Spotlight_CoE(XI)_(2022-23)_Day-2_DPP_Chemistry

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CoE(XI)

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DAY-2_DPP_CHEMISTRY
Topic : States of Matter, Equilibrium

1. The van der Waals' equation for one mole may be expressed as

 RT  2 aVm ab
Vm3.   b  Vm   0
 p  p p

where Vm is the molar volume of the gas. Which of the following is incorrect?
(a) For a temperature less than Tc, V has three real roots
(b) For a temperature less than Tc, V has three imaginary roots
(c) For a temperature equal to Tc, all three roots of V are real and identical
(d) On increasing the temperature (T < Tc), the three roots become closer to one another
2. 11 moles N2 and 12 moles of H2 mixture reacted in 20 litre vessel at 800 K. After equilibrium was reached,
6 mole of H2 was present. 3.58 litre of liquid water is injected in equilibrium mixture and resultant gaseous mixture
suddenly cooled to 300 K. What is the final pressure of gaseous mixture? Neglect vapour pressure of liquid solution.
Assume (i) all NH3 dissolved in water (ii) no change in volume of liquid (iii) no reaction of N2 and H2 at 300 K

N2 : 11 moles N2, H2 T = 300 K ; P = ?

T = 800 K
H2 : 12 moles V = 20 L

Initial condition

(a) 18.47 atm (b) 60 atm

(c) 22.5 atm (d) 45 atm
3. A mixture of NH3(g) and N2H4(g) is placed in a sealed container at 300 K. The total pressure is 0.5 atm. The
container is heated to 1200 K at which time both substances decompose completely according to the equations
2NH3(g)  N2(g) + 3H2(g) and N2H4(g)  N2(g) + 2H2(g)
After decomposition is complete, the total pressure at 1200 K is found to be 4.5 atm. Find the mole% of N 2H4
in the original mixture.
(a) 20% (b) 25%
(c) 50% (d) 75%
4. Three closed rigid vessels, A, B and C without energy transfer with surroundings, which initially contain three
different gases at different temperatures are connected by tube of negligible volume. The vessel A contains
2 mole Ne gas, at 300 K, vessel ‘B’ contains 2 mole SO2 gas at 400 K and vessel ‘C’ contains 3 mole CO2 gas

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at temperature 500 K. What is the final pressure (in atm) attained by gases when all valves of connecting three
vessels are opened and additional 15.6 kcal heat supplied to vessel through valve. The volume of A, B and C vessel
is 2, 2 and 3 litre respectively

Ne SO 2 CO2

Given: R = 2 calorie/mol-K; Cv (Ne) = 3/2R, Cv (CO2) = 5/2 R and Cv (SO2) = 3R

(a) 73.89 atm (b) 67.31 atm
(c) 80.00 atm (d) 85.42 atm
5. A bulb of constant volume is attached to a manometer tube open at other end as shown in figure. The manometer
is filled with a liquid of density (1/3)rd that of mercury. Initially h was 228 cm.

gas h

dp
Through a small hole in the bulb gas leaked assuming pressure decreases as  kP .
dt
If value of h is 114 cm after 14 minutes. What is the value of k ( in hour–1)?
[Use : In (4/3) = 0.28 and density of Hg = 13.6 g/mL]
(a) 0.6 (b) 1.2
(c) 2.4 (d) 1.8
Paragraph For Q. Nos. 6 & 7
Three ideal gas samples in separate equal volume containers are taken and following data is given :
Pressure Temperature Mean free paths Mol. wt.
Gas A 1 atm 1600 K 0.16 nm 20
Gas B 2 atm 200 K 0.16 nm 40
Gas C 4 atm 400 K 0.04 nm 80
6. Calculate ratio of collision frequencies (Z11) for the above three gases (A : B : C)
(a) 1 : 2 : 4 (b) 4 : 2 : 1
(c) 1 : 4 : 16 (d) 16 : 4 : 1
7. Calculate the ratio of number of collisions by one molecule per sec (Z1) for the above three gases (A : B : C)
(a) 4 : 1 : 4 (b) 1 : 4 : 4
(c) 4 : 3 : 2 (d) 1 : 2 : 4
8. 1 mole of a gas is changed from its initial state (15 L, 2 atm) to final state (4 L 10 atm) reversibly. If this change
can be represented by a straight line in P-V curve, calculate maximum temperature, the gas attained.

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9. Which one of the following statements is wrong?

(a) Critical temperature is the highest temperature at which condensation of a gas is possible
(b) Critical pressure is the highest pressure at which a liquid will boil when heated
(c) Boyle temperature is the temperature at which the second virial coefficient is zero
(d) Inversion temperature is the temperature above which the gas becomes cooler during Joule-Thomson expansion
10. Which one of the following volume (V) – temperature (T) plots represents the behaviour of one mole of an ideal
gas at one atmospheric pressure?

V(L) (38.8 L, 373 K) V(L)

(28.6 L, 373 K)

(a) (b)
(22.4 L,
(20.4 L,
273 K)
273 K)
T(K) T(K)

V(L) (30.6 L, 373 K) V(L)

(c) (d) (14.2 L, 373 K)

(22.4 L, (22.4 L,
273 K) 273 K)
T(K) T(K)

11. The minimum volume of water required to dissolve 0.1 g lead (II) chloride to get a saturated solution
(Ksp of PbCl2 = 3.2 × 10–8; atomic mass of Pb = 207 u) is
(a) 1.798 L (b) 0.36 L
(c) 17.95 L (d) 0.18 L

12. For a reversible gaseous reaction N2  3H2  2NH3 at equilibrium, if some moles of H2 are replaced by same
number of moles of T2 (T is tritium, isotope of H and assume isotopes do not have different chemical properties)
without affecting other parameters, then which one of the following statements is correct?
(a) The sample of ammonia obtained after sometime will be radioactive.
(b) Moles of N2 after the change will be different as compared to moles of N2 present before the change
(c) The value of Kp or Kc will change
(d) The average molecular mass of new equilibrium will be same as that of old equilibrium
13. Attainment of the equilibrium A(g)  2C(g)  B(g) gave the following graph. Find the correct option.
(% dissociation = fraction dissociated × 100)

10
A
8

C
4
2
B

t=5 s time

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(a) At t = 5 s equilibrium has been reached and Kc = 40 (mol/litre)2

(b) At t = 5 s equilibrium has been reached and % dissociation of A is 20%
(c) At t = 5 s equilibrium has been reached and % dissociation of A is 30%
(d) At t = 5 s, Kc = Kp (RT)2

14. CuSO 4  5H2O(s)  CuSO 4  3H2O(s)  2H2O(g); K p  4  10 4 atm2 . If the vapour pressure of water is 38 torr then
the percentage relative humidity is (Assume all data at constant temperature)
(a) 4 (b) 10
(c) 40 (d) None of these
15. Ammonia at a pressure of 15 atm at 27°C is heated to 347°C in a closed vessel in the presence of a catalyst.
Under the conditions, NH3 is partially decomposed according to the equation,
2NH3  N2  3H2 the vessel is such that the volume remains effectively constant whereas pressure increases
to 50 atm. Calculate the percentage of NH3 actually decomposed.
(a) 65% (b) 61.3%
(c) 62.5% (d) 64%
16. The graph which represents all the equilibrium concentrations for the reaction
N2O 4 (g)  2NO2 (g)
Then select the correct graph for concentrations of NO2 against concentrations of N2O4.

(a) (b)
[NO2]

[N O2]

[N 2O4] [N2O 4]

(c) (d)
[N O2]
[NO2]

[N2O4] [N2O4]

17. An equilibrium mixture at 700 K of 0.05 M N2(g), 0.3 M H2(g) and 0.2 M NH3(g) is present in a container. Now if
this equilibrium is disturbed by adding N2(g) so that its concentration becomes 0.15 M just after addition then
which of the following graphs represents the above situation more appropriately?

Initial eq. New eq. New eq.

Initial eq.
0.3 0.3 NH 3(g)
H 2(g)
Conc. (M)

Conc. (M)

0.2 NH3(g) 0.2

H2(g)
(a) (b)
N 2(g)
0.1 0.1
N2(g)

Time Time

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Initial eq. New eq. New eq.

Initial eq.
0.3 H 2(g) 0.3
Conc. (M) NH3(g)

Conc. (M)
0.2 NH3(g) 0.2
H2(g)
(c)
N2(g) (d)
0.1 0.1
N2(g)

Time Time

18. Solid Ca(HCO3)2 decomposes as

Ca(HCO3 )2 (s)  CaCO3 (s)  CO2 (g)  H2O(g)
If the total pressure is 0.2 bar at 420 K, what is the standard free energy change for the given reaction (rG°)?
(a) 840 kJ/mol (b) 3.86 kJ/mol
(c) 6.98 kJ/mol (d) 16.083 kJ/mol
19. The gas A2 in the left flask allowed to react with gas B2 present in right flask as A2(g) + B2(g)  2AB(g);
Kc = 4 at 27°C. What is the concentration of AB when equilibrium is established?

2 mole 4 mole
A2 B2

1 litre
at 27°C 3 litre
at 27°C
(a) 1.33 M (b) 2.66 M
(c) 0.66 M (d) 0.33 M
20. Given that 2 × 10–4
mole each of Mn2+
and Cu2+
was contained in one litre of a 0.003 M HClO4 solution, and
this solution was saturated with H2S. Determine whether or not each of these ions, Mn2+ and Cu2|, will precipitate
as sulphide. The solubility of H2S, 0.1 mole per litre, is assumed to be independent of the presence of other
materials in the solution.
Ksp (MnS) = 3 × 10–14, Ksp(CuS) = 8 × 10–37.
K1 and K2 for H2S are 1 × 10–7 and 1.1 × 10–14 respectively. Also, calculate the percentage of Cu remaining
unprecipitated. Will MnS precipitate if the above solution is made neutral by lowering the [H +] to 10–7 M?

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