COMMON P. G. ENTRANCE TEST — 2020) Test Booklet No. : DEPT. OF HIGHER EDUCATION, GOVT. OF ODISHA TEST BOOKLET Subject Code( 15] Siok Subject (CHEMISTRY ffime Allowed : 90 Minutes) Fall Marks: 70) 8. : INSTRUCTIONS TO CANDIDATES = IMMEDIATELY AFTER THE COMMENCEMENT OF THE EXAMINATION, YOU SHOULD CHECK THAT THIS TEST BOOKLET DOES NOT HAVE ANY UNPRINTED OR TORN OR MISSING PAGES, OR ITEMS ETC. IF SO, GET IT REPLACED BY ACOMPLETE TEST BOOKLET. You have to enter your Halll Ticket No. on the Test Booklet in the Box provided alongside. DO NOT write anything else on the Test Booklet. YOU ARE REQUIRED TOFILL UP & DARKEN HALL TICKET NO. & TEST BOOKLET NO. IN THE, ANSWER SHEET AS WELL AS FILL UP TEST BOOKLET SERIAL NO. & ANSWER SHEET SERIAL NO. IN THE ATTENDANCE SHEET CAREFULLY. WRONGLY FILLED UP ANSWER ‘SHEETS ARE LIABLE FOR REJECTION AT THE RISK OF THE CANDIDATE. This Test Booklet contains 70 items (questions). Each item (question) comprises four responses (answers). You have to select the correct response (answer) which you want to mark (darken) on the Answer Sheet. In case, you feel that there is more than one correct response (answer), you should mark (darken) the response (answer) which you consider the best. In any case, choose ONLY ONE response (answer) for each item (question). You have to mark (darken) all your responses (answers) ONLY on the separate Answer ‘Sheet provided by using BALL POINT PEN (BLUE OR BLACK). See instructions in the Answer Sheet. A\l items (questions) carry equal marks. All items (questions) are compulsory. Your total marks will depend only on the number of correct responses (answers) marked by you in the Answer Sheet. There is no negative marking. After you have completed filling in all your responses (answers) on the Answer Sheet and after conclusion of the examination, you should hand over to the Invigilator the Answer Sheet issued to you. You are allowed to take with you the candidate's copy / second page of the Answer Sheet along with the Test Booklet, after completion of the examination, for your reference. ‘Sheets for rough work are appended in the Test Booklet at the end. DO NOT OPEN THIS TEST BOOKLET UNTIL YOU ARE ASKED TO DO SO XL-25/10 (Turn over )XL—25/10 (2) (Continued )1. Which one of the following compounds gives a primary alcohol upon reaction with methyl magnesium bromide ? (A) Ethylene oxide (B) Propylene oxide (©) Ethylformate (0) Carbon dioxide 2. Which one of the following statements is correct for alkyl halide ? (A) Alky! halide will always show Sy1 mechanism (B) Ina unimolecular reaction increasing the temperature does not favour E1 mechanism (C)_ E1 mechanism is favored over $1 mechanism for primary alkyl halides (0) E1 mechanism is favored over $1 mechanism for tertiary alkyl halides 3. Arylhalides are less reactive towards nucleophilic substitution reactions as compared toalkyl halides. This is due to : (A) The formation of a less stable carbanion (B). The inductive effect (C)_ Longer carbon halogen bond (D) sp*-hybridized carbon attached to the halogen 4, Identify the reactant ‘X’ in the following reaction sequence : H Br ir x PAO, y es, pet , ew : (A) Benzoic acid (8) Salicylic acid (©) Aniline (D) Phenol XL-25/10 (3) (Tur over)5. Which one of the following structures represent the major products in the following reaction ? CH; H+-OH ee: HsC-H > 2 CH as etH a) HjC--H H, CH CH, H Br+-H (C) Hj;C4-Br H3C—-H CH, CH, CH; CH (02) HC-+H HCH, H-PBr Br-H “GH, Gils 6. If 2-methyl butane will be subjected to monobromination, then how many isomers will it form? A) 4 (B) 6 (C) § (0) 2 XL-25/10 (4) (Continued )Calculate the Ams, Value for the following compound using Woodward and Fischer (A) 254nm (8) 279nm (C) 290mm : (0) 315mm Which one of the following compounds with molecular formula C,HzNO, shows ‘H-NMR peaks at 8 5.30 (broad, 1H), 4.10(q, 2H), 2.80 (d, 3H) and 1.20 (t, 3H) ppm ? (A) CH,CH,NHCOOCH, (B) CH,OCH,CONHCH, (©) CH,NHCOOCH,CH, (D) CH,CH,OCH,CONH, The sodium extract of an organic compound develops a blood-red color on treatment with FeCl, solution. The ion responsible for this color tests : (A) CN” (8) NCS (c) CNO™ (0) s* Which one of the following statements is correct regarding the following reaction ? Oxsts {-8U0%" _, Br t-Bu0H (A) Major product is endocyclic alkene formed according to Saytzeff (8) Major product is exocyclic alkene formed according to Saytzeff (C)_ Major product is endocyclic alkene formed according to Hoffmann (D) Major product is exocyclic alkene formed according to Hoffmann XL-25/10 (5) (Tum over )1. 12. ‘Suggest the product of the following reaction : H Micu, Macro ‘OH ° F w one 4 HC) OH ®) CH, ‘OH 3 H © “cH, ‘OCH, 9 o om Which one of the following reactions is not an example of E1CB reaction ? (a) KE ws, ot, (B) Ph Ph —OH_, oy SR ama i) NMey () es —eeLy XL-25/10 (6) (Continued )13. Whatis the correct statement for the given reactions ? oT, a Sax Cl 2100", y HJCOOH COCH, OCH, (A) Breacts faster thanA (B) Both give the same product (C) Agives cis- and B gives trans-product (0) Agives trans- and B givesvis-product 414. Whichis the correct order of nucteophilictyin the following options ? (A) (CH,)sCO™> CHS (8) (CH,CH,),N > (CH,CH,),P (C) CH,S">CH,SH (0) CH,CH,CH,O7<(CH,),CO™ 15. Which one of the following statements is true about the reaction given below ? Naot ne Sa HCO. Be (A) Itproceeds via a concerted S,2 pathway (8) ‘ Itinvolves a carbanion intermediate (C)_Itinvolves a carbocation intermediate (0) Itproceeds via a concerted S\1 pathway 16. Which one of the following substituents on the benzene ring is not a meta directing group in an electrophilic substitution reaction? Oper ®) (no, ©) ()-s 0) ()tH, XL-25/10 (7) (Turn over )17. 19. 20. Which one of the following alkanes exhibits optical activity ? (A) Neopentane (8) Isopentane (C) 3-Methylpentane (0) 3-Methythexane . What will be the most appropriate reagent for the following transformation ? “Ym (A) CH,N, (8) Ph,P=CH, (C) CH,Li (D) (CH,),CuLi Which one of the following carbocations is the most stable 7 WO oe oe ai Name the process associated with acylation of benzene : (A) Friedel craft reaction (8) Wurtz reaction (C) Wurtz fitting reaction (D) Aldol reaction XL-25/10 (8) (Continued )21. 23. 24, 25. 26. Which one of the following statements is incorrect ? (A) First step in photochemistry is the excitation of electron (6) Whenamolecule or atom in the ground state (S,) absorbs light, one electron is excited to a higher orbital level (©) Photochemical reactions are caused by absorption of ultraviolet light only (D) tis possible for the excited state S, to undergo spin inversion Arrange the following intermediates in the descending order of their stabilities : Ho )-EH, Hn>-8H, Hc )-8x, oH) SH, W Ww (ly () (A) I> Ile ill>iv (8) > Ivelll>l (©) l>t>iveitl (0) l>t>ul>tv The IUPAC name of the following compound is : Br (A) 5-bromo-4-chlorohept-1-en-6-yne (8) 5-bromo-4-chlorohept-6-en-1-yne (C)’ 3-bromo-4-chlorohept-6-en-1-yne (D) 3-bromo-4-chlorohept-1-en-6-yne Which type of macromolecule carries out catalysis in biological systems ? (A) Proteins (8) Carbohydrates (©) Lipids (0) Nucleic acids Anucleotide is constituted from which of the following units ? (A) Nitrogen base and phosphate (B) Nitrogen base, sugar and phosphate (©) Nitrogen base and sugar (D) Sugar and phosphate The change in free energy of a reaction at equilibrium is : (A) Negative (8) Positive (©) Zero (D) Difficultto predict XL-25/10 (9) (Tum over)ar 28. 29. 30. 31. 32. 33. 35. XL- If doubling the initial concentration of a reactant doubles the halt-life period (t1,2) of the reaction, then the order of the reaction is : @ 3 (B) 2 (c) 1 (D) 0 ify is the wave function, then whatis the probability of finding an electron in a given region within the atom ? @ v ® v Ov el (0) y™ One coulomb is the charge of: (A) One mole of electron (B) 1/96500 mole of electron (C) 96500 mole of electron (D) None of these ‘The pressure correction in the van der Waals equation is due to the : (A) Attractive force of the molecules toward the interior (8) Attractive force of the molecules toward the boundary wall (C)_ Repulsive force of the molecules toward the interior (D) Repulsive force of the molecules toward the boundary wall The rebtpnsh® be w een Cp and Cy forn mole of ideal gasis : (A) C=C, +nR (8) C,=C,+nR (©) Cy=C,#nRT (0) C,=C,+nRT The relationship between the contact angle and wettability of a liquid is : (A) Proportional (B) Inversely proportional (C) Independent (D) None of these What will be the amount of work done if 10 moles of an ideal monoatomic gas at 10 atm pressure and 27°C temperature is allowed to expand isothermally against a constant pressure of 1 atm? (A) -5.36 kcal (8) 5.36 kcal (C) -4.32kcal (D) 4.32kcal Which of the following is not applicable to the adsorption phenomena ? (A) Langmuir equation (8) BET equation (C)_ Henderson equation (0) Freundlich equation Which one of the following terms is not associated with phase rule ? (A) Triple point (8) Eutectic point (C) Critical point (0) Plaitpoint 25/10 (10) (Continued )37. 38. 39. 40. 4. 42. 43. XL- ‘Which of the following is an intensive property ? (A) Specificheat (8) Molar volume (©) Surface Tension (0) Allofthese Whatis the degree of freedom of 0.11N aqueous solution of NaCl? A 3 (B) 2 c) 0 (02) 1 Whats the ionic strength of 0.2 M of Na,HPO,? () 04M io (8) 05M (©) 06M 4 (0) 08M Which of the following is not the rate expression for a reaction A+2B —— 3P ? afA\ 1 g[B) OW ~at © 2a ola 4 4(°] () +e ©) +3 "at At equilibrium, the process of adsorption involves : (A) aH>o (8) AH=Tas (C) AH> Tas (0) AH A” has a large negative reduction potential. The consequence will be : (A) Ais readily reduced (8) Aisreadily oxidized (©) A’isreadily reduced (0) Ais readily oxidized Atthe end point of acid-base titration involving a strong acid and a strong base using an appropriate indicator, the pH of the solution would be : (A) Slightly alkaline (8) Slightly acidic (C) Neutral (0) Strongly alkaline According to transition state theory for a bimolecular reaction, the activated complex has : (A) No vibrational degrees of freedom (8) Vibrational degrees of freedom but they never participate in product formation (C) One high frequency vibration that leads to product formation (D) One low frequency vibration that leads to product formation 25110 (11) (Turn over)47. 48. 49. 50. 51. 52. 53. XL- The unit of molar extinction coefficient is : (A) Litmol'.cm™ (8) Litmor.cm (C) Litmolcem™ (D)_Lit’.mor.cm™ Which of the following statements is correct ? (A) ,H' and ,He®are isotopes (8) Cand ,N“ are isotopes (C) 49K and ,,Ca® are isotones (0) oF"and ,,Na*are isobars A molecule is Raman active, if: (A) the molecule is polarisable (B) the molecule is paramagnetic (C)_ the molecule contains non-bonding electrons (0) the molecule contains centre of symmetry Cathode rays are deflected towards : (A) Positive electrode (B) Negative electrode (C) Both (A) and (8) (D) None ofthese Which is not a renewable energy ? (A) Solar Energy (8) Wind Energy (C) Tidal Energy (D) LPG After bubbling air through pure water (pH 7.0), its pH decreased. Which of the following is responsible for the pH change ? @,N (8) Co, (C) He (D) O, ‘Which of the following is the correct order with respect to their relative stabilities ? (A) O$ > 0, > 03" > 05 (B) 03 > 0, >O3 > 03 (C) Oz >0} > 03 > 03 (0) OF >0;>0$>0, According to Bohr's theory, the angular momentum of an electron in the 5" orbitis h h (A) 262 ®) 1.07 h h (©) 107 (0) 252 Ina crystal lattice, the Madelung constant depends on the : (A) _ lonic radius of the cation (B) _lonic radius of the anion (C)_ Nature of the crystal system (0) _lonic radius of both cation and anions 25/10 (12) (Continued )565. 57. 58. 59. 60. 61. XL Which of the following is the correct order of ionic radii ? (A) Na’ Mg? (C)_si**Mg* >Na* (0) Na*>Mg* >Ar* > si Which of the following pairs corresponds to soft base pair ? (A) NO, (8) R,S,07 (C) CO,CH,Coo™ (0) SCN’,s,02 . The ionic compound which indicates pyrosilicate is : (A) (Si0)* . (8) (Si,0))° (C) [(Si0,,P" (D) (Si,0,)> The reaction of XeF,, with CsF produces a compound that undergoes decomposition after 50°C. The compound is : (A) Cs,XeF, (8) Cs,XeF, (C) CsXeF, (0) Cs,Xe,F,5 What are the precursors used for the synthesis of borazine in Stock's process ? (A) BH, and NH, (8) NH,Cland NaBH, (C) NH,Cland BCI, (D) NH,and BCI, Which type of isomerism exists between [Co(NH,),Br]SO, and [Co(NH,),(SO,)]Br ‘compounds ? (A) « Linkage isomerism (B) Coordination isomerism (C) Ionization isomerism (0) Coordination position isomerism The primary and secondary valences of cobalt atom in [Co(NH,),Cl,]Cl complex are : (A) 3and4 (8) 1and6 (C) 4and3 (0) 3and6 The rate of reversible hydration of carbon dioxide is accelerated by which of the following biomolecules ? (A) Carboxypeptidase (B) Carbonic anhydrase (C) Haemoglobin (D) Catalase Among the following complexes, the one which shows zero crystal field stabilization energy is : (A) [Mn(H,0).* 8) [Fe(H,0),* (C) [Co(H,0),)** (0) [Co(H,0),)* 25/10 (13) (Turn over )63. 65. 67. 68. 69. 70. pn The complex (n*-C,H,)M(CO), follows 18-electron rule. Which of the following first row transition metal (M) is presentin it ? (A) Co (8) Fe (Cc) Mn (0) Ni One mole of [PtCl,]*~ while reacting with two moles of NH, gives : (A) cisfPt(NH,),Ch] (8) trans-{Pt(NH,),Cl} (C)_[PUNH,) CI" F (0) [PtNH,) Cl)” The reaction of NaCl and K,Cr,0, in the presence of conc. H,SO, produces a vapor that turns aqueous solution of NaOH into yellow colour. While treating this yellow color solution with aqueous lead acetate in the presence of excess CH;COOH, it gives yellow precipitate. Which of the following compounds does correspond to this vapor ? (A) Cr0,C! (8) cro,CI, (©) Na,CrO, (0) crocl, The number of radial nodes present in 3s and 3d orbitals respectively are : (A) 2ando (8) Oand2 (C) 3and2 (0) 2and1 The brown ring complex compound is formulated as [Fe(H,0),(NO)]SO,. The oxidation state of iron in this compound is : (A) +3 (B) +2 (cy) +1 (D0) 0 Which of the following hybridization is present in CIF, molecule ? (A) dsp* (8) sp'd (C) sp’a? (D) sp* Which of the following sets of quantum numbers are correct for an electron present in the 4f orbital ? (A) n=4,£=3,m=+4,s=+3 (B) n=3,¢=2,m=-2,s=+ 4 (C) n=4,£=3,m=+1,8=+ $ (D) n=4,¢=4,m=-4,s=-4 Which of the following is the incorrect statement about Zeise's salt ? (A) Zeise's salt is diamagnetic (B) Allthe Pt—Cl bond lengths in Zeise’s salt are equal (C) Oxidation state of Pt in Zeise's salt is +2 (0) C—C bond length of ethylene moiety in Zeise’s salt is longer than the free ethylene molecule 25/10 (14) (Continued )PACE FOR ROUGH WORK XL-25/10 (6,470) (15) Chemistry