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Annexe Production of Acetic Acid-1

I. This document contains physical property data for several substances including methanol, acetic acid, carbon monoxide, and propionic acid. It lists parameters like molecular weight, freezing point, heat of formation, and density. II. Safety information is provided on the substances. Hazard classifications, pictograms, and precautionary statements are listed regarding flammability, toxicity, and reactivity. Storage and disposal precautions are also outlined. III. Equations are given for the specific heat capacity and vapor pressure of acetic acid and methanol as they relate to temperature.

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28 views4 pages

Annexe Production of Acetic Acid-1

I. This document contains physical property data for several substances including methanol, acetic acid, carbon monoxide, and propionic acid. It lists parameters like molecular weight, freezing point, heat of formation, and density. II. Safety information is provided on the substances. Hazard classifications, pictograms, and precautionary statements are listed regarding flammability, toxicity, and reactivity. Storage and disposal precautions are also outlined. III. Equations are given for the specific heat capacity and vapor pressure of acetic acid and methanol as they relate to temperature.

Uploaded by

abdokhorssa23
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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I.

The physical properties of substances:

Component Component Component Component Component Component Component


Parameters Units Data set
METHA-01 ACETI-01 CARBO-01 CARBO-02 WATER PROPI-01 HYDRO-01
API 1 46,2 2,6 340 340 10 10,1 340
CHARGE 1 0 0 0 0 0 0 0
DCPLS J/KMOL-K 1 6692,65 27299,7 14258,4 38028,2 26702,4 6892,2
DGFORM J/KMOL 1 -1,62E+08 -3,75E+08 -1,37E+08 -3,94E+08 -2,29E+08 -3,67E+08 0
DGSFRM J/KMOL 1 0 0 0 0 0 0 0
DHAQFM J/KMOL 1 0 0 0 0 0 0 0
DHFORM J/KMOL 1 -2,01E+08 -4,33E+08 -1,11E+08 -3,94E+08 -2,42E+08 -4,54E+08 0
DHSFRM J/KMOL 1 0 0 0 0 0 0 0
DHVLB J/KMOL 1 3,53E+07 2,34E+07 6,00E+06 1,64E+07 4,07E+07 3,11E+07 896545
DLWC 1 1 1 1 1 1 1 1
DVBLNC 1 1 1 1 1 1 1 1
FREEZEPT K 1 175,47 289,81 68,15 216,58 273,15 252,45 13,95
HCOM J/KMOL 1 -6,38E+08 -8,15E+08 -2,83E+08 0 0 -1,40E+09 -2,42E+08
HCTYPE 1 0 0 0 0 0 0 0
HFUS J/KMOL 1 3,22E+06 1,17E+07 840984 9,02E+06 6,00E+06 1,07E+07 117100
MUP (J*CUM)**.5 1 5,38E-25 5,50E-25 3,55E-26 0 5,85E-25 5,54E-25 0
MW 1 32,0422 60,0526 28,0104 44,0098 18,0153 74,0794 2,01588
OMEGA 1 0,565831 0,466521 0,0481621 0,223621 0,344861 0,579579 -0,215993
PC N/SQM 1 8,08E+06 5,79E+06 3,50E+06 7,38E+06 2,21E+07 4,67E+06 1,31E+06
RHOM KG/CUM 1 0 0 0 0 0 0 0
RKTZRA 1 0,23616 0,22401 0,28944 0,27256 0,243172 0,23107 0,321
S025E J/KMOL-K 1 0 0 0 0 0 0 0
SG 1 0,7962 1,0553 0,3 0,3 1 0,9992 0,3
TB K 1 337,85 391,05 81,7 194,7 373,15 414,32 20,39
TC K 1 512,5 591,95 132,92 304,21 647,096 600,81 33,19
TPT K 1 175,47 289,81 68,15 216,58 273,16 252,45 13,95
TREFHS K 1 298,15 298,15 298,15 298,15 298,15 298,15 298,15
VB CUM/KMOL 1 0,0427452 0,0639308 0,0354426 0,0350189 0,0188311 0,086085 0,0285681
VC CUM/KMOL 1 0,117 0,177 0,0944 0,094 0,0559472 0,235 0,064147
VCRKT CUM/KMOL 1 0,117 0,177 0,0944 0,094 0,0559472 0,235 0,064147
VLSTD CUM/KMOL 1 0,0403346 0,05763 0,0535578 0,0535578 0,01805 0,0742798 0,0535578
ZC 1 0,222 0,208 0,299 0,274 0,229 0,22 0,305
ZWITTER 1 0 0 0 0 0 0 0

1
II. Safety properties of substances:

a) Safety Pictogrammes :

b) Safety properties of reactant and product substances:

Name of Molecular Hazard class and Hazard Pictograms Precautionary Precautionary


substance formula category statement statements- statements -
prevention response

• Flammable liquid, H225 GHS02 P210 P301 + P310


Category 2

• Acute toxicity Oral, H301


Category 3
• Acute toxicity, H331 P233 P303 + P361 +
Inhalation, P353
Methanol CH4O Category 3 H311
GHS06
• Acute toxicity, H370
Dermal, Category 3
• Specific target
organ toxicity- P304 + P340 +
single exposure, GHS08 P280 P311
Category 1, Eyes,

2
Central nervous
system

• Flammable gases, H220 GHS02 P202 P304+P340+P315


category 1

• Gases under H280


pressure, GHS04
Compressed gas P308+P313

H331
• Acute toxicity
GHS06 P210
(inhalation),
Carbon CO category 3
P377
monoxide H360 P260
• Toxic to GHS08
reproduction,
category 1
H372
• Specific target
organ toxicity
(repeated P381
exposure),
Category 1
• Flammable liquid, H226 GHS02 P210 P301+P330+P331
Category 3
P303+P361+P353
• Skin
Corrosion/irritation, H314 P305+P351+P338
Acetic C₂H₄O₂ Category 1A GHS05 P280
acid
• Serious eye H318
damage/ eye
P310
irritation, Category
1
• Flammable liquid, H226 GHS02 P210 P312
Category 3

• Acute toxicity H303


(oral), Category 5
GHS07
Propionic C₃H₆O₂ • Acute toxicity H313
acid P261
(dermal), Category
5
P370+P378
• Specific target
organ toxicity -
single exposure H335
(respiratory tract-
irritation), Category
3

3
c) Precautionary statements-Storage and disposal:

❖ Carbon monoxide:
P403: Store in a well-ventilated place.
P405: Store locked up.
❖ Methanol:
P405: Store locked up;
P403+P235: Store in a well-ventilated place. Keep cool.
P501: Dispose of contents and container in accordance with all local, regional, national and
international regulations.
❖ Acetic acid:
P405: Store locked up
P403+P233: Store in a well-ventilated place. Keep container tightly closed
P501: Dispose of contents/container to an approved waste disposal plant.
❖ Propionic acid:
P403+P233: Store in a well-ventilated place. Keep container tightly closed.
P403+P235: Store in a well-ventilated place. Keep cool.
P501: Dispose of contents/container to industrial combustion plant.

III. The equation of acetic acid and methanol:

a) Specific heat capacity Cp:

❖ Methanol:
Equation y=1,47084365x²-476,4365612x+103382,89
❖ Acetic acid:
Equation y=1,962245063x²-1309,629327x+297898,15

b) The vapor pressure P:

❖ Methanol:
Equation y=4411,4538x+13,0623142
❖ Acetic acid:
Equation y=-4785,5937x+12,2308206

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