I10032

Safety Data Sheet Pickling Bath 302 EU - Eng

1. IDENTIFICATION OF PREPARATION AND COMPANY

PRODUCT IDENTIFIER
Trade name: Avesta Pickling Bath 302
Avesta Classic Pickling Bath 302
RELEVANT IDENTIFIED USES AND USES ADVISED AGAINST
Application and use: Pickling of stainless steel
Not to be used on Other metals than stainless steel

DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET

Manufacturer: Böhler Welding Group Nordic AB
Avesta Finishing Chemicals
Lodgatan 14, 211 24 MALMÖ, Sweden
Telephone: +46 (0)40 288 300
E-mail: [email protected]
EMERGENCY TELEPHONE NUMBER

+44 1 132 450 530 (Leeds.)

MISCELLANEOUS

Issue date: 2013-08-16

Version No: 6

Valid from: 2013-08-31

2. HAZARDS IDENTIFICATION
CLASSIFICATION
Health hazard in case of accidental exposure (R-phrases):
Very toxic by inhalation, contact with skin and if swallowed. It causes severe burns.
Environmental effects:
Pickling Fluid will strongly reduce pH in water. Must be neutralised. See also section 12.
Physical and chemical risks:
When heated nitrous gases can be developed.

LABEL ELEMENTS
Hazard symbols:
Print date: 2013-09-09 by Castro Mirna

Very Corrosive
toxic

Risk phrases:
R 26/27/28

Utgåva: Utgivningsdatum: 1/10

6, Aktivt 2013-08-16

Digitalt styrt dokument, utskriven kopia måste jämföras med digitala kopian innan användning.
 I10032
Safety Data Sheet Pickling Bath 302 EU - Eng

R 35
Safety phrases:
S 1/2
S 7/47
S 23
S 26
S 28
S 36/37/39
S 45
S 61

OTHER HAZARDS
The mixture contains sulphates which in the acidic environment can form sulphuric acid.

3. COMPOSITION/INFORMATION ON INGREDIENTS

PREPARATION
Chemical identity: Strong acid paste/solution with corrosive properties.

INFORMATION ON IGREDIENTS
CLASIFICATION ACCORDING TO REGULATION 67/548/EEG OR 1999/45/EG
Hazardous components, CAS No. EC No. Contents Hazard symbol/
chemical name, formula weight-% Risk phrase*

Nitric acid, HNO3 7697-37-2 231-714-2 40-50 O, C: R8, R35

Hydrofluoric acid, HF 7664-39-3 231-634-8 10-15 T+, C: R26, 27, 28-35

CLASIFICATION ACCORDING TO REGULATION (EG) no 1272/2008
Hazardous components, CAS No. EC No. Contents Hazard Hazard
category statements
chemical name, formula weight-% cod
1 H290
Nitric acid, HNO3 7697-37-2 231-714-2 40-50 1A H314

2 H330
1 H310
Hydrofluoric acid, HF 7664-39-3 231-634-8 10-15
2 H300
1A H314

*The full texts of the phrases are shown in section 16.

Additional information Classification according to directive 67/548/EEC.
Symbols and risk phrases are for concentrated substances.

4. FIRST AID MEASURES

DESCRIPTION OF FIRST AID MEASURES AND INDICATION OF INMEDIATE AND

SPECIAL TREATMENT NEEDED
Print date: 2013-09-09 by Castro Mirna

Inhalation:
Remove to fresh air. Keep victim lying down, quiet and warm. Rinse nose and mouth with
water. Might require assistance with breathing. Seek medical care even if only slight
discomfort occurs.

Utgåva: Utgivningsdatum: 2/10

6, Aktivt 2013-08-16

Digitalt styrt dokument, utskriven kopia måste jämföras med digitala kopian innan användning.
 I10032
Safety Data Sheet Pickling Bath 302 EU - Eng

Ingestion:
If victim is conscious and alert give milk or water to drink. Thereafter 20 lime tablets
dissolved in 2 L of water. Do not induce vomiting. Seek medical care.
Skin contact:
Alternative A - Rinse immediately with plenty of water, then treat with 2.5% Calcium
Gluconate gel, follow the instructions on the packaging. If not available, see alt. B.
Alternative B - Rinse immediately with Avesta First Aid Spray 910. Spray liberally onto the
affected area, always using the complete content. Avoid rinsing with water first, as it
reduces the effect of the solution.
After alternative A and B seek medical help.
Eye contact:
Protect intact eye. Rinse immediately with plenty of water for at least 15 minutes and seek
immediate medical care (eye specialist).
Information for medical care:
Inform the doctor that the injury has been caused by contact with hydrofluoric and nitric
acid mixtures.

SYMPTOMS ACUTE AND DELAYED

Pain in the mouth, throat and breast may occur at inhalation. Salivation and easier
dysphonia and discomfort feeling in the breast. In contact with the skin symptoms can be
delayed.

5. FIRE FIGHTING MEASURES

EXTINGUISHING MEDIA
Use most appropriate media to extinguish surrounding fire depending on what is burning.

SPECIAL HAZARDS ARISING FROM THE MIXTURE

Chemical exposure risks caused by released gases/vapours:
The Pickling Fluid will emit toxic fumes and nitrous fumes when exposed to heat/fire.

ADVICE FOR FIREFIGHTERS

Danger of fire/explosion:
Fluid is non-flammable. Bottles close to fire should be removed or cooled with water.
Protective clothing for firemen:
Appropriate protective acid-resistant clothing should be used.
Breathing protection:
Gas mask with filter of chlorine type B (grey) and dust filter P2, according to CEN (Central
European Norms).
How to clean or destroy soiled fire equipment:
Thoroughly wash with water.
Print date: 2013-09-09 by Castro Mirna

6. ACCIDENTAL RELEASE MEASURES

Utgåva: Utgivningsdatum: 3/10

6, Aktivt 2013-08-16

Digitalt styrt dokument, utskriven kopia måste jämföras med digitala kopian innan användning.
 I10032
Safety Data Sheet Pickling Bath 302 EU - Eng

PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY

PROCEDURES
Personal precautions:
Avoid direct contact. If there is still a risk of direct contact or stench protect with some form
of acid-resistant material. Wear eye protection, skin protection, rubber gloves and breathing
apparatus. Keep working area well ventilated.
ENVIRONMENTAL PRECAUTIONS
Spillage (water, air, soil):
Prevent spillage from entering sewage or public waters or nature.
METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP
Methods for cleaning up:
Neutralise with Avesta Neutralising Agent or a strong alkaline compound i.e. slaked lime.
Embank with sand. Arrange for pick up. Rinse with plenty of water.
Spillage should be picked up and disposed of in full compliance with federal, state and local
regulations as acid waste.

REFERENCE TO OTHER SECTIONS

Handling and storage section 7, exposure control/personal protection section 8 and
disposal considerations section 13.

7. HANDLING AND STORAGE

PRECAUTIONS FOR SAFE HANDLING

Technical measures:
Working place and methods should be worked out in order to avoid direct contact. Work and
storage area should be well ventilated. A closed rinse water system with filtration and reuse
of clear water is recommended.
To prevent fire and explosion:
Bottles close to fire should be removed or cooled with water.
Precautions:
Avoid fume generation and accumulation by using in a well-ventilated area. Use in areas
having local exhaust and general ventilation.
Avesta First Aid Spray 910 should be available at the premises. Emergency eyewash and
safety shower must be available at the working place.

CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES

Technical measures:
Storage room should be kept separate, cool, dry, well ventilated and closed to unauthorised
persons.
Incompatible products:
Not applicable.
Storage conditions:
Keep containers securely closed when not in use and in an upright position. Store in areas
where temperature remains between 0-30 oC at all times.
Packaging materials:
Print date: 2013-09-09 by Castro Mirna

Package must be of acid resistant plastic material.

SPECIFIC END USES
See section 1. Contact the manufacturer for more information.

8. EXPOSURE CONTROL/PERSONAL PROTECTION

Utgåva: Utgivningsdatum: 4/10

6, Aktivt 2013-08-16

Digitalt styrt dokument, utskriven kopia måste jämföras med digitala kopian innan användning.
 I10032
Safety Data Sheet Pickling Bath 302 EU - Eng

CONTROL PARAMETERS
Hydrofluoric acid:
EU: IOEL 1,5 mg/m3 (8 hr), 2,5 mg/m3 (15 min)
Nitric acid:
EU: IOEL 0,05 mg/m3 (8 hr)
Sulphuric acid:
EU: IOEL 0,05 mg/m3 thoracic fraction (8 hr)
Chronic effects, inhalation:
Exposure to strong inorganic acid mists containing sulphuric acid is known to be a human
carcinogen, based on sufficient evidence of carcinogenicity from studies in humans.

EXPOSURE CONTROLS
Respiratory protection:
Gas mask with a filter of the chlorine type B (grey) and dust filter P2
Hand protection:
Acid resistant rubber gloves.
Eye protection:
Face shield.
Skin and body protection:
Rubber boots and acid resistant clothes, which covers all body parts exposed to splashes.
Specific hygienic measures:
Do not inhale fumes, avoid contact with eyes, skin and clothes. It is not allowed to eat,
drink and smoke at workplace. Remove contaminated clothes immediately. Wash hands and
face thoroughly after working with pickling paste. Avesta First Aid Spray 910 should be
available at the premises.

Environmental exposure controls: See section 6 and 7.

9. PHYSICAL AND CHEMICAL PROPERTIES

INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES

Physical state (form, colour, smell) at 20oC:

Colourless liquid with a pungent smell.
Boiling point:
80-100oC
Flash point / Explosion properties:
Not applicable
Specific temperatures:
Solid-fluid 40oC, Fluid-gas 50-60oC (nitric fumes)
Vapour pressure at 20oC:
< 0.01 kPa
pH:
0 at 20oC
Density:
Print date: 2013-09-09 by Castro Mirna

1.1-1.4 g/cm3 at 20oC

Solubility in water at 20oC:
100 weight %

10. STABILITY AND REACTIVITY

Utgåva: Utgivningsdatum: 5/10

6, Aktivt 2013-08-16

Digitalt styrt dokument, utskriven kopia måste jämföras med digitala kopian innan användning.
 I10032
Safety Data Sheet Pickling Bath 302 EU - Eng

REACTIVITY
Reacts vigorously with base metals and alkaline substances
CHEMICAL STABILITY
Stable under normal conditions.

POSSIBILITY OF HAZARDOUS REACTIONS

Polymerization will not occur
CONDITIONS TO AVOID
Avoid high temperatures, must not be exposed to direct sunshine. When heated, nitrous
gases will be developed.
INCOMPATIBLE MATERIALS
Contact with low alloyed metals and alkaline compounds causes a heavy exothermic
reaction with heat development and stench risk.
HAZARDOUS DECOMPOSITION PRODUCTS
Will emit nitrous gases, hydrofluoric acid and sulphuric oxides.

11. TOXICOLOGICAL INFORMATION

INFORMATION ON TOXICOLOGICAL EFFECTS

Effects on the skin:
Gives corrosive damages with yellowish discoloration of the skin, blisters and slow-healing
wounds.
Effects on the eyes:
Causes intensive pain and corrosive damages. Risk of irreparable damage to the eyes.
After ingestion:
Gives corrosive damages with burning pain, possibly severe general effect and damage to
kidneys and liver.
Upon inhalation:
Inhalation of fumes or mist might cause aches, cough and difficulty in breathing. Risk for
pulmonary oedema.
Additional information:
Symptoms will not appear immediately.

OTHER RELEVANT INFORMATION

CMR-effects:
Exposure to strong inorganic acid mists containing sulphuric acid is known to be a human
carcinogen (IARC Group 1), based on sufficient evidence of carcinogenicity from studies in
humans.

12. ECOLOGICAL INFORMATION

TOXICITY (Hydroflouric acid):
Fish (fresh water), 60ppm, lethal (time period not specified)
LC50 Fish 96h: 441 mg/l (Gambusia affinis)
Print date: 2013-09-09 by Castro Mirna

EC50 Daphnia 48h: 10-100 mg/l

IC50 Algae 72 h: 2 mg/l

Utgåva: Utgivningsdatum: 6/10

6, Aktivt 2013-08-16

Digitalt styrt dokument, utskriven kopia måste jämföras med digitala kopian innan användning.
 I10032
Safety Data Sheet Pickling Bath 302 EU - Eng

PERSISTENCE AND DEGRADABILITY

Will be protolized in water to H+, NO-3 , F-

BIOACCUMULATIVE POTENTIAL
The product is not regarded as bioaccumulative.
MOBILITY IN SOIL
The product is viscous and, after a period could hike down to the groundwater.
RESULTS OF PBT AND vPvB ASSESSMENT
Non-current

OTHER ADVERSE EFFECTS

Acute effects due to the lowering of pH and burns, i.e. there is a significant decrease in the
number of algae at pH<6.

13. DISPOSAL CONSIDERATIONS

WASTE TREATMENT METHODS

Methods of disposal the product:

Discarded product and related waste is hazardous waste. Alloting of EWC-code should be
made on the basis of the source causing the waste.
Suggested EWC-code is 11 01 05* Pickling acids.
Waste from residues:
Upon neutralization of remaining acid rests and rinsing water can heavy metals precipitate
and these constitute hazardous waste. Neutralise with Avesta Neutralising Agent or slaked
lime. Suggested EWC-code 11 01 09* Sludges and filter cakes containing dangerous
substances.
Contaminated packing:
Rinse with plenty of water.
Additional information:
Effluent must be separated and disposed of as acidic waste. The product has in the
undiluted form toxic effects on soil and water. The remaining acid rests and rinsing water
can lower the pH value of wastewater and therefore should not be released until it has
undergone a neutralization process.
Consult with your local authorized and licensed waste disposal agency and ministry of
environment for instructions and procedures for approved waste disposal.

14. TRANSPORT INFORMATION

UN-Classification No:
2922
UN PROPPER SHIPPING NAME
CORROSIVE LIQUID, TOXIC, N.O.S. (hydrofluoric acid, nitric acid)
TRANSPORT HAZARD CLASS(ES)
Print date: 2013-09-09 by Castro Mirna

Classification Code:
CT1
PACKING GROUP
II

Utgåva: Utgivningsdatum: 7/10

6, Aktivt 2013-08-16

Digitalt styrt dokument, utskriven kopia måste jämföras med digitala kopian innan användning.
 I10032
Safety Data Sheet Pickling Bath 302 EU - Eng

ENVIRONMENTAL HAZARDS
IMDG (Sea):
Class 8 (6.1) EmS F-A, S-B
Marine Pollutant: No
ADR/RID (road, rail):
Class 8 (6.1)
Tunnel restriction code:
(E)
IATA/DGR (air):
Class 8 (6.1)
ADDITIONAL INFORMATION
The product is to be transported according to dangerous goods regulations.

15. REGULATORY INFORMATION

SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS

Regulations:
1907/2006/EC, 1272/2008/EC Table 3.1, 67/648/EEC, EWC 2000/532/EC

Other regulations:
IMDG
ADR/RID
IATA/DGR
Chemical Safety Assessment:
Has not been carried out for this product (or substances in the preparation).

16. OTHER INFORMATION

CHANGES MADE SINCE LAST VERSION
Information on dual classification of elements in section 3, explanation of the
hazard classes referred to in section 16.

TRAINING ADVICE
The Avesta Welding “Handbook for the pickling and cleaning of stainless steel” and
“Guidelines for Planning and Designing a Pickling Workshop”.

KEY LITTERATURE REFERENCES AND SOURCES FOR DATA

Standard Practice for cleaning stainless steel (ASTM-A-380),
Fluorides WHO (Env. Health Criteria 36), International Standard ISO 11014-1l

LIST OF RELEVANT R- AND S-PHRASES, HAZARD CATEGORIES AND STATEMENTS

CODES AS WELL AS PRECAUTIONARY STATEMENTS IN SECTION 2 AND 3.

Risk phrases:
Print date: 2013-09-09 by Castro Mirna

R 8: Contact with combustible material may cause fire.

R 26/27/28: Very toxic by inhalation, in contact with skin and if swallowed.
R 35: Causes severe burns.

Utgåva: Utgivningsdatum: 8/10

6, Aktivt 2013-08-16

Digitalt styrt dokument, utskriven kopia måste jämföras med digitala kopian innan användning.
 I10032
Safety Data Sheet Pickling Bath 302 EU - Eng

Hazard classes to the hazard categories and hazard statements codes

1/H290: May be corrosive to metals
1/H310: Fatal in contact with skin
1A/H314: Causes severe skin burns and eye damage
2/H300: Fatal if swallowed
2/H330: Fatal if inhaled

Safety phrases:
S 1/2: Keep locked up and out of the reach of children.
S 7/47: Keep container tightly closed and at temperature not exceeding 30oC.
S 23: Do not breathe fumes.
S 26: In case of contact with eyes rinse immediately with plenty of water and seek medical
advice.
S 28: After contact with skin, wash immediately with plenty of water or Avesta First Aid
Spray.
S 36/37/39: Wear suitable protective clothing, gloves and eye/face protection.
S 45: In case of accident or if you feel unwell, seek medical advice immediately. Show the
label where possible.
S 61: Avoid release to environment. Refer to special instructions/safety data sheet.
Print date: 2013-09-09 by Castro Mirna

Utgåva: Utgivningsdatum: 9/10

6, Aktivt 2013-08-16

Digitalt styrt dokument, utskriven kopia måste jämföras med digitala kopian innan användning.
 I10032
Safety Data Sheet Pickling Bath 302 EU - Eng

10/10