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com

NRT/KS/19/2171
Bachelor of Science (B.Sc.) Semester—VI Examination
CH-601 : INORGANIC CHEMISTRY
Compulsory Paper—1
(Chemistry)
Time : Three Hours] [Maximum Marks : 50
N.B. :— (1) All five questions are compulsory and carry equal marks.
(2) Write equations and draw diagrams wherever necessary.
1. (A) What are the postulates of CFT ? How does the ‘d’ orbitals splitting of octahedral complexes
takes place ? Explain with suitable example. 5
(B) State and explain the following with examples :
(i) Laporte selection rule
(ii) Spin selection rule and
(iii) Hole formalism principle. 5
OR
(C) On the basis of CFT, explain, why tetrahedral complexes have lower 10 Dq than octahedral
complexes ? 2½
(D) Calculate CFSE for the following :
(i) d7 weak field octahedral and
(ii) d5 tetrahedral. 2½
2H
(E) Discuss the visible absorption spectrum of [Cu(H2O)6] with respect to intensity and width
of band. 2½
(F) Write a note on spectrochemical series. 2½
2. (A) Explain the following using CFT :
(i) [CoF6]3– is paramagnetic, while [Co(NH3)6]3+ is diamagnetic and
(ii) [Ni(CN)4]2– is diamagnetic while [NiCl4]2– is paramagnetic. 5
(B) (i) What is chelate effect ? How does it affect the stability of the complexes ?
(ii) Explain the thermodynamic and kinetic stability of complexes with suitable example.
5
OR
(C) Identify the following configurations which have quenching towards orbital moments :
(i) t2g2
(ii) t2g3eg2
(iii) t2g3
(iv) t2g4eg2. 2½
(D) Describe the method for determination of magnetic susceptibility of metal complex by
Gouy’s method. 2½
(E) Explain why stability constant value decreases in order :
[Cu(trien)]2+ > [Cu(en)2]2+ > [Cu(NH3)4]2+ 2½
(F) Derive relationship between stepwise and overall stability constant. 2½

CLS—865 1 (Contd.)
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3. (A) State Beer-Lambert’s law. Write its mathematical expression. The molar absorptivity of the
solution is 2.5×102 dm3 mol–1 cm–1. If a solution has an absorbance of 0.85 in a cell of
1 cm length. Calculate :
(i) Transmittance and
(ii) Concentration of solution. 5
(B) Define chromatography. Give the principle and technique involved in ascending paper
chromatography. 5
OR
(C) Define the following terms :
(i) Elution
(ii) Retardation factor and
(iii) Mobile phase. 2½
(D) Draw a well labelled schematic diagram of single beam spectrophotometer. 2½
(E) Define ion-exchange capacity. How is ion exchange capacity determined for cation exchange
resin ? 2½
(F) Discuss qualitative applications of photoelectric colorimeter in estimation of Cu(II) as
copper ammonia complex. 2½
4. (A) What do you mean by silicones ? Explain synthesis of straight chain and cross-linked
silicones. 5
(B) (i) Discuss structure and bonding in (NPCl2)3.
(ii) What are poly-phosphazenes ? What is the action of the following on triphosphonitrilic
chloride ?
(a) Alcohol and
(b) Excess of ammonia. 5
OR
(C) Give one method for preparation of silicone resins. Write its two uses. 2½
(D) Write a note on silicone elastomer. 2½
(E) Give uses of phosphonitrilic halides. 2½
(F) What is the action of the following :
(i) Benzene and
(ii) Sodium alkoxide on (NPCl2)3 ? 2½
5. Attempt any ten of the following :
(i) Define degenerate orbitals.
(ii) How does CFSE varies with change in oxidation state of central metal ion ?
(iii) Why is [Ti(H2O)6]3+ purple coloured ?
(iv) Calculate magnetic moment of Cr3+(Z = 24).
(v) Define molar magnetic susceptibility.
(vi) Why are octahedral complexes of Co(III) more stable than Co(II) ?
(vii) Define optical density and transmittance.
(viii) Calculate absorbance if %T is 60%.
(ix) Define solvent extraction technique.
(x) Give the chemical formula of the following silane :
(a) Methyltrichlorosilane
(b) Dimethylsilanol.
(xi) What is RTV and HTV ?
(xii) What do you mean by liquid rubber ? 1×10=10

CLS—865 2 NRT/KS/19/2171

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 NIR/KW/18/2171
Bachelor of Science (B.Sc.) Semester—VI Examination
CH—601 INORGANIC CHEMISTRY
Compulsory Paper—1
(Chemistry)
Time : Three Hours] [Maximum Marks : 50
N.B. :— (i) All five questions are compulsory and carry equal marks.

6
(ii) Write equations and draw diagram wherever necessary.
3
1.
8
(A) Define crystal field splitting energy. Explain splitting of d orbitals in the following complexes on the
basis of CFT :
(i) [Fe(CN6 )]3– and

6
(ii) [Fe(H2 O)6 ]3+. 5

83
(B) Draw absorption spectra of [Ti(H2 O)6 ]3+ and [Cu(H2 O)6 ]2+. Compare them on the basis of :
(i) Position of band and
(ii) Symmetry of absorption band. 5
OR
(C) Explain spin allowed and spin forbidden transition on the basis of spin selection rule with examples.
2½

3 6
(D) Calculate CFSE in terms of ∆t in d4 and d6 tetrahedral complexes. 2½
8metal complexes.
(E) Give limitations of valence bond theory of 2½
(F) What is Jahn Teller distortion ? Give conditions of Jahn Teller distortion with examples.
2½
2. (A) Explain magnetic behaviour of d5 and d7 octahedral complexes in weak and strong crystal field
using energy splitting diagram. 5
(B) (i) What is stepwise and overall stability constants ? How are they correlated ?
(ii) How nature of ligand affects stability of metal complexes ? 5
OR
(C) What is spin only magnetic moment ? Explain orbital contribution to magnetic moment. 2½
(D) Explain which of the following configurations show quenching towards orbital moments ?
(i) t2g3 eg°
(ii) t2g4 eg2
(iii) t2g3 eg2

3 6
(iv) t2g5 eg2
3 6
(v) 8 4
t2g eg . ° 8 2½
(E) Describe Gouy’s method for determination of magnetic susceptibility. 2½
(F) How the composition of Fe – SSA complex is determined by Job’s method ? 2½

BKR—4351 1 (Contd.)
3. (A) State and derive Beer-Lambert’s law. A solution having concentration 1.5 × 10–3 M of a compound
in a cell of path length 2.0 cm shows % T of 65. Calculate molar absorptivity of the solution. 5
(B) Define chromatography. How it is classified ? Discuss the principle and technique involved in paper
chromatography. 5
OR
(C) Draw flowsheet diagram of Single beam photoelectric colorimeter. 2½
(D) Discuss application of colorimetry in estimation of Cu(II) as copper ammonia complex. 2½
(E) What is ion exchange capacity ? How is it determined for anion exchanger ? 2½

3 6
(F) Discuss the principle involved in solvent extraction. 2½
4. (A) 8
What are silicones ? How are cross linked silicones manufactured ? What is the action of :
(i) RMgCl

6
(ii) Alkyl Lithium and

83
(iii) LiAlH4 on silicone ? 5
(B) What are phosphazenes ? Discuss the structure of Triphosphonitrilic chloride. 5
OR
(C) Write a note on silicon resins. Give its three applications. 2½
(D) What are silicon elastomers ? Give its two applications. 2½
(E) What is the action of :
(i) Ammonia and
3 6
(ii) Sodium alkoxide on (NPCl2 )3 ? 8 2½
(F) Give any two methods for preparation of (NPCl2 )4 . 2½
5. Attempt any ten from the following :
(i) Define crystal field stabilization energy.
(ii) State Laporte selection rule.
(iii) Draw crystal field splitting diagram of [Ni(CN)4 ]2– .
(iv) Define kinetic stability.
(v) Why are low spin tetrahedral complexes not observed ?
(vi) Define molar magnetic susceptibility.
(vii) Define chromatogram and eluate.
(viii) What are penetration complexes ?
(ix) Define Rf and λmax.

6
(x) Give two uses of phosphagen.
3 3 6
8
(xi) Give two applications of silicon oils.
(xii) What is island of π characters ?
8 1×10=10

BKR—4351 2 NIR/KW/18/2171
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NKT/KS/17/5204

Bachelor of Science (B.Sc.) Semester—VI (CBS) Examination

CH—601 : INORGANIC CHEMISTRY
3 5 Paper—1
8 (Chemistry)
Time : Three Hours] [Maximum Marks : 50

5
N.B. :— (1) All FIVE questions are compulsory and carry equal marks.

83
(2) Write equations and draw diagrams wherever necessary.
1. (A) Define crystal field splitting energy and explain the crystal field splitting of ‘d’ orbitals in :
(i) [Co(NH3)6 ] 3+ and
(ii) [Co F6]3– ion. 5
(B) (i) What is Jahn-Teller effect ? Explain it with respect to distortion in Cu(11) Octahedral complexes.
(ii) Explain spin allowed and spin-forbidden selection rule with examples. 5

3 5
OR

(i) d5 low spin octahedral and

8
(C) Calculate CFSE value in terms of ∆ο value in the following :—

(ii) d6 high spin octahedral. 2½

(D) Explain why ∆t value is less than ∆ο and give the relationship between the two. 2½
(E) Discuss the electronic spectra of [Ti(H2 O6 )]3+ ion with respect to :—
(i) Position of the band and
(ii) Intensity of the band. 2½
(F) Explain Hole formalism principle considering d1 – d9 configuration system. 2½
2. (A) (i) Define :—
(a) Magnetic susceptibility
(b) Gram magnetic susceptibility
(c) Molar magnetic susceptibility and
explain the significance of molar magnetic susceptibility.

35 35
(ii) Calculate spin only magnetic moment of d7 system in weak octahedral field. 5

NXO—20048
8 1
8 (Contd.)

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(B) (i) What is thermodynamic and kinetic stability of complexes ? How are they correlated ?
(ii) How do the following factors affect the stability of complexes :—
(a) Chelate effect and

35
(b) Concentration of Ligand ? 5

8 OR
(C) What is orbital magnetic moment ? Give the conditions required to contribute to the orbital magnetic
moment. 2½

5
83
(D) On basis of CFT determine the number of unpaired electrons and calculate the spin only magnetic
moment of [Mn(CN)6 ]4 – complex ion. 2½
(E) Derive the relationship between stepwise stability constant and overall stability constant. 2½
(F) Discuss the Job’s method of determination of composition of Fe(III)–5 SSA complex. 2½
3. (A) (i) State Beer Lambert’s law and derive a mathematical expression for it.
(ii) A solution of compound having concentration of 1.5×10–3 M when placed in a cell with path length
of 2 cms, show % T of 65. Calculate the molar absorptivity of the compound. 5
(B) (i) 5
What are ion exchange resins ? Discuss the different types.
3
(ii) 8
Explain the technique of ascending paper chromatography. 5
OR
(C) Draw a well labelled schematic diagram of double beam colorimeter. 2½
(D) Discuss the different causes for deviation from Beer’s law. 2½
(E) What is ion exchange capacity ? How is it determined for cation exchange resin ? 2½
(F) Discuss the principle of solvent exctraction and give any two applications of it. 2½
4. (A) (i) What are Organosilicones ? How are cross-linked silicones prepared ?
(ii) What are Silicon oils ? Give any three uses of it.
(B) (i) What are phosphonitrilic halides ? Discuss the structure of (NPCl2 )4. 5
(ii) Give any one method of preparation of (NPCl2 )3 . What is the action of following on (NPCl2 )3 ?
(a) Excess of ammonia and
(b) Potassium alkoxide. 5

35 5
OR

8 8 3
NXO—20048 2 NKT/KS/17/5204

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(C) What is Silicone rubber ? Give any three uses of Silicone rubber. 2½
(D) What are Linear Silicones ? Give a method of preparation of Linear Silicones. 2½
(E) What is the action of following on (NPCl2 )3 ?
(i)
3 5 Benzene in presence of AlCl3 and

8
(ii) Boiling water.
(F) Draw the structure of (NPCl2 )3 and give any three uses of phosphonitric halides.
2½
2½
5. Solve any TEN of the following :—

5
(i) Define crystal field stabilization energy.

83
(ii) Draw crystal field splitting diagram of d5 system in tetrahedral field.
(iii) State Laporte’s selection rule.
(iv) Which of the following CFT configuration will show orbital contribution to magnetic moment ?
(a) t2g 2 ego
(b) e2 t2 o .
(v) What are inert complexes ?
(vi) What are Penetration complexes ?
3 5
8
(vii) Define molar extinction coefficient and give its units.
(viii) Calculate the % T for 0.5 absorbance.
(ix) Define :—
(a) Rf value and
(b) Elution.
(x) Give any two uses of Silicones.
(xi) What is the action of heat on (NPCl2 )3 ?
(xii) Give one reaction to prove that phosphonitrilic halides are Lewis bases. 1×10=10

3 5 3 5
NXO—20048 8 3 8 NKT/KS/17/5204

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NRJ/KW/17/3171
Bachelor of Science (B.Sc.) Semester-VI (C.B.S.) Examination
CH-601 INORGANIC CHEMISTRY
Paper—1
(Chemistry)
Time : Three Hours] [Maximum Marks : 50
N.B. :— (1) All FIVE questions are compulsory and carry equal marks.
(2) Write equations and draw diagrams whenever necessary.

3 5
1.
8
(A) Give the important postulates of CFT. Explain the crystal field splitting with diagram in
[Ni(CN)4 ]2– . 5
(B) What is John-Teller effect ? Explain the following with respect to [Cu(H2 O) 6 ]2+ ion

5
(i) Unsymmetrical band and

83
(ii) Low intensity band in its electronic spectrum. 5
OR
(C) Draw and explain position of absorption band in electronic spectrum of [Ti(H2 O)6 ]3+ ion
using CFT. 2½
www.mpboardonline.com

(D) How does d-orbital splitting take place in d4 ion in presence of strong and weak octahedral
field ? 2½
(E) Explain how the nature of central metal ion affects the magnitude of ∆o . 2½
5
(F) Calculate CFSE for [Cr(H2 O) 6 ]2+ for which ∆o value is 12600 cm–1 and mean pairing energy
3
is 23500 cm–1 . 8 2½
2. (A) (i) What is thermodynamic and kinetic stability of complexes ? Explain with example.
(ii) Correlate stepwise and overall stability constant. 5
(B) (i) Describe the Gouy’s method for the determination of magnetic susceptibility of complex.
(ii) Calculate spin only magnetic moment of d4 -system in strong octahedral field. 5
OR
(C) How does the nature of ligand affect the stability of complex ? 2½
(D) Discuss the Job’s method for determination of composition of Fe(III)-SSA complex. 2½
(E) On the basis of CFT, calculate the number of unpaired electrons and predict magnetic
property in [ Fe F6 ]3– complexion. 2½
(F) Which of the following configurations show orbital contribution towards magnetic
moment ? Explain (i) t2 g3 lg1 , (ii) t2 g4 eg1 . 2½
3. (A) (i) Draw well-labelled diagram of double beam colorimeter

35 35
(ii) Differentiate between colorimeter and spectrophotometer. 5

8 8
(B) What is ion exchange resin ? Explain its principle. Give application in the separation of
cations by ion exchange method. 5
OR
(C) Explain the technique of ascending paper chromatography. 2½
(D) Discuss any two applications of solvent extraction. 2½

POY—25171 1
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www.rtmnuonline.com
(E) A solution absorbs 70% of the incident light. If the path length of the medium is 1.5 cm
and molar absorptivity of a solute is 250 dm3 mol–1 cm–1 , calculate concentration of the
solution. 2½
(F) Draw well-labelled diagram of single beam spectrophotometer. 2½
4. (A) What are silicones ? How will you prepare linear silicones ? Give two important applications
of silicones. 5
(B) Discuss the structure and sigma bonding in (NPCl2 )3 . 5
OR

35
(C) Write a note on silicone elastomers. 2½

8
(D) How is cross linked silicone prepared ?
(E) Give any two methods of preparation of (NPCl2 )4 .
2½
2½
(F) How does (NPCl2 )3 react with :

5
(i) C6 H5 MgBr, (ii) C6 H6 ? 2½

83
5. Solve any TEN of the following :
(i) Draw crystal field splitting diagram in tetrahedral complex of d5 system.
(ii) What is pairing energy ?
(iii) Give any one selection rule for electronic spectra.
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(iv) What is chelate effect ?

(v) Write spin only formula of magnetic moment.
(vi) What are Labile complexes ?
(vii) What is paper chromatography ?
3 5
(viii) Define Rf value. 8
(ix) Define the term Eluent.
(x) What are silicone fluids ?
(xi) Write any two uses of silicone resins.
(xii) Draw the structure of (NPCl2 )4 . 1×10

3 5 3 5
8 8

POY—25171 2
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(C) Write a note on Silicone elastomers. 2½ TKN/KS/16/5917

(D) Write uses of silicone oils. 2½
(E) What happens when (NPCl2)3 is treated with : Bachelor of Science (B.Sc.) Semester–VI (C.B.S.)
(i) Moist air and Examination
CH-601 : INORGANIC CHEMISTRY
(ii) Excess NH3 ? 2½
Paper—1
(F) Write one method of preparation of each :
(NPCl3)3 and (NPCl3)4 . 2½ Time—Three Hours]
5. Attempt any TEN of the following : [Maximum Marks—50
(i) Explain effect of geometry on 10 Dq. N.B. :— (1) All FIVE questions are compulsory and
(ii) State Laporte selection rule. carry equal marks.
(iii) Calculate CFSE value for d6 tetrahedral. (2) Write equations and draw diagrams
(iv) Write CFT configuration and predict number of wherever necessary.
impaired electrons in [CoCl4] 2¯ ion.
1. (A) Draw d-orbital splitting diagram and write CFT
(v) Calculate magnetic moment of weak field d 5 configuration of the following :
octahedral complex using CFT. 5
3+ 3
(i) [Co(NH3 )6] and (ii) [CoF6] ¯
(vi) Why Fe (III) complexes are more stable than Fe(II) (B) Explain the following :
complexes ? (i) Position and intensity of the absorption band in
(vii) Write two advantages of spectrophotometer over an electronic spectrum of [Ti (H2O)6]3+ .
colorimeter.
(ii) Spin selection rule. 5
(viii) What is Rf value ?
OR
(ix) Explain cation exchange.
(x) Give two uses of Silicone resins. (C) Explain how the nature of the ligands and oxidation
(xi) What is the action of heat on (NPCl2)3 ? states of the metal ion affects the value of 10 Dq.
2½
(xii) Write any two uses of polyphosphazenes.
1×10=10
MXP-M—3532 4 6450 MXP-M—3532 1 Contd.

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(D) Explain the John-Teller effect with suitable example. (F) Describe Job’s method for the determination of
2½ composition of Fe(III)–SSA complex. 2½
3+
(E) Calculate CFSE for [Co(NH3)6 ] ion for which 3. (A) State and derive mathematical expression of Beer-
∆o value is 23,000 cm–1 and mean pairing energy is Lambert’s Law. Explain the terms :
21,000 cm–1 . 2½ (i) Absorbance
(F) Write limitations of valence bond theory of metal
(ii) Molar absorptivity and
complexes. 2½
2. (A) Draw d-orbital splitting diagram and explain magnetic (iii) λmax. 5
properties of the following : (B) What is Chromatography ? Discuss the principle
4 3
(i) [Fe(CN)6] ¯ and (ii) [FeF6] ¯ 5 and technique involved in paper chromatography.
(B) (i) Explain thermodynamic and kinetic stability of 5
the complexes with suitable example. OR
(ii) What is Chelate effect ? How does it affect the (C) Draw Well-labelled diagram of single beam
stability of the metal complexes ? 5 spectrophotometer. 2½
OR
(D) A standard solution of 2.5×10–4 M in a cell with
(C) Identify the following having quenching towards orbital 1.5 cm path length showed a percentage transmittance
moment : of 65% at a wavelength of 500 nm. 2½
(i) t2g2
(E) Explain the terms eluent, eluate and elution. 2½
(ii) t2g6
(F) Discuss the technique involved in the separation of
(iii) t2g6 eg1
cations by ion-exchange method. 2½
(iv) t2g1
4. (A) What are Silicones ? Give one method of preparation
(v) t2g4eg2 2½
of each, Linear and Two dimentional cross-linked
(D) Write CFT configuration and calculate magnetic silicon. 5
moment for [Ni(NH3)6 ]2+ ion. 2½
(B) What is meant by phosphonitrilic halides ? Discuss
(E) Discuss correlation between stepwise and overall
the bonding and structure of (NPCl2)3 . 5
stability constant. 2½
OR
MXP-M—3532 2 Contd. MXP-M—3532 3 Contd.

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KNT/KW/16/5204

Bachelor of Science (B.Sc.) Semester—VI (C.B.S.) Examination

CH–601 : INORGANIC CHEMISTRY
Paper—1
(Chemistry)
Time : Three Hours] [Maximum Marks : 50

N.B. :— (1) All FIVE questions are compulsory and carry equal marks.
(2) Write equations and draw diagrams wherever necessary.
1. (A) Explain crystal field splitting in tetrahedral complexes. Give reasons for smaller value of crystal
field splitting in tetrahedral than in octahedral complexes. 5
(B) Explain the following with example :
(i) Spin selection rule and
(ii) Laporte selection rule. 5
OR
(C) Explain how the nature of central metal ion affects the magnitude of crystal field splitting. 2½
(D) What is CFSE ? Calculate CFSE for the following ions in octahedral complexes :
(i) d4 strong field and
(ii) d6 weak field. 2½
(E) Explain electronic absorption spectra of [Ti(H2O)6 ]3+ complex ion with respect to :
(i) Position of absorption band and
(ii) Intensity of absorption band. 2½
(F) What is meant by hole formalism principle ? Explain with example. 2½
2. (A) (i) Discuss spin and orbital contribution to the magnetic moment.
(ii) Explain in which of the following cases there is orbital contribution to magnetic moment :
(a) d4 high spin octrahedral complex and
(b) d5 low spin octrahedral complex. 5
(B) Explain what are stepwise stability and overall stability constants. Derive relationship between
them. 5
OR

NVM—5447 1 (Contd.)

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(C) What are high spin and low spin complexes ? Explain with example. 2½
(D) Explain on basis of CFT, [Ni (CN)4] 2 – is dimagnetic in nature. 2½
(E) What is thermodynamic stability of complexes ? Which complex of the following two is more
stable and why :
(i) [Fe (CN)6] 3 – or
(ii) Fe [(CN)6] 4 – ? 2½
(F) Explain the terms labile complexes and inert complexes. 2½
3. (A) (i) Derive the equation A = ∈ ⊂ t.
(ii) Explain the conditions for deviation from Beer-Lambert’s Law. 5
(B) Describe the principle and technique used in ascending paper chromatography. Give any two
applications of it. 5
OR
(C) The molar absorptivity of a compound in an aqueous solution at 765 nm is 1.54 × 103.
The % T of a solution of this compound in a cell with 1 cm path length is 43.2. Calculate
concentration of the solution. 2½
(D) Draw schematic diagram of double beam colorimeter. 2½
(E) What is ion exchange capacity ? How is it determined for an acidic resin ? 2½
(F) Discuss the different factors which influence solvent extraction. 2½
4. (A) What are silicones ? Give one method of preparation of :
(i) Linear silicones and
(ii) Crosslinked silicones. 5
(B) What are phosphonitrilic halides ? Give one method of preparation of :
(i) Triphosphonitrilic chloride and
(ii) Tetraphosphonitrilic chloride. 5
OR
(C) What are silicone oils ? Give any three uses of silicone oils. 2½
(D) What happen when (NPCl2)3 is :
(i) Heated at 150-300ºC and
(ii) Hydrolysed ? 2½
(E) Write notes on Silicon resins. 2½
(F) Discuss the structure and bonding in (NPCl2)3 molecule. 2½

NVM—5447 2 (Contd.)

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5. Attempt any TEN of the following :

(i) Draw crystal field splitting diagram of d-orbitals in octahedral field.
(ii) Calculate CFSE for d6 system in tetrahedral field.
(iii) Explain why electronic spectra of [Cu(H2O)6] 2+ complex ion shows a broadband.
(iv) Calculate spin only magnetic moment of d5 low spin octahedral complex.
(v) Write the formula for total magnetic moment (µS + µL).
(vi) What is chelate effect ?
(vii) Define Molar extinction coefficient.
(viii) Give any two differences between colorimeter and spectrophotometer.
(ix) Define :
(i) Rf value and
(ii) Elution.
(x) Write reaction for the action of benzene on (NPCl2)3 in presence of AlCl3.
(xi) What are silicon resins ?
(xii) Draw the boat form structure of (NPCl2). 1×10=10

NVM—5447 3

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