Sankalp Rank Enhancement Test - PH 3 - Paper 1
Sankalp Rank Enhancement Test - PH 3 - Paper 1
Pleas e read the instructions carefully. You are allotted 5 minutes specific ally for this purpose.
You are not allowed to leave the Examination Hall before the end of the test.
INSTRUCTIONS
Caution: Question Paper CODE as given above MUST be correctly marked in the answer OMR sheet before
attempting the paper. Wrong CODE or no CODE will give wrong results.
A. General Instructions
1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.
2. This question paper contains Three Parts.
3. SECTION–I is Physics, SECTION–II is Chemistry and SECTION–III is Mathematics.
4. Each section is further divided into two parts: Part – A & C
5. Rough spaces are provided for rough work inside the question paper. No additional sheets will be provided for rough work.
6. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic devices, in any form, are
not allowed.
B. Filling of OMR Sheet
1. Ensure matching of OMR sheet with the Question paper before you start marking your answers on OMR sheet.
2. On the OMR sheet, darken the appropriate bubble with HB pencil for each character of your Enrolment No. and write in ink
your Name, Test Centre and other details at the designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.
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SANKALP RANK ENHANCEMENT TEST SERIES-Paper-1 (Ph-3)-PCM(000000.1)-2
SECTION – I : PHYSICS
PART – A: (Multi Correct Answer Type)
This section contains 07 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONE OR MORE may be correct.
y
1. The figure shows a taut string, initially aligned
with the x-axis, which carries a waveform
travelling towards the right without any change
its shape. The bold line and the dotted line 45
P
indicate the displacement of the string (i.e.,
O x
shape of the waveform) at time = t second and
at time = (t + dt) second, respectively. The
speed of particle at point P at t = 2 sec is 1 cm/s.
Choose the correct statement(s) from the
following (assume that dt is positive).
vy vy
(A) (B)
O x O x
(C) Speed of waveform is 1 cm/s and it (D) Speed of waveform is 1 cm/s and it is
is moving along positive x-axis moving along negative x-axis
2. A window whose area is 2m2 is open on a street where street noise results in an intensity level at the
window of 60 dB. Then
(A) Acoustic power enters the window via sound waves, if an acoustic absorber is fitted at the window
is 2 W.
(B) Acoustic power enters the window via sound waves, if an acoustic absorber is fitted at the window
is 4 W.
(C) Energy from street noise collected in 10 hours is 72 103 Joule
(D) Energy from street noise collected in 10 hours is 36 103 Joule
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3. A bottle is kept on the ground as shown in the figure. The bottle can be R
modelled as having two cylindrical zones. The lower zone of the bottle has
a cross-sectional radius of R 2 and is filled with honey of density 2. 2H
The upper zone of the bottle is filled with the water of density and has a
cross-sectional radius R. The height of the lower zone is H while that of
the upper zone is 2H. If now the honey and the water parts are mixed
together to form a homogeneous solution (Assume that total volume does Honey H
not change)
(A) The pressure inside the bottle at the base will remain unaltered.
(B) The normal reaction on the bottle from the ground will change.
(C) The pressure inside the bottle at the base will increase by an amount (1/2)gH
(D) The pressure inside the bottle at the base will decrease by an amount (1/4) gH
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5. An insulated container is filled with ice at 0C, and another container is Insulators
filled with water that is continuously boiling at 100C. In series of
experiments, the container connected by various, thick metal rods that
pass through the walls of container as shown in the figure. water ice
100C Metal rod 0C
In the experiment I: a copper rod is used and all ice melts in 20 minutes.
In the experiment II: a steel rod of identical dimensions is used and all ice melts in 80 minutes.
In the experiment III: both the rods are used in series and all ice melts in t10 minutes.
In the experiment IV: both rods are used in parallel all ice melts in t20 minutes.
(A) The value of t10 is 100 minutes (B) The value of t10 is 50 minutes
(C) The value of t 20 is 16 minutes (D) The value of t 20 is 8 minutes
6. A cubical block is floating in a liquid with one third of it’s volume immersed in the liquid. When the
whole system accelerates upwards with acceleration of g/2.
(A) The fraction of volume immersed in the liquid will change.
(B) The buoyancy force on the block will change.
(C) The buoyancy force will increase by 50 percent.
(D) The pressure in the liquid will increased.
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8. A small hole is made at the bottom of a symmetrical jar shown in figure. A liquid y
is filled into the jar upto certain height. The rate of descension of liquid is
independent of the level of the liquid in the jar. Then, the surface of the jar is a
surface of revolution of the curve
(A) y = kx2 (B) y = kx4
3
(C) y = kx (D) y = kx5 hole x
(Where k is constant)
15 15
(A) (B)
4 8
7 7
(C) (D)
12 6
10. Solid cube of side ' ' made of a material of bulk modulus B is surrounded by a liquid in a cylindrical
container. A massless piston of area ‘A’ floats on the surface of the liquid. When a mass ‘M’ is placed
on the piston to compress the liquid, the fractional decrease in length of the cube is (side of cube is
very small as compare to height of cylinder).
Mg Mg
(A) (B)
BA 3BA
Mg Mg
(C) (D)
2BA 4BA
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2
11. A thermal engine having three moles of P (N/m )
mono-atomic gas as its working fluid 2 3
P2
undergoes the cyclic process as shown
in the figure. Find the mechanical work
over one cycle approximately
1
(R = 8.314 J/mole/k) P1
(A) 40 kJ 4
(B) 30 kJ
(C) 20 kJ
(D) 10 kJ
400 800 1200 2400 T (in K)
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1 We would like to prepare a scale whose length does not change with temperature. It is proposed to
prepare a unit scale of this type whose length remains, say 10 cm. We can use a bimetallic strip made
of brass and iron each of different length whose length (both components) would change in such a way
that difference between their lengths remain constant. If iron = 1.2 105/K and brass = 1.8 105/K, if
we take as length of iron strip 10n cm. Find the value of n.
2 A cubical block ‘A’ of mass m 0(= a3 = 3 kg) of edge ‘a’ and density floats in a liquid of density 3.
The lower surface of the cube just touches the free end of massless spring of spring constant
2
k(= a g) fixed at the bottom of the vessel. Another block ‘B’ of mass ‘m’ put over the block ‘A’, so that
it is completely immersed in liquid without wetting the block ‘B’. Then find the value of m in kg.
3 The absolute temperature of air in a region linearly increases from 1092 K to 2457 K in a space of
width 33 m. Speed of sound at 273 K is 330 m/s. The time taken by a sound wave to go though the
1
region is 2 sec . n will be (approximately)
n
5. A sonometer wire 64 cm long produces 8 beats per second with a tuning fork. If length of sonometer
wire is increased by one centimeter it resonates with the tuning fork. The frequency of tuning fork is
observed 64x. The value of x is
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SANKALP RANK ENHANCEMENT TEST SERIES-Paper-1 (Ph-3)-PCM(000000.1)-8
SECTION – II : CHEMISTRY
PART – A: (Multi Correct Answer Type)
This section contains 07 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONE OR MORE may be correct.
2. An organic compound (P) of molecular formula C5H8, when treated with sodium in liquid ammonia
followed by reaction with n-propyl iodide yield (Q), C8H14.(P) gives a ketone (R), C5H10O, when
treated with dilute H2SO4 and HgSO4. (Q) on oxidation with alkaline KMnO4 gives two isomeric acids
(S) and (T), C4H8O2:
(A) Compound ‘R’ is C3H7 – CO – CH3 and ‘S’ is C3H7COOH
(B) Compound ‘P’ is C2H5 C CH
(C) H3C
Compound 'T' is CH COOH
H3C
(D) H3C
Compound 'Q' is CH C C CH2CH2CH3
H3C
3. The standard enthalpies of formation of CO2(g) and HCOOH ( ) are –393.7 kJmol–1 and –409.2
–1
kJmol respectively. Which of the following statements are correct?
–1
(A) –393.7 kJ mol is the enthalpy change for the reaction, C(s) O2 (g) CO2 (g).
–1
HCOOH(), would be –15.5 kJmol .
(B) The enthalpy change for the reaction, CO2 (g) H2 (g)
–1
(C) The enthalpy change for the reaction, H2 O CO HCOOH, is –409.2 kJmol .
–1
(D) The enthalpy change for the reaction, H2 (g) CO2 (g) H2O( ) CO(g), is –409.2 kJmol .
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4.
1 equiv. Br2
CH2
FeBr3 /
Product s
O 2N
Product(s) is/are
(A) (B) Br
Br CH2
CH2
O 2N
O 2N
(C) (D) Br
CH 2 Br
CH2
O 2N
O 2N
5. Which of the following is true when a gas move freely from one part to another part of a rigid system:
(A) work is zero because the external pressure is zero
(B) work is zero because U of the system is zero
(C) work is zero only if temperature is held constant
(D) work is zero only if the external pressure is held constant
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SANKALP RANK ENHANCEMENT TEST SERIES-Paper-1 (Ph-3)-PCM(000000.1)-10
This section contains 06 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONLY ONE is correct.
9. Limiting your answer to cycloalkanes and ignoring stereoisomers, how many C6H12 constitutional
isomers are there?
(A) 6 B) 9
(C) 12 D) 13
10 Amphibole silicate structure has ‘x’ number of corner shared per tetrahedron. The value of ‘x’ is
(A) 2 (B) 2.5
(C) 3 (D) 4
11. The entropy change involved in the isothermal reversible expansion of 2 moles of an ideal gas from a
3 3 o
volume of 10 dm to a volume of 100 dm at 27 C is
–1 –1 -1 –1
(A) 42.3 JK mol (B) 38.3 JK mol
(C) 35.8 JK–1mol–1 (D) 32.3 JK–1mol–1
12. The solution of CaCl2.6H2O in a large volume of water is endothermic to the extent of 3.5 kcal/mole.
For the reaction CaCl2(s) + 6H2O(l) → CaCl2.6H2O(s) H = - 23.2 kcal. Then the heat of solution of
CaCl2 (anhydrous) in a large volume of water is:
(A) + 19.7 kcal (B) - 23.2 kcal
(C) - 19.7 kcal (D) + 23.2 kcal
13. Which of the following option is incorrectly matched for maximum prescribed concentration of metal in
drinking water?
(A) Fe 0.2 ppm (B) Al 0.2 ppm
(C) Cd 0.05 ppm (D) Zn 5.0 ppm
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SANKALP RANK ENHANCEMENT TEST SERIES-Paper-1 (Ph-3)-PCM(000000.1)-11
This section contains 05 questions. The answer to each question is a single-digit integer, ranging from 0 to
9. The correct digit below the question number in the ORS is to be bubbled.
1. 4.48 L of an ideal gas at STP requires 12 cal to raise the temperature by 15oC at constant volume.
Find the CP of the gas in cal/K-mol.
Br2 ,h
2. CxHy (organic compound, A)
(Monobromin ation)
Pr oduct(Enantiomeric)
Br2 ,CCl4
A no reaction
Br2 ,Fe
A mono bromo derivative product
What can be the minimum number of carbon atom (x) for the organic compound A?
C OH
4. The number of monochloro product formed from given reaction? (Including stereoisomers)
Cl2 /h
5. Total number of moles of hydrochloric acid react with one mole of borax to converts all borons to
boric acid.
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This section contains 07 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONE OR MORE may be correct.
1. If in a triangle sin2B sin2C + 2 sin2C sin2A + 2 sin2A sin2B = sin4A + sin4B + sin4C, then its angle A is
equal to
(A) (B)
12 6
5 7
(C) (D)
6 6
4. A forecast is to be made of the results of five cricket matches, each of which can be a win or a draw
or a loss for Indian team test :
p = number of forecast with exactly one error
q = number with exactly three error and
r = number of forecast with all the error then the correct statement(s) is / are
(A) 2q = 5r (B) 8p = q
(C) 8p = 5r (D) 2(p + r) >q
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2 2
7. If graph of xy = 1 is reflected in y = 2x to give the graph 12x + rxy + sy + t = 0, then
(A) r = 1, s = 12, t = 25 (B) r = –1, s = 12, t = 1
(C) r = –7, s = –12, t = 25 (D) r + s = –19
This section contains 06 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONLY ONE is correct.
2 2 2
8. The number of integral points on the hyperbola x – y = (2000) is (an integral point is a point both of
whose co-ordinates are integer)
(A) 98 (B) 96
(C) 48 (D) 24
9. If the equation x 3 bx 2 cx 1 0, b c , has only one real root . Then the value of
2 tan1 cosec tan1 2sin sec 2 , is
(A) (B)
2
(C) (D)
2
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10. In the triangle ABC the medians from B and C are perpendicular. The value of cot B + cot C cannot
be
1 2
(A) (B)
3 3
4 5
(C) (D)
3 3
13. The locus of a point whose chord of contact with respect to the ellipse x 2 + 2y2 = 1 subtends a right
angle at the centre of the ellipse is
(A) x2 + 4y2 = 3 (B) y2 = 4x
2 2
(C) 2x + y = 1 (D) none of these
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SANKALP RANK ENHANCEMENT TEST SERIES-Paper-1 (Ph-3)-PCM(000000.1)-15
This section contains 05 questions. The answer to each question is a single-digit integer, ranging from 0 to
9. The correct digit below the question number in the OMR is to be bubbled.
1. Angle between the asymptotes of the hyperbola x 2 2xy 3y2 x 7y 9 0 is . Then tan is
equal to __________.
x 4 2 y 3 2
2. If the equation of the curve on reflection of the ellipse 1 about the line x – y – 2 =
16 9
2 2
0 is 16x + 9y + k1x – 36y + k2 = 0, then k1 + k2 – 131 is _________
61
3. If f(x) = cot–1(4x2 + 6x + 3) + cot–1(4x2 + 10x + 7) + cot–1(4x2 + 14x + 13) + … 10 terms, then f 0
10
is equal to ____________
9
a
4. 20
c 2r 20
c 2r 2
a 1
39
c 21 19
c10
r 0
+
and xy = 4a then total number of ordered pair solution (x, y) where x, y I is __________.
2 4 3 4 3 4
5. If LCM of (a, b) = 5 3 , LCM of (b, c) = 5 3 and LCM of (a, c) = 5 3 , then number of possible
k
triplets of (a, b, c) are k, then is __________
13
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PART – C
1. 2 2. 1 3. 6 4. 8
5. 5
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SOLUTIONS
PHYSICS (SECTION –I)
PART – A
I
2. 10log 60
I0
6 6
I = I0 10 = 1012 10
2
I = 106 watt/m
P = IA = 106 2 = 2w
E = P.t. = 2 106 10 60 60
= 72 103 Joule (where I intensity, P power, E Energy)
K1A(100 0)
5. P1 Q = P1 t1
L
K A(100 0)
P2 2 Q = P2 t2
L
Q Q
P1P2 t t Q
P3 1 2
P1 P2 Q Q t1 t 2
t1 t 2
Q P3 (t1 t 2 )
t10 = t1 + t2 = 100 minutes
Q Q Q(t1 t 2 )
P2 P1 P2
t1 t 2 t1t 2
tt t1t 2 20 80
Q P4 1 2 t 20 16 min
t1 t 2 t1 t 2 100
V
6. If the volume immersed initially is (V/3). Then
g mg …(i)
3
If the volume immersed when the system accelerates is V then
g mg
V ' g mg
2 2
V
V'
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3
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SANKALP RANK ENHANCEMENT TEST SERIES-Paper-1 (Ph-3)-PCM(000000.1)-18
A vS P B
v
7. f f0
v v s cos
v
fmin f0
v vs O
300
1800 2000
300 v s
vS = 33.33 m/sec
v v
f f0 f max = f0 = 2250 Hz
v v s cos v vS
dy
8. Let y be the height of liquid at some instant, then constant (given)
dt
dy
From equation of continuity (x 2 ) a 2gy (a area of hole)
dt
4
Squaring the equation y = kx
9. xmax = 2 S1
xmin = 0
0 x 2 d = 2
2 2 3 90
x = d 4 x =
2 x
S2 x P
7
x=
12
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SANKALP RANK ENHANCEMENT TEST SERIES-Paper-1 (Ph-3)-PCM(000000.1)-19
1
ibrass 10 cm ibrass = 20 cm
2
and iiron = 30 cm
2 In equilibrium
(3hg)A = (Aa)g
h = a/3 h
when block ‘B’ put on block ‘A’ 3
2a k
mg + (a3)g = k (a3 3)g
3
2kq 2
m 2a3 2a3 a3 m B
3g 3
A
8 3 8
m a m0
3 3 k
x
3. T = 1092 + (2457 1092)
RT
v
M
33 t
dx R
0
T
0
M
dt
(r1 r2 )
4. t 5 102 sec
2 T
V
5. +8=
4(0.64)
V
=
4(0.65)
P Q
KMnO 4
HgSO 4 / H2 SO 4
3.
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= –15.5 kJ mol–1
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SANKALP RANK ENHANCEMENT TEST SERIES-Paper-1 (Ph-3)-PCM(000000.1)-20
12. CaCl2 .6H2O Ca2 aq 2Cl aq Ho 3.5 kcal
CaCl2 6H2 O
CaCl2 .6H2 O Ho 23.2 kcal
H2 O
CaCl2 Ca2 aq 2Cl aq Ho 19.7 kcal
PART – C
4.48
1. n 0.2
22.4
U 12
CV 4 cal /K-mol
nT 0.2 15
CP = CV + R = 4 + 2 = 6
2.
CH3
1. B, C
Adding 2sin2B sin2C both the sides
2 2 2 2 2 2
3 sin B sin C = (sin B + sin C – sin A)
2 2 2 2 2 2
3b c = (b + c – a ) (by sine rule)
b2 c 2 a2 3 2 3
cos A = .
2bc 4 4
3 5
cosA = A = or .
2 6 6
2. A, B
sin ( cos ) = cos ( sin)
1
cos( sin) = cos cos sin = 2n cos
2 2
1 1
sin cos = 2n 2 sin 2n
2 4 2
1 3
Hence n = 0, 1 sin2 = sin2 = .
4 4
3. B, D
Since m < n
n m
2978 – 2978 = 1000k, k N
m n–m
2978 (2978 – 1) = 1000k
Hence m = 3 and n – m = 100
Hence least value of m = 3 and n = 100 + 3 = 103.
4. A, B, D
5 2 5 2 3
p = C4 × C1 = 10, q = C2 ( C1) = 80
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5 2 5
r = C0 ( C1) = 32.
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SANKALP RANK ENHANCEMENT TEST SERIES-Paper-1 (Ph-3)-PCM(000000.1)-21
5. B, C
an/2 and a(n+1)/2 are both 1, Note that the number of ways to choose numbers left of an/2 and
a n1 a1 a 2 a3 ...a n ;a n1 is same as that of right. We started with 9
2 2 2
n 9 8 C 4 70 rejected
n 10 9 C 4 126 rejected
n 11 10C5 252
n 12 11C5 462
n 13 12C6 924 rejected .
6. A, D
(7, 3)
(2, 3) (0, 3) (2, 3)
l1 = 80, l 2 = 24
7. C, D
Image of point A(, ) about y = 2x is B(a, b)
a b
mid point of AB i.e. M , lie on y – 2x = 0
2 2
b a
2 + b = 2 + 2a
2 2
1
and slope of AB = –
2
b 1 1 a
–b= –
a 2 2 2
5 3 4b 3a
2b = a
2 2 5
8b 6a 3b 4a
2a b
5 5
4b 3a 3b 4a
also = 1 1
5 5
2 2
12b – 9ab + 16ab – 12a = 25
2 2
12a + 7ab – 12b + 25 = 0
r = –7, s = –12, t = 25.
8. A
2 2 2 4 3 2
x – y = 2000 = (2 5 )
8 6
(x + y)(x – y) = 2 5
for y = 0, x = 2000.
Let (x > 0, y > 0) x + y and x – y are both even.
77 1
number of integral values of x, y = = 24
2
TG ~ @bohring_bot
number of integral points = 24 4 + 2 = 98.
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SANKALP RANK ENHANCEMENT TEST SERIES-Paper-1 (Ph-3)-PCM(000000.1)-22
9. A
Let f x x 3 bx 2 cx 1. f 0 1 0, f 1 b c 0
so, 1,0 . So, 2 tan1 cosec tan1 2sin sec 2
1 1 2sin 1 1
2 tan1 tan 2 2 tan
1
tan sin
sin 1 sin sin
2 as sin 0
2
10. A
y A
tanPBF =
2x
y
tanPBC = F E
x
y y y x
3xy
tan B = 2x 2x 2x
2y
y 2x 2 y 2
1 2 B
2x C
2x 2 y 2
cot B = .
3xy
2y 2 x 2
Similarly cot C =
3xy
x2 y2 2
cot B + cot C = .
3xy 3
11. C
If n even
4 n 4 n
n + 4 even and n + 4 > 2
4 n
n + 4 is not a prime
if n odd, let n = 2k + 1
n4 + 4n = (2k + 1)4 + 42k + 1
4 k 4 k 2 2 k 2 2
= (2k + 1) + 4(2 ) + 4(2 ) (2k + 1) – 4(2 ) (2k + 1)
2 k 2 2 k 2
= ((2k + 1) + 2(2 ) ) – (2(2 )(2k + 1))
2 k 2 k 2 k 2 k
= ((2k + 1) + 2(2 ) + 2(2 )(2k + 1))((2k + 1) + 2(2 ) – 2(2 )(2k + 1)).
12. B
The number of students answering at least r questions incorrectly = 2n – r
The number of students answering exactly r questions (where 1 r (n – 1))
Incorrectly = 2n – r – 2n – (r + 1)
The number of students answering all questions wrongly
2º = 1
Thus the total number of wrong answer is
1.(2n – 1 – 2n – 2) + 2(2n – 2 – 2n – 3)
2n – 1 = 4095
2n = 4096
n = 12
13. A
Let (h, k) be the point.
2 2
Equation of chord of contact w.r.t. to ellipse x + 2y = 1 is given by
hx + 2ky = 1 ...(1)
TG ~ @bohring_bot
Making curve x2 + 2y2 = 1 homogenous with the help of (1) we can write
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SANKALP RANK ENHANCEMENT TEST SERIES-Paper-1 (Ph-3)-PCM(000000.1)-23
2 2 2
x + 2y = (hx + 2ky)
Now coefficient of x 2 + coefficient of y2 = 0
2 2
(1 – h ) + (2 – 4k ) = 3
2 2
h + 4k = 3
so locus of (h, k) is x 2 + 4y2 = 3.
PART – C
1. 2
2 h2 ab 2 1 3
tan 2
ab 1 3
2. 1
x 4 2 y 3 2
1
16 9
any point P on the curve 4(1 + cos), 3(1 + sin).
The reflection of the point P about the line x – y – 2 = 0 can be found using
h 4 1 cos k 3 1 sin 2 4 1 cos 3 1 sin 2
= – (4 cos – 3 sin)+1
1 1 2
h = 4(1 + cos) – 4 cos + 3 sin + 1 = 4 + 3 sin + 1
and k = 3(1 + sin) + 4 cos – 3 sin –1 = 3 + 4 cos – 1
2 2
h 5 k 2
1
3 4
2 2
equation of image 16(x – 5) + 9(y – 2) = 144
2 2
16x + 9y – 160x – 36y + 292 = 0
k1 = – 160, k2 =292
k1 + k2 =132.
3. 6
1 1
f(x) = tan1 2
tan1
... 2
4x 6x 3 4x 10x 7
1 1
= tan1 tan1 ...
1 2x 2 2x 1 1 2x 3 2x 2
–1 –1
f(x) = tan (2x + 11) – tan (2x + 1)
60
f(0) = – .
61
4. 8
20 20
1 x 1 x 20 20
c0 c2 x2 20
c 4 x4 20
c 20 x 20
2
20
c0 x20 20
c 2 x18 20
c 4 x16 20
c 20
2
9 1 x 20 1 x 20
coeff of x in
20 20 22
So,
r 0
c 2r c 2r 2
4
a = 10 xy = 40 has total order pair (x, y) solution = 4 2 = 8
5. 5
Let a = 51 31 , b = 52 32 , c = 53 33 .
For 1, 2, 3 we have 5 ways and 1, 2, 3, we have 13 ways.
TG ~ @bohring_bot
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