Spotlight_CoE(XI)_(2022-23)_Day-1_DPP_Chemistry

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CoE(XI)

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DAY-1_DPP_CHEMISTRY
Topic : Stoichiometry, Redox Reaction, Atomic Structure

1. It is known that atom contain protons, neutrons and electrons. If the mass of neutron is assumed to be half of
14
its original value whereas that of proton is assumed to be twice of its original value then the atomic mass of 6C

will be
(a) Same (b) 14.28% less
(c) 14.28% more (d) 28.56% less
2. Suppose two elements X and Y combine to form two compounds XY2 and X2Y3 . 0.05 mole of XY2 weighs
5 g while 3.011 × 1023 molecules of X2Y3 weigh 85 g. The atomic masses of X and Y are respectively
(a) 20, 30 (b) 30, 40
(c) 40, 30 (d) 80, 60
3. Some older emergency oxygen masks containing potassium superoxide, KO 2 which reacts with CO2 and water
in exhaled air to produce oxygen according to the given equation. If a person exhales 0.667 g of CO2 per minute,
how many grams of KO2 are consumed in 5.0 minutes?
4KO2 + 2H2O + 4CO2  4KHCO3 + 3O2
(a) 10.7 (b) 0.0757
(c) 1.07 (d) 5.38
4. The chief ore of Zn is the sulphide, ZnS. The ore is concentrated by froth floatation process and then heated in
air to convert ZnS to ZnO.
80%
2ZnS + 3O2   2ZnO + 2SO2
100%
ZnO + H2SO 4  ZnSO 4 + H2O
80%
2ZnSO 4 + 2H2O   2Zn + 2H2SO4 + O2
The number of moles of ZnS required for producing 2 moles of Zn will be
(a) 3.125 (b) 2
(c) 2.125 (d) 4
5. One gram of the silver salt of an organic dibasic acid yields, (on strong heating) 0.5934 g of silver. If the weight
percentage of carbon in it is 8 times the weight percentage of hydrogen and one-half the weight percentage of
oxygen, determine the molecular formula of the acid.
(a) C4H6O4 (b) C4H6O6
(c) C2H6O2 (d) C5H10O5

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6. 0.80 g of impure (NH4)2SO4 was boiled with 100 mL of a 0.2 N NaOH solution till all the NH3(g) evolved. The
remaining solution was diluted to 250 mL. 25 mL of this solution was neutralized using 5 mL of a 0.2 N H 2SO4
solution. The percentage purity of the (NH4)2SO4 sample is
(a) 82.5 (b) 72.5
(c) 62.5 (d) 17.5
7. A mixture of NaOH and Na2CO3 required 25 mL of 0.1 M HCl using phenolphthalein as the indicator. However,
the same amount of the mixture required 30 mL of 0.1 M HCl when methyl orange was used as the indicator.
The molar ratio of NaOH and Na2CO3 in the mixture was
(a) 2 : 1 (b) 1 : 2
(c) 4 : 1 (d) 1 : 4
8. 11.6 g of an organic compound having formula CnH2n + 2 is burnt in excess of O 2(g) initially taken in a
22.41 litre steel vessel. Before reaction the gaseous mixture was at 273 K with pressure reading 2 atm. After
complete combustion and loss of considerable amount of heat, the mixture of product and excess of O 2 had a
temperature of 546 K and 4.6 atm pressure. The formula of organic compound is
(a) C2H6 (b) C3H8
(c) C5H12 (d) C4H10
9. One litre of an acidified solution of KMnO4 containing 15.8 g of KMnO4 is decolourised by passing sufficient amount
of SO2. If SO2 is produced by roasting of iron pyrites (FeS2), what will be the amount of pyrites required to
produce the necessary amount of SO2? [Given : FeS2 + O2  Fe2O3 + SO2]
10. A mixture containing KClO3, KHCO3, K2CO3 and KCl was heated, producing CO2,O2 and H2O gases according
to the following equations:
2KClO3(s)  2KCl(s) + 3O2
2KHCO3(s)  K2O(s) + H2O(g) + 2CO2(g)
K2CO3(s)  K2O(s) + CO2(g)
The KCl does not react under the conditions of the reaction. If 100.0 g of the mixture produces 1.80 g of H 2O,
13.20 g of CO2 and 4.0 g of O2, what was the composition of the original mixture?
11. 5.22 × 10–4 mole of a gas containing H2, O2 and N2 exerted a pressure of 67.4 mm in a certain standard volume.
The gas was passed over a hot platinum filament which combined H2 and O2 into H2O which was frozen out. When
the gas was returned to the same volume, the pressure was 14.3 mm. Extra oxygen was added to increase the
pressure to 44.3 mm. The combustion was repeated, after which the pressure read 32.9 mm. What was the mole
fraction of H2, O2 and N2 in the gas sample?
12. A chemist is preparing to analyse sample that will contain no more than 0.5 g of uranium. His procedure calls
for preparing the uranium as U4+ ion and oxidising it by MnO 4 in acid solution.

5U4   2MnO 4  6H2O  5UO 22  2Mn2  4H3 O 

If he wants to react the total U4+ sample with a maximum of 50 mL of KMnO4 solution, what concentration
should he choose?
13. 1.00 g of a moist sample of a mixture of KCl and KClO3 was dissolved in water and made up to 250 mL.
25 mL of this solution was treated with SO2 to reduce the chlorate to chloride and excess SO2 was removed by
boiling. The total chloride was precipitated as silver chloride. The weight of the precipitate was 0.1435 g. In another
experiment, 25 mL of the original solution was heated with 30 mL of 0.2 N solution of ferrous sulphate and
unreacted ferrous sulphate required 37.5 mL of 0.08 N solution of an oxidising agent for complete oxidation.
Calculate the molar ratio of chlorate to chloride in the given mixture. Fe2+ reacts with ClO 3 according to the
reaction.
ClO 3 + 6Fe2+ + 6H+  Cl– + 6Fe3+ + 3H2O

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14. 0.6 g of a sample of pyrolusite was boiled with 200 mL of N/10 oxalic acid and excess of dilute H2SO4. The liquid
was filtered and the residue washed. The filtrate and washings were mixed and made up to 500 mL. 100mL of
this solution required 50 mL of N/30 KMnO4 solution. Calculate the percentage of MnO2 in the given sample of
pyrolusite.
15. A light source of wavelength  illuminates a metal and ejects photoelectrons with (K.E.)max = 1 eV.

Another light source of wavelength , ejects photoelectrons from same metal with (K.E.)max = 4 eV..
3
Find the value of work function.
(a) 1 eV (b) 2 eV
(c) 0.5 eV (d) None of these
16. V on two particles A and B are plotted against de-Broglie wavelengths. Where V is potential difference applied
on the particles. Which of the following relation is correct about the mass of particles? (Assume equal charge
on the two particles)

V
B
A


(a) mA = mB (b) mA > mB

(c) mA < mB (d) mA  mB
17. The Schrodinger wave equation for hydrogen atom is

3/2
1  Z (   1) (2  8  12) e  /2
 (radial)   
16 4  a0 

2Zr
where a0 and Z are the constant in which answer can be expressed and   .
a0

Minimum and maximum position of radial nodes from nucleus are ...... respectively.

a0 3a0 a0 a0
(a) , (b) ,
z z 2z z

a0 3a0 a0 4a0
(c) , (d) ,
2z z 2z z
18. An element undergoes a reaction as shown :
X + 2e–  X2–, energy released = 30.87 eV/atom. If the energy released, is used to dissociate 4 gms of H 2
molecules, equally into H+ and H*, where H* is excited state of H atoms where the electron travel in orbit whose
circumference equal to four times its de Broglie’s wavelength. Determine the least moles of X that would be
required :
Given : I.E. of H = 13.6 eV/atom, bond energy of H2 = 4.526 eV/molecule.
(a) 1 (b) 2
(c) 3 (d) 4

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19. In a measurement of quantum efficiency of photosynthesis in green plants, it was found that 10 quanta of red light
of wavelength 6850 Å were needed to release one molecule of O2. The average energy storage in this process
is 112 kcal/mol O2 evolved.
What is the energy conversion efficiency in this experiment?
Given: 1 cal = 4.18 J; NA = 6 × 1023; h = 6.63 × 10–34 Js
(a) 23.5 (b) 26.9
(c) 66.34 (d) 73.1
20. The radial distribution functions [P(r)] is used to determine the most probable radius, which is used to find the
 dP(r) 
electron in a given orbital   for 1s-orbital of hydrogen like atom having atomic number Z, is
 dr 

dP 4Z3  2Zr 2  2Zr /a0 .

 3  2r  e
dr a0  a0 

Then which of the following statements is/are correct?

dP(r)
(a) At the point of maximum value of radial distribution function 0
dr
a0
(b) Most probable radius of Li2+ is pm
3
a0
(c) Most probable radius of He+ is pm
2
(d) Most probable radius of hydrogen atom is a0 pm

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