8 April Shift 1
8 April Shift 1
Please read the instructions carefully. You are allotted 5 minutes specifically for this
purpose.
Important Instructions:
1. The test is of 3 hours duration.
2. This test paper consists of 90 questions. Each subject (PCM) has 30 questions. The
maximum marks are 300.
3. This question paper contains Three Parts. Part-A is Physics, Part-B is Chemistry and
Part-C is Mathematics. Each part has only two sections: Section-A and Section-B.
4. Section – A : Attempt all questions.
6. Section-A (01 – 20) contains 20 multiple choice questions which have only one correct
answer. Each question carries +4 marks for correct answer and –1 mark for wrong
answer.
7. Section-B (1 – 10) contains 10 Numerical based questions. The answer to each question
is rounded off to the nearest integer value. Each question carries +4 marks for correct
answer and –1 mark for wrong answer.
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JEE-MAIN-2023 (8th April-First Shift)-PCM-2
PART – A (PHYSICS)
SECTION - A
(One Options Correct Type)
This section contains 20 multiple choice questions. Each question has four choices (A), (B), (C) and
(D), out of which ONLY ONE option is correct.
1
Q1. Dimension of should be equal to
0 0
(A) L2 / T 2 (B) L/T
(C) T/L (D) T 2 / L2
Q3. An air bubble of volume 1cm3 rises from the bottom of a lake 40m deep to the surface at a
temperature of 12 C. The atmospheric pressure is 1 105 Pa, the density of water is 1000 kg/m 3
and g = 10 m/s2. There is no difference of the temperature of water at the depth of 40m and on
the surface. The volume of air bubble when it reaches the surface will be :
(A) 3 cm3 (B) 5 cm3
3
(C) 2 cm (D) 4 cm3
E E
(A) (B)
r=R r r=R r
E E
(C) (D)
r=R r r=R r
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JEE-MAIN-2023 (8th April-First Shift)-PCM-3
Q6. Proton (P) and electron (e) will have same de-Broglie wavelength when the ratio of their
momentum is (assume, mP = 1849 me) :
(A) 43 : 1 (B) 1 : 1849
(C) 1 : 43 (D) 1 : 1
Q7. The weight of a body on the earth is 400N. Then weight of the body when taken to a depth half of
the radius of the earth will be :
(A) Zero (B) 200 N
(C) 100 N (D) 300 N
Q8. An aluminium rod with Young’s modulus Y 7.0 1010 N / m2 undergoes elastic strain of 0.04%.
The energy per unit volume stored in the rod in SI unit is :
(A) 8400 (B) 11200
(C) 2800 (D) 5600
A
Q9. For a nucleus X having mass number A and atomic number Z
z
A. The surface energy per nucleon bs a1A 2 / 3 .
Z Z 1
B. The Coulomb contribution to the binding energy bc a2
A 4/ 3
C. The volume energy bv a3 A
D. Decrease in the binding energy is proportional to surface area.
E. While estimating the surface energy, it is assumed that each nucleon interacts with 12
nucleons. ( a1 , a2 , and a3 are constants)
Choose the most appropriate answer from the options given below :
(A) B, C only (B) C, D only
(C) B, C, E only (D) A, B, C, D only
B
0 1 2 3 4
t
A
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JEE-MAIN-2023 (8th April-First Shift)-PCM-4
(A) (B) 0
0
1 2 3 4 1 2 3 4
t t
(C) 0 (D) 0
1 2 3 4 1 2 3 4
t t
Q11. A charge particle moving in magnetic field B, has the components of velocity along B as well as
perpendicular to B. The path of the charge particle will be
(A) helical path with axis along magnetic field B
(B) circular path
(C) helical path with the axis perpendicular to the direction of magnetic filed B
(D) straight along the direction of magnetic field B
Q12. A cylindrical wire of mass 0.4 0.01 g has length 8 0.04 cm and radius 6 0.03 mm. The
maximum error in its density will be :
(A) 3.5% (B) 5%
(C) 4% (D) 1%
Q13. The engine of a train moving with speed 10 ms-1 towards a platform sounds a whistle at
frequency 400Hz. The frequency heard by a passenger inside the train is : (neglect air speed.
Speed of sound in air = 330 ms-1)
(A) 388 Hz (B) 400 Hz
(C) 200 Hz (D) 412 Hz
Q14. Two projectiles A and B thrown with initial velocities of 40 m/s and 60m/s at angles 30 and
60 with the horizontal respectively. The ratio of their ranges respectively is
g 10m / s
2
(A) 4 : 9 (B) 1 : 1
(C) 3 : 2 (D) 2 : 3
Q15.
At any instant the velocity of a particle of mass 500g is 2t ˆi 3t 2 ˆj ms1. If the force acting on the
particle at t 1s is ˆi x ˆj N. Then the value of x will be :
(A) 6 (B) 3
(C) 4 (D) 2
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JEE-MAIN-2023 (8th April-First Shift)-PCM-5
Q17. A TV transmitting antenna is 98m high and the receiving antenna is at the ground level. If the
radius of the earth is 6400 km, the surface area covered by the transmitting antenna is
approximately :
(A) 3942 km2 (B) 4868 km2
2
(C) 1240 km (D) 1549 km2
A
Q18. Two forces having magnitude A and are perpendicular to each other. The magnitude of
2
their resultant is :
5A 5A
(A) (B)
2 2
5A 5A 2
(C) (D)
4 2
Q20. Certain galvanometer have a fixed core made of non magnetic metallic material.
The function of this metallic material is
(A) to make the magnetic field radial
(B) to bring the coil to rest quickly
(C) to produce large deflecting torque on the coil
(D) to oscillate the coil in magnetic field for longer period of time
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JEE-MAIN-2023 (8th April-First Shift)-PCM-6
SECTION - B
(Numerical Answer Type)
This section contains 10 Numerical based questions. The answer to each question is rounded off to the
nearest integer value.
Q1. An electric dipole of dipole moment is 6.0 10 6 Cm placed in a uniform electric field of
1.5 103 NC 1 in such a way that dipole moment is along electric field. The work done in rotating
by 180 in this field will be ________mJ.
Q2. The momentum of a body is increased by 50%. The percentage increase in the kinetic energy of
the body is __________%.
Q3. The magnetic intensity at the centre of a long current carrying solenoid is found to be
1.6 103 Am1. If the number of turns is 8 per cm, then the current flowing through the solenoid is
_________A.
Q4. Two vertical parallel mirrors. A and B are separated by 10cm. A point
object O is placed at a distance of 2cm from mirror A. The distance
of the second nearest image behind mirror A form the mirror A
is________ cm. 2cm
O
10cm
Q5. The moment of inertia of a semicircular ring about an axis, passing through the centre and
1
perpendicular to the plane of ring, is MR2 , Where R is the radius and M is the mass of the
x
semicircular ring. The value of x will be _________.
Q6. An organ pipe 40cm long is open at both ends. The speed of sound in air is 360ms 1. The
frequency of the second harmonic is _________Hz.
Q7. A nucleus with a mass number 242 and binding energy per nucleon as 7.6MeV breaks into two
fragment each with mass number 121. If each fragment nucleus has binding energy per nucleon
as 8.1 MeV, the total gain binding energy is ________MeV.
Q9. An air bubble of diameter 6mm rises steadily through a solution of density 1750kg/m 3 at the rate
of 0.35cm/s. The co-efficient of viscosity of the solution (neglect density of air) is _________Pas
(given, g = 10ms-2).
Q10. A current of 2 A flows through a wire of cross-sectional area 25.0mm 2. The number of free
28 -6 -1
electrons in a cubic meter are 2.0 × 10 . The drift velocity of the electrons is ________× 10 ms
-19
(given, charge on electron = 1.6 × 10 C).
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JEE-MAIN-2023 (8th April-First Shift)-PCM-7
PART – B (CHEMISTRY)
SECTION - A
(One Options Correct Type)
This section contains 20 multiple choice questions. Each question has four choices (A), (B), (C) and
(D), out of which ONLY ONE option is correct.
Q2. The correct order of spin only magnetic moments for the following complex ions is
3 3 3 2
(A) Fe CN6 Mn CN6 CoF6 MnBr4
2 3 3 3
(B) MnBr4 CoF6 Fe CN6 Mn CN6
3 2 3 3
(C) CoF6 MnBr4 Fe CN6 Mn CN6
3 3 2 3
(D) Fe CN6 CoF6 MnBr4 Mn CN6
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JEE-MAIN-2023 (8th April-First Shift)-PCM-8
Q7. Choose the halogen which is most reactive towards S N1 reaction in the given compounds
(A, B, C & D)
Br(a)
B. I(a) I(b)
A.
Br(b)
C. Br(b)
Br(b) D.
Br(a) Br(a)
Me
(A) A Br(b) ;B I(a) ;C Br(a) ;D Br(a) (B) A Br(a) ;B I(a);C Br(b);D Br(a)
(C) A Br(b) ;B I(b);C Br(b) ;D Br(b) (D) A Br(a) ;B I(a);C Br(a) ;D Br(a)
B. HBF4 , II. CN
C. Cu,HCl III.
N N NH2
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JEE-MAIN-2023 (8th April-First Shift)-PCM-9
Q9. In chromyl chloride, the number of d-electrons present on chromium is same as in (Given at no.
of Ti: 22,V: 23, Cr:24, Mn:25, Fe:26)
(A) Fe(III) (B) Ti(III)
(C) Mn(VII) (D) V(IV)
(A) x (B) x
log
m m
constatnt
p log p
(C) x (D) x
m m
constant
c p1/n
Choose the correct answer from the options given below;
(A) A, B only (B) A,C,D only
(C) A,B, D only (D) B, C, D only
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JEE-MAIN-2023 (8th April-First Shift)-PCM-10
Q15. Which of the following complex is octahedral diamagnetic and the most stable?
(A) Na3[CoCl6] (B) K3[Co(CN)6]
(C) [Ni(NH3)6]Cl2 (D) [Co(H2O)6]Cl2
NH2
B. Neutral FeCl3 solution II.
CHO
C. Alkaline chloroform solution III.
OH
Potassium iodide and
D. IV.
sodium hypochlorite
Q18. Given below are two statements: One is labelled as Assertion A and the other is labelled as
Reason R.
Assertion A: Butan -1- ol has higher boiling point than ethoxyethane.
Reason R: Extensive hydrogen bonding leads to stronger association of molecules.
In the light of the above statements, choose the correct answer from the options given below:
(A) A is false but R is true
(B) Both A and R are true but R is not the correct explanation of A
(C) A is the true but R is false
(D) Both A and R are true and R is the correct explanation of A
Q19. Which of the following metals can be extracted through alkali leaching technique?
(A) Cu (B) Pb
(C) Sn (D) Au
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JEE-MAIN-2023 (8th April-First Shift)-PCM-11
SECTION - B
(Numerical Answer Type)
This section contains 10 Numerical based questions. The answer to each question is rounded off to the
nearest integer value.
Q1. Molar mass of the hydrocarbon (X) which on ozonolysis consumes one mole of O3 per mole of
(X) one mole each of ethanal and propanone is ___________ g mol1(Molar mass of C: 12g mol
1
, H= 1g mol1)
Q2. The number of following factors which affect the percent covalent character of the ionic bond
is____________.
(A) Polarising power of cation
(B) Extent of distortion of anion
(C) Polarisability of the anion
(D) Polarising power of anion
Q3. The vapour pressure vs. temperature curve for a solution solvent system is shown below.
1atm
Vapour Pressure
80 81 82 83
Temperature
o
( C)
The boiling point of the solvent is____________ oC.
Q5. The titration curve of weak acid vs strong base with phenolphthalein as indicator) is
shown below. The K phenolphthalein = 4 1010,
Given log 2 = 0.3
12
10
8
pH
0
5 10 15 20 25
VNaOH
The number of following statement/s which is / are correct about phenolphthalein is ____.
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JEE-MAIN-2023 (8th April-First Shift)-PCM-12
A. It can be used as an indicator for the titration of weak acid with weak base.
B. It begins to change colour at pH = 8.4
C. It is a weak organic base
D. It is colourless in acidic medium
Q6. 0.5 g of an organic compound (X) with 60% carbon will produce__________101 g of CO2 on
complete combustion.
Q7. The number of following statement/s which is/ are incorrect is_____________.
(A) Line emission spectra are used to study the electronic structure
(B) The emission spectra of atoms in the gas phase show a continuous spread of wavelength
from red to violet
(C) An absorption spectrum is like the photographic negative of an emission spectrum
(D) The element helium was discovered in the sun by spectroscopic method
Q8. When a 60 W electric heater is immersed in a gas for 100s in a constant volume container with
adiabatic walls, the temperature of the gas rises by 5oC. The heat capacity of the given gas is
_____JK1(Nearest integer)
Q10.
P=2 atm P=4atm P=3atm
V= 2L V= 3L V= 4L
CH4(g) CO2(g) Ne(g)
Three bulbs are filled with CH4, CO2 and Ne as shown in the picture. The bulbs are connected
through pipes of zero volume. When the stopcocks are opened and the temperature is kept
constant throughout, the pressure of the system is found to be______ atm. (Nearest integer)
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JEE-MAIN-2023 (8th April-First Shift)-PCM-13
PART – C (MATHEMATICS)
SECTION - A
(One Options Correct Type)
This section contains 20 multiple choice questions. Each question has four choices (A), (B), (C) and
(D), out of which ONLY ONE option is correct.
a b c is equal to
(A) 18 (B) 22
(C) 20 (D) 24
x 1
Q3. Let I x 2
dx, x 0 . If lim I x 0 , then I 1 is equal to
x 1 x ex x
e1 e2
(A) loge e 1 (B) loge e 1
e2 e1
e1 e2
(C) loge e 1 (D) loge e 1
e2 e1
n
1 2 .... K n
Q4. Let SK
K
and S
j1
2
j
A
Bn2 Cn D , where A,B,C,D N and A has least value.
Then
(A) A + B + C + D is divisible by 5 (B) A + C + D is not divisible by B
(C) A + B is divisible by D (D) A B 5 D C
Q5. If for z i, z 2 z 4 1 i , then and are the roots of the equation
(A) x 2 x 12 0 (B) x 2 3x 4 0
(C) x 2 2x 3 0 (D) x 2 7x 12 0
Q6. In a bolt factory, machines A, B and C manufacture respectively 20%, 30% and 50% of the total
bolts. Of their output 3, 4 and 2 percent are respectively defective bolts. A bolt is drawn at random
from the product. If the bolt drawn is found the defective, then he probability that it is
manufactured by the machine C is
5 9
(A) (B)
14 28
2 3
(C) (D)
7 7
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JEE-MAIN-2023 (8th April-First Shift)-PCM-14
Q7. Let R be the focus of the parabola y 2 20x and the line y mx c intersect the parabola at two
points P and Q. Let the point G 10, 10 be the centroid of the triangle PQR. If c m 6 , then
2
PQ is
(A) 296 (B) 346
(C) 317 (D) 325
9ˆ ˆ
Q8. If the points with position vectors ˆi 10ˆj 13k,
ˆ 6iˆ 11jˆ 11 k,
ˆ i j 8kˆ are collinear, then
2
2
19 6 is equal to
(A) 49 (B) 36
(C) 16 (D) 25
Q10. Let the number of elements in sets A and B be five and two respectively. Then the number of
subsets of A x B each having at least 3 and at most 6 elements is :
(A) 792 (B) 782
(C) 752 (D) 772
n
Q11. If the coefficients of three consecutive terms in the expansion of 1 x are in the ratio 1 : 5 : 20,
then the coefficient of the fourth terms is
(A) 1827 (B) 5481
(C) 3654 (D) 2436
Q12. The number of ways, in which 5 girls and 7 boys can be seated at a round table so that no two
girls sit together, is
2 2
(A) 7 720 (B) 7 360
2
(C) 126 5! (D) 720
Q13. The number of arrangements of the letters of the word “INDEPENDENCE” in which all the vowels
always occur together is
(A) 14800 (B) 16800
(C) 18000 (D) 33600
1 cos2 3x sin3 4x
Q14. lim is equal to………
x 0 cos3 4x
5
loge 2x 1
(A) 9 (B) 18
(C) 15 (D) 24
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JEE-MAIN-2023 (8th April-First Shift)-PCM-15
Q16. Negation of p q q p is
(A) q p (B) p q
(C) p q (D) q p
2 1 0
Let A 1 2 1 . If adj adj adj 2A 16 , then n is equal to
n
Q17.
0 1 2
(A) 12 (B) 9
(C) 10 (D) 8
3 1
1 1 a b
Q19. Let P 2 2
,A and Q PAPT . If P T Q2007 P , then 2a b 3c 4d equal
1 3 0 1 c d
2 2
to
(A) 2005 (B) 2007
(C) 2004 (D) 2006
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JEE-MAIN-2023 (8th April-First Shift)-PCM-16
SECTION - B
(Numerical Answer Type)
This section contains 10 Numerical based questions. The answer to each question is rounded off to the
nearest integer value.
n3
Q1. If a is the greatest term in the sequence an 4
, n 1, 2, 3,...., then is equal to……..
n 147
Q3. Consider a circle C1 : x 2 y 2 4x 2y 5 . Let its mirror image in the line y 2x 1be
another circle C 2 : 5x 2 5y 2 10fx 10gy 36 0 . Let r be the radius of C2 . Then r is equal
to………
Q4. Let A 0, 3, 4, 6, 7, 8, 9, 10 and R be the relation defined on A such that
R x,y A A : x y is odd positive int eger or x y 2 . The minimum symmetric relation, is
equal to………..
5
Q5. Let 1, 2 be the values of for which the points , 1, and 2, 0, 1 are at equal distance
2
from the plane 2x 3y 6z 7 0 . If 1 2 , then the distance of the point 1 2 , 2 , 1 from
x 5 y 1 z 7
the line is……….
1 2 2
Q6. The largest natural number n such that 3n divides 66! is…………
Q7. Let the mean and variance of 8 numbers x, y, 10, 12, 6, 12, 4, 8 be 9 and 9.25 respectively. If x > y,
then 3x 2y is equal to………
5 6
2
Q8. Let t denote the greatest integer t . Then
8 cos ec x 5 cot x dx is equal to………..
/6
Q9.
Let a 6iˆ 9ˆj 12k, ˆ b ˆi 11jˆ 2kˆ and c be vectors such that a c a b . If a c 12 ,
c ˆi 2ˆj kˆ 5 , then c ˆi ˆj kˆ is equal to………
7
1
Q10. Let t denote the greatest integer t . If the constant term in the expansion of 3x2 5 is
2x
, then is equal to……..
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JEE-MAIN-2023 (8th April-First Shift)-PCM-17
FIITJEE
KEYS to JEE (Main)-2023
PART – A (PHYSICS)
1. A 2. D 3. B 4. A
5. A 6. D 7. B 8. D
9. B 10. B 11. A 12. C
13. B 14. A 15. B 16. D
17. A 18 A 19. D 20. B
SECTION - B
1. 18 2. 125 3. 2 4. 18
5. 1 6. 900 7. 121 8. 9
9. 10 10. 25
PART – B (CHEMISTRY)
SECTION - A
1. A 2. A 3. C 4. B
5. A 6. DROP 7. B 8. C
9. C 10. D 11. D 12. C
13. C 14. D 15. B 16. C
17. A 18. D 19. C 20. A
SECTION – B
1. 70 2. 3 3. 82 4. 2
5. 2 6. 11 7. 1 8. 1200
9. 11 10. 3
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JEE-MAIN-2023 (8th April-First Shift)-PCM-18
PART – C (MATHEMATICS)
SECTION - A
1. D 2. B 3. D 4. C
5. D 6. A 7. D 8. B
9. A 10. A 11. C 12. C
13. B 14. B 15. A 16. D
17. C 18 C 19. A 20. C
SECTION - B
1. 5 2. 3 3. 2 4. 19
5. 9 6. 31 7. 25 8. 14
9. 11 10. 1275
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JEE-MAIN-2023 (8th April-First Shift)-PCM-19
FIITJEE
Solutions to JEE (Main)-2023
PART – A (PHYSICS)
SECTION – A
1
Sol1. C2
0 0
1 L2
Dimension of = Dimension of C2 2
0 0 T
Sol3. 1000kg / m3 V2 , T2 T1
P1v1 P2 v 2 P2 P0 1 105 Pa.
T1 T2
1000kg / m3 40 cm
P
v 2 1 v1
P2
v i 1cm3
5 105 T1 12 C
5
1cm3
1 10 P0 1 105 Ra
5cm3 P1 P0 gh 1 105 1000 10 40 5 105 Ra
k
Sol4. Er r ; r R
R3 R
k r
Er 2 ; r R
r
h
Sol6. P e Momentum P Momentum e
P
R
Sol7. g g 1
R g/ 2
d
2 2R
W Surface
W dR 200N
2 2
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JEE-MAIN-2023 (8th April-First Shift)-PCM-20
4
Sol8. Y 7 1010 N / m2 . Strain 0.04%
10000
1
Energy per unit volume Stress Strain
2
1 2
Y Strain
2
2
1 4
7 1010
2 10000
3
56 100 5600 J/m .
A 2Z 2 Z Z 1
Sol9. EB a v A as A 2/3 a A 1/3
ac A,Z
A A1/ 3
Volume Surface Asymmetry Coulomb Pairing
Term Term Term Term Term
So, most appropriate options are C and D
Sol10. Y A A B B AA
A
A A B B
A A B B Y
A B
B
BB
A
o o
0 t
1 2 3 4
B
o o
0 t
1 2 3 4
A B Y
=
A
+
B
0 0 0
0 1 1
1 0 1
1 1 1
o
t
0 1 2 3 4
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JEE-MAIN-2023 (8th April-First Shift)-PCM-21
Sol11. Helical path with axis along B V sin V
B
V cos
Sol15. m 500 g
v 2t ˆi 3t 2 ˆj m / s
dv
a 2 ˆi 6t ˆj m / s 2
dt
1 1
F ma a 2iˆ 6t ˆj N
2 2
1
at t 1sec, F 2iˆ 6 ˆj N ˆi 3ˆj
2
x3
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JEE-MAIN-2023 (8th April-First Shift)-PCM-22
4 4 1 B
Sol16. i A 6
6 2 8 16 4 C2
1 A D
Vc1 i 6 2 8 2v G
4
1 C1 8
Vc 2 i 2 8 10 2.5 A i
4 C
VC1 2 4
VC2 2.5 5 4v
Sol17. h 98m
2Rh
h x
Area 2 2Rh Receiver
3
2 6400 98 10
Transmitter
3942km2
R= 6400 km
2
A 5
Sol18. R A 2 A
2 2
A/2
18 10 3 J 18mJ
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JEE-MAIN-2023 (8th April-First Shift)-PCM-23
2
P
P2 P 9 P2
2
Sol2. Ki ;
2m 2m 4 2m
2
9 P
1
k 4 2m
100 100
k P2
2m
5
100 125%
4
Sol4. 18 A B
18cm 8cm
I2 2cm
I1 O I'1
10cm
1
Sol5. I MR2 MR2 x 1
x
I
Sol6. 40cm
u 360m / s
u
0
2
Second Harmonic frequency,
2u u 360 100
20 900Hz.
2 40
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JEE-MAIN-2023 (8th April-First Shift)-PCM-24
Sol8. C 1.2 F
Q 2.7C C L=75mH
2
Q 1
Li2
2C 2
Q2 Q 2.7 106
imax
LC LC 75 10 3 1.2 10 6
2.7 10 6
90 10 9
2.7 106
3 104
.9 102 A
9mA
Sol10. J neVd i = 2A
j 2
Vd A = 25mm
2
ne 25 106 2 1028 1.6 10 19 28
ne = 2 ×10
2 10 3
25 10 6 m / s
80
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JEE-MAIN-2023 (8th April-First Shift)-PCM-25
PART – B (CHEMISTRY)
SECTION – A
Sol1.
COOH COOH
(I) LiBH4 / EtOH
Sol2.
2 3
d sp
2 3
d sp
3 2
sp d
3
sp
CN strong field ligand F & Br are weak field ligand
n N 2 BM
Sol3. Lithium & Magnesium form oxide & not superoxide due to small size, ionic size of Li + > ionic size
of Mg+2.
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JEE-MAIN-2023 (8th April-First Shift)-PCM-26
Sol7.
(B)
I Allylic carbocation is more stable
(C)
Non bridged tertiary carbocation are more stable
Br
Sol8.
OH
N NCl H NH2 N N NH2 + HCl
Coupling reaction
N NCl HBF 4 N NBF 4 F + BF 3 +N 2
Cu / HCl
N NCl Cl + N2 + CuCl
Gatterman reaction
CuCN / KCN
N NCl CN
Sol9. CrO2Cl2
x+4x(2) + 2x(1)=0
x6=0
x=6
5 1 0
Cr(O) 3d 4s Cr(VI) [Ar]3d
5
Fe(III) [Ar]3d
Ti(III) [Ar]3d1
Mn(VII) [Ar]3d0
1
Sol10. H2 H e (Anode)
2
AgCl(s) e Ag (s) Cl (cathode)
Cell Pt / H2 (g) / HCl(s) | AgCl(s) / Ag
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JEE-MAIN-2023 (8th April-First Shift)-PCM-27
x
Sol12. p1/n
m
x
kp1/n
m
x 1
log logk logp
m n
Graphically represented by A, B & D only
Co
Sol14. CO 2H2 CH3 OH
Sol15. K 3 Co CN 6 Co 3 3d6
3
Co CN 6 CN strong field ligand
2 3
d sp
All the electrons are paired up hence diamagnetic.
Sol17. Alkaline solution of copper sulphate and sodium citrate (test of aldehyde)
CHO
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JEE-MAIN-2023 (8th April-First Shift)-PCM-28
Sol20. Br = 3.0
C = 2.5
At = 2.2
P = 2.1
SECTION – B
H CH3 CH3
| | |
Sol2. According to Fajan’s rule a, b and c are the factor on which percent covalent character of the
ionic bond depend.
Solution
1atm
VP
o
Temperature 82 C
60
Sol6. Mass of C 0.5 0.3 gm
100
0.3
Moles of C
12
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JEE-MAIN-2023 (8th April-First Shift)-PCM-29
0.3
Moles of CO2
12
0.3
Mass of CO2 44
12
1.1 gm
11 101 gm
1
Sol9. XeF4 SbF5 XeF3 SbFe
2
XeFm n SbFy
m 3 , n 1, y 6 z 1
m n y z 3 1 6 1 11
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JEE-MAIN-2023 (8th April-First Shift)-PCM-30
PART – C (MATHEMATICS)
SECTION – A
1 1
2 sin x cos x 1
Sol1. f x 2 2
1 1
2 sin x cos x
2 2
sin x 1
f x 4
sin x
4
1
f 'x
1 cos x
4
sin x
4
f " x 2
1 cos x
4
7 sin 2 1 1
f 1
4 sin
3 1
2
3
sin
7 2 1
f " 2
1
4 3 12
1 cos
2
7 7
f f " 1
4 4
ˆ ˆ ˆ
Sol2. D.R’s of line n1 5i 7 j 3k
D.R’s of normal of second plane
n2 5iˆ 2jˆ 3kˆ
n1 n2 27iˆ 30ˆj 25kˆ
11 14
0, 5 , 5
A point on required plane is
x 1
x 1 x e 2
dx; x 0
Sol3.
x
x x
let 1 x e t t 1 x e
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JEE-MAIN-2023 (8th April-First Shift)-PCM-31
dt
x ex ex
dx
dt
x 1 dx x
e
dt
t 1 t 2
t t 1
t t 1 dt
2
1 1
t t 1 dt t 2
dt
t t 1 1
dt dt
t t 1 t2
1
n t 1 n t 1 6
t
1
n x e x n 1 x e x 1 x ex
c
x ex 1
n x
c
1 x e 1 x ex
lim I x 0 C
x
e 1
I 1 n
1 e 1 e
1
I 1 ne n 1 e
1 e
e2
n 1 e
e 1
k 1
Sk
Sol4. 2
k 2 1 2k
Sk2
4
n
1 n n 1 2n 1 2 n n 1
S2j n
j1 4 6 2
n 2n2 3n 1
n 2
4 6
n 2n2 9n 13
4 6
n
2n2 9n 13
24
A 24, B 2, C 9, D 13
5 D C 20
A + B = 26,
A + B + C = 35 A + B + D = 39
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JEE-MAIN-2023 (8th April-First Shift)-PCM-32
z 2 i 2 i 4 4i
Sol5.
2
2 2 4 i 4
4 0 4
2 2
2 16 4
4 4
1
3
4
Sum of roots = 7
Product of roots = 12
Sol6.
2 3 5
PA P B P C
10 , 10 , 10
Let defective be D
D 3
P
A
100
,
D 4
P
B 100
D 2
P
C
100
5 2
P E 10 100
2 3 3 4 5 2
10 100 10 100 10 100
10
28
5
14
y 2 20x y
Sol7.
y mx c
y c x1, y1
y 2 20
m P
20y 20c
y2
m m
R
20y 20c x
y2 0 5, 0
m m ………..(i)
20
y1 y 2 Q
m
0 y1 y 2 x2 , y2
10
Now, 3
y1 y2 30
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JEE-MAIN-2023 (8th April-First Shift)-PCM-33
20
30
m
20
m
30
2
m
3
c m 6 (given)
2
c 6
3
20
c
3
Now from equation (i)
20
20
2
y 30y 3 0
2
3
y 2 30y 200 0
y 10 , y 20
P 5,10 Q 20, 20
,
PQ 2 325
9
, , 8
Sol8.
,10,13 ; 6,11,11 , 2
6 1 2
3 11 19
2
3
6
19 , 19 22 2
117
19 ; 2 41
19 117 , 123
2 2
19 6 117 123 36
a b n n
1 2
Sol9. Shortest distance =
n1 n2
a 4, 2, 3 n1 4,5,3
b 1,3,4 n2 3,4,2
i j k
n1 n2 4 5 3
3 4 2
2 i j 1 kˆ 1 2,1,1
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JEE-MAIN-2023 (8th April-First Shift)-PCM-34
6 5 7
d 3 6
6
n A B 10
Sol10.
10 10 10 10
C3 C4 C5 C6 792
n n
Cr Cr 1
n
5 n
4
Cr 1 Cr
Sol11. ;
nr 1 n r 1 1
5 4
r ; r 1
n 6r 1 ; n 5r 4
n 29 , r = 5
29
th C3
Coefficient of 4 term =
= 3654.
7
Sol12. 6! C 5 5!
720 21 150
2
126 5!
8! 6!
16800
Sol13. 3!2! 4!
1 cos2 3x sin3 4x
lim
x 0 cos3 4x
loge 2x 15
Sol14.
3
sin 4x 5
1 cos 3x 9x 2
2 4x 64 x
lim
x 0 9x 2 cos3 4x 5
n 1 2x 5
32 x
2x
1 9 1 64
lim 2 18
x2
2 1 1 32
3
Sol15. x bx c 0
1 , 1
3 b c 0
1 b c 0
c b 1
c
1 c c 1
b=0
x3 1 0
2
1 , ,
b3 2c 3 3 3 63 8 3
0 2 3 6 8 19
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JEE-MAIN-2023 (8th April-First Shift)-PCM-35
Sol16.
p q q p
p q q p
p q q p
p q q p
q p
A 4
Sol17.
adj adj adj 2A
3
n 1
2A
8
2A
8
2 3
A 16n
8
2 3
22 16n
240 16n
1610 16n
n = 10
Sol18.
y x2
1, 7 1,7
y=7
2, 4 2,4
2 1 1 2 x
8 x2
1 2 2
A 2 7 x 2 dx 8 x 2 dx x 2 dx
0 1 1
A 20
T
Sol19. Q PAP
PT Q2007 P
PT Q2006 Q P
P T Q2006 PA P T P
PT Q2006PA
A 2007
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JEE-MAIN-2023 (8th April-First Shift)-PCM-36
1 2007
A 2007
0 1
a 1, b 2007, c 0, d 1
2a b 3b 4d 2005
f ' x
x 4 147 3x 2 x3 4x 3
2
x 4
147
f 'x 0
x 21
f max of f 4 or f 5
f 4 0.158, f 5 0.161
a5
dy 1 y
Sol2.
dx x 2xnx
dy y 1
dx 22n x x
1
I.F. e 2xnx
dx
1
I.F = nx 2
y I.F n I.F dx
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JEE-MAIN-2023 (8th April-First Shift)-PCM-37
nx
y nx dx
x
3
2
y nx nx 2 c
3
4
At point e,
3
y 2
c
3 3
2
c
3
3
2 2
y nx nx 2
3 3
At point e4 ,
3
Sol3. x 2 y 2 4x 2y 5 0
C1 2, 1 , r1
2x y 1 0
Image of 2, 1
x 2 y 1 2 4 1 1
2 1 5
x 2 y 1 8
2 1 5
16 6
x 2
5 5
8 13
y 1
5 5
36
x 2 y 2 2fx 2gy 0
5
c 2 f,g
36
r2 f 2 g2
5
36
f 2 g2
5
6 13
f ,g
5 5
36 169 36
25 25 5
36 169 36
25
1, r = 1
r 2
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JEE-MAIN-2023 (8th April-First Shift)-PCM-38
Odd No. – 3, 7, 9
Even No. – 0, 4, 6, 8, 10
3
C1 5 C1 15
Difference = 2
6, 4 , 8,6 10, 8 , 9, 7
Total = 15 + 4 = 19.
Sol5. 2x 3y 6z 7 0
5
2 , 1, , 2, 0, 1
5 3 6 7
d1
7
4 6 7
d2
7
Now,
15 6 3
15 6 3 or 15 6 3
1 3 or 2 2 as 1 2
P 1 2 , 2 , 3
P 1, 2, 3
x 5 y 1 z 7
distance of point P 1, 2, 3 from the line
1 2 2
18i 18j 9kˆ
d 9
3
x y 52
Sol7. 9
8
x y 20
For variance
x 9, y 9, 3, 3, 1, 5, 1, 3
x0
2 2
x 9 y 9 54 2
8
0 9.25
2 2
x 9 11 x 20
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JEE-MAIN-2023 (8th April-First Shift)-PCM-39
x 7, 13
y 13, 7
3x 2y 3 13 2 7 25
5 /6
2
Sol8. I
/ 6
8 cos ecx 5 cot x dx
5 /6 5 /6
2
8 cosecx dx 5 cot x dx
/ 6
/6
I1 I2
5 /6
I1 8 dx
/6
16
I1
3
5 /6
I2 5 cot x dx
/ 6
1 4
I2
2 6 3
2 16 5
I
n 3 3
2 21 42
n 3 3
42
14
3
Sol9. a c a b
a c b 0
a parallel c b
a c b
6, 9, 12 x , y 11 , z 2
x y 11 z 2
2 3 4
4y 44 3z 6
4y 3z 50
6x 9y 12z 12
2x 3y 4z 4
2x 4y 2z 10
y 2z 14
y 2, z 14, x 23
c 23, 2, 14
c 1,1,1 23 2 14 11
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JEE-MAIN-2023 (8th April-First Shift)-PCM-40
7
1
Sol10. 3x2 5
2x
r
7 r 1
Tr 1 7 Cr 3x 2 5
2x
r2
T3 1275.75
1275
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