Daily Practice Problems

CLASS - 12TH

SECTION – I
SINGLE CORRECT CHOICE TYPE

1. CH3CH2CH2CHO (I), CH3CH2CH2CH2OH (II)

CH3CH2OCH2CH3 (III), CH3CH2CH2CH2CH3 (IV)
The decreasing order of boiling point of above compounds is:
(A) I > II > IV > III (B) I > II > III > IV
(C) II > I > III > IV (D) II > I > IV > III

2. In which of the following reaction the carbonyl carbon of carbonyl compounds changes from
sp2 to sp3 hybridization?
(A) Nucleophilic addition reaction
(B) Nucleophilic addition followed by elimination reaction
(C) Haloform reaction
(D) Electrophilic substitution reaction

3. The difference between hemiacetal and acetal is that

(A) In hemiacetal all the carbons are sp2 and in acetal they are sp3
(B) The hemiacetal of a particular carbonyl compound contains less number of carbon atoms
than the corresponding acetal.
(C) Hemiacetals contains more number of oxygen atoms than acetals.
(D) The boiling point of acetals are higher than hemiacetals.

4. Which of the following reaction forms an unsubstituted imine?

O

(A) CH3  C  CH3  NH3  (B) HCHO  NH3 


O

(C) CH3CHO  NH3  (D) CH3CH2C  CH2Br  NH3 


5. RCHO   Ag NH3 2   OH  Pr oducts
Which of the following is not a product of above reaction?
(A) Ag (B) NH3
(C) CH3COOH (D) CH3COO-

6. Sodium hypoiodite (NaOI) is used to distinguish between:

(A) HCHO and CH3OH (B) CH3CHO and CH3COCH3
(C) CH3CH2CHO and CH3CHO (D) CH3COOH and CH3CH2CHO

7. An organic compound gives the following reactions:

(i) It forms an orange red ppt. with 2, 4-DNP reagent
(ii) It gives a yellow ppt. when heated with I2/NaOH.
(iii) It neither reduces Tollen’s or Fehling’s reagent
(iv) It does not decolourise bromine water or Baeyer’s reagent
(v) On drastic oxidation with chromic acid it forms benzoic acid
Therefore, the compound is
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 Daily Practice Problems

CLASS - 12TH
O O
C C
(A) CH3 (B) C2H5

O
CH3
C
(C) (D)
O

8. Which of the following reaction produces CH3 – CH = CH – CHO?

HCl dil.NaOH
(A) 2CH3 CHO  Heat
 (B) 2CH3CHO  
dil.NaOH Conc.NaOH
(C) 2CH3CHO Heat
 (D) 2CH3CHO 

9. HCHO 2undergoes
NH2 disproportionation reaction(B)
when
Conc.NaOH
reacts with
(C) NH2OH (D) Br2/CH3COOH

O
C
10. Cl H2

PdBaSO 4
 Pr oduct P 
Which of the following property of the product of above reaction is incorrect?
(A) It reduces Fehling’s solution
(B) It forms silver mirror when reacts with ammonical AgNO3 solution
(C) If also formed when benzyl alcohol reacts with PCC
(D) It forms an alcohol when reacts with CH3MgBr followed by acidic hydrolysis

11. Acetic acid does not form dimmer in

O

(A) vapour state (B) its solution with dioxane

O
(C) its solution with water (D) its solution with DMSO [(CH3)2SO]

12. CH3COOH does not react with

(A) Na (B) NaOH
(C) NaHCO3 (D) None of these

13. Which is the correct order of decreasing of acidic strength of the following acids?

COOH COOH COOH

OCH3 NO2
(I) ( II ) ( III )
(A) I > II > III (B) III > II > I
(C) II > III > I (D) III > I > II

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 Daily Practice Problems

14. Which of the following reaction produces CH4?

(A) PCl5 NaOH, CaO
CH3COOH   (B) CH3COONa  
Heat
i LiAlH4 3 CH OH
(C) CH3COOH   (D) CH3COONa 
 ii H3O  H

15. Formaline is a/an

(A) Aqueous solution of HCOOH (B) aqueous solution of HCHO
(C) solution of HCHO in NH4OH (D) solution of HCOOH in aqueous ammonia

SECTION – II
MULTIPLE CORRECT CHOICE TYPE

16. Choose correct statement(s) regarding the properties of acetone.

(A) The carbonyl carbon is an electrophilic centre
(B) The carbonyl oxygen is a nucleophilic centre
(C) It’s dipole moment is higher than CH3OCH3
(D) All carbon atoms undergo sp2-hybridization

17. Carbonyl compounds are prepared by dehydrogenation of alcohols. In this process alcohol
vapours are passed over metal catalysts. The metal catalysts used in this process is/are

(A) Cu (B) Ag
(C) K (D) Al
CH3

18.
Cl2  2 eq H2O

h
  A  
373K
 B 

Choose correct statement(s) regarding the properties of products of the above reaction.

(A) Formation of (A) takes place through an electrophilic substitution reaction

(B) Product (B) is a carbonyl compound
(C) (A) gives (B) through a nucleophilic substitution followed by elimination reaction

(D) (A) is Cl CH3

Cl

19. Which of the following compound(s) is/are more reactive than benzaldehyde towards
nucleophilic addition reactions?
(A) CH3CH2CHO (B) CH3CHO

H3C CHO
(C) CHO (D)
H3C

CN
20. C=O C
OH
Which of the following reagent(s) can perform the above conversion?
(A) HCN/NaOH (B) NaCN/HCl
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 Daily Practice Problems

(C) CH3CN/NaOH (D) HCN/HCl

21. Which of the following is/are more acidic than C6H5COOH?

(A) C6H5CH2COOH (B) HCOOH
(C) CH3COOH (D) FCH2COOH

22. The OH group of a monocarboxylic acid can be replaced by ‘Cl’ atom if it reacts with

(A) PCl5 (B) SOCl2

(C) Cl2/red P (D) PCl3

23. The product(s) of the following reaction is/are:

COOH

Br2 /FeBr3
  Pr oduct  s

COOH COOH

Br
(A) (B)

Br
COOH
COBr

(C) (D)

Br

24. Which of the following compound(s) do/does not form(s) red precipitate with Fehling’s
solution?

(A) CHO (B) CHO

(C) CH2COCH3 (D) CH2CHO

25. Carboxylic acids can form their corresponding anhydrides when react with:

(A) H2SO4/ (B) P2O5/

(C) PCl3/ (D) NaOH/

SECTION – III
STATE TRUE OR FALSE

26. The IUPAC name of salicylaldehyde is ortho hydroxybenzaldehyde.

27. Dehydrogenation of alcohols results in the formation of only aldehydes.

28. Hydration of propyne in presence of H2SO4 and HgSO4 forms propanal.

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 Daily Practice Problems

CHO

29. undergoes Gatterman-Koch reaction to form

30. CH3CHO is more soluble in water than CH3COCH3.

31. C=O CH2 + H2O

The reagent(s) used in the above reaction is/are Zn-Hg amalgam and KOH.

32. Oxidation of toluene with hot alkaline permanganate solution produces benzaldehyde.

33. NO2CH2COOH has more acidic strength than NCCH2COOH.

34. CH3COOH does not undergo HVZ reaction with X2/ red P followed by hydrolysis.

35. The molecular mass of CH3COOH becomes 120 in vapour state.

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 Daily Practice Problems
ANSWERS

1. C 2. A 3. B 4. C
5. C 6. C 7. A 8. C
9. B 10. A 11. C 12. D
13. B 14. B 15. B 16. ABC
17. AB 18. BC 19. ABC 20. AB
21. BD 22. ABD 23. B 24. BC
25. AB 26. True 27. False 28. False
29. True 30. True 31. False 32. False
33. True 34. False 35. True

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