No. 5797992 (Huff) discloses treatment of
heavy metal, according to which method is to use synthetic apatite such as
hydroxyapatite calcium phosphate mineral will lead the paint surface
contamination stabilized and harmless. Another method of Huff U.S. Patent No.
6,001,185 discloses the use of calcium phosphate compounds are effective
in treating the surface of the coating of heavy metal pollution,
industrial by-products and industrial waste water contaminated with
heavy metals, heavy metal compounds, including arsenic, lead,
cadmium, chromium, nickel, silver, stability and human and
biological harmless. Huff calcium phosphate compound employed is in the
form of at least one compound selected from natural apatite, synthetic
hydroxyapatite, dibasic calcium phosphate, or phosphate rock.

[0011] Although the prior art and the development of the technology has been
proven effective phosphate used in heavy metal contaminated soil remediation,
waste incineration fly ash, bottom slag, heavy metal pollution of surface coatings,
heavy metal waste, industrial by-products and industrial waste water
contaminated with heavy metals but so far no domestic proprietary
technology or R & D results can provide a method or food grade
products, even including the popular health food detox on the market
such as vitamin C, green algae, barley green powder, or dietary fiber foods such
 7

as parsley, celery , green beans, pumpkin, sweet potatoes, mushrooms, konjac,

and a proposed reaction mechanism and demonstrate brewing, cooking, or
flavoring process, or in the human gastrointestinal effectively in food, food,
medicine contained heavy metals leaching and reducing the concentration of
toxic form harmless, chemically inactive form of the heavy metal was stable, i.e.,
reduce the body's absorption or its crop, and it is discharged from the body to the
environment may prevent or avoid the heavy metal back to the food chain.

[0012] Chinese Patent CN 101011432 B invention provides Flavonoids

Extracts use as medicaments Lead poisoning and remission, the
experiment, per day per kilogram of body weight Pteridium
aquilinum flavonoids used in an amount of 30-180mg, can be up to
Lead a significant effect; per day per kilogram of body weight using
bracken flavonoids 50_300mg, can achieve significant results to
alleviate or treat lead poisoning. Chinese patent CN 1506070 A
discloses an aqueous lyxose Lead health care products, by calcium,
zinc, iron scientific ratio, a synergistic effect against the activity of
lead toxicity, reducing lead absorption. Supplemented stachyose can
adsorb heavy metals lead, but also a rapid proliferation of
Bifidobacterium intestinal bacteria, intestinal emptying time was
significantly shortened, promotion of Lead. Lead poisoning and toxic
effects of the damage by the good prevention and treatment. Chinese invention
patent application (Application No. CN101933937 A) discloses a low
molecular weight citrus pectin A citrus pectin extracted in the
discharge of heavy metals Lead Clinical Applications. Through animal
and clinical experiments demonstrated, citrus pectin, low molecular weight
different from the general chemical chelating agent, in addition to
effectively lead in the exhaust toxin, mercury, arsenic, excreted,
without affecting the other, such as calcium, magnesium, zinc or
mineral the key level material. Citrus pectin intake of 15 grams a day
for all subjects showed a significant decrease in mercury content.
Average decrease of 72.17%, 38.13% -84.83% range, without any side
effects. [0013] Chinese Patent Application (Application No. W02013127146
A1) discloses a method to alleviate the toxicity of lead Lactobacillus
and their use. The Lactobacillus is Lactobacillus CCFM8661, having
acid resistance, has good in vitro tolerance to lead ions, capable of
withstanding the initial concentration of 150mg / L solution of lead
ions, lead ions and strong adsorption, can reduce the lead mouse
blood, liver, kidney, stomach exposed lead content, significantly
improved oxidation index in mice exposed lead body, to alleviate the
pathological symptoms in mice exposed to lead.

[0014] A number of studies or other article reported that many natural food
antioxidants and have some anti-lead and lead dispel function and detoxification.
Malic acid and citric acid and the like are typical of heavy metal
sequestrant. Kelp iodine and alginic acid can promote the discharge
of lead. Protein contained in milk can be combined with lead is
 8

formed insolubles, can prevent the absorption of calcium contained

in the lead. Polysaccharides and other macromolecules pectin, alginic
acid, and dietary fiber polysaccharide macromolecules thereon
abundant free sugar chain - 0H and -C00H group may be complexed
with lead, it is difficult to form a gel uptake, the effective prevent lead
absorption in the gastrointestinal tract, play a role in the promotion of lead.
Garlic and onion in sulfide can dissolve the toxic effects of lead. Sea
buckthorn, prickly pear and kiwi fruit rich in vitamin C, can prevent
lead absorption, reduce lead toxicity. Folic acid and vitamin
B1,B2,B6,B12 organ recovery will certainly help to strengthen and
promote detoxification. Lipoic acid, known as the "universal
antioxidant", is also a heavy metal chelating agent, also used as a food
poisoning early or metal poisoning antidotes used. Glutathione is an
important in vivo antioxidant, glutamic acid, cysteine and glycine,
cysteine sulfhydryl group on its active group (abbreviated as G-SH),
easily toxin ( radical such as heavy metals, lead, mercury, arsenic,
etc.) and the like in combination, but with detoxification. Selenium
has a role in detoxification of heavy metals detoxification, known as
the "natural antidote heavy metals." Selenium as negatively charged
non-metallic ions, in vivo may be combined with harmful heavy
positively charged ions to form a protein complex (complex)
compound (ligand compound), thereby achieving detoxification
detoxification and metal selenides. Also, according to Reuters Health NEW
YORK - New research shows that eating tofu will help to reduce blood lead
concentrations in the metal. Researchers tofu is not yet known is how to reduce
blood lead concentration of the metal mechanism, but they suspect is due to
calcium in soy inhibits the body's absorption of metallic lead, strengthen the
protection of metallic lead. Carrots are effective mercury, food containing
a large amount of pectin, may be combined with mercury, which can
effectively lower blood concentrations of mercury ions.

[0015] These foods and natural antioxidants, Flavonoids Extracts invention

patent, patent disclosure aqueous lyxose Lead Health and low molecular weight
citrus pectin display only the function thereof adsorbed, complexed or
chelated heavy metal free , into the intestines, promoting the
excretion of heavy metals can be quickly eliminated from the body,
but no scientific proof or according to the reaction mechanism
thereof capable of heavy metals harmful to food safety, including
leaching toxic concentrations of lead, cadmium, arsenic, copper, mercury
significant reducing effect, and to form harmless, chemically inactive
form of the efficacy of heavy metal was stable, i.e. after the discharge
to the environment may still be reduced to the hazards most soluble,
free heavy metals via the environment Gan shift, diffusion, and then
converted back to the food chain, eventually went back to the table.
Metal complex is a complex of molecules or ions of metal ions (or atoms) such
as (Cu + 2, Zn + 2) and a ligand covalently combining formed. Ligands
are those molecules containing a lone pair electrons provide atom,
 9

organic molecules N, 0, S can provide lone pair of electrons, these

donors may complexation with the metal ions, thereby forming a
composite. Is a special chelate complex, which means that one or more groups
with a metal ion complex having a cyclic ligand structure generated by the
reaction. Also known as the chelate complex, because of its cyclic structure, they
are generally more stable than complexes. However, practical experience and
mortar cured according to landfill chelating heavy metal contaminants,
temperature, humidity, pH landfill environment, many changes, due to aging or
chelating agents and foreign matter (e.g., acid rain) reaction of decomposition,
the results could be the key knot heavy metal cations, heavy metal cations allow
reduction of heavy metal atoms and leach back into the environment.

[0016] After the macro from the words, so adsorption, heavy metal
complexing or chelating free their way root of the problem is not
eliminated from the body of the practice, but only to the transfer and
dissemination-style food chain cycle, coupled with sustained
economic development, threatens to cause environment and
accumulation of heavy metal contamination of the food chain
enrichment and amplification will only worsen, potentially
threatening the sustainable development of agriculture, could spread
through the food chain more harm animals and people's life and
health, affecting the quality of the living environment of the people as
well as social, economic and all countries. Food chain, heavy metal
pollution is also spread diffusion of food safety issues of global concern.

[0017] Another person, with the continuous improvement of China's rapid

economic development, urbanization and people's living standards, production of
municipal solid waste with the Japanese Ju increase. Which easily degradable
kitchen waste garbage dominant position accounted for 40-80% of the total
municipal solid waste in municipal waste. Kitchen waste refers to food residues
and food processing waste, mainly food waste in the solid residue.

[0018] Accordingly, the innovation, the development of food-grade stabilization

method or a low-cost products suitable for people mainly of food, such as rice,
and a variety of food, food, medicine to its immersion, brewing, cooking, or
Add seasoning process, i.e. capable of adsorbing stirring, chelating or
complexing food, food, medicine contained in heavy metals, including
lead, cadmium, arsenic, copper, mercury, and can be in food, food, medicine into
the human tongue, gastrointestinal before toxic concentrations effective to reduce
leaching of heavy metals and convert it to a free chemically inactive form
harmless stable material, body or organism and which does not
absorb them from the body or is discharged via the kitchen or food
kitchen discard garbage anywhere, after piling or landfill, reduce
harm to the environment and is not easy to shift environment Gan,
proliferation and transformation, thereby preventing, reducing heavy
metals and then back to the food chain, in order to maintain the
quality of the environment, the implementation of heavy metal
 10

pollution prevention, conservation natural ecological security, is

currently an urgent need of China and various regions of the world affected by
heavy metal contamination of the food chain.

SUMMARY

[0019] The present invention solves the technical problem is to provide a method
of reducing food, food, medicine toxic heavy metals in the leaching, enhance food
safety, and environmentally friendly method for preparing a stabilizer to prevent
the food chain and heavy metal back to improve the prior art insufficient.

[0020] A present invention reduce food, food, medicine toxic heavy metals in the
leaching, enhance food safety, environmental stabilizing agent, said stabilizing
agent is a phosphoric acid or phosphate material, an acidity regulator and
chlorides.

[0021] The phosphoric acid or phosphate is the People's Republic of

China national standard GB 2760 Safety of food additives permitted
in food tricalcium phosphate, calcium dihydrogen phosphate, calcium
hydrogen phosphate, sodium pyrophosphate, sodium
hexametaphosphate, trimetaphosphoric acid sodium
tripolyphosphate, trisodium phosphate, tripotassium phosphate,
sodium dihydrogen phosphate, potassium dihydrogen phosphate,
disodium hydrogen phosphate, dipotassium hydrogen phosphate,
disodium dihydrogen pyrophosphate, ammonium dihydrogen
phosphate, hydrogen phosphate ammonium, tetrapotassium
pyrophosphate, trisodium monohydrogen pyrophosphate,
polyvinylidene potassium phosphate, acid pyrophosphate, sodium
aluminum phosphate acidic, People's Republic of China national standard
GB 14880 allows the use of food safety, magnesium hydrogen phosphate in
nutritional supplements, calcium glycerophosphate, ferric
pyrophosphate, casein phosphopeptides, and phosphate-containing
foods include bone meal, bone soup powder, one or more of fish
meal. The non-soluble salts include calcium phosphate salts. Preferably
calcium salts, including tricalcium phosphate, calcium dihydrogen
phosphate, calcium hydrogen phosphate, as they are in contact with a
basic substance or environmental most quickly converted to calcium
hydroxyapatite, Ca5 (P 〇 4) 3 (OH), i.e. mineral Hydroxyapatite (abbreviated
HA), which is free of heavy metals dissolve and precipitate a substitution reaction
to form harmless, stable, and even if extreme abnormalities of the natural
environment such as acid rain erosion, but also difficult to dissolve, decompose
the complex of formula P mineral salts and complexes of formula yl source of
heavy metal minerals. In addition, calcium dihydrogen phosphate, calcium
hydrogen phosphate can also be used simultaneously to make a leavening agent,
tricalcium phosphate, calcium hydrogen phosphate is a calcium fortifier food
ingredient may be increased.
 11

[0022] The pH adjusting agent is People's Republic of China national standard

GB 2760 Safety of food additives permitted in food phosphate, the pH
adjusting agent is tricalcium phosphate, monocalcium phosphate,
sodium pyrophosphate, sodium trimetaphosphate , sodium
tripolyphosphate, trisodium phosphate, tripotassium phosphate,
sodium dihydrogen phosphate, potassium dihydrogen phosphate,
disodium hydrogen phosphate, dipotassium hydrogen phosphate,
disodium dihydrogen pyrophosphate, magnesium hydrogen
phosphate, magnesium phosphate tribasic, sulfate calcium, calcium
hydroxide, potassium hydroxide, magnesium hydroxide, lactic acid,
calcium lactate, sodium lactate, sodium carbonate, potassium
carbonate, potassium bicarbonate, sodium bicarbonate, sodium
sesquicarbonate, sodium acetate, sodium citrate, monosodium citrate
, potassium citrate, one or several. Preferably, potassium hydroxide,
sodium carbonate, potassium carbonate, potassium bicarbonate,
sodium bicarbonate, sodium sesquicarbonate, because they are water
soluble and provide rapid synthesis advantageously hydroxide
Hydroxyapatite required. Less preferred is calcium hydroxide,
sodium lactate, sodium tripolyphosphate and combinations of
sodium dihydrogen phosphate with disodium hydrogen phosphate of
calcium as calcium hydroxide can advantageously provide rapid
synthesis Hydroxyapatite required. Solution of sodium
tripolyphosphate, sodium dihydrogen phosphate combination of
disodium hydrogen phosphate and having the pH buffering ability to
slow changes in the pH maintained weakly alkaline, which is a
favorable response leaching of heavy metals and toxic concentration
and degradation to form harmless complexes of formula mineral
stable alkaline environment phosphonium salt thereof. Sodium
lactate are not only used as an acidity regulator, also has antioxidant,
a thickener and other multiple functions, it will be advantageous
complex of formula phosphonium salt was generation of stable
minerals.

[0023] The chloride is sodium chloride, People's Republic of China

National Standard GB2760 GB14880 food safety and allows the use of
potassium chloride, one or more of calcium chloride, magnesium
chloride in. Preferably sodium chloride. Sodium chloride is a
commonly used food preservatives, with the function of penetration,
the food can be heavy metals in the tissues, particularly lead (Pb), and
leaching of toxic chemicals, to improve the mobility of heavy metals,
i.e., increased dietary fiber is captured and adsorbed with synthetic
calcium phosphate or hydroxy opportunities to contact and react.
Food grade chloride chloride complex ions may also be provided,
which can accelerate the precipitation reaction was stabilized calcium
chloride complex of formula or a hydroxyl-substituted (0H)
Hydroxyapatite is synthesized calcium chloride, dissolved in turn,
free of heavy metals to form harmless, stabilized chlorine complex
 12

was phosphate minerals such as phosphorus chloride lead, cadmium

chloride phosphate mineral (Pb5 (P 〇 4) 3 (Cl), Cd5 (P 〇 4) 3 (C1))
and the like.

[0024] The starting material further comprises a stabilizer containing dietary

fiber, gum, abundant phlegm, or can be made to increase the food or processed
food probiotics, food grade iron compound, an antioxidant, a thickener, nutrition
enhancer, one or more preservatives.

[0025] The dietary fiber-containing, gums or mucous or rich substance, can

increase the probiotic food fruits and vegetables, cereal grains, beans and algae
such as blue-green algae food, edible fungus / mushroom including yeast, black
fungus, Ganoderma lucidum, mushrooms, mushroom, Poria and other algae
including brown algae, red algae, green algae and diatoms, figs, pumpkin,
papaya, sweet potato, sweet potato leaves, bitter melon, bamboo shoots, bamboo
shoots, asparagus, carrots, white radish , onions, lotus seeds, lotus root, spinach,
celery, parsley, Royal Palace, broccoli (broccoli), cauliflower, cabbage, bean
sprouts, red chicken dish, leeks, eggplant, avocado, lemon, hawthorn, arrowroot,
yam, purple Su, nuts, ginger, garlic, chili, pepper, pepper, green pepper, purple
sweet potato, potato, taro, sprouting fenugreek, natto, Black-eyed beans, butter
beans, soybeans, red beans, mung beans, black beans, green beans class, rice
including white rice, brown rice and the like embryo rice, linseed, maize, millet,
oats, barley, okra, sesame, burdock, soybean milk, milk black, lentils, grape,
grapefruit, guava, dates Jujube, plum and the like; The tool dietary fiber, pectin,
phlegmatic, or rich, can increase the probiotics food plants, fruit and vegetables,
cereal grains, beans and algae food, or milk as raw material are processed into
food, health food , flavorings or thickening agents, such as polyphenols,
metallothionein, chicken powder, barley green powder, ginseng powder, yeast,
yogurt (yogurt, yogurt), miso, pickles, tempeh, blue-green algae products such as
seaweed, spirulina, green algae products such as Enteromorpha, Ulva and other
products such as brown algae seaweed, kelp, sodium alginate, red algae products
such as seaweed, red algae gum products such as carrageenan and agar , prebiotic
foods such as stachyose, inulin (inulin), soluble soybean polysaccharide,
polydextrose, resistant dextrin, flax seed powder, taro, wheat germ powder, Poria
powder, arrowroot powder, mung bean flour, bean flour , black soybean meal,
bean sprouts, almond powder, walnut powder, kelp powder, allspice, clove
powder, licorice powder, curry powder, Jiang Huang powder, cumin powder,
cumin powder, chili powder, pepper, salt and pepper, shichimi ( Qiwei capsaicin),
Lo Meng Powder, pumpkin powder, papaya powder, coconut powder, bitter
gourd powder, pollen, carrot powder, chickpea flour, black fungus powder,
mushroom powder, mushroom powder, pea powder, green soy flour, peanut
flour, corn flour, cocoa powder, spinach powder, coriander powder, mountain
powder, basil powder, hawthorn powder, plum powder, lemon powder, mountain
powder, Kwa root powder, purple flour, food starch include sweet potato flour,
tapioca flour, cornstarch and arrowroot flour, lily flour, potato flour, konjac flour,
apple powder, grape powder, jujube powder, jujube powder, ginger powder,
garlic powder, soybean milk powder, soybean milk powder, barley flour, sesame
 13

flour, rice noodles, rice, rice, pasta, flour, fruit juices such as papaya, sugar cane
juice, grape juice, pineapple juice, lemon juice, orange juice, grapefruit juice,
prune juice, mango juice, tomato juice, cranberry juice, pudding, honey, syrup,
instant cereals, rice sauce , noodles sauce, sweet sauce, barbecue sauce, hoisin
sauce, jelly, jam, cranberry sauce, bean sauce, tomato sauce, sesame paste,
peanut butter, chili sauce, mustard sauce, guacamole, salad dressing, barbeque
sauce, sand satay sauce, teriyaki sauce One or more of soy sauce, pectin, guar
gum, sprouting fenugreek gum, locust bean gum and the like.

[0026] The dietary fiber containing glial, abundant phlegm, or can be made to
increase probiotics foods or processed foods encompasses preferably 6.0 or more
(The pH range in order to avoid excessive consumption of free hydroxyl
Hydroxyapatite synthesis advantageously phosphate) food, including sodium
alginate, inulin, alkalized cocoa powder, arrowroot flour, mushroom powder,
bitter gourd powder, kelp powder, curry powder, paprika, black fungus powder,
parsley powder, coconut flour, red bean flour, rye flour, barley flour, wheat germ
meal, mountain powder, walnut powder, tapioca flour, tapioca flour purple,
konjac powder of one or more.

[0027] The food-grade iron compound food safety People's Republic of China
national standard GB 2760 allows the use of food additives in the black iron
oxide, red iron oxide and the People's Republic of China national standard GB
14880 allows the food safety of ferrous Fortified compound, including ferrous
sulfate, ferrous gluconate, ferric ammonium citrate, ferrous fumarate, ferric
citrate, ferrous citrate, ferrous lactate, high-heme iron chloride, ferric
pyrophosphate, iron porphyrin, ferrous glycinate, reduced iron, one or more of
ethylenediaminetetraacetic acid sodium iron, carbonyl iron, ferrous carbonate,
ferrous fumarate, ferrous succinate, heme iron, electrolytic iron, and the like.
Preferably ferrous sulfate, which is easily soluble in water cap can be provided
complexed iron ions and sulfate ions can accelerate iron-phosphorus complexes
of formula galena (Corkite) stabilizing means for generating a solubility of all
currently known network lead salts of phosphorus minerals were fit lowest.

[0028] The antioxidant is a food safety People's Republic of China national

standard GB 2760 allows the use of vitamin E in food additives, disodium
edetate, calcium disodium ethylenediaminetetraacetic acid, sulfur dioxide,
potassium metabisulfite, sodium metabisulfite, sodium sulfite, sodium bisulfite,
low sodium sulfite, ascorbic acid (vitamin C), D- erythorbic acid and its sodium
salt, sodium ascorbate, calcium ascorbate, ascorbyl palmitate, phospholipids,
gallic acid propyl ester (PG), licorice antioxidants, phytic acid, sodium phytate,
bamboo antioxidants, rosemary extract, polyphenols, polyphenols palmitate, and
lipoic acid, L- methionine, glutathione, cysteine , taurine, and the like of one or
several.

[0029] The thickener is a food safety People's Republic of China national

standard GB 2760 allows the use of food additives in propylene glycol, tara gum,
starch acetate, sodium carboxymethyl starch, acid-treated starch, sodium starch
 14

phosphate, aluminum octenyl succinate starch, oxidized starch, hydroxypropyl

oxidized starch, cyclodextrins, gum arabic, guar gum, carrageenan, cassia gum,
gelatin, curdlan, pectin, locust bean gum, sea dill gum, Abelmoschus gum,
xanthan gum, gum Artemisia, Tian Jing gum, flax seed gum (Frank gum), gum
acacia, gellan gum, agar, alginic acid propylene glycol ester, chitin (chitin) ,
deacetylation of chitin (chitosan), alginic acid, sodium alginate, potassium,
maltitol, lactitol, sorbitol, pullulan, soluble soybean polysaccharide, tamarind
seed gum, carboxymethyl cellulose Su, methyl cellulose, sodium carboxymethyl
cellulose, a polyglycerol fatty acid ester, distarch phosphate, phosphated distarch
phosphate, acetylated distarch phosphate, acetylated distarch adipate of one or
more.

[0030] The nutritional supplements for the People's Republic of China national
standard GB 14880 food safety to allow food fortifier use, including calcium
carbonate, calcium gluconate, calcium citrate, calcium lactate, L- calcium lactate,
calcium hydrogen phosphate, L- threonate, glycine, calcium aspartate, calcium
citrate, calcium malate, calcium acetate (calcium acetate), calcium chloride,
tricalcium phosphate (calcium phosphate), vitamin E, calcium succinate, glycerol
calcium phosphate, calcium oxide, calcium sulfate, bone meal (ultrafine fresh
bone meal), sodium selenite, sodium selenate, selenoproteins, selenium-rich
edible mushroom powder, L- Se - methyl-selenocysteine, selenides carrageenan,
selenium enriched yeast, casein phosphopeptides, calcium caseinate peptides,
taurine, L- methionine, L- lysine, L-carnitine, vitamin Bl, B2, B6, B12, folic acid,
and the like or more. Preferably dibasic calcium phosphate, tribasic calcium
phosphate (calcium phosphate), calcium carbonate. Dibasic calcium phosphate,
tribasic calcium phosphate (calcium phosphate) may provide a source of
formation of calcium hydroxyapatite. Advantageously calcium carbonate is able
to provide rapid synthesis Hydroxyapatite required, particularly not applied to
high calcium foods, food. In addition, calcium carbonate, because of its small
molecule clinical easier for the body to absorb calcium in the bones than other
health care products.

[0031] The preservative is potassium cinnamon, cinnamic aldehyde, polylysine

hydrochloride [epsilon], [epsilon] polylysine, nisin, sodium diacetate, sorbic acid
and potassium salts and the like one or several. Preferably hydrochloride, poly-
lysine [epsilon], [epsilon] potassium cinnamate polylysine.

[0032] Suitable preservatives are also useful to use to enhance food security. The
FDA (Food and Drug Administration, FDA) depending on the size of the degree
of harm, the food safety issues in turn divided into the following six: toxigenic
and pathogenic microorganisms, nutritional hazards, environmental
contaminants, natural toxins, pesticides residues and food additives. Which
ranked first in terms of "toxigenic and pathogenic microorganisms" topped the
more serious harm, due to microbial ubiquitous in nature, but also the microbial
food safety problems are more serious main reason.
 15

[0033] wide ε- ε- polylysine or polylysine hydrochloride pH range (at pH 2 ~ 9),

thermal stability (120 ° C, 20min or above) is not decomposed, heat can be
suppressed bacteria, it was added after the food, the food can be a heat treatment,
not only inhibit fungal and gram-positive bacteria, Gram-negative bacteria but
also aerogenes, Pseudomonas putida, Pseudomonas aeruginosa, Proteus
vulgaris , E. coli, Campylobacter jejuni, Salmonella typhimurium and other
bacteria that cause food poisoning and corruption also has a strong inhibitory
effect. ε_ polylysine hydrochloride, [epsilon] not only gram-negative E. coli
polylysine easily suppressed, Salmonella very good inhibitory effect to other
natural preservatives (e.g., Ni s in), and some of which viruses include
Lactobacillus bulgaricus, Streptococcus thermophilus, also inhibited the growth
of yeast. ε - polylysine hydrochloride, ε - polylysine homopolymer is composed of
lysine, a lysine can be decomposed in the human body, it can be fully digested
and absorbed by the body. Lysine is one of eight essential amino acids, can
promote human development, enhance immune function, and enhance the role
of the central nervous tissue function acid. Thus polylysine hydrochloride
[epsilon], [epsilon] is a polylysine nutritional bacteriostatic agents, safe in other
chemical preservatives that acute oral toxicity LD50 of 5g / kg. Since the lysine
content in cereals is very low and susceptible to damage and lack of process, it is
known as the first limiting amino acid, countries in the world to allow enhanced
amino acid added in foods. Cinnamon potassium sorbate are international FAO
and WHO recommended safe and efficient preservative, made stringent
requirements in the recommended amount of sodium sorbate, and to advocate
for them gradually canceled, but that belongs to no potassium cinnamon drug, its
dosage and daily intake without any restrictions. For dairy products in China is
also benzoic acid, sorbic acid range, the amount has strict rules, but potassium
cinnamon did not make any demands.

[0034] one or more of said heavy metal is lead, cadmium, copper, arsenic,
mercury and other soluble ions.

[0035] The product of the present invention, the basic composition range of mass
percentage:

[0036] phosphate 0.5% to 90%;

[0037] pH adjusting agent 0.5 to 65%;

[0038] (food grade) 0.5% to 40% chloride;

[0039] contain dietary fiber, gum, abundant phlegm, or can be made to increase
the food or processed food probiotics 0 to 98%;

[0040] Food grade iron compound 0 to 5%;

[0041] 0 to 5% of an antioxidant;
 16

[0042] Thickener 0 to 5%;

[0043] 0 to 5% nutritional supplements;

[0044] 0 to 2% of preservatives.

[0045] The above raw materials at normal temperature and pressure uniformly
stirred to scale, and mixed.

[0046] The composition of the present invention, the percentage of the mass of
raw material has a great range of choice, depending on many factors:

[0047] The present invention has utilized the product itself dietary fibers, pectin,
phlegm, or rich, the processing is made to increase the use of probiotic bacteria in
general the amount of diet food, for example, if the product of the present
invention is selected mushroom powder such as pasta general noodle seasoning
(only a small amount for each soup bowl, such as 1 g), mass percent range of the
basic composition may be:

[0048] 40 to 70% mushroom powder;

[0049] phosphate 5 to 50%;

[0050] pH adjusting agent 5 to 20%;

[00511 food grade chloride (NaCl) 0.5 to 20%.

[0052] The above raw materials at normal temperature and pressure uniformly
stirred to scale, and mixed.

[0053] If the product of the present invention is used for selection of pumpkin
powder solid drink (10 Kernan guar powder was dissolved in 250ml hot water
directly brewed into tea) foods as a dietary fiber supplement, consisting
essentially of mass percent range may be:

[0054] 75 ~ 98% pumpkin powder;

[0055] Phosphate 0.5 to 20%;

[0056] pH adjusting agent 0.5% to 10%;

[0057] Food grade chloride (NaCl) 0.5 to 5%;

[0058] The above raw materials at normal temperature and pressure uniformly
stirred to scale, and mixed.
 17

[0059] If the present invention is applied to the product itself is made rich
vegetable fiber ingredient as pickles, if the amount of ingredients does not exceed
10% by the general salt content of the pickles is 2% to 4%, the percentage mass
consisting essentially of can range from:

[0060] 0.5 ~ 60% phosphate;

[0061] pH adjusting agent 0.5% to 10%;

[0062] Food grade chloride (NaCl) 20 to 40%.

[0063] The product of the present invention is added to the soaking, brewing,
cooking, or flavoring foods, food, medicine contained in heavy metal species
(single or multiple) and the degree of contamination (heavy metals leaching toxic
concentrations of various types of light and heavy), for example, cadmium,
copper contamination of raw oysters, rice arsenic contamination, or an excess of
mercury, lead powder Eight medicine, contained more heavy metal species or
heavy metals contained in the leaching higher toxic concentrations, the required
relatively large amount of chloride and phosphate or ; lead (Pb) by weight of the
contamination of food, the need to add a greater amount of food grade iron
compound.

[0064] The present invention was added to the soaking product, brewing,
cooking, or flavoring food, the food composition itself, such as whether a
sufficient amount inclusive of calcium, or chloride salt, iron ions, sulfate ions,
and dietary fiber, gum, or abundant phlegm, probiotics can be increased;
containing trace amounts of calcium, dietary fiber contamination of foods such as
rice and rice products, the demand relatively large amount of calcium phosphate
or gum, and dietary fiber having, phlegm, by food thickening agent.

[0065] The product of the present invention is added to the soaking, brewing,
cooking, or flavoring foods, food softness, hard fried food, dried fruit can be used
with a large amount of bulky materials or functional ingredients such as calcium
phosphate salts .

[0066] The product of the present invention is added to the soaking, brewing,
cooking, or flavoring foods, food pH value, the lower the pH, an alkaline pH
adjusting agent relative to the amount of the required more.

The addition amount of [0067] the present invention depends on the amount of
food product, food, medicine, and the amount of heavy metals contained in the
type of heavy metals contained in the leaching toxic concentration.

[0068] In the present invention, the infusion product, cooking, or degradation

during food seasoning, food, medicine leaching toxicity of heavy metals contained
and follows its stable and harmless reaction mechanism:
 18

[0069] The main key reaction mechanism is this: series of Gibbs free energy
generated spontaneous effect of substitution and precipitation reactions. Since
uniform mixing, the raw material mixture composition, from the package after
sterilization bags / cans, phosphoric acid or phosphate with a basic part of the
regulator and by the solubility of the chloride began disparity, the Gibbs free
energy generated by conversion of hydroxy acid calcium chloride phosphate
(apatite chloride) reaction, for immersion, brewing, cooking, or flavored water
was added, the conversion reaction is not completed I will also quickly and
phosphate hydroxide, calcium ion, chloride ion synthesis of hydroxyl calcium
phosphate, calcium chloride, and calcium phosphate and hydroxyl-based, "heavy
metal complex-type phosphorus chloride, phosphorus complex hydroxyl heavy
metals' solubility of phosphorus and calcium chloride has the disparity, and
Gibbs free enthalpy was generated free of heavy metals in food, medicine and
heavy metals contained in the precipitate to form a substituted easily
decomposed chemically inactive form of stabilization, the sound "heavy metal
complex of formula mineral" as pyromorphite pyromorphite Pbs ( Jie 04) 3 (〇
1), galena takes hydroxyapatite (11'〇 forks 5 ^ 7 Jie 〇 1] 1 〇 plate 11;? ^ 6 5
dagger (04?) 3 (011), thousand and "1 < :;!? (? 04) ^ 6 dagger Jie 63 (011) 6S 〇 4,
Jin hydroxyapatite Cadmium Hydrox yapatite Cd5 (P 〇 4) 3 (OH), Kam-chloro
phosphorus ore Cadmium Chloroapatite Cd5 (P 〇 4) 3 (Cl), copper
hydroxyapatite CopperHydroxyapatite Cu5 (P 〇 4) 3 (OH), phosphorus
atacamite Copper Chloroapatite Cu5 (P 〇 4) 3 (Cl), Johnbaumite Ca5 (As 〇 4) 3
(OH), Turneaureite Ca5 (As 〇 4) 3 (Cl), Levin and phosphate ore Mercury (II)
phosphate Hg3 (P 〇 4) 2, etc. Secondly, the use of dietary fiber having
adsorption, gum, abundant phlegm, or probiotics, and iron or compounds,
thickeners, antioxidants, nutritional supplements and other substances,
complexing or chelating fixed free heavy metals, together with winding, braiding
action, may be formed "thermodynamic" Ping Heng effect acceleration Gibbs
phenomena produce heavy metal substitution and precipitation reactions.

[0070] pH adjusting agent preferably used in products of the invention are

sodium carbonate, potassium carbonate, potassium bicarbonate, sodium
bicarbonate, sodium sesquicarbonate and potassium phosphates soluble in water
and quickly provide an advantageous synthesis of the HAP need hydroxide.

[0071] from the viewpoint of thermodynamics chemical reaction, at a certain

temperature and pressure conditions, the reaction may be carried out direction
Gibbs free energy (enthalpy) reduction (AG <0) direction. AG, and the greater the
negative value, the greater thermodynamic driving force for the reaction. Calcium
salts such as Ca3 (P 〇 4) 2 Ca5 than HAP (P 〇 4) 3 (OH) less stable, i.e. calcium
hydroxyphosphate Ca 5 (P 〇 4) 3 (OH) Gibbs free enthalpy as Ca3 (P 〇 4) lower
than the Gibbs' free enthalpy calcium salt of 2, since this Ca3 (P 〇 4) 2 solubility
Ksp / 25 ° C of 2 · 07χ 10-33, and calcium hydroxyphosphate Ca5 (P 〇 4) 3 (OH)
solubility Ksp / 25 ° C or is 6.8110-37 ~ 1110-36 (reference DRHandbook from
Lide of Chemistry and Physics Edition .82nd Boca Raton:. the CRC Press, 2001).
And hydroxy phosphate 1 ^^ 5 ^ 04) 3 ( OH) less stable than chlorophosphate 1
 19

^^ 5 ^ 04) 3 ( Cl), i.e., calcium chloride Gibbs free Gibbs enthalpy HAP low free
enthalpy, calcium chloride because this Ca5 (P 〇 4) 3 (Cl) solubility Ksp / 25 ° C
is 10-46.89 (from the reference BSCrannell et al./Waste Management 20
(2000) ). Therefore, once the chloride ions and hydroxide salt (NaCl) or chloride
provides, sodium salts and calcium salts spontaneous reaction produces the
following effects since Gibbs:

[0072] sodium phosphate + calcium carbonate + 0H- (aq) -Ca5 (P 〇 4) 3 (OH)

(s), HAP

[0073] calcium salt + 0H- (aq) -Ca5 (P 〇 4) 3 (OH) (s), HAP

[0074] Hydroxyapatite Ca5 (P 〇 4) 3 (OH) (s) + sodium chloride (NaCl) or

chloride ---------> Ca5 (P 〇 4) 3 (Cl) (s) calcium chloride (chlorapatite)

[0075] Similarly, due to the Gibbs phenomena HAP Ca5 (P 〇 4) 3 (OH) or

chlorine calcium Ca 5 (P 〇 4) 3 (Cl) for Pb, ^ &!,! ^^ 8 and other attraction is
very strong. For example, when such dissolved heavy metals, free lead calcium
hydroxyphosphate contacts, which will be adsorbed chlorine calcium phosphate,
calcium, and produces the following substituted and the other a more stable
spontaneous precipitation reaction, a lower Gibbs free energy, low solubility
"complex-type phosphorus mineral salt", its harmless to humans or the
environment.

[0076] 5Pb + 2 + Ca5 (P 〇 4) 3 (OH) -5Ca + 2 + Pb5 (P 〇 4) 3 (OH),

hydroxylapatite galena

[0077] 5Pb + 2 + Ca5 (P 〇 4) 3 (Cl) -5Ca + 2 + Pb5 (P 〇 4) 3 (Cl), cadmium

chloride phosphate ore

[0078] Similarly, if the iron ions and sulfate ions contained in the same solution,
it is easy to form a more stable phosphate hydroxy, lower Gibbs free energy, ultra
low solubility "galena iron-phosphorus complex formula" ( Corkite) PbFe3 (P 〇
4) (OH) 6S 〇 4 solubility Ksp / 25 ° C = 10-112 · 6-chloro-phosphorus ratio of
galena Pb5 (P 〇 4) 3 (Cl) (solubility 10-84 · 43) about 1028 times more stable.

[0079] Similarly, in terms of the heavy metal cadmium, cadmium stabilizing and
harmless calcium substitution reaction as follows:

[0080] 5Cd + 2 + Ca5 (P 〇 4) 3 (OH) -5Ca + 2 + Cd5 (P 〇 4) 3 (OH), cadmium

hydroxyapatite

[0081] 5Cd + 2 + Ca5 (P 〇 4) 3 (Cl) -5Ca + 2 + Cd5 (P 〇 4) 3 (C1), cadmium

chloride phosphate ore
 20

[0082] Similarly, for heavy metals, copper stabilization and harmless calcium
substitution reaction as follows:

[0083] 5Cu + 2 + Ca5 (P 〇 4) 3 (OH) -5Ca + 2 + Cu5 (P 〇 4) 3 (OH), copper

hydroxyapatite

[0084] 5Cu + 2 + Ca5 (P 〇 4) 3 (Cl) -5Ca + 2 + Cu5 (P 〇 4) 3 (Cl), phosphorus

atacamite

[0085] of Hg, the Gibbs effect to promote stabilization of mercury and harmless
calcium substitution reaction as follows:

[0086] 3Hg + 2 + calcium salts, including tricalcium phosphate Ca3 (P 〇 4) 2-

3Ca + 2 + Hg3 (P 〇 4) 2, mercury phosphate ore

[0087] in terms of heavy metals arsenic, heavy metals and arsenic stabilized
harmless reaction mainly theoretical AsO arsenate ions, substituted Ca5 (P 〇 4)
3 (OH) or Ca5 (P 〇 4) 3 (Cl) Gibbs effect of phosphate ions, the reaction is as
follows:

[0088] 3As 〇 4-3 + Ca5 (P 〇 4) 3 (OH) Ca5 -3P 〇 4-3 + (As 〇 4) 3 (OH)
Johnbaumi you

[0089 ] 3As 〇 4-3+Ca5 (P 〇 4) 3 (Cl)-3P 〇 4-3+Ca5 (As 〇 4) 3 (Cl) Turneaure i

te

[0090] The chemical reactions described above cell product of the present
invention in the soaking, brewing, cooking, or degradation during food flavoring,
food, medicine contained in heavy metals, including lead, cadmium, copper,
arsenic, mercury and other toxic leaching and decontamination and the main
reaction mechanism of stabilization.

[0091] summary overview of the overall reaction principle:

[0092] In the soaking, brewing, cooking, or flavoring process by adding directly

to the product of the present invention of adding water or aqueous food, food,
medicine and stirred or heating mode uniformly mixed; the use of soaking,
brewing , cooking itself or with bulky to be functional raw materials or
ingredients such as calcium hydrogen phosphate, sodium lactate, calcium
carbonate make food, food, medicine to increase bulky, soft and porous, so that
some soluble heavy metal hidden in the depths of a more soluble ; chlorides such
as using a food grade salt (sodium chloride) with the permeate, can be heavy
metals, especially lead (Pb), and toxic chemicals from the food tissue extraction
features that enhance the solubility and mobility of heavy metals with the
stabilizer phosphates such as capture, and the contact chance of the reaction; and
the chloride ions using a food grade chloride; rich in dietary fiber using, gums,
 21

mucilaginous or probiotic-rich foods, food, or thickening agent, food, Chinese

harmful substances including heavy metals adsorption dissolve free adhesive
anchorage; or together with the use of antioxidants such as sulfides, ascorbic acid
or ascorbate, sodium phytate, tea Phenol, with which to resolve the toxicity of
lead to prevent lead absorption, or with metal ions have a strong chelating action,
food, food, medicine dissolved heavy metal chelate of free and fixed resolve the
toxicity of lead; or with food grade properties of pig iron ion; Using acidity (basic)
regulators such as potassium hydroxide, sodium hydroxide, calcium hydroxide or
produce other free acidity regulator such as sodium tripolyphosphate food, food,
medicine to buffer, to maintain the desired pH range ; Gibbs effect because,
phosphate and calcium ions, hydroxide, chloride ions complexed calcium
hydroxyphosphate, calcium chloride and phosphoric acid or phosphate contained
in the food and thus, food, medicine heavy metals contained in the free, or iron
ions and, dietary fibers, gums, mucilaginous, rich in probiotics, antioxidants,
thickening agents, adsorption enhancers nutrition, heavy metal chelating or
complexing fixed spontaneous precipitation reaction to be substituted and, in the
food , food, cooked and medicine into the body when the tip of the tongue, before
parenteral, already formed in the human stomach acid than the acid strength of
abnormal or extreme environments such as iN hydrochloric acid solution is also
difficult to dissolve in acid rain, decomposition, harmless phosphorous complex
of formula mineral salt stabilizing means, such as pyromorphite, iron-
phosphorus galena. And the use of dietary fiber, gum, phlegm, or stimulation of
peristalsis rich probiotics, greatly reducing harmful substances and carcinogenic
substances wall contact time, quickly most of the body of harmful toxins and
heavy metals of such complex of formula stabilizing excreted. At the same time,
adequate intake of nutritional supplements, antioxidants, dietary fiber, pectin,
phlegmatic, or probiotics can also help health, including improving immune
function and enhance immunity, improve intestinal health, the prevention of
cardiovascular disease, prevention cancer, prevention of diabetes and other
diseases. Suitable preservatives are also useful to use to enhance food security.

[0093] A present invention reduce food, food, medicine toxic heavy metals in the
leaching, enhance food safety, environmentally friendly method of preparing a
stabilizer, comprising: a phosphoric acid or phosphate, acidity regulators,
chloride, respectively, in proportion to each accurate measurement of the raw
material, then all fed into a mixer at ambient temperature and pressure
uniformly stirred and mixed, packaging (before sterilization or sterile packaging
can) to obtain.

[0094] beneficial effects

Stabilizer [0095] The present invention is directly added to food, the food, the
medicine, in brewing, cooking, or flavoring process, before entering the human
tongue, or parenterally in the kitchen or food waste via anywhere discarded, prior
to stacking or landfill, leaching of heavy metals contained therein degradable
toxicity, i.e., reduce the amount of dissolved heavy metals leaching, even better
than the human stomach acid environment such as acid rain or extreme
 22

abnormalities in acid strength of 1N hydrochloric acid solution can be formed

easily decompose heavy metal, chemical product properties inactive form, its not
easy for the body, crops absorb and enhance food security and reduce its Gan
shift in the environment, proliferation and transformation, enhance
environmental protection and then go back to the food chain to stop the heavy
metal, has a good prospect.

detailed description

[0096] The following embodiments with reference to specific embodiments,

further illustrate the present invention. It should be understood that these
embodiments are illustrative only and the present invention is not intended to
limit the scope of the invention. Furthermore, it should be understood that, after
reading the teachings of the present invention, those skilled in the art that
various changes or modifications may be made to the present invention, and
these equivalents also fall within the scope of the appended claims of the present
application as defined.

[0097] Example 1

[0098] Select lead (Pb) leaching a low amount of toxic concentrations of this
embodiment of instant noodles as water samples, and preparing a boiled liter (in
1,000 ml of) a.

[0099] (1) a suitable amount (e.g. 500ml i.e. 500g) above the hot water boiling
water containing a lead (Pb) concentration low toxicity leaching amount of
instant noodles in a glass bottle clearance, and the appended added seasonings,
uniform stirring, then half of the sample surface (a surface of at least 50g) and
the rear cover half of the soup is placed in another vial clearance, inspection
analysis. Hazardous waste identification GB5085.3-2007 using standard
extraction procedure toxicity standard sample HJ / T299-2007 solid waste
leaching toxicity test, but the lixiviant using IN HC1 (to simulate strength than
gastric acidity but acid) as well as face and soup sample and shaken for 24 hours
(a longer extraction time) in an extraction flask, I HJ / T299-2007 same method.
After filtration, using graphite furnace atomic absorption spectrometer leaching
toxic concentrations of lead (Pb) in the detoxification of heavy metals before the
stabilizer was not added to the leaching solution was measured.

[0100] (2) boiling water in hot water with low leaching of lead toxicity (1) above
(Pb) as well as instant noodles and seasoning soup and half of the sample for
testing the surface, the remaining half of the bottles in the same infusion was
added little 〇.3g surface (300mg) with a good heavy metal stabilizer (weight
percentage composition: dietary fiber (konjak flour) is 40%, phosphate (disodium
dihydrogen pyrophosphate + calcium hydrogen phosphate) 48% , acidity
regulator (potassium hydroxide) was 8%, 4% sodium chloride)), after uniformly
stirred, then the closure Determination inspection. Hazardous waste
identification GB5085.3-2007 using standard extraction procedure toxicity
 23

standard sample HJ / T299-2007 solid waste leaching toxicity test, but the
lixiviant using IN HC1 (to simulate strength than gastric acidity but acid) as well
as face and soup sample containing the heavy metal stabilizers extraction bottle
was shaken for a 24 hours (longer extraction time), I HJ / T299-2007 same
method. After filtration, using graphite furnace atomic absorption measurement
was added to the leachate lead (Pb) after detoxification of heavy metals leaching
stabilizer 0.3g toxic concentrations.

[0101] After testing, i.e., before the stabilization treatment (1), and after the
stabilization treatment (2) samples of instant noodles heavy metals lead (Pb) list
of toxic concentrations of the leaching are as follows:

[0102]

[G iuj "measuring junction meters Μ not constant, the buried mesh lattice Cloth
force U of the article 1 in the history back to punch out divination Existing
coupling WWb raspberries Ί 'King concentrated sheath 734 generous brother / kg
(i.e. 4yg / Kg or 0.004mg / after kg), after the stabilization process, the above-
described embodiment is added 0.3g of heavy metal stabilizers 2) (1, sample
instant noodles lead (Pb) leaching toxic concentration of 1 mg / l (i.e. lyg / kg or
0.001mg / kg ), i.e. heavy metals lead (Pb) leaching toxic concentrations of toxic
leaching or indeed 75% degradation.

[0104] Example 2

[0105] Select two packages at the same time later, the same brand of lead (Pb)
the amount of the high concentration of toxic leaching noodles as the present
sample embodiment, and ready, boil a liter (l, 〇〇〇 ml) pure water.

[0106] (1) i.e. 500g to 500ml boiling water above a hot water containing lead (Pb)
concentration high leaching toxic amount of a clearance of instant noodles in a
glass bottle, and the accompanying seasonings added, after uniformly stirred,
then after half of the sample surface (a surface of at least 50g) and half of the
broth was placed in another clearance vial closure, inspection analysis.
Hazardous waste identification GB5085.3-2007 using standard extraction
procedure toxicity standard sample HJ / T299-2007 solid waste leaching toxicity
test, but the lixiviant using IN HC1 (to simulate strength than gastric acidity but
acid) as well as face and soup sample and shaken for 24 hours (a longer
extraction time) in an extraction flask, I HJ / T299-2007 same method. After
filtration, using graphite furnace atomic absorption spectrometer leaching toxic
concentrations of lead (Pb) in the detoxification of heavy metals before the
stabilizer was not added to the leaching solution was measured.
 24

After [0107] (2) (1) above the hot water boiling water as well as instant noodles
and sauces and soups sampled half face test, in the same infusion bottle
remaining half was added l.〇 g plane (l, 〇〇〇 mg) heavy metal stabilizers
(mass percent composition as follows: dietary fiber (mushroom powder) was
60%, phosphate (disodium hydrogen phosphate, sodium dihydrogen phosphate
+) 8%, acidity regulator (sodium carbonate) of 20%, nutritional supplements
(calcium carbonate) 8%, 4% sodium chloride), stirring homogeneously, then the
closure Determination inspection. Hazardous waste identification GB5085.3-
2007 using standard extraction procedure toxicity standard sample HJ / T299-
2007 solid waste leaching toxicity test, but the lixiviant using IN HC1 (to simulate
strength than gastric acidity but acid) as well as face and soup sample containing
the heavy metal stabilizers extraction bottle was shaken for a 24 hours (longer
extraction time), I HJ / T299-2007 same method. After filtration, using graphite
furnace atomic absorption measurement was added to the leachate lead (Pb)
after l.Og stabilizer detoxification of heavy metals leaching toxic concentrations.

[0108] (3) further take the package-containing high lead (Pb) disposed noodles
500g was added 500ml i.e. the brewing water within a hot water bottle clearance,
and the accompanying seasoning added, stirred uniformly. Thereafter, half of the
surface of the sample immediately (at least surface 50g) and placed in the other
half of the soup clearance vial, was added 1 .〇 g (l, 〇〇〇 mg) with a good heavy
metal stabilizers (percent by mass Composition : dietary fiber (mushroom
powder) was 44%, phosphate (disodium hydrogen phosphate, sodium
dihydrogen phosphate +) 8%, acidity regulator (sodium carbonate) is 20%,
nutritional supplements (calcium carbonate) 8% , 20% sodium chloride)), after
uniformly stirred, then the closure Determination inspection. Hazardous waste
identification GB5085.3-2007 using standard extraction procedure toxicity
standards sample injection HJ / T299-2007 solid waste leaching toxicity test, but
the lixiviant using IN HC1 (to simulate strength than gastric acidity but acid) as
well as face and soup sample containing the heavy metal stabilizers extraction
bottle was shaken for a 24 hours (longer extraction time), I HJ / T299-2007 same
method. After filtration, using graphite furnace atomic absorption measurement
was added to the leachate lead (Pb) after l.Og stabilizer detoxification of heavy
metals leaching toxic concentrations.

[0109] After testing, i.e., before the stabilization treatment (1) containing a high
lead (Pb), and instant noodles stabilization treatment after the sample (2) and (3)
containing a high lead (Pb) sample instant noodles heavy metals lead (Pb)
leaching cytotoxic concentration list below:

[0110]
 25

[0111] Test results showed that (1) the noodle samples stabilized leaching toxic
concentration of heavy metals lead (Pb) pretreatment of 0.031 mg / kg (i.e. 31yg /
Kg), in the same instant noodles sample (2) in the stabilizing treatment , after 2 is
added l.Og (2) heavy metal stabilizers in the above-described embodiments, the
lead (? 13) leaching toxic concentrations of 0.019 mg / l (8 Jie 19 8 / ^ 1), i.e.
heavy metals lead (Pb) leaching toxic degradation, decreased by about 38%. (3) in
Example 2 was added after the heavy metal stabilizer (3) stabilization process
noodle samples lead (Pb) 1.0g embodiment leaching toxic concentrations of
0.005 mg / l (i.e. 5yg / Kg), and (1) also purchased, leaching concentrations of
heavy metals lead (Pb) in front of the same brand of instant noodles stabilized 31
mg / l as compared to heavy metals lead (Pb) leaching toxic degradation,
decreased by about 84%. Example 2 also shows that the amount of heavy metal
stabilizers containing more sodium chloride can be more degradable, to reduce
the toxic concentrations of lead leaching of heavy metals.

[0112] Example 3

[0113] Example 2 are simultaneously selected and later, one of the same brand of
lead (Pb) the amount of the high concentration of the leaching instant noodles as
the present sample embodiment, and ready, boil a liter (l, 〇〇〇 ml) purified
water .

[0114] (1) In the above-described water 500g 500ml i.e. a hot water infusion bag
and at the same time according to the second embodiment later, the same brand
of lead (Pb) concentration high leaching in a quantity of instant noodles
clearance vial, and added with attached seasoning uniformly stirred, then
sampled half plane (at least 50g surface) and half of the broth was added 0.5g
(500mg) and first embodiment (2) of the same heavy metal stabilizers used
(composition by mass percentage: dietary fiber food (konjac powder) was 40%,
phosphate (disodium dihydrogen pyrophosphate + calcium hydrogen phosphate)
was 48%, acidity regulator (potassium hydroxide) was 8%, 4% sodium chloride)),
uniformly stirred after then sampled soup and other clearance faces disposed
within the closure glass, inspection analysis. Hazardous waste identification
GB5085.3-2007 using standard extraction procedure toxicity standard sample
HJ / T299-2007 solid waste leaching toxicity test, but the lixiviant using IN HC1
(to simulate strength than gastric acidity but acid) as well as face and soup
sample containing the heavy metal stabilizers extraction bottle was shaken for a
24 hours (longer extraction time), I HJ / T299-2007 same method. After
filtration, using graphite furnace atomic absorption measurement was added to
the leachate lead (Pb) after detoxification of heavy metals leaching stabilizer 0.5g
toxic concentrations.
 26

[0115] (2) (1) above the hot water boiling water containing a low amount of lead
(Pb) as well as instant noodles and seasoning soup sample surface and a half to
do after the test, in the same infusion bottle remaining half plane Add l.Og first
embodiment and (2) and the third embodiment (1) of the same stabilizing agent
with heavy metal (mass percentage composition: dietary fiber (konjak flour) 40%
disodium (phosphate dihydrogen pyrophosphate + calcium hydrogen phosphate)
was 48%, acidity regulator (potassium hydroxide) was 8%, 4% sodium chloride),
stirring homogeneously, then the closure Determination inspection. Hazardous
waste identification GB5085.3-2007 using standard extraction procedure toxicity
standard sample HJ / T299-2007 solid waste leaching toxicity test, but the
lixiviant using IN HC1 (to simulate strength than gastric acidity but acid) as well
as face and soup sample containing the heavy metal stabilizers extraction bottle
was shaken for a 24 hours (longer extraction time), I HJ / T299-2007 same
method. After filtration, using graphite furnace atomic absorption measurement
was added to the leachate lead (Pb) after detoxification of heavy metals leaching
stabilizer 1.0g toxic concentrations.

[0116] After testing, Example 3 (1) and before stabilization treatment after
stabilizing processing list leach toxic concentrations Embodiment 3 (2) samples
of instant noodles heavy metals lead (Pb) in the following Example:

[0117]

[0118] Test results showed that while the Example 2 later, the leaching toxic
concentration of heavy metals lead (Pb) of the same brands of instant noodles
before stabilizing processing of 31yg / Kg compared to Example 3 (1) was added
0.5g stabilizing heavy metals after the stabilization treatment agent noodle
samples lead (Pb) concentration of the leaching of toxic lyg / Kg, heavy metal lead
(Pb) leaching toxic degradation, reduced by about 96%. Example 3 (2) above was
added after the heavy metal stabilizer 1.0g same sample instant noodles lead (Pb)
leachate concentration <lyg / Kg *, heavy metal lead (Pb) leaching toxic
degradation, reduced> 96%. * Graphite furnace atomic absorption detection limit
of lead measurement value of lug / L (i.e. lyg / Kg), less than lug / L
concentration that is read can not be accurately measured. Example 3 also
showed the same heavy metal added more stabilizers, may be more degraded,
reducing the toxic concentrations of heavy metal leaching. From Example 3
Example 2 (2) comparison, also showed more phosphate is added, the
degradation can reduce the toxic concentrations of heavy metal leaching.

[0119] Example 4
 27

[0120] Select two packages at the same time later, the same label arsenic (As) the
amount of the high concentration of toxic leaching noodles as the present sample
embodiment, and ready, boil a liter (l, 〇〇〇 ml) pure water.

[0121] (1) i.e. 500g to 500ml boiling water above a hot water containing a high
arsenic (As) the amount of leaching of toxic concentrations of instant noodles in a
glass bottle clearance, and the accompanying seasonings added, after uniformly
stirred, then after half of the sample surface (a surface of at least 50g) and half of
the broth was placed in another clearance vial closure, inspection analysis.
Hazardous waste identification GB5085.3-2007 using standard extraction
procedure toxicity standard sample HJ / T299-2007 solid waste leaching toxicity
test, but the lixiviant using IN HC1 (to simulate strength than gastric acidity but
acid) as well as face and soup sample and shaken for 24 hours (a longer
extraction time) in an extraction flask, I HJ / T299-2007 same method. After
filtration, using hydride generator atomic absorption arsenic (As) before
detoxification of heavy metals leaching toxicity stabilizer was not added to the
leachate concentration measurement.

After [0122] (2) above (1) in the hot water boiling water containing a high arsenic
(As) as well as instant noodles and seasoning sampled and soups half face test, in
the same infusion bottle surface remaining half was added l.〇 g with a good
heavy metal stabilizers (mass percent composition of: seasoning (pepper) was
67%, phosphates (tricalcium phosphate dibasic calcium +) was 20%, acidity
regulator (sodium bicarbonate) as 4%, nutritional supplements (calcium
carbonate) 5%, NaCl 4%), stirring homogeneously, then the closure
Determination inspection. Hazardous waste identification GB5085.3-2007 using
standard extraction procedure toxicity standard sample HJ / T299-2007 solid
waste leaching toxicity test, but the lixiviant using IN HC1 (to simulate strength
than gastric acidity but acid) as well as face and soup sample containing the
heavy metal stabilizers extraction bottle was shaken for a 24 hours (longer
extraction time), I HJ / T299-2007 same method. After filtration, using hydride
generator atomic absorption measurement was added to the leachate arsenic (As)
concentration after leaching of toxic heavy metal detoxification l.Og stabilizer.

[0123] (3) above takes another package containing a high arsenic (As) was placed
in another clearance glass noodles, pure water was added to hot water, i.e. above
500ml infusion of 500g, and the appended added seasonings, uniform stir.
Thereafter, half of the surface of the sample immediately (at least surface 50g)
and placed in the other half of the soup clearance vial, was added l.Og with a good
heavy metal stabilizer (weight percentage composition: seasoning (pepper) 43 %,
phosphates (tricalcium phosphate dibasic calcium +) was 20%, acidity regulator
(sodium bicarbonate) 16%, nutritional supplements (calcium carbonate) 5%, 16%
NaCl), uniformly stirred after then capped Determination inspection. Hazardous
waste identification GB5085.3-2007 using standard extraction procedure toxicity
standard sample HJ / T299-2007 solid waste leaching toxicity test, but the
lixiviant using IN HC1 (to simulate strength than gastric acidity but acid) as well
as face and soup sample containing the heavy metal stabilizers extraction bottle
 28

was shaken for a 24 hours (longer extraction time), I HJ / T299-2007 same

method. After filtration, using hydride generator atomic absorption measurement
was added to the leachate arsenic (As) after the detoxification of heavy metals
leaching toxic concentrations stabilizer.

[0124] After testing, i.e., before the stabilization process of Example 4 (1)
containing a high arsenic (As), and instant noodles sample after the stabilization
process of Example 4 (2) and Example 4 (3) containing a high arsenic (As)
instant noodles sample heavy metals arsenic (as) list of toxic concentrations of
the leaching are as follows:

[0125]

[0126] The results show the detection, with high arsenic (As) arsenic leaching
process prior to stabilization of the concentration of instant noodles
concentration of the leaching amount of 0.142 mg / kg (i.e. 142yg / Kg), after the
stabilization process, is added 1.0g Example (2) heavy metal stabilizers 4,
leaching toxic concentration noodle samples arsenic 0.081 mg / l (i.e. 8Uig / Kg),
i.e. heavy metals arsenic (as) leaching toxic concentrations or leaching toxic
degradation, reduction 42.96%, about 43% . Example 4 (3) was added 1.0 g of (3)
heavy metal stabilizers stabilizing post-treatment sample instant noodles arsenic
(As) leaching toxic concentrations of 0.011 mg / l (i.e. llyg / Kg), and Example 4
(1) simultaneously later, the same brand of instant noodles toxic concentration of
heavy metals leaching arsenic (As) stabilized pretreatment 142 mg / l as
compared to heavy metals arsenic (As) leaching toxic degradation, decreased by
about 92%. Example 4 also shows the amount of heavy metal stabilizers
containing sodium chloride, and pH adjusting agent (sodium bicarbonate) may
be the more degraded, reducing the toxic concentrations of heavy metals leaching
arsenic.

[0127] Example 5

[0128] Select about 500g arsenic (As) the amount of leaching toxic concentration
sample rice as the present embodiment, all of the first to washing with water.

[0129] (1) above from the washed arsenic (As) 175g samples of rice contaminated
press a conventional method (e.g., rice and water ratio of 1: 1) was added an
appropriate amount of purified water, then, into electric cooking pot . Uncooked
rice boiled after a meal, let it cool ten (10+) minutes, then taken at least 250g rice
pot was placed Determination inspection after a clearance within the bottle
closure. Hazardous waste identification GB5085.3-2007 using standard
 29

extraction procedure toxicity standards oscillating leaching procedure the sample

arsenic (As) leaching toxicity test, but the lixiviant using IN HC1 (to simulate
strength than gastric acidity but acid) and rice sample and shaken for 24 hours (a
longer extraction time) in an extraction flask, I HJ / T299-2007 same method.
After filtration, using hydride generator atomic absorption arsenic (As) before
detoxification of heavy metals leaching toxicity stabilizer was not added to the
leachate concentration measurement.

[0130] (2) and a self-test (1) in the same bag the washed with arsenic (As) 175 g of
sample contamination rice, 5.0g of heavy metal stabilizers (weight percentage
composition: Dietary Fiber (pumpkin powder) 76%, phosphate (disodium
hydrogen phosphate, sodium dihydrogen phosphate + + + tricalcium phosphate,
dicalcium phosphate) was 13%, acidity regulator (sodium bicarbonate) 4%, 3%
sodium chloride, magnesium chloride 2%, a preservative (poly-lysine [epsilon])
of 2%). Thereafter, test and (1) the same amount of water as added, stirred
uniformly, into electric cooking pot. Uncooked rice boiled after a meal, let it cool
down after ten minutes, then at least 250g rice pot take place after the closure
Determination inspection clearance within a glass bottle. Hazardous waste
identification GB5085.3-2007 using standard extraction procedure toxicity
standard sample HJ / T299-2007 solid waste leaching toxicity test, but the
lixiviant using IN HC1 (to simulate strength than gastric acidity but acid) and rice
samples extraction in a shaking flask 24 hours (longer extraction time), I HJ /
T299-2007 same method. Yu HJ / T299-2007 method unchanged. After
filtration, using hydride generator atomic absorption arsenic (As) containing
stabilizers rice detoxification of heavy metals leaching toxic leachate
concentrations measured.

[0131] After testing, i.e., before the stabilization treatment (1) and the
stabilization process after (2) the sample rice heavy metals arsenic (As)
concentration of the leaching toxicity following list:

[0132]

[0133 "Μ detection result is not adopted, the concentration of the poor Cape Ai
Wo leaching by Starling sufficient processing cape contaminated surgery indica
boiled postprandial 0.136 mg / kg (i.e. 136yg / Kg), by the stabilization treatment
of arsenic contamination indica rice, i.e. indica rice added 5.0g 175g Example 5
above (2) heavy metal stabilizers, rice boiled after leaching arsenic toxic
concentrations of 0.007 mg / kg (i.e. 7yg / kg), i.e. heavy metals arsenic Indica
rice arsenic contamination of the sample (as ) reducing the concentration of toxic
leaching or degradation of toxic leaching can be described as about 95%.
 30

[0134] Example 6

[0135] Select about 500g containing cadmium (Cd) rice as the amount of leaching
toxic concentration of this sample embodiment, all of the water prior to washing
with.

[0136] (1) from above the washed-containing cadmium (Cd) contaminated rice
and 175g sample was added 175g (rice and water ratio of 1: 1) pure water, then,
into electric cooking pot. Uncooked rice boiled after a meal, let it cool ten (10+)
minutes, then taken at least 250g rice pot was placed Determination inspection
after a clearance within the bottle closure. Hazardous waste identification
GB5085.3-2007 using standard extraction procedure toxicity standard sample
HJ / T299-2007 solid waste leaching toxicity test, but the lixiviant using IN HC1
(to simulate strength than gastric acidity but acid) and rice samples extraction in
a shaking flask 24 hours (longer extraction time), I HJ / T299-2007 same
method. After filtration, the graphite atomic absorption cadmium (Cd) before
detoxification of heavy metals leaching toxicity stabilizer was not added to the
leachate concentration measurement.

[0137] (2) and a self-test (1) in the same bag containing washing through with
cadmium (Cd) 175 g of sample contamination rice, 5.0g of heavy metal stabilizers
(weight percentage composition: Dietary Fiber (pumpkin powder) of 78%,
phosphate (disodium hydrogen phosphate, sodium dihydrogen phosphate + + +
tricalcium phosphate, dicalcium phosphate) was 13%, acidity regulator (sodium
bicarbonate) 4%, 3% sodium chloride, magnesium chloride 2 %). Thereafter, 175
g of (rice and water ratio of 1: 1) pure water, uniformly stirred, into electric
cooking pot. Uncooked rice boiled after a meal, let it cool down after ten minutes,
then at least 250g rice pot take place after the closure Determination inspection
clearance within a glass bottle. Hazardous waste identification GB5085.3-2007
using standard extraction procedure toxicity standard sample HJ / T299-2007
solid waste leaching toxicity test, but the lixiviant using IN HC1 (to simulate
strength than gastric acidity but acid) and rice samples extraction in a shaking
flask 24 hours (longer extraction time), I HJ / T299-2007 same method. After
filtration, the use of cadmium (Cd) graphite atomic absorption measurement was
added to the leachate stabilizer detoxification of heavy metals leached toxic
concentrations.

[0138] After testing, cadmium (Cd) contamination stabilized rice i.e. (1) and the
stabilization process after the rice (2) of the heavy metal contamination of rice
samples Kam list below toxic concentrations leaching pre-treatment:

[0139]
 31

[0140] Test results showed that the concentration of toxic leaching process
unstabilized rice boiled cadmium cadmium-containing meal 5.4 g / kg (i.e.
5.4yg / Kg), cadmium stabilized rice processing, i.e. 175g rice was added 5.0g
Example 6 above (2) heavy metal stabilizers, boiled meal cadmium leaching toxic
concentrations of 1.0 g / kg (i.e. l.Oyg / kg), i.e., the sample rice cadmium
cadmium (Cd) toxicity leaching reducing the concentration of toxic degradation
or leaching can be described as about 81%.

[0141] Example 7

[0142] Select about 500g lead (Pb) the amount of leaching toxic concentration of
brown rice sample as the present embodiment, all of the first to washing with
water.

[0143] (1) from the washed containing lead (Pb) and pollution brown rice sample
was added 175g 175g (rice and water ratio of 1: 1) pure water, then, into electric
cooking pot. Uncooked rice boiled after a meal, let it cool down after ten minutes,
then taken at least 250g rice pot disposed within the lid, a clearance
Determination inspection glass. Hazardous waste identification GB5085.3-2007
using standard extraction procedure toxicity standard sample HJ / T299-2007
solid waste leaching toxicity test, but the lixiviant using IN HC1 (to simulate
strength than gastric acidity but acid) and rice samples extraction in a shaking
flask 24 hours (longer extraction time), I HJ / T299-2007 same method. After
filtration, using graphite furnace atomic absorption spectrometer leaching toxic
concentrations of lead (Pb) in the detoxification of heavy metals before the
stabilizer was not added to the leaching solution was measured.

[0144] (2) and a self-test (1) In the same bags, washing through with lead (Pb)
175 g of sample contamination brown rice, 5.0g of heavy metal stabilizers (weight
percentage composition: (+ phosphate disodium hydrogen phosphate sodium
dihydrogen phosphate + calcium hydrogen phosphate) was 80%, acidity
regulator (calcium hydroxide) was 10%, 7% sodium chloride, magnesium
chloride, 3%). Thereafter, and test (1) as an equivalent amount of pure water (175
g of) was added, stirred uniformly, into electric cooking pot. Uncooked rice boiled
after a meal, let it cool down after ten minutes, then at least 250g rice pot take
place after the closure Determination inspection clearance within a glass bottle.
Hazardous waste identification GB5085.3-2007 using standard extraction
procedure toxicity standard sample HJ / T299-2007 solid waste leaching toxicity
test, but the lixiviant using IN HC1 (to simulate strength than gastric acidity but
acid) and rice samples extraction in a shaking flask 24 hours (longer extraction
time), I HJ / T299-2007 same method. After filtration, using graphite furnace
 32

atomic absorption determination of leachate containing stabilizers rice

detoxification of heavy metals lead (Pb) leaching toxic concentrations.

[0145] After testing, i.e., before the stabilization treatment (1) and the
stabilization process after (2) the sample rice heavy metals lead (Pb) leaching
toxic concentrations listed below:

[0146]

[0147] The results show the detection, lead boiled brown rice meal without
stabilization treatment of toxic concentrations of lead leach 0.010 mg / kg (i.e. 1
〇 provision / here), the stabilization treatment lead brown rice, 8 Jie 1758 brown
added 5. (^ Example 7. (2) heavy metal stabilizers, lead concentration after
leaching toxicity was boiled rice <〇.〇〇 lmg / kg (i.e., <lyg / kg *), i.e., a sample
lead brown rice the lead (Pb) to reduce the concentration of toxic leaching or
degradation of toxic leaching can be described as 90%. * graphite furnace atomic
absorption detection limit of lead measurement value of lug / L (i.e. about lyg /
Kg), a concentration of less than lug / L of That is not accurate readings.

[0148] Example 8

[0149] Select about 500g arsenic (As) and lead (Pb) the amount of leaching toxic
concentration samples of rice as the present embodiment, all of the first to
washing with water.

[0150] (1) above from the washed arsenic (As) and lead (Pb) and 175g
contaminated rice sample was added 175g (rice and water ratio of 1: 1) pure
water, then, into the electric pot rice. Uncooked rice boiled after a meal, let it cool
ten (10+) minutes, then taken at least 250g rice pot was placed Determination
inspection after a clearance within the bottle closure. Hazardous waste
identification GB5085.3-2007 using standard extraction procedure toxicity
standard sample HJ / T299-2007 solid waste leaching toxicity test, but the
lixiviant using IN HC1 (to simulate strength than gastric acidity but acid) and rice
samples extraction in a shaking flask 24 hours (longer extraction time), I HJ /
T299-2007 same method. After filtration, using hydride generator atomic
absorption of leachate arsenic (As) leaching toxic concentrations prior to
measurement detoxification of heavy metals stabilizer was not added, and a
measurement lead is not added detoxification of heavy metals stabilizer rice
leaching solution by graphite furnace atomic absorption spectrometer (Pb)
leaching toxic concentrations.
 33

[0151] (2) and a self-test (1) in the same bag the washed with arsenic (As) and
lead (Pb) contaminated rice sample was added 175g 10.〇 g heavy metal stabilizer
(weight percentage composition: Meal fiber foods (barley flour) 60%, phosphates
(tricalcium phosphate dibasic calcium +) was 18%, acidity regulator (calcium
hydroxide) was 10%, 10% sodium chloride, a thickening agent (soluble soybean
polysaccharide) 1%, antioxidant (ascorbic acid) 1%). Thereafter, and test (1) as an
equivalent amount of pure water (175 g of) was added, stirred uniformly, into
electric cooking pot. Uncooked rice boiled after a meal, let it cool down after ten
minutes, then at least 250g rice pot take place after the closure Determination
inspection clearance within a glass bottle. Hazardous waste identification
GB5085.3-2007 using standard extraction procedure toxicity standard sample
HJ / T299-2007 solid waste leaching toxicity test, but the lixiviant using 1N HC1
(to simulate strength than gastric acidity but acid) and rice samples extraction in
a shaking flask 24 hours (longer extraction time), I HJ / T299-2007 same
method. After filtration, using hydride generator atomic absorption of leachate
arsenic (As) Determination of heavy metal detoxification stabilizer rice TCLP
concentration, and graphite furnace atomic absorption leaching solution
measurement of heavy metal detoxification stabilizer rice lead (Pb ) leaching
toxic concentration.

[0152] After testing, i.e., before the stabilization treatment (1) and the
stabilization process after (2) the sample rice heavy metals arsenic (As) and lead
(Pb) concentration of the leaching toxicity following list:

[0153]

[0155] Test results showed that without the stabilization treatment of arsenic and
lead contamination boiled rice meal arsenic leaching of toxic concentrations of
0.126 mg / kg (i.e. 126yg / Kg), toxic concentrations of lead leaching 0.00134
mg / kg (i.e. 1.34yg / kg) <a75g arsenic and lead contamination of rice added
10.0g Example 8 (2) after the treatment of heavy metal stabilizers, boiled meal
concentration of arsenic in the leaching solution <〇.〇〇 lmg / kg (i.e., <LYG /
kg *), i.e. heavy metals in samples of rice arsenic (as) or reduced leaching toxic
degradation of toxic concentrations> 99%; boiled meal of toxic concentrations of
lead leaching <0.001mg / kg (i.e., <Uig / kg *). * Graphite furnace atomic
absorption spectrometer lead, arsenic, detection limit of the measurement value
are both lug / L (i.e. about lyg / Kg), less than lug / L concentration that is read
can not be accurately measured.

[0156] Example 9
 34

[0157] Select about 600g of cadmium, copper (Cd, Cu) concentration of the
leaching toxic amount as the present embodiment oyster samples, all prior to
washing with water.

[0158] (1) Wash oysters 250g sample placed within the cap immediately after
Determination of a clearance inspection glass. Hazardous waste identification
GB5085.3-2007 using standard extraction procedure toxicity standard sample
HJ / T299-2007 solid waste leaching toxicity test, but the lixiviant using IN HC1
(to simulate strength than gastric acidity but acid) and oysters Sample extraction
in a shaking flask 24 hours (longer extraction time), I HJ / T299-2007 same
method. After filtration, before the heavy metal cadmium stabilizer is not added,
the copper (Cd, Cu) leaching toxic concentration meter measured absorption
leachate graphite atoms.

[0159] (2) and a self-test (1) in the same bag with the washed sample oysters
250g, 5.0g of heavy metal stabilizers (weight percentage composition: phosphate
(sodium hexametaphosphate) was 85%, acidity adjusting agent (sodium
bicarbonate + calcium hydroxide) of 12% sodium chloride, 3%), stirring
homogeneously, all samples were placed immediately after the closure
Determination inspection clearance within a glass bottle. Hazardous waste
identification GB5085.3-2007 using standard extraction procedure toxicity
standard sample HJ / T299-2007 solid waste leaching toxicity test, but the
lixiviant using IN HC1 (to simulate strength than gastric acidity but acid) and
said oysters samples were shaken for 24 hours (a longer extraction time) in an
extraction flask, I HJ / T299-2007 same method. After filtration, the graphite
atomic absorption was measured on the leaching of cadmium added after the
heavy metal stabilizer 5.0g, copper (Cd, Cu) leaching toxic concentrations.

[0160] After testing, i.e. stabilized oysters (1) and oysters after stabilization
treatment (2) heavy metal cadmium sample oysters, a listing of copper leaching
toxic concentration (Cd, Cu) pretreatment as follows:

[0161]

[0162] Test results showed that the leaching toxic concentration oyster samples
Cadmium (Cd) without a stabilization treatment of 0.226 mg / kg, oysters sample
cadmium (Cd) after stabilization treatment leachate concentration of 0.010 mg /
kg, is added 5.0g above Example 9 (2) 250g samples of heavy metal cadmium
oysters stabilizer (Cd) leaching toxic concentration was reduced by about 95%.
Stabilized leaching toxic concentration of heavy metals copper (Cu) oysters
sample pre-treatment was 31.0 mg / kg, after the stabilization treatment oysters
 35

samples of copper (Cu) leaching toxic concentrations of 20.5 mg / kg, 8 Jie 25 (^

copper oysters sample of (& 1 ) was added 1 toxicity leaching (^ degradation while
the above-described heavy metal stabilizer, a decrease of about 30%.

[0163] Example 10

[0164] Select about 600g mercury (Hg) leaching amount of toxic concentrations
Danggui head as the present sample embodiment, all of the first order with pure
water.

[0165] (1) 500g sample washed mercury (Hg) Danggui head, the first slice, into
the pot, add appropriate amount of boiling water, fire of boiled, wait until boiling,
about half of the sampling pot 250g Angelica head soup and a half, ten minutes
let it cool down, after the cap is placed Determination inspection clearance within
a glass bottle. Hazardous waste identification GB5085.3-2007 using standard
extraction procedure toxicity standard sample HJ / T299-2007 solid waste
leaching toxicity test, but the lixiviant using IN HC1 (to simulate strength than
gastric acidity but acid) and Angelica head samples were shaken for 24 hours (a
longer extraction time) in an extraction flask, I HJ / T299-2007 same method.
After filtration, leaching toxic concentration using mercury (Hg) prior to
detoxification of heavy metals stabilizer was not added to the leaching solution
was measured by atomic absorption was hydrogenated generator.

[0166] (2) (1) half of the sampling head and half of Angelica soups test, in the
same pot and the remaining half of Angelica head soup placed in the other half of
the empty glass bottles, heavy metal stabilizer was added 2.0g (mass composition
percentage: phosphates (tricalcium phosphate + calcium hydrogen phosphate)
was 90%, acidity regulator (sodium carbonate) was 7%, 3% sodium chloride),
stirring homogeneously, placed in capped glass bottles in a clearance after the
inspection analysis. Hazardous waste identification GB5085.3-2007 using
standard extraction procedure toxicity standard sample HJ / T299-2007 solid
waste leaching toxicity test, but the lixiviant using IN HC1 (to simulate strength
than gastric acidity but acid) and Angelica head samples were shaken for 24
hours (a longer extraction time) in an extraction flask, I HJ / T299-2007 same
method. After filtration, the hydrogenation of atomic absorption mercury (Hg)
after the generator was added 2.0g of heavy metals in the leachate measured
leaching toxicity stabilizer concentration.

[0167] After testing, before the stabilization treatment head Angelica i.e. (1) and
the stabilization treatment after Angelica head (2) listing the leaching toxic
concentrations of mercury (Hg) as follows:

[0168]
 36

[0170] Test results showed that the concentration of toxic heavy metals leaching
mercury (Hg) after treatment Angelica head unstabilized sample was boiled
billion. 8 [mu] g / kg, after the stabilization treatment, i.e. about 250g boiled with
some head angelica soup 2.0g was added the above-described Example 10 (2)
after the heavy metal stabilizers, Angelica head sample mercury (Hg) leaching
toxic concentration of 0.3 g / kg, i.e., the first sample Angelica mercury (Hg)
leaching toxic degradation, decreased by about 62% .

[0171] Example 11

[0172] Select an amount of from about 800g leaching concentration of cadmium

(Cd) Danggui head as the present sample embodiment, together with pure water
cleaning of all.

[0173] (1) 600g washed sample containing cadmium (Cd) Danggui head, the first
slice, into the pot, add appropriate amount of boiling water, fire of boiled, wait
until boiling, the sampling pot head of Angelica 1/3, about 200g, add 1/3 soup, let
it cool down after ten minutes, after inspection Determination disposed within a
clearance vial closure. Hazardous waste identification GB5085.3-2007 using
standard extraction procedure toxicity standard sample HJ / T299-2007 solid
waste leaching toxicity test, but the lixiviant using IN HC1 (to simulate strength
than gastric acidity but acid) and Angelica head samples were shaken for 24
hours (a longer extraction time) in an extraction flask, I HJ / T299-2007 same
method. After filtration, the graphite atomic absorption of toxic leachate leaching
of cadmium (Cd) detoxification of heavy metals before measurement stabilizer
was not added.

[0174] (2) (1) sampling head angelica 1/3 and 1/3 of soups test, the sample pot
with the remaining half of Angelica head soup, i.e. containing about 200g of
boiling pot Angelica head together with the remaining half soup (i.e. 1/3 soup),
placed in another vial headroom, heavy metal stabilizer was added 5.0g (mass
percent composition as follows: dietary fiber (mushroom powder) 20%,
phosphates (tricalcium phosphate) is 16%, acidity regulator (sodium bicarbonate,
sodium tripolyphosphate + + lactate) 60% NaCl 4%), let it cool down after ten
minutes, after uniformly stirred, after inspection cover for analysis. Hazardous
waste identification GB5085.3-2007 using standard extraction procedure toxicity
standard sample HJ / T299-2007 solid waste leaching toxicity test, but the
lixiviant using IN HC1 (to simulate strength than gastric acidity but acid) and
Angelica head samples were shaken for 24 hours (a longer extraction time) in an
extraction flask, to rest HJ / T299-2007 same method. After filtration, the
 37

graphite atomic absorption measurement was added to the leachate cadmium

(Cd) after the heavy metal stabilizer 5.0g leaching toxic concentrations.

[0175] (3) (1) above and (2) sampling the original pot Angelica head soup and 2/3
of the total amount for testing, in the same pot the remaining about 1/3 of
Angelica head soup containing about 200g of boiling Angelica head clearance
placed in another vial, was added 5g and (2) the same heavy metal stabilizer with
pure mushroom powder, uniformly stirring, after the closure Determination
inspection. Hazardous waste identification GB5085.3-2007 using standard
extraction procedure toxicity standard sample HJ / T299-2007 solid waste
leaching toxicity test, but the lixiviant using IN HC1 (to simulate strength than
gastric acidity but acid) and Angelica head samples were shaken for 24 hours (a
longer extraction time) in an extraction flask, I HJ / T299-2007 same method.
After filtration, the graphite atomic absorption measurement was added to the
leachate cadmium (Cd) after only 5.0g of pure mushroom powder leaching toxic
concentrations.

[0176] After testing, before the stabilization treatment head Angelica i.e. (1),
Angelica stabilization treatment after the first (2) and (3) add only Angelica head
mushroom powder of pure cadmium (Cd) list of toxic concentrations following
leaching :

[0177]

[0178] Test results showed that the leaching toxic concentration Angelica head
sample Cadmium (Cd) before stabilization processing is 1.3 g / kg, Angelica head
sample cadmium (Cd) after stabilization treatment leach toxic concentrations of
0.7 g / kg, i.e., angelica Add 5.0g sample head above Example 11 (2) cadmium
(Cd) after leaching toxic degradation stabilizers, decreased by about 46%. Then
add 5.0g of pure mushroom powder, but only the first sample of cadmium
angelica without any phosphate-containing formulations or the like acidity
regulator (Cd) leaching toxicity remains unchanged and the same as the former
and stabilization treatment. Example 11 also shows that only the food with
dietary fiber, such as pure mushroom powder, without added heavy metal
stabilizers, no effect of reducing the leaching of heavy metals toxic
concentrations.

[0179] Example 12
 38

[0180] Select about 600g of lead, the concentration of the leaching amount of
copper (Pb, Cu) yam as the present sample embodiment, together with pure
water cleaning of all.

[0181] (1) 500g sample washed lead, copper (Pb, Cu) yam, the first slice, into the
pot, add appropriate amount of boiling water, fire of boiled, wait until boiling, the
sampling pot yams of 1/2, about 250g, plus half soup, let it cool down after ten
minutes, after inspection Determination disposed within a clearance vial closure.
Hazardous waste identification GB5085.3-2007 using standard extraction
procedure toxicity standard sample HJ / T299-2007 solid waste leaching toxicity
test, but the lixiviant using IN HC1 (to simulate strength than gastric acidity but
acid) and Yam extraction in a shaking flask 24 hours (longer extraction time), I
HJ / T299-2007 same method. After filtration, detoxification of heavy metals
before the lead stabilizer was not added, the copper (Pb, Cu) leaching toxic
concentration meter measured absorption leachate graphite atoms.

[0182] (2) (1) and half of the sampling half yam soup made after the test, in the
same pot the remaining half of the grated yam soup placed in another empty
glass bottles, 5.0g of heavy metal stabilizers (weight percentage composition:
phosphate (disodium hydrogen phosphate, sodium dihydrogen phosphate + +
calcium hydrogen phosphate) 60%, 35% acidity regulator (sodium bicarbonate),
5% sodium chloride, after uniformly stirred, placed in a capped bottle clearance
after inspection analysis. GB5085.3-2007 using hazardous waste identification
standard extraction procedure toxicity standard sample HJ / T299-2007 solid
waste leaching toxicity test, but the lixiviant using iN HC1 (to simulate gastric
acidity strength but wins after the acid had) yam and shaken for 24 hours (a
longer extraction time) in an extraction flask, it HJ / T299-2007 same method.
after filtration, the graphite atomic absorption measurement was added to the
leachate stabilizer detoxification of heavy metals lead, copper (Pb, Cu) leaching
toxic concentrations.

[0183] After testing, i.e., pre-treatment stabilization yam (1), yam lead after
stabilization treatment (2), the list of toxic concentrations of copper leaching (Pb,
Cu) as follows:

[0184]

[0185] Test results showed that the leaching toxic concentration Yam heavy metal
lead (Pb) without a stabilization treatment of 0.012 mg / kg (i.e. 12yg / Kg),
stabilized after treatment Yam lead (Pb) leachate concentration of 4 [mu] g / kg,
i.e., the above-described Example 12 was added 5.0g (2) of the heavy metals lead
 39

yam stabilizer (Pb) leaching toxic concentration decreased about 67%.

Stabilization treatment leach toxic concentrations before Yam heavy metals
copper (Cu) is 2.42 mg / kg, after the stabilization treatment Yam copper (Cu)
leaching toxic concentrations of 1.28 mg / kg, i.e. 250g copper yam sample of
(Cu) Extraction Toxicity after adding 5.0g degradation while the above-described
heavy metal stabilizer, a decrease of about 47%.

Classifications
International ClassificationA23L29 / 00 , A23L5 / 20 , A23L29 / 294Legal
Events
DateCodeEventDescription3 Aug 2016C06Publication31 Aug 2016C10Entry
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