Operating Manual

inoLab
pH Level 2

Laboratory pH meter

ba12218e04 10/2002 71
 Accuracy when The use of advanced technology and the high quality stan-
going to press dard of our instruments are the result of continuous devel-
opment. This may result in differences between this
operating manual and your instrument.
We cannot guarantee that there are absolutely no errors in
this manual. We are sure you will understand that we cannot
accept any legal claims resulting from the data, figures or
descriptions.

Warranty declara- The designated instrument is covered by a warranty of three

tion years from the date of purchase.
The instrument warranty extends to manufacturing faults
that are determined within the period of warranty.
The warranty excludes components that are replaced during
maintenance such as batteries, etc.

The warranty claim extends to restoring the instrument to

readiness for use but not, however, to any further claim for
damages. Improper handling or unauthorized opening of the
instrument invalidates any warranty claim.

To ascertain the warranty liability, return the instrument and

proof of purchase together with the date of purchase freight
paid or prepaid.

Copyright © Weilheim 2002, WTW GmbH & Co. KG

Reprinting - even as excerpts - is only allowed with the ex-
plicit written authorization of WTW GmbH & Co. KG, Weil-
heim.
Printed in Germany.

72
 List of contents

1 Overview . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 75
1.1 Keyboard . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .76
1.2 Display . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .77
1.3 Sockets . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .77

2 Safety . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 79
2.1 Authorized use . . . . . . . . . . . . . . . . . . . . . . . . . . .80
2.2 General safety instructions . . . . . . . . . . . . . . . . . .80

3 Commissioning . . . . . . . . . . . . . . . . . . . . . . . . . . 83
3.1 Scope of delivery . . . . . . . . . . . . . . . . . . . . . . . . . .83
3.2 Initial commissioning . . . . . . . . . . . . . . . . . . . . . . .83

4 Operation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 85
4.1 Switch on the instrument . . . . . . . . . . . . . . . . . . . .85
4.2 Measuring . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .86
4.2.1 Measuring the pH value . . . . . . . . . . . . . . .88
4.2.2 Measuring the Redox voltage . . . . . . . . . . .89
4.2.3 Transmitting measured values . . . . . . . . .90
4.3 Calibrating . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .91
4.3.1 Calibration interval (Int 3) . . . . . . . . . . . . . .94
4.3.2 AutoCal TEC . . . . . . . . . . . . . . . . . . . . . . .95
4.3.3 AutoCal DIN . . . . . . . . . . . . . . . . . . . . . . . .98
4.3.4 ConCal . . . . . . . . . . . . . . . . . . . . . . . . . . .101
4.4 Storing . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .104
4.4.1 Manual storage . . . . . . . . . . . . . . . . . . . . .104
4.4.2 Switching on AutoStore (Int 1) . . . . . . . . .106
4.4.3 Outputting the data storage . . . . . . . . . . .108
4.4.4 Clearing the storage . . . . . . . . . . . . . . . . .111
4.5 Data transmission . . . . . . . . . . . . . . . . . . . . . . . .112
4.5.1 Data transmission interval (Int 2) . . . . . . .112
4.5.2 Recorder (analog output) . . . . . . . . . . . . .114
4.5.3 PC/external printer (RS232 interface) . . .115
4.5.4 Remote control . . . . . . . . . . . . . . . . . . . . .116
4.6 Configuration . . . . . . . . . . . . . . . . . . . . . . . . . . . .117
4.7 Reset . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .121

73
List of contents

5 Maintenance, cleaning, disposal . . . . . . . . . . . 123

5.1 Maintenance . . . . . . . . . . . . . . . . . . . . . . . . . . . .123
5.2 Cleaning . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .124
5.3 Disposal . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .124

6 What to do if... . . . . . . . . . . . . . . . . . . . . . . . . . . 125

7 Technical Data . . . . . . . . . . . . . . . . . . . . . . . . . . 129

8 Lists . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 133

9 Appendix . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 139

74
 Overview

1 Overview
The compact inoLab pH Level 2 precision pH meter lets you
perform pH measurements rapidly and reliably. The inoLab
pH Level 2 provides the highest degree of operating com-
fort, reliability and measuring safety for all applications.

The proven MultiCal ® calibration procedures and

special AutoRead function support your work with the pH
meter.

1 Keypad
2 Display
3 Sockets

Note
The measuring instrument can also be delivered as part of
a set.
Information on this and other accessories is available in the
WTW catalog LABORATORY AND FIELD INSTRUMENTATION or
via the Internet.

75
Overview

1.1 Keyboard

2 4

1 5

1 Call up calibration procedure

2 Select measuring mode
3 Display or transmit measured values
4 Measuring instrument ON/OFF
5 Activate/deactivate AutoRead function
6 Store measured value
7 Increase values, scroll
8 Confirm inputs, start AutoRead
9 Reduce values, scroll

76
 Overview

1.2 Display
Status line

Measured value display

Function and
temperature display

1.3 Sockets

4
3

1 2

Connectors:
1 pH electrode
2 Temperature probe
3 Reference electrode
4 RS 232 interface / analog output
5 Plug-in power supply

Caution
Only connect probes to the instrument that cannot feed ex-
cessive voltages or currents (> SELV and > circuit with cur-
rent limiter).

77
Overview

78
 Safety

2 Safety
This operating manual contains basic instructions that you
must follow during the commissioning, operation and main-
tenance of the instrument. Consequently, all responsible
personnel must read this operating manual before working
with the instrument.
The operating manual must always be available within the
vicinity of the instrument.

Target group This measuring instrument was developed for use in the lab-
oratory.
Thus, we assume that, as a result of their professional train-
ing and experience, the operators will know the necessary
safety precautions to take when handling chemicals.

Symbols used

Caution
indicates instructions that have to be followed to prevent
damage to your instrument.

Warning
indicates instructions that have to be followed to protect
yourself and the instrument from dangerous electrical volt-
age.

Note
Indicates notes that draw your attention to special features.

Note
Indicates cross-references to other documents, e.g. appli-
cation reports, operating manuals of combination elec-
trodes, etc.

79
Safety

2.1 Authorized use

This instrument is authorized exclusively for pH and Redox
measurements in the laboratory.
The technical specifications as given in chapter 7 TECHNICAL
DATA, must be observed. Only the operation and running of
the measuring instrument according to the instructions given
in this operating manual is authorized.
Any other use is considered unauthorized.

2.2 General safety instructions

This instrument is constructed and tested in compliance with
the EN 61010-1 safety regulations for electronic measuring
instruments.
It left the factory in a safe and secure technical condition.

Function and opera- The smooth functioning and operational safety of the instru-
tional safety ment can only be guaranteed if the generally applicable
safety measures and the specific safety instructions in this
operating manual are followed.

The smooth functioning and operational safety of the instru-

ment can only be guaranteed under the climatic conditions
specified in chapter 7 TECHNICAL DATA.

If the instrument was transported from a cold environment to

a warm environment, the formation of condensate can lead
to the faulty functioning of the instrument. In this event, wait
until the temperature of the instrument reaches room tem-
perature before putting the instrument back into operation.

Caution
The instrument is only allowed to be opened by personnel
authorized by WTW.

80
 Safety

Safe operation If safe operation is no longer possible, the instrument must

be taken out of service and secured against inadvertent op-
eration.
Safe operation is no longer possible if:
l the instrument has been damaged in transport
l the instrument has been stored under adverse conditions
for a lengthy period of time
l the instrument is visibly damaged
l the instrument no longer operates as described in this
manual.

If you are in doubt contact the supplier of the instrument.

Obligations of the The operator of this measuring instrument must ensure that
operator the following laws and guidelines are observed when using
dangerous substances:
l EEC directives for protective labor legislation
l National protective labor legislation
l Safety regulations
l Safety datasheets of the chemical manufacturer

81
Safety

82
 Commissioning

3 Commissioning
3.1 Scope of delivery
l Laboratory measuring instrument, inoLab pH Level 2
l Plug-in power supply
l Operating manual and short manual in the cover
l 4 x type AA Mignon 1.5 V batteries

3.2 Initial commissioning

Perform the following activities:
l Set the date and time
l Connect the plug-in power supply.

Setting the date 1 Press and hold down the m key.

and time
2 Press the e key.
The Display test appears briefly on the display.
The measuring instrument then switches automati-
cally to the setting of the baud rate.
3 Press the g key repeatedly until the date flashes on
the display.
4 Set today’s date by pressing u d.
5 Confirm with g.
The date (month) flashes on the display.
6 Set the current month by pressing u d.
7 Confirm with g. The year appears on the display.
8 Set the current year by pressing u d.
9 Confirm with g. The hour field flashes on the dis-
play.
10 Set the current time by pressing u d.
11 Confirm with g.
The minutes field flashes on the display.
12 Set the current time by pressing u d.

83
Commissioning

13 Confirm with g. The measuring instrument then

switches to the pH measuring mode.
14 Switch off the instrument by pressing e.

Connecting the The plug-in power supply supplies the pH meter with low
plug-in power voltage (7.5 V ... 12 V DC).
supply

Warning
The line voltage on site must lie within the input voltage
range of the original plug-in power supply unit (see chapter
7 TECHNICAL DATA).

Caution
Use original plug-in power supplies only
(see chapter 7 TECHNICAL DATA).

1 Insert the plug (1) into the socket (2) of the pH meter.
2 Connect the original WTW plug-in power supply (3) to
an easily accessible mains socket.

Note
You can also perform measurements without a plug-in pow-
er supply.

84
 Operation

4 Operation
4.1 Switch on the instrument

1 Place the instrument on a flat surface and protect it

against intense light and heat.
2 Press the e key.
The display test appears briefly on the display.
The instrument then switches automatically to the
previously selected measuring mode.

Note
The instrument has an energy saving feature to avoid
unnecessary battery depletion.
The energy saving feature switches the instrument off if no
key has been pressed for an hour.
The energy saving feature is not active:

l if the power is supplied by the plug-in power supply

l if the AutoStore function is active
l if the communication cable is connected
l if the recorder cable is connected
l if the printer cable is connected
(for external printers)

85
Operation

4.2 Measuring
Preparatory Perform the following preparatory activities when you want
activities to measure:

1 Connect the electrode to the instrument.

2 Adjust the temperature of the buffer or test solutions
or measure the current temperature if the measure-
ment is made without a temperature probe.
3 Calibrate or check the instrument with the electrode.
4 Select the measuring mode by pressing m.

Note
Incorrect calibration of the pH electrode will result in incor-
rect measured values. Therefore, regularly perform calibra-
tion before measuring.

Caution
When connecting an earthed PC/printer, measurements
cannot be performed in earthed media as incorrect values
would result.
The RS232 interface is not galvanically isolated.

86
 Operation

Temperature probe Measurements can be performed with and without a temper-

ature probe. A connected temperature probe is indicated by
TP on the display.

Note
The pH meter automatically recognizes the type of the tem-
perature probe used. As a result, you can connect elec-
trodes with the NTC30 or Pt1000.

The temperature measurement is absolutely essential for a

reproducible pH measurement. If the measurement is made
without a temperature probe, proceed as follows:

1 Determine the current temperature using a thermo-

meter.
2 Set up the temperature by pressing u d.

Note
When calibrating without a temperature probe, set up the
current temperature of the respective buffer solution manu-
ally by pressing the u d keys.

87
Operation

4.2.1 Measuring the pH value

1 Perform the preparatory activities according to sec-

tion 4.2.
2 Immerse the pH electrode into the test sample.
3 Press the m key until pH appears in the status dis-
play. The pH value appears on the display.

AutoRead AR The AutoRead function (drift control) checks the stability of

(Drift control) the measurement signal. The stability has a considerable
effect on the reproducibility of the measured values.

For identical measurement conditions, the following criteria

apply:
l pH value: better than 0.02 (response time: > 30 s)

1 Call up the pH measuring mode by pressing m.

2 Activate the AutoRead function by pressing a.
The current measured value is frozen (Hold function).
3 Start the AutoRead function by pressing g.
AR flashes on the display until a stable measured val-
ue is reached.
This measured value is transmitted to the interface.
4 If necessary, start the next AutoRead measurement
by pressing g.
5 To cancel the AutoRead function: Press the a key.

88
 Operation

Note
The current AutoRead measurement (with acceptance of
the current value) can be terminated at any time by pressing
g.

4.2.2 Measuring the Redox voltage

The instrument can measure the Redox voltage (mV) of a
solution when connected with a Redox electrode, e.g. Sen-
Tix ORP.

1 Perform the preparatory activities according to sec-

tion 4.2.
2 Immerse the Redox electrode into the test sample.
3 Press the m key repeatedly until U appears in the
status line. The Redox voltage (mV) of the sample
appears on the display.
4 Wait for a stable measured value.

Note
Redox electrodes are not calibrated. However, you can
check Redox electrodes using a test solution.

89
Operation

4.2.3 Transmitting measured values

You can transmit measured values (data records) in 3 ways:

l Switch on the data transmission (Int 2) (see page 112)

– After expiry of the selected interval, the current data
record is sent to the interface.
l Switch on AutoStore (Int 1) (see page 106)
– After expiry of the selected interval, the current data
record is sent to the interface and in addition is stored
in the data storage of the instrument
– AutoStore (Int 1) covers the data transmission interval
(Int 2).
l Press the g key
This manually transmits the current measured values at
any time - independently of the selected intervals.

Note
If you connect a recorder (analog output), the output to the
digital output is switched off.

90
 Operation

4.3 Calibrating
Why calibrate? pH electrodes age. This changes the asymmetry (zero
point) and slope of the pH electrode. As a result, an inexact
measured value is displayed. Calibration determines the
current values of the asymmetry and slope of the electrode
and they are stored in the instrument.
Thus, you should calibrate at regular intervals.

When to calibrate? l After connecting another electrode

l When the sensor symbol flashes:
– after expiry of the calibration interval
– after a voltage interruption, e.g. battery change
Calibration points Calibration can be performed using one, two or three buffer
solutions (single point calibration, two-point calibration and
three-point calibration). In three-point calibration, two sepa-
rate asymmetry and slope values (ASY1/S1 and ASY2/S2)
are determined for the two ranges between the three buff-
ers. For measuring, the calibration values relevant for the
respective range are used.

You can choose between 3 calibration procedures:

AutoCal TEC is specially adapted to the WTW technical buffer solutions

as a fully automatic two or three-point calibration. The buffer
solutions are automatically recognized by the instrument.

AutoCal DIN is specially adapted to permanently programmed buffer

solutions according to DIN 19266 as a fully automatic two or
three-point calibration. The buffer solutions are automati-
cally recognized by the instrument.

ConCal is the conventional two-point calibration with 2 freely select-

able buffer solutions or single-point calibration as the rapid
method.

91
Operation

AutoRead In calibration using AutoCal TEC and AutoCal DIN, the

AutoRead function is automatically activated.
The current AutoRead measurement (with acceptance of
the current value) can be terminated at any time by pressing
g.
Calibration protocol The calibration protocol contains the calibration data of the
current calibration. You can call up the calibration protocol
by outputting the data storage (section 4.3.2).

Note
You can automatically print out a calibration protocol after
the calibration. To do so, connect a printer according to sec-
tion 4.5.3 before the calibration. After a valid calibration, the
protocol is printed.

Sample printout:

CALIBRATION PROTOCOL
02.03.99 14:19
Device No.: 12345678
CALIBRATION pH
Cal Time: 01.03.99 / 15:20
Cal Interval: 7d
AutoCal DIN Tauto
Buffer 1 1.679
Buffer 2 4.008 *
Buffer 3 6.865
Buffer 4 9.180 *
C1 174.1mV 25.0°C
C2 -133.3mV 25.0°C
S1 -59.4 mV/pH
ASY1 - 4 mV
Probe: +++

92
 Operation

Calibration evalua- After the calibration, the instrument automatically evaluates

tion the current status. The asymmetry and slope are separately
evaluated. The worst evaluation appears on the display.

Display Asymmetry Slope [mV/

[mV] pH]
-15 ... +15 -60.5 ... -58

-20 ... +20 -58 ... -57

-25 ... +25 -61 ... -60.5

or
-57 ... -56

-30 ... +30 -62 ... -61

or
-56 ... -50

Clean the electrode accord-

ing to the sensor operating
manual
E3 < -30 or < -62 or
> 30 > -50
Clear the fault according to
chapter 6 WHAT TO DO IF...

Preparatory 1 Switch on the instrument by pressing e.

activities
2 Connect the pH electrode to the instrument.
3 Keep the buffer solutions ready.
4 Adjust the temperature of the solutions and measure
the current temperature if the measurement is per-
formed without a temperature probe.

93
Operation

4.3.1 Calibration interval (Int 3)

The flashing sensor symbol reminds you to calibrate regu-
larly. After the selected calibration interval (Int 3) expires,
the sensor symbol flashes. Measurements can continue.

Note
To ensure the high measuring precision of the measuring
system, perform a calibration after the calibration interval
expires.

Setting the The calibration interval (Int 3) is set to 7 days in the factory.
calibration interval The interval can be changed (1 ... 999 days):

1 Switch off the instrument.

2 Press m and hold down the key.
3 Press the e key.
The display test appears briefly on the display.
The instrument then switches automatically to the
configuration level.
4 Press the g key until Int 3 appears on the display.

5 Press u d to set the required time interval until the

next calibration.
6 Confirm with g.
7 Change to the measuring mode by pressing m.

94
 Operation

4.3.2 AutoCal TEC

Use any two or three of the WTW technical buffer solutions
for this procedure in increasing or decreasing order.

Note
Steps 2, 6 and 13 are not required if you use a temperature
probe.

1 Press the c key repeatedly until the AutoCal TEC

function display appears.

2 If necessary, set the temperature of the buffer solu-

tion by pressing u d.
3 Submerse the pH electrode in the first buffer solution.
4 Press the g key.
AR flashes on the display.
The electrode voltage (mV) appears on the display.
As soon as a stable value is recognized, Ct2 ap-
pears.

5 Thoroughly rinse the electrode with distilled water.

95
Operation

6 If necessary, set the temperature of the second buffer

solution by pressing u d.
7 Submerse the electrode in the second buffer solution.
8 Press the g key.
AR flashes on the display.
The electrode voltage (mV) appears on the display.
As soon as a stable value is recognized, AR disap-
pears.
The sensor symbol shows the electrode evaluation
after the two-point calibration.
The value of the slope (mV/pH) appears on the dis-
play.
9 Press the g key.
The value of the asymmetry (mV) appears on the dis-
play.
10 To return to the measuring mode: Press the m key
or continue with three-point calibration.

96
 Operation

Three-point 11 Press the g key.

calibration Ct3 appears on the display.
12 Thoroughly rinse the electrode with distilled water.
13 If necessary, set the temperature of the third buffer
solution by pressing u d.
14 Submerse the electrode in the third buffer solution.
15 Press the g key.
AR flashes on the display.
The electrode voltage (mV) appears on the display.
As soon as a stable value is recognized, AR disap-
pears.
The sensor symbol shows the electrode evaluation
after the three-point calibration.
The value of the slope (mV/pH) appears on the dis-
play.
16 Press the g key.
The value of the asymmetry (mV) appears on the dis-
play.
17 To return to the measuring mode: Press the m key.

Note
You can also prematurely terminate the three-point calibra-
tion by pressing m. The values of the two-point calibration
for the slope and asymmetry are then stored.

97
Operation

4.3.3 AutoCal DIN

Use two or three different DIN buffer solutions (type A, C, D
or F with the pH values 1.679, 4.006, 6.865, 9.180) for this
procedure in increasing or decreasing order.

Note
Steps 2, 6 and 13 are not required if you use a temperature
probe.

1 Press the c key repeatedly until the AutoCal DIN

function display appears.

2 If necessary, set the temperature of the buffer solu-

tion by pressing u d.
3 Submerse the pH electrode in the first buffer solution.
4 Press the g key.
AR flashes on the display.
The electrode voltage (mV) appears on the display.
As soon as a stable value is recognized, Cd2 ap-
pears.

98
 Operation

5 Thoroughly rinse the electrode with distilled water.

6 If necessary, set the temperature of the second buffer
solution by pressing u d.
7 Submerse the electrode in the second buffer solution.
8 Press the g key.
AR flashes on the display.
The electrode voltage (mV) appears on the display.
As soon as a stable value is recognized, AR disap-
pears.
The sensor symbol shows the electrode evaluation
after the two-point calibration.
The value of the slope (mV/pH) appears on the dis-
play.
9 Press the g key.
The value of the asymmetry (mV) appears on the dis-
play.
10 To return to the measuring mode: Press the m key
or continue with the three-point calibration.

99
Operation

Three-point 11 Press the g key.

calibration Cd3 appears on the display.
12 Thoroughly rinse the electrode with distilled water.
13 If necessary, set the temperature of the third buffer
solution by pressing u d.
14 Submerse the electrode in the third buffer solution.
15 Press the g key.
AR flashes on the display.
The electrode voltage (mV) appears on the display.
As soon as a stable value is recognized, AR disap-
pears.
The sensor symbol shows the electrode evaluation
after the three-point calibration.
The value of the slope (mV/pH) appears on the dis-
play.
16 Press the g key.
The value of the asymmetry appears on the display
(mV).
17 To return to the measuring mode: Press the m key.

Note
You can also prematurely terminate the three-point calibra-
tion by pressing m. The values of the two-point calibration
for slope and asymmetry are retained.

100
 Operation

4.3.4 ConCal
Two-point Use two buffer solutions for this procedure:
calibration
l pH 7.0 ± 0.5
l any other buffer solution

Note
Steps 2 and 9 are not required if you use a temperature
probe.

1 Press the c key repeatedly until the ConCal func-

tion display appears.

2 If necessary, set the temperature of the buffer solu-

tion by pressing u d.
3 Submerse the pH electrode in the first buffer solution
pH 7.0 ± 0.5.
4 Press the g key.
The measured pH value appears on the display.
5 Set the nominal pH value of the buffer solution (at the
current temperature) by pressing the u d keys.
6 Press the g key.
The value of the asymmetry (mV) and the sensor
symbol appear on the display.
7 Press the g key.
SLO(pe) appears on the display.

101
Operation

8 Thoroughly rinse the electrode with distilled water.

9 If necessary, set the temperature of the second buffer
solution by pressing u d.
10 Submerse the electrode in the second buffer solution.
11 Press the g key.
The second measured pH value appears on the dis-
play.
12 Set the nominal pH value of the second buffer solu-
tion (at the current temperature).
13 Press the g key.
The value of the slope (mV/pH) appears on the dis-
play.
The sensor symbol shows the evaluation of the elec-
trode after the two-point calibration.
14 Press the g key.
The value of the asymmetry (mV) appears on the dis-
play again.
15 To return to the measuring mode: Press the m key.

102
 Operation

Single-point Use a buffer solution in the range pH = 7.0 ± 0.5 for this pro-
calibration cedure.

Note
Only the electrode asymmetry is determined in single-point
calibration. The slope of the last two-point calibration is
retained.

Note
Step 2 is not required if you use a temperature probe. The
TP message indicates an active temperature measurement.

1 Press the c key repeatedly until the ConCal func-

tion display appears.

2 Set the temperature of the buffer solution by pressing

u d.
3 Submerse the pH electrode in the buffer solution.
4 Press the g key.
The measured pH value appears on the display.
5 Set the nominal pH value of the buffer solution (at the
current temperature) by pressing the u d keys.
6 Press the g key.
The value of the asymmetry (mV) and the sensor
symbol for the evaluation of the electrode appears on
the display.
7 To return to the measuring mode: Press the m key.

103
Operation

4.4 Storing
The pH meter has an internal data storage device. Up to 800
data records can be stored in it.
A complete data record consists of:

l Memory location
l Date/time
l Measured value
l Temperature
l Temperature measurement procedure
l I.D. number

You can transmit measured values (data records) to the

data storage in 2 ways:

l Manual storage
l Switching on the AutoStore function (Int 1).

4.4.1 Manual storage

You can transmit a measured value to the data storage as
follows:

1 Press the s key.

The current number of the next free memory location
appears on the display.

104
 Operation

2 Confirm with g.
The display changes to the input of the I.D. number.

3 Enter the required I.D. number (1 ... 999) by pressing

u d.
4 Confirm with g.
The instrument changes to the measuring mode.

StoFull message This message appears if all 800 memory locations are full.

You have the following options:

Store the current measured value. Press g

The oldest measured value (memory
location 1) is overwritten by this
Return to the measuring mode without Press any key
storing
Output the data storage See section
4.4.3
Delete the data storage See section
4.4.4

105
Operation

4.4.2 Switching on AutoStore (Int 1)

The storage interval (Int 1) determines the time interval
between automatic storage processes.
After the time interval expires, the current data record is
transmitted to the data storage and to the interface.

Setting the storage The storage interval (Int 1) is set to OFF in the factory.
interval Thus, the AutoStore function is switched off.
To switch the function on, set up a time interval (5 s, 10 s,
30 s, 1 min, 5 min, 10 min, 15 min, 30 min, 60 min):

1 Press and hold down the g key.

2 Press the s key. Int 1 appears on the display.

3 Press the u d keys to set up the required time in-

terval between storage processes.
4 Confirm with g.
The number of free memory locations appears on the
display.

106
 Operation

5 As soon as all 800 memory locations are full, the

AutoStore function is terminated (Int 1 = OFF).
If too few storage locations are available for your
measurements:
– backup the data storage (see page 108) and
– clear the data stored (see page 111).
6 Confirm with g.
The prompt for the I.D. number appears on the dis-
play.

7 Press u d to set the required I.D. number

8 Confirm with g.
The instrument changes to the pH measuring mode
and starts the measuring and storage procedure.
AutoStore flashes on the display.

Note
The AutoStore function is interrupted if you perform other
functions, e.g. output data storage.
After completing the other function, the AutoStore function
continues. However, as a result, gaps can occur in the
recording of the measured values.

Switching off the Switch off the AutoStore function by:

AutoStore
l Setting the storage interval (Int 1) to OFF or
l Switch the pH meter off and on again.

107
Operation

4.4.3 Outputting the data storage

The contents of the data storage can be output to the:

l display
l interface

Outputting to the 1 Press the r key repeatedly until Sto disp appears
display on the display.
2 Press the g key.
A measured value appears on the display.
The memory location of the data store appears for
approx. 2 s. This is followed by the corresponding
temperature.

You can perform the following activities:

Display further parameters of the data record Press g

(I.D. no., date, time, memory location)
Advance one data record (memory location) Press u
Go back one data record (memory location) Press d

108
 Operation

Note
If you want to find a specific parameter (e.g. date), proceed
as follows:

1 Select the parameter (e.g. date) by pressing g.

2 Press u or d repeatedly until the required
date appears on the display.
After approx. 2 s, the temperature of the displayed
measured value appears.

Outputting to the 1 Press the r key repeatedly until Sto SEr appears
interface on the display.

2 Press the g key.

Sto CAL appears on the display. The calibration pro-
tocol is transmitted to the interface.
Following the calibration protocol, the complete con-
tents of the storage is transmitted to the interface.

Note
You can cancel the transmission by pressing m or g.

109
Operation

Sample printout:
CALIBRATION PROTOCOL
02.03.99 14:19
Device No.: 12345678
CALIBRATION pH
Cal Time: 01.03.99 / 15:20
Cal Interval: 7d
AutoCal DIN Tauto
Buffer 1 1.679
Buffer 2 4.008 *
Buffer 3 6.865
Buffer 4 9.180 *
C1 174.1mV 25.0°C
C2 -133.3mV 25.0°C
S1 -59.4 mV/pH
ASY1 - 4 mV
Probe: +++

No. 1:
09.03.99 17:10
pH 10.01 25 °C
Tman AR
Ident : 1

No. 2:
09.03.99 17:11
pH 10.01 24,7 °C
Tauto AR
Ident : 1

No. 3:
09.03.99 17:12
305 mV
Tauto
Ident : 13

The printout contains:

l calibration protocol
l storage contents

110
 Operation

4.4.4 Clearing the storage

This function can erase the stored data records. 800 mem-
ory locations will then become available again.

Note
The Clear store function only appears if data records have
already been stored in the storage. Otherwise, the pH meter
automatically changes to the measuring mode.

In order to delete all the data records, proceed as follows:

1 Switch off the instrument.

2 Press and hold down the s key.
3 Press the e key.
The display test appears briefly on the display.

4 Confirm the clearing process by pressing g.

Pressing any other key stops the clearing process
and the data records remain in the storage.

Note
The calibration data remain in the storage and can be called
up via the calibration protocol.

111
Operation

4.5 Data transmission

You can use the following options to transmit data:
l One of the following options:

– The AutoStore function (page 106) is used to

periodically (Int 1 storage interval) save measured
values internally and output them on the interface.
– The data transmission interval (Int 2) function is used to
periodically output measured values to the interface
(see below).
l The Output data store function (page 108) is used to out-
put calibration data and stored measured values to the
interface.
l The analog recorder output (page 114) is used to output
measured values as voltages.
l Data can be transmitted bidirectionally (page 116) using
the KOM pilot communication package (accessory).

4.5.1 Data transmission interval (Int 2)

The interval for the data transmission (Int 2) is determined
by the time interval between automatic data transmissions.
After the time interval expires, the current data record is
transmitted to the interface.

Note
The setting of the interval (Int 2) only has an effect when the
storage interval (AutoStore function) is switched off.

112
 Operation

Setting the The interval is set to OFF in the factory.

data transmission To start the data transmission, set up an interval (5 s, 10 s,
interval 30 s, 1 min, 5 min, 10 min, 15 min, 30 min, 60 min):

1 Press and hold down the g key.

2 Press the a key.
Int 2 appears on the display.

3 Press u d to set up the required time interval be-

tween storage processes.
4 Confirm with g.
The instrument changes automatically to the pH
measuring mode.

Note
If the AutoStore function is active, the data transmission is
performed according to the setting of the storage interval
(Int1). Set the storage interval (Int1) to OFF to activate the
data transmission interval (Int2).

Note
You can also set the data transmission interval (Int2) in the
Configuration menu (see page 117).

113
Operation

4.5.2 Recorder (analog output)

You can transmit the data to a recorder via the analog out-
put. Connect the analog output to the recorder via the
AK323 interface cable.
The data output switches automatically to recorder output.

1 Free
Socket assignment 2 Plug coding
1 2
3 Ground
4 3 4 Analog output
RS 232
low impedance electrode signal
REC corresponds to 50 ... 62 mV/pH
(internal resistance < 5 Ohm)

Note
Activate the analog output by connecting 2 and 3.

114
 Operation

4.5.3 PC/external printer (RS232 interface)

You can transmit data to a PC or an external printer via the
RS232 interface.
Connect the interface to the instrument via the AK340/B
cable (PC) or AK325/S cable (external printer).
The data output switches automatically to RS232.

Note
The RS232 interface is not galvanically isolated.
If it is connected to an earthed PC/printer, measurements
cannot be made in earthed media as this would give incor-
rect results!

Set up the following transmission data on the PC/printer:

Baud rate Selectable between: 1200, 2400, 4800,

9600
Handshake RTS/CTS + Xon/Xoff
PC only:
Parity None
Data bits 8
Stop bits 1

1 CTS
Socket assignment
2 RxD
1 2
3 Ground
4 3 4 TxD
RS 232
REC

115
Operation

4.5.4 Remote control

The pH meter can be remotely controlled from a PC. This
requires the KOM pilot communication package that is avail-
able as an accessory.
The instrument is then controlled via commands that
simulate keystrokes and request the current display con-
tents.

Note
A more detailed description is provided within the scope of
delivery of the communication package.

116
 Operation

4.6 Configuration
You can adapt the pH meter to your individual requirements.
To do this, the following parameters can be changed (the
status on delivery is marked in bold):

Baud rate 1200, 2400, 4800, 9600

Data transmission inter- OFF, 5 s, 10 s, 30 s, 1 min,
val (Int 2) 5 min, 10 min, 15 min, 30 min,
60 min
Calibration interval (Int 3) 1 ... 7 ... 999 d
Temperature unit °C, °F
Date/time As required
Resolution of pH display 0.01, 0.001

Note
You can leave the configuration menu at any time. Parame-
ters that have already been changed are stored.
To do this, press the m key.

1 Switch off the instrument.

2 Press and hold down the m key.
3 Press the e key.
The display test appears briefly on the display.
The instrument then switches automatically to the
setting of the baud rate.

Baud rate

117
Operation

4 Set up the required baud rate by pressing u d.

5 Confirm with g.
Int 2 appears on the display.

Data transmission
interval

6 Set up the required time interval by pressing u d.

7 Confirm with g.
Int 3 appears on the display.

Calibration
interval

8 Set up the required time interval by pressing u d.

9 Confirm with g.
USE °C appears on the display.

118
 Operation

Temperature unit

10 Change between °C and °F by pressing u d.

11 Confirm with g.
The date flashes on the display.

Date and time

12 Set today’s date by pressing u d.

13 Confirm with g.
The date (month) flashes on the display.
14 Set the current month by pressing u d.
15 Confirm with g.
The year appears on the display.
16 Set the current year by pressing u d.
17 Confirm with g.
The hours flash on the display.
18 Set the current time by pressing u d.
19 Confirm with g.
The minutes flash on the screen.

119
Operation

20 Set the current time by pressing u d.

21 Confirm with g.
The instrument changes automatically to the pH
measuring mode.

Adjusting the
1 Press and hold down the g key.
resolution
2 Press the m key.
The measured values appear with the higher resolu-
tion on the display, e.g. pH = 4.012.
3 Press the g key and m key again.
The measured values with the lower
resolution appear on the display, e.g. pH = 4.01.

120
 Operation

4.7 Reset
You can reset (initialize) measuring and configuration
parameters separately from one another.

Measuring The following measuring parameters (pH InI) are reset to the
parameters values they had on delivery:

Measuring mode pH
Asymmetry 0 mV
Slope -59.16 mV/pH
Calibration procedure AutoCal TEC
Temperature, manual 25°C
Resolution of pH display 0.01

Note
When the measuring parameters are reset, the calibration
data are lost. After the parameters have been reset, cali-
brate!

Configuration The following configuration parameters (InI) are reset to the

parameters values they had on delivery:

Baud rate 4800

Interval 1
(automatic storing) OFF
Interval 2
(for data transmission) OFF

121
Operation

Resetting 1 Press and hold down the g key.

measuring
parameters 2 Press the c key.

3 Use u d to toggle between no and yes.

yes: reset measuring parameters.
no: retain settings.
4 Confirm with g.
The instrument changes to the configuration
parameters.

Resetting 5 Toggle between no and yes by pressing u d.

configuration yes: reset configuration parameters.
parameters no: retain settings.
6 Confirm with g.
The instrument changes automatically to the pH
measuring mode.

122
 Maintenance, cleaning, disposal

5 Maintenance, cleaning, disposal

5.1 Maintenance
The measuring instrument is almost maintenance-free. The
only maintenance task is replacing the batteries:

1 Open the battery compartment (1) on the underside

of the instrument.
2 Remove the four batteries from the battery compart-
ment.
3 Insert four new batteries (Type Mignon AA) into the
battery compartment.
4 Close the battery compartment (1).
The date (day) flashes on the display.
5 Set up the date and time according to section 3.2.

Caution
Make sure that the poles of the batteries are the right way
round. The ± signs in the battery compartment must corre-
spond to the ± signs on the batteries.
Only use leakproof alkaline manganese batteries.

Note
See the relevant operating manual of the electrode for in-
structions on maintenance.

123
Maintenance, cleaning, disposal

5.2 Cleaning
Occasionally wipe the outside of the measuring instrument
with a damp, lint-free cloth. Disinfect the housing with iso-
propanol as required.

Caution
The housing is made of synthetic material (ABS). Thus,
avoid contact with acetone or similar detergents that contain
solvents. Remove any splashes immediately.

5.3 Disposal
Packing The measuring instrument is sent out in a protective trans-
port packing.
We recommend: Keep the packing material. It protects the
instrument against damage during transport.

Batteries This note refers to the battery regulation that applies in the
Federal Republic of Germany. We would ask end-consum-
ers in other countries to follow their local statutory provi-
sions.

Note
In compliance with §14 of the BATTERY REGULATION, we
would like to point out that this instrument contains batteries.
Batteries that have been removed must only be disposed of
at the recycling facility set up for this purpose or via the retail
outlet.
It is illegal to dispose of them in household refuse.

Measuring Dispose of the measuring instruments as electronic waste at

instrument an appropriate collection point. It is illegal to dispose of them
in household refuse.

124
 What to do if...

6 What to do if...

Error message, Cause Remedy

OFL pH electrode:
– Not connected – Connect electrode
– Air bubbles in front of the – Remove air bubbles
diaphragm
– Air in the diaphragm – Extract air or
moisten diaphragm
– Cable broken – Replace electrode
– Gel electrolyte dried out – Replace electrode

Error message, Cause Remedy

E3 pH electrode:
– Diaphragm contaminated – Clean diaphragm
– Membrane contaminated – Clean membrane
– Moisture in the plug – Dry plug
– Electrolyte obsolete – Replenish electrolyte or
replace electrode
– Electrode obsolete – Replace electrode
– Electrode broken – Replace electrode

Measuring instrument:
– Incorrect calibration – Select correct
procedure procedure
– Incorrect solution – Set up correct
temperature (without temperature
temperature probe)
– Socket damp – Dry socket

125
What to do if...

Buffer solutions:
– Incorrect buffer solutions – Change calibration
procedure
– Buffer solutions too old – Only use once.
Note the shelf life
– Buffer solutions depleted – Change solutions

No stable Cause Remedy

measured value
pH electrode:
– Diaphragm contaminated – Clean diaphragm
– Membrane contaminated – Clean membrane

Sample:
– pH value not stable – Measure with air
excluded if necessary
– Temperature not stable – Adjust temperature if
necessary

Electrode + sample:
– Conductivity too low – Use suitable electrode
– Temperature too high – Use suitable electrode
– Organic liquids – Use suitable electrode

Sensor symbol Cause Remedy

flashes – Calibrating interval – Newly calibrate measuring
expired system

126
 What to do if...

Cause Remedy
LoBat display
– Batteries almost – Replace batteries
depleted (see section
5.1 MAINTENANCE)

Cause Remedy
to display
– Timeout of the interface – Checkout connected
instrument

Obviously incorrect Cause Remedy

measured values
pH electrode:
– pH electrode unsuitable – Use suitable electrode
– Temperature difference – Adjust temperature of
between buffer and buffers or samples
sample too large
– Measuring procedure not – Follow special procedure
suitable

Instrument does not Cause Remedy

react to keystroke
– Operating state – Processor reset:
undefined or EMC Press the a key and
electric stress unallowed switch on instrument

You would like to Cause Remedy

know which soft-
– e.g. question of the WTW – Press the a key and
ware version is in
service department switch on instrument.
the instrument
The software version
is displayed.

127
What to do if...

Cause Remedy
StoFull message – All 800 memory locations – Output data store and
are full clear data store

128
 Technical Data

7 Technical Data

Ambient Storage temperature - 25 °C ... + 65 °C

temperature Operating temperature 0 °C ... + 55 °C
Allowable relative Annual mean: < 75 %
humidity 30 days/year: 95 %
Other days: 85 %

Measuring rang- pH - 2.000 ... + 19.999

es and resolution - 2.00 ... + 19.99
U [mV] - 999.9 ... + 999.9
- 1999 ... + 1999
T [°C] - 5.0 ... + 105.0
T [°F] + 23.0 ... + 221.0

Accuracy pH ± 0.005
(± 1 digit) (in the measuring range (at operating temperature
of 2 pH units around the + 15°C ... + 35 °C)
calibration point)
± 0.01
U [mV] ± 0.3 (at + 15 °C ... + 35 °C)
±1
T [°C] NTC 30: ± 0.1
PT 1000:
± 0.5 at 0 °C ... 15 °C
± 0.1 at 15 °C ... 35 °C
± 1 at 35 °C ... 55 °C
T [°F] NTC 30: ± 0.2
PT 1000:
± 0.9 at 32 °F ... 59 °F
± 0.2 at 59 °F ... 95 °F
± 1.8 at 95 °F ... 131 °F

129
Technical Data

Dimensions and Length [mm] 250

weight Width [mm] 300
Height [mm] 70
Weight [kg] Approx. 1.3 (without plug-in power
supply)

Analog output Automatic switch-over when the AK 323 recorder cable is

connected.

Output signal corresponds to electrode voltage,

i. e. 50...62 mV/pH unit
Accuracy ± 0.1% of measured value ± 4mV
Internal < 5 ohms (current limitation to max.
resistanace 0.2 mA output current)

Serial interface Automatic switch-over when the AK 340/B or AK 325/S

cable is connected.

Type RS 232, data output

Baud rate can be set to
1200, 2400, 4800, 9600 Baud
Data bits 8
Stop bit 1
Parity none
Handshake RTS/CTS+Xon/Xoff
Cable length max. 15m

130
 Technical Data

Energy supply Batteries 4 x 1.5 V AA type alkaline manganese

batteries
Runtime Approx. 3000 operating hours
Mains power Connection max. overvoltage category
supply (option) II (valid for all plug-in power supplies):

Plug-in power supply (Euro plug):

FRIWO FW1199, 11.7864
Friwo Part. No. 1762613
Input: 230 V ~ / 50 Hz / 5.6 VA
Output: 12 V = / 130 mA / 1.56 VA

Plug-in power supply (US plug):

FRIWO FW1199, 11.7880
Friwo Part. No. 1794043
Input: 120 V ~ / 60 Hz / 6 VA
Output: 12 V = / 150 mA

Plug-in power supply (UK plug):

FRIWO FW3288, 11.8453
Friwo Part No. 1816491
Input: 230V ~ / 50 Hz / 23 VA
Output: 12 V = / 130 mA / 1,56 VA

Guidelines EMC E.C. guideline 89/336/EEC

and norms used EN 61326-1:1997
EN 61000-3-2 A14:2000
EN 61000-3-3:1995
FCC Class A
Instrument safety E.C. guideline 73/23/EEC
Protective class 3, EN 61010-1 A2:1995
Climatic class 2, VDI/VDE 3540

Test marks TÜV GS,UL/CUL, CE

131
Technical Data

132
 Lists

8 Lists
This chapter provides additional information and orientation
aids.

Abbreviations The list of abbreviations explains abbreviations that appear

on the display or when dealing with the instrument.

Specialist terms The glossary briefly explains the meaning of the specialist
terms. However, terms that should already be familiar to the
target group are not described here.

Index The index helps you find the topics that you are looking for.

133
Lists

Abbreviations
AR AutoRead (drift control)
ARng Automatic range switching
Measuring instrument measures with high-
est resolution
ASY Asymmetry
AutoCal DIN Automatic calibration with DIN buffer
solutions
AutoCal TEC Automatic calibration with WTW technical
buffer solutions
Cal Calibration
Cd... Calibration with DIN buffer solutions
(acc. to DIN 19 266)
ConCal Conventional one/two point calibration
Ct... Calibration with WTW technical buffer
solutions
disp Display
Displays the data storage on the screen
E3 Error message (see WHAT TO DO IF ...)
InI Initialization
Resets individual basic functions to
the status they had on delivery
LoBat Low Battery
Batteries are almost empty
mV Voltage unit
mV/pH Unit of the electrode slope
OFL Overflow
Display range exceeded
pH pH value
RCL Recall
memory dump

134
 Lists

S Slope
SELV Safety Extra Low Voltage
SEr Serial interface
Output of the data storage on the RS 232
or on the internal printer
SLO Slope
Slope setting on calibration
Sto Store
Memory
TP Temperature probe
Temperature measurement active
UASY Asymmetry potential
°C Temperature unit, °Celsius
°F Temperature unit, Fahrenheit

135
Lists

Glossary

Asymmetry Zero point of a pH electrode.

Resolution Number of decimal places that appear for a measured val-

ue.

AutoRead Monitors the electrode drift and releases the measured val-
ue only after the stability criterion has been reached. In this
way, this procedure ensures the highest degree of precision
and reproducibility.

Baud rate Transmission rate in bits/s.

Diaphragm Contact point between the reference electrolytic solution

and the sample.

Drift control See AUTOREAD.

MultiCal® Group term for the various WTW calibration procedures

used for automatic calibration in buffer solutions.

Test sample Sample to be measured (can be liquid or solid).

Test solution Stable solution with a precisely known Redox voltage.

Buffer solution Stable solution with a precisely known pH value.

Redox voltage Potentiometric quantity.

Slope Specifies the voltage change per pH unit.

136
 Lists

Index

A interval
analog output 114 calibration 94
asymmetry 91 data transmission 112
authorized use 80 storing 106
AutoCal DIN 91, 98
AutoCal TEC 91, 95 K
AutoRead 88 keys 76

B L
battery compartment 123 LoBat 127
baud rate
setting 117 M
measuring precision 94
C
calibrating 91 O
calibration operational safety 80
evaluation 93
P
interval 94
place of the instrument 85
procedures 91
plug-in power supply
protocol 92
connecting 84
ConCal 91, 101
printing
condition on delivery 121
calibration protocol 92
D measured values 90
data record 104 printing measured values 90
data transmission (interval) 113
R
date
Redox electrode 89
setting 83, 119
Redox voltage 89
display 77
remote control 116
drift control 88
replacing the batteries 123
E reset 121
energy saving feature 85 RS232 interface 115
error messages 125
S
I safety 79
initial commissioning 83 safety precautions 79
initialize 121 scope of delivery 83

137
Lists

single-point calibration 91
ConCal 103
slope 91
sockets 77

T
temperature probe 87
three-point calibration 91
AutoCal DIN 100
AutoCal TEC 97
time
setting 83, 119
two-point calibration 91
AutoCal DIN 99
AutoCal TEC 96
ConCal 101

138
 Appendix

9 Appendix

139
Appendix

Note
If you need further informationen or application notes you
can ask for:
l Application reports
l Primers
l Safety data sheets.

You can find information on available literature in the WTW

catalog, LABORATORY AND FIELD INSTRUMENTATION or via the
Internet.

140