Nep Chemistry Sem I &II
Nep Chemistry Sem I &II
S. Z. S. P. Mandal’s
Shri Pancham Khemraj Mahavidyalaya,
Sawantwadi-416510
(Autonomous)
Affiliated to University of Mumbai
Syllabus for
Semester I
and
Semester II
2
Sr. No. Headings Particulars
1 Title of the Program Science- Chemistry
3
Preamble
1. Introduction
Shri Pancham Khemraj Mahavidyalaya (S.P.K.M.), Sawantwadi (Autonomous) believes in
implementing several measures to bringequity, efficiency and excellence in higher education system
in conformity to the guidelines laid down by the University Grants Commission (UGC). In order to
achieve these goals, all efforts are made to ensure high standards of education by implementing
several steps to enhance the teaching- learning process, examination and evaluation techniques and
ensuring the all-round development oflearners.
The four-year course in B.Sc. Chemistry has been designed to have a progressive and
innovative curriculum in order to equip our learners to face the future challenges in the field of higher
education. In semesters I and II learners are introduced to the basic areas of Chemistry such as
Thermodynamics, Periodic table, Chemical Kinetics, Reaction and Mechanism.
In semesters III and IV the course content is made more rigorous by introducing the details of
each of the above area. In semesters V and VI, course are designed to help in specialization in the
core areas of Chemistry such as Molecular spectroscopy, Nuclear Chemistry, Chemical
thermodynamics, Chemical kinetics, Molecular Symmetry and Chemical Bonding, Solid state
Chemistry, Electrochemistry polymers, Quantum chemistry with Renewable energy resources
Chemistry of inner transition elements, Theories of the metal-ligand bond, Organometallic chemistry,
Mechanism of organic reactions , Stereochemistry, Synthesis of organic compounds, Quality in
Analytical Chemistry, Chemical Calculations, Optical Methods, Electro analytical techniques and
Applied components dyes and drugs. The practical course has been designed to help the student have
a firm grip on the theoretical concepts through relevant experiments in each course.
2. Objectives:
To help learners in developing a scientific attitude through the Chemistry curriculum that
involves basic and core areas of Chemistry along with the recent scientific and technological
advancements in applied areas of Chemistry
To enhance knowledge of Chemistry through problem solving, tutorials and seminars
To develop practical skills in Chemistry using a range of an activities such as projects
inexperimental Chemistry, study tours, industrial and research institutes visit.
To inculcate a research attitude by involving learners in simple research projects review of
research articles/papers, participation in scientific events etc.
To help learners in developing analytical abilities and skills so as to address real world
problems
To help learners to plan a progressive and successful career in Chemistry, education and
industry
4
3. Program Outcome: After successful completion of this programme learners will be able to
Develop the knowledge of basic concepts of different branches of science required for
postgraduate studies.
Inculcate the skills useful in science laboratories for pursuing jobs in Industries.
Introduce learners to the concepts useful for environment protection.
Follow interdisciplinary approach for developing scientific temperament.
Identify, formulate and analyze scientific problems and reach concrete solutions for
societal benefits.
Expected Outcome
Acquire & explore essential skills to succeed in various chemical industries.
Get a hold on higher educational opportunities like post-graduation in chemistry.
Pursue higher studies in interdisciplinary areas such as biochemistry, genetics, pathology
etc.
Explore research areas in chemistry and related fields.
5
4. Credit Structure of the Programme (Semester I & II)
Shri Pancham Khemraj Mahavidyalaya, Sawantwadi
Proposed First Year Curriculum as per NEP 2020
Department of Chemistry
Proposed Structure for Major / Minor/OE/VSE/SEC/VEC/IKS
6
Title of the Programme – B.Sc. Chemistry
7
Letter Grades and Grade points
AB (absent) Absent
8
DEPARTMENT OF CHEMISTRY
Syllabus
Proposed Syllabus for CBCS
F. Y. B. Sc. Major Chemistry
No of
No of
Semester Course Code Course title Lectures
Credits
In Hours
S101CHT
Physical and AnalyticalChemistry-I 2 30
(Major)
S102CHT
Inorganic and Organic Chemistry -I 2 30
(Major)
I S103CHP
2 60
(Major) Chemistry Practical-I
9
SEMESTER-I
COURSE TITLE: - PHYSICAL AND ANALYTICAL CHEMISTRY-I
Course Code: S101CHT
Pre-requisites:
Knowledge of Chemical Thermodynamics, Chemical Kinetics, Chemical Calculations, Ionic
Equilibrium.
Course Objectives: To introduce students to;
Understand basic concepts of physical and analytical chemistry.
Recognize the importance of basics chemical thermodynamic.
Learn the rate and order of reactions.
Classify the electrolytes based on their dissociation phenomenon
Learn about the concentration units and preparation of solutions.
Desired Outcomes: After the completion of this course, learners will be able to:
Understand the basics of thermodynamic properties.
Analyze the rate and orders of reactions by using different methods.
Evaluate different physical properties of liquids by using diverse techniques.
Prepare solutions of different concentrations from solid and liquid analyte.
Differentiate strong and weak electrolytes based on knowledge of degree of ionization.
Calibrate the volumetric apparatus required for the day-to-day Practicals.
Course Content
UNIT Description Lecture
s
I Chemical Thermodynamic
(Physical
1.1:Introduction to Thermodynamics
Chemistry) 8
1.1.1 Thermodynamic terms:-
1. System,
2. surrounding,
3. boundaries,
4. types of system,
5. Intensive and Extensive properties,
6. State functions and
7. path functions,
1.1.2 Thermodynamic processes.
1.1.3 First law of thermodynamics:
1. Concept of heat (q),
2. Work (w),
3. Internal energy (U),
4. Enthalpy,
5. Heat capacity,
6. Relation between heat capacities,
7. Sign conventions,
1.1.4 Calculations of Heat, work, Internal energy and Enthalpy (H).
10
1.1.5 Thermo Chemistry:
1. Heat of reactions,
2. Standard states,
3. Enthalpy of formation of molecules,
4. Enthalpy of combustion and its applications
1.1.6 Calculations of bond energy, bond dissociation energy and
resonance energy from thermo chemical data,
1.1.7 Kirchhoff’s equation (Numerical problems expected wherever
necessary).
11
2.2 Chemical Calculations:
2.2.1 Methods of expressing concentration of solutions:
1. Normality,
2. Molality,
3. Molarity,
4. Formality,
5. Mole fractions, 5
6. Weight ratio,
7. Volume ratio,
8. Weight to volume ratio,
9. Parts per million (ppm),
ppb, milimol, miliequivalace, Preparation of solutions
(Numerical problems expected wherever necessary).
2.3 Ionic Equilibria:
2.3.1 Strong and weak electrolytes,
Degree of ionization, factors affecting degree of ionization,
Ionization constant and
Ionic product of water,
2.3.2 Ionization of weak acids and bases,
2.3.3 Dissociation constants of monoprotic acids. 6
1. pH scale,
2. Buffer solutions,
3. Types of buffers,
4. Derivation of Henderson equation for acidic and basic buffers,
Buffer action, buffer capacity
(Numerical problems expected, wherever necessary)
References:
1. Atkins, P.W. and Julio de Paulo, Atkins’ Physical
Chemistry, Oxford University Press, UK, Indian Edition 9, 2011.
2. Samuel Glasstone, Thermodynamic for chemist, East West Press
Pvt.Ltd, Edition 3, (1947) ISBN: 9788176710145
3. Barrow, G.M. Physical Chemistry Tata McGraw‐Hill (2007).
4. Castellan, G.W. Physical Chemistry 4th Ed. Narosa (2004).
5. K.L. Kapoor A textbook of Physical Chemistry 3rd Ed.
vol.1,2Macmillan Publishing Co., NewDelhi(2001)
6. Vogel’s Textbook of Quantitative Chemical Analysis, 5th edition,
John Wiley Publication, 1989.
Total 30
12
SEMESTER-I
COURSE TITLE: - INORGANIC & ORGANIC CHEMISTRY –I
Knowledge of Atomic Structure, Periodic table and periodicity and comparative chemistry of
main group elements.
Course Objectives:
To Introduce students to:
Systematic and coherent understanding of the fundamental concepts in
InorganicChemistry and Organic Chemistry.
Understand the basic knowledge of periodic table and Atomic Structure.
Classification of elements in the periodic table.
Comparative chemistry of Main Group Elements.
The concepts of Nomenclature of Organic Compounds.
Bonding and Structure of organic compounds.
Fundamentals of organic reaction mechanism .
Basic concept of stereochemistry.
Course Outcomes: On successful completion of this course students will be able to:
Understand the basic theories of atomic structures.
Students will be able to understand the concept of atomic orbitals.
Calculate the effective nuclear charge according to Slater’s Rule.
Predict the oxidation states of main group elements.
Assign the correct IUPAC name to the organic compounds and write the structure from
their IUPAC name.
Identify the hybridization of carbon in the given molecule.
Write the mechanism using fundamental concepts of writing mechanism.
Understand the advanced concepts in stereochemistry using the fundamental chemistry.
13
Course Content
UNIT Description Lectures
I Introduction to Inorganic Chemistry
(Inorganic 1.1 Atomic structure (8L) 15
Chemistry) 1.1.1 Historical perspectives of the atomic structure:
J. J. Thomson Model,
Rutherford’s Atomic Model- alpha particle scattering experiment,
Bohr’s theory, its limitations and atomic spectrum of hydrogen
atom. Structure of hydrogen atom.
1.1.2 Hydrogenic atoms:
1. Simple principles of Quantum Mechanics
2. Atomic orbitals
i) Shells, subshells and orbitals
ii) Electron spin
iii) Radial shapes of orbitals
iv) Hydrogenic Energy Levels
v) Angular shapes of orbitals.
vi) Aufbau principle,
vii) Hund’s rule of maximum multiplicity and
viii) Pauli exclusion principle
1.2 Periodic Table and periodicity (4L)
1.2.1 Long form of Periodic Table:
Classification :
1. Main Group,
2. Zero Group Elements
3. Transition Elements and
4. Inner transition elements.
1.2.2 Periodicity in the following properties:
1. Atomic and ionic size,
2. Electron gain enthalpy,
3. Ionization enthalpy,
4. Effective nuclear charge (Slater’s rule),
5. Electronegativity, Pauling and
6. Mullikan methods
(Numerical problems expected, wherever applicable).
1.3 Comparative Chemistry of Main Group Elements (3L):
1.3.1 Properties of Main Group Elements-
1) Metallic and Non-metallic nature,
2) Oxidation States.
1.3.2 Anomalous behavior of Second Period elements,
1.3.3 Diagonal relationship of Second & Third Period Elements
1.3.4 Allotropy. Types of Allotropy
1.3.5 Allotropy of Carbon, Phosphorous, Tin.
1.3.6 Catenation,
1.3.7 Some important compounds- NaHCO3, Na2CO3, CaCO3, CaO,
NaOH, NaCl.
1.3.8 Oxides of Nitrogen, Sulfur, Oxygen w.r.t Environmental aspect
14
III
(Organic 2.1 Nomenclature of Organic Compounds (3L): 15
Chemistry) Review of basic rules of IUPAC nomenclature. Nomenclature of mono and
bi-functional aliphatic compounds on the basis of priority order of the
following classes of compounds: alkanes, alkenes, alkynes, halo alkanes,
alcohols, ethers, aldehydes, ketones, carboxylic acids, carboxylic acid
derivatives (acid halides, esters, anhydrides, amides), nitro compounds,
nitriles and amines; including their cyclic analogues.
2.2 Bonding and Structure of organic compounds (4L):
Hybridization: sp3, sp2, sp hybridization of carbon in Organic compounds
(alcohol, ether, aldehyde, ketone, carboxylic acid, ester, cyanide)
Overlap of atomic orbitals: Overlaps of atomic orbitals to form sigma
and pi bonds, shapes of organic molecules.
Shapes of molecules; Influence of hybridization on bond properties
(as applicable to ethane, ethene, ethyne).
15
(Reference Book:
1. Concise Graduate Chemistry – I, II, III & IV, University Text Book
of Chemistry, University of Mumbai.
2. Morrison, R. T. and Boyd, R. N. Organic Chemistry, Dorling
Kindersley (India) Pvt Ltd.(Pearson Education).2012
3. Finar, I. L. Organic Chemistry (Volume 1), Dorling Kindersley (India)
Pvt Ltd. (Pearson Education).
4. Finar, I. L. Organic Chemistry (Volume 2: Stereochemistry and the
Chemistry of Natural Products), Dorling Kindersley (India) Pvt Ltd.
(Pearson Education).
5. Eliel, E. L. and Wilen, S. H. Stereochemistry of Organic Compounds,
Wiley: London, 1994
6. Kalsi, P. S. Stereochemistry Conformation and Mechanism, New Age
International, 2005.
7. Mc Murry, J.E. Fundamentals of Organic Chemistry, 7th Ed. Cengage
Learning India Edition, 2013
8. Paula Y Bruice, Organic Chemistry, 7th Ed, Pearson education,
Asia.2014
9. Bahl and Bahl, Advanced Organic chemistry by S. Chand
publication.2010
10. Peter Sykes. Guidebook to the mechanism in Organic chemistry ,6 th
edition
11. D. Nasipuri.Stereochemistry of Organic Compounds,Principles and
Applications, Second Edition.
Total = 30
16
SEMESTER-I
Course Title: BASIC CHEMISTRY PRACTICAL-1
Course Code: S103 CHP
Leaning Outcome: On successful completion of this course learners will be able to:
1. Handle Electronic Balance and calibrate the glass apparatus used for various experiments.
2. Apply the Concepts of Rate of Reaction and Volumetric Analysis through experiments.
3. Standardize different solutions using suitable primary standard.
4. Prepare the solution of desired concentrations.
5. Perform gravimetric analysis using crucibles.
List of the experiments:
Physical Chemistry Experiments
1. To calibrate the volumetric apparatus used in titrimetric analysis.
2. To prepare 0.1 N succinic acid and standardize NaOH of two different concentrations.
3. To determine the rate constant for the hydrolysis of ester using HCl as catalyst.
4. To determine the amount of strong acid in the given solution by titrating against strong base
conductometrically.
5. To determine the dissociation constant of weak acid (Ka) using Henderson’s equation and the
method of incomplete titration pH metrically.
Inorganic Chemistry Experiments
1. Commercial analysis of
a) Organic acid.
b) Mineral Acid
2. Titration using double indicator: analysis of solution of Na2CO3 and NaHCO3.
3. Redox Titration: To determine the percentage of copper(II) present in a given sample by
titration against a standard aqueous solution of sodium thiosulfate (iodometry titration)
Organic Chemistry Experiments
1. Purification of any two organic compounds by recrystallization selecting suitable solvent.
(Provide 1g.).
Learners are expected to report
a) Solvent for recrystallization.
b) Mass and the melting point of purified compound.
2. Chromatography Separation of a mixture of two organic compound by ascending Thin Layer
Chromatography.
Reference Books:
1. Systematic experimental Physical chemistry – T. K. Chondhekar & S.W. Rajbhoj, Anjali
Publications, Aurangabad.
2. Experiments in chemistry – D.V. Jahagirdhar, Himalaya Publishing House.
3. Spectrometric Identification of Organic Compounds- R.M.Silverstein, G.C.Bassler,
Wiley: New York, 5th edition.
4. Experiments and Techniques in Organic Chemistry-D.J.Pasto, C.R.Johnson, Prentice-Hall:
Englewood Cliffs.
All Experiments are compulsory for the Semester-I.
Write the Experiments Paper wise in Journal.Certified journal is a must to be eligible for appearing
term end examination.
17
EXAMINATION PATTERN FOR MAJOR SUBJECTS
A) Continuous Internal Assessment (40 Marks):
Total 82 60
18
C) Semester End Practical Examination (50 marks):
Scheme of examination:
There will be no internal assessment for practical.
A candidate will be allowed to appear for the semester end practical examination only if the candidate
submits a certified journal at the time of practical examination of the semester or a certificate from
the Head of the Department/Institute to the effect that the candidate has completed the practical course
of that semester of F.Y.B.Sc. Chemistry as per the minimum requirement
The practical examination will be conducted in ONE SESSIONS of three hours each.
The learners will be evaluated based on the experiments performed during the examination.
The questions on slips for the same should be framed in such a way that candidate will be able to
complete the task and should be evaluated for the skill and understanding of Chemistry.
Examination Pattern
Distribution of Marks in Practical Examination
19
S. Z. S. P. Mandal’s
SHRI PANCHAM KHEMRAJ MAHAVIDYALAYA
SAWANTWADI
DIST: SINDHUDURG- 416 510, MAHARASHTRA
6 Level UG
8 Status Revised
Date:
Signature
HoD,
Dept. of Chemistry
2
PREAMBLE:
3
Program Outcome: After successful completion of this programme learners will be able to
Develop the knowledge of basic concepts of different branches of science required for
postgraduate studies.
Inculcate the skills useful in science laboratories for pursuing jobs in Industries.
Introduce learners to the concepts useful for environment protection.
Follow interdisciplinary approach for developing scientific temperament.
Identify, formulate and analyze scientific problems and reach concrete solutions forsocietal
benefits.
4
DEPARTMENT OF CHEMISTRY
Syllabus
Proposed Syllabus for CBCS
F. Y. B. Sc.: Minor Chemistry
No of
No. of
Semester Course Course title Lectures
Credits
Code In Hours
S104 CHT
Physical and AnalyticalChemistry-I 2 30
(Minor)
S105 CHT
I
Inorganic and OrganicChemistry -I 2 30
(Minor)
5
SEMESTER-I
Course Title: - Physical and Analytical Chemistry-I
Course Code: S104 CHT
Pre-requisites:
Knowledge of Chemical Thermodynamics, Chemical Kinetics, Chemical Calculations, Ionic
Equilibrium.
Course Objectives: To introduce students to;
1. Understand basic concepts of physical and analytical chemistry.
2. Recognize the importance of basics chemical thermodynamic.
3. Learn the rate and order of reactions.
4. Classify the electrolytes based on their dissociation phenomenon
5. Learn about the concentration units and preparation of solutions.
Course Outcomes: After the completion of this course, learners will be able to:
1. Understand the basics of thermodynamic properties.
2. Analyze the rate and orders of reactions by using different methods.
3. Evaluate different physical properties of liquids by using diverse techniques.
4. Prepare solutions of different concentrations from solid and liquid analyte.
5. Differentiate strong and weak electrolytes based on knowledge of degree of ionization.
6. Calibrate the volumetric apparatus required for the day-to-day Practicals.
Course Content
UNIT Description Lectures
6
1.2 Chemical Kinetics 7L
Rate of reaction, rate constant, measurement of reaction rates, order and
molecularity of reaction, Integrated rate equation of first order and
Second order reactions (with equal initial concentration of reactants)
Determination of order of reaction by a) Integration method b) Graphical
method c) Ostwald’s isolation method d) Half time method, Effect of
temperature on the rate of reaction, Concept of activation energy and its
calculation from Arrhenius equation (derivation not expected).
(Numerical problems expected wherever necessary)
References:
1. Atkins, P.W. and Julio de Paulo, Atkins’ Physical Chemistry,
Oxford University Press, UK, Indian Edition 9, 2011.
2. Samuel Glasstone, Thermodynamic for chemist, East West Press
Pvt.Ltd, Edition 3, (1947) ISBN: 9788176710145
3. Barrow, G.M. Physical Chemistry Tata McGraw‐Hill (2007).
4. Castellan, G.W. Physical Chemistry 4th Ed. Narosa (2004).
5. K.L. Kapoor A textbook of Physical Chemistry, Thermodynamics
and Chemical Equilibria, 3rd Ed. vol.1,2, 3, Macmillan Publishing
Co., New Delhi (2001)
II 2.1 Calibration of Apparatus: 4L
(Analytical Introduction and objectives of calibration of volumetric apparatus,
Chemistry)
Categories of glassware’s as class A and class B, Calibration of standard
volumetric flask, calibration of pipette and calibration of burette.
7
References:
1. Atkins, P.W. and Julio de Paulo, Atkins’ Physical
Chemistry, Oxford University Press, UK, Indian Edition 9, 2011.
2. Samuel Glasstone, Thermodynamic for chemist, East West Press
Pvt.Ltd, Edition 3, (1947) ISBN: 9788176710145
3. Barrow, G.M. Physical Chemistry Tata McGraw‐Hill (2007).
4. Castellan, G.W. Physical Chemistry 4th Ed. Narosa (2004).
5. K.L. Kapoor A textbook of Physical Chemistry 3rd Ed.
vol.1,2Macmillan Publishing Co., NewDelhi(2001)
6. Vogel’s Textbook of Quantitative Chemical Analysis, 5th edition,
John Wiley Publication, 1989.
Total 30 L
SEMESTER-I
Course Title:- Inorganic & Organic Chemistry –I
Course Code : S105 CHT
Pre-requisites:
Knowledge of Atomic Structure, Periodic table and periodicity and comparative chemistry of
main group elements.
Course Objectives:
To introduce students to
1. Systematic and coherent understanding of the fundamental concepts in Inorganic
Chemistry and Organic Chemistry.
2. Understand the basic knowledge of periodic table and Atomic Structure.
3. Classification of elements in the periodic table.
4. Comparative chemistry of Main Group Elements.
5. The concepts of Nomenclature of Organic Compounds.
6. Bonding and Structure of organic compounds.
7. Fundamentals of organic reaction mechanism .
8. Basic concept of stereochemistry.
Course Outcomes: On successful completion of this course students will be able to:
1. Understand the basic theories of atomic structures.
2. Students will be able to understand the concept of atomic orbitals.
3. Calculate the effective nuclear charge according to Slater’s Rule.
4. Predict the oxidation states of main group elements.
5. Assign the correct IUPAC name to the organic compounds and write the structure from
their IUPAC name.
6. Identify the hybridization of carbon in the given molecule.
7. Write the mechanism using fundamental concepts of writing mechanism.
8. Understand the advanced concepts in stereochemistry using the fundamental chemistry.
8
Course Content
UNIT Description Lectures
I 2.1 Atomic structure (8L) 15 L
( Inorganic
Chemistry)
2.1.1 Historical perspectives of the atomic structure: J. J. Thomson
Model, Rutherford’s Atomic Model- alpha particle scattering experiment,
Bohr’s theory, its limitations and atomic spectrum of hydrogen atom.
Structure of hydrogen atom.
2.1.2 Hydrogenic atoms:
1. Simple principles of quantum mechanics
2. Atomic orbitals
i) Shells, subshells and orbitals
ii) Electron spin
iii) Radial shapes of orbitals
iv) Angular shapes of orbitals. Aufbau principle, Hund’s rule of
maximum multiplicity and Pauli exclusion principle
9
2.2 Bonding and Structure of organic compounds (4L):
Hybridization: sp3, sp2, sp hybridization of carbon in Organic compounds
(alcohol, ether, aldehyde, ketone, carboxylic acid, ester, cyanide)
2.3 Fundamentals of organic reaction mechanism (5L):
Electronic Effects: Inductive, electromeric, resonance and mesomeric
effects, hyperconjugation; Dipole moment.
Bond fission: Homolytic and Heterolytic fission with suitable examples.
Electrophiles and Nucleophiles;
Types (primary, secondary, tertiary, allyl, benzyl),: shape and their
relative stability of reactive intermediates: Carbocations, Carbanions
and Free radicals.
Introduction to types of organic reactions: Addition, Elimination and
Substitution reaction. (With one example of each)
2.4 Stereochemistry I (3L)
Flying-Wedge Projection, Fischer Projection, Newman and Sawhorse
Projection formulae and their interconversions (for isomers of tartaric
acid and 2,3 dichlorobutane) Optical Isomerism: Optical Activity,
Specific Rotation (numerical problems), Chirality/Asymmetry,
Enantiomers, Molecules with two similar and dissimilar chiral-centres,
Distereoisomers, meso structures, racemic mixture and resolution
(methods of resolution not expected).
(Reference Book:
1. Concise Graduate Chemistry – I, II, III & IV, University Text Book of
Chemistry, University of Mumbai.
2. Morrison, R. T. and Boyd, R. N. Organic Chemistry, Dorling Kindersley
(India) Pvt Ltd.(Pearson Education).2012
3. Finar, I. L. Organic Chemistry (Volume 1), Dorling Kindersley (India) Pvt
Ltd. (Pearson Education).
4. Finar, I. L. Organic Chemistry (Volume 2: Stereochemistry and the
Chemistry of Natural Products), Dorling Kindersley (India) Pvt Ltd. (Pearson
Education).
5. Eliel, E. L. and Wilen, S. H. Stereochemistry of Organic Compounds,
Wiley: London, 1994
6. Kalsi, P. S. Stereochemistry Conformation and Mechanism, New Age
International, 2005.
7. Mc Murry, J.E. Fundamentals of Organic Chemistry, 7th Ed. Cengage
Learning India Edition, 2013
8. Paula Y Bruice, Organic Chemistry, 7th Ed, Pearson education, Asia.2014
9. Bahl and Bahl, Advanced Organic chemistry by S. Chand
publication.2010
10. Peter Sykes. Guidebook to the mechanism in Organic chemistry ,6 th
edition
11. D. Nasipuri.Stereochemistry of Organic Compounds,Principles and
Applications, Second Edition.
Total = 30L
10
EXAMINATION PATTERN FOR MAJOR SUBJECTS
A) Continuous Internal Assessment (40 Marks):
Total 80 60
11
C) Semester End Practical Examination (50 marks):
Scheme of examination:
There will be no internal assessment for practical.
A candidate will be allowed to appear for the semester end practical examination only if the
candidate submits a certified journal at the time of practical examination of the semester or a
certificate from the Head of the Department/Institute to the effect that the candidate has completed
the practical course of that semester of F.Y.B.Sc. Chemistry as per the minimum requirement
The practical examination will be conducted in ONE SESSIONS of three hours each.
The learners will be evaluated based on the experiments performed during the examination.
The questions on slips for the same should be framed in such a way that candidate will be able to
complete the task and should be evaluated for the skill and understanding of Chemistry.
Examination Pattern
Distribution of Marks in Practical Examination
12
S. Z. S. P. Mandal’s
SHRI PANCHAM KHEMRAJ MAHAVIDYALAYA
SAWANTWADI
DIST: SINDHUDURG- 416 510, MAHARASHTRA
6 Level UG
8 Status Revised
Date:
Signature
HoD,
Dept. of Chemistry
Shri Pancham Khemraj Mahavidyalaya, Sawantwadi
Proposed First Year Curriculum as per NEP 2020
Department of Chemistry
Structure for Vocational Skill Course
Semester Paper Code Paper Title Type Credits/Hr
VSCHE 01 Experimental Chemistry Practical 2/60Hr
I
Vocational Skill Course:
Experimental Chemistry
Semester – I
S. Z. S. P. Mandal’s
SHRI PANCHAM KHEMRAJ MAHAVIDYALAYA SAWANTWADI
DIST: SINDHUDURG- 416 510, MAHARASHTRA
No of
No of Lectures
Semester Course Code Course Title Credits in
Hours
Industrial Chemistry -I :
I SECHE 01 Qualitative Analysis and 02 30
Chemical Handling
SEMESTER-I
Course Objectives:
1. To understand basic principles involved in quantitative and qualitative analysis.
2. To differentiate between organic and inorganic compounds.
3. To analyze various organic and inorganic compounds.
4. To categorize compounds into groups.
Course Outcome: On successful completion of this course students will be able to:
1. Understand the basic concepts involved in quantitative and qualitative analysis.
2. Students will be able to understand the principles of titrimetric analysis.
3. Predict the chemical type, elements and functional groups of organic compounds.
Practical in Skill Enhancement Course
2. Handling of instruments
3. Preparation of solutions based on different units of concentration
4. Calibrations of Apparatus
1.3 Organic Preparation
1. Preparation of Phthalic Anhydride
2. Preparation of Methyl Salicylate
1.4 Analysis of water sample
1) PH
2) TDS
3) Conductivity
1.5 Preparation of Buffer solutions and determination of their PH
References:
1. College Inorganic Chemistry, Himalaya Publishing House
2. Concepts in Inorganic Chemistry, Chetana Publications Pvt. Ltd.
3. Vogel’s Textbook of Practical Organic Chemistry, Fifth Edition, B.
S. Furniss.
Examination Pattern
Distribution of Marks in SEC Practical Examination
6 Level UG
8 Status Revised
Date:
Signature
HoD,
Dept. of Chemistry
Shri Pancham Khemraj Mahavidyalaya, Sawantwadi
Proposed First Year Curriculum as per NEP 2020
Department of Chemistry
Structure for Open Elective
Cosmetics are products designed to cleanse, protect and change the appearance of external parts of our
bodies. The key ingredients present in most cosmetics include water, emulsifiers, preservatives,
thickeners, moisturisers, colours and fragrances. Ingredients can be naturally occurring or artificial, but
any potential impact on our health depends mainly on the chemical compounds used as raw material.
The salient feature of this programme is the emphasis being laid on the overall development of
student with major focus on application and filed work. The course manly focuses on Cosmetics,
Advances in cosmetic product development, Perfume Chemistry, Learning of analytical techniques used
in cosmetic and perfume industries etc. Students will get many opportunities of interactions with experts
in these fíelds during the course tenure. The students can gain hands on experience in the field while doing
internships in industries/research institutes/health sectors etc.
Course Objectives: To provide the learner with knowledge of cosmetics and perfumes with respect to
the types of formulations, evaluation and regulatory aspects.
Course Outcome: Upon completion of the course, the learner shall be able to:
3. Discuss the various cosmetics products w.r.t. raw materials, large scale manufacture and
functional and physiochemical evaluation.
COSMETICS:
Introduction:
History of Cosmetics,
A general study including preparation and uses of the following: Hair dye,
hair spray,
o shampoo, suntan lotions, face powder, lipsticks, talcum powder, nail
enamel, creams (cold, vanishing and shaving creams), antiperspirants and
OECHT 01 artificial flavours, Facial Make-up, Eye-Products, Lip Products
o Raw materials in cosmetics : Water, Oils, Fats, Waxes
o
References:
Books recommended:
1. Ann Eaton and Flurence Openshaw, Cosmetic Make – Up and Manicure.
2. A Professional Guide to Hair Dressing and Beauty Therapy by VeenaPitre
3. The Science of Cosmetics by John V. Simmons
4. Complete Beauty Book by Helen Foster
5. Vogue- Body and Beauty Book by Bronwen Meredith 6. A Guide for Health
& Beauty Therapist Vol.-1 Face, hands and feet by Gaynor Winyard
6. Foucher’s Perfumes, Cosmetics and Soaps – 10th Edition
Scheme of Examination
S. Z. S. P. Mandal’s
Shri Pancham Khemraj Mahavidyalaya,
Sawantwadi-416510
(Autonomous)
Affiliated to University of Mumbai
Syllabus for
Sem I and Sem II
2
Sr. No. Headings Perticulars
1 Title of the Program Science- Chemistry
3
Preamble
1. Introduction
Shri Pancham Khemraj Mahavidyalaya (S.P.K.M.), Sawantwadi (Autonomous) believes in
implementing several measures to bringequity, efficiency and excellence in higher education system
in conformity to the guidelines laid down by the University Grants Commission (UGC). In order to
achieve these goals, all efforts are made to ensure high standards of education by implementing
several steps to enhance the teaching- learning process, examination and evaluation techniques and
ensuring the all-round development oflearners.
The four-year course in B.Sc. Chemistry has been designed to have a progressive and
innovative curriculum in order to equip our learners to face the future challenges in the field of higher
education. In semesters I and II learners are introduced to the basic areas of Chemistry such as
Thermodynamics, Periodic table, Chemical Kinetics, Reaction and Mechanism.
In semesters III and IV the course content is made more rigorous by introducing the details of
each of the above area. In semesters V and VI, course are designed to help in specialization in the
core areas of Chemistry such as Molecular spectroscopy, Nuclear Chemistry, Chemical
thermodynamics, Chemical kinetics, Molecular Symmetry and Chemical Bonding, Solid state
Chemistry, Electrochemistry polymers, Quantum chemistry with Renewable energy resources
Chemistry of inner transition elements, Theories of the metal-ligand bond, Organometallic chemistry,
Mechanism of organic reactions , Stereochemistry, Synthesis of organic compounds, Quality in
Analytical Chemistry, Chemical Calculations, Optical Methods, Electro analytical techniques and
Applied components dyes and drugs. The practical course has been designed to help the student have
a firm grip on the theoretical concepts through relevant experiments in each course.
2. Objectives:
To help learners in developing a scientific attitude through the Chemistry curriculum that
involves basic and core areas of Chemistry along with the recent scientific and technological
advancements in applied areas of Chemistry
To enhance knowledge of Chemistry through problem solving, tutorials and seminars
To develop practical skills in Chemistry using a range of a activities such as projects in
experimental Chemistry, study tours, industrial and research institutes visit.
To inculcate a research attitude by involving learners in simple research projects review of
research articles/papers, participation in scientific events etc.
To help learners in developing analytical abilities and skills so as to address real world
problems
To help learners to plan a progressive and successful career in Chemistry, education and
industry
4
3. Program Outcome: After successful completion of this programme learners will be able to
Develop the knowledge of basic concepts of different branches of science required for
postgraduate studies.
Inculcate the skills useful in science laboratories for pursuing jobs in Industries.
Introduce learners to the concepts useful for environment protection.
Follow interdisciplinary approach for developing scientific temperament.
Identify, formulate and analyze scientific problems and reach concrete solutions for
societal benefits.
Expected Outcome
Acquire & explore essential skills to succeed in various chemical industries.
Get a hold on higher educational opportunities like post-graduation in chemistry.
Pursue higher studies in interdisciplinary areas such as biochemistry, genetics, pathology
etc.
Explore research areas in chemistry and related fields.
5
4. Credit Structure of the Programme ( Sem I & II)
Shri Pancham Khemraj Mahavidyalaya, Sawantwadi
Proposed First Year Curriculum as per NEP 2020
Department of Chemistry
Proposed Structure for Major / Minor/OE/VSE/SEC/VEC/IKS/VEC
6
Title of the Programme – B.Sc. Chemistry
7
Letter Grades and Grade points
AB (absent) Absent
8
DEPARTMENT OF CHEMISTRY
Syllabus
Proposed Syllabus for CBCS
F. Y. B. Sc. Major Chemistry
No of
No of
Semester Course Course title Lectures
Credits
Code In Hours
S106CHT
Physical and AnalyticalChemistry-II 2 30
(Major)
S107CHT
II Inorganic and OrganicChemistry -II 2 30
(Major)
S108CHP
2 60
(Major) Chemistry Practical-II
9
SEMESTER-II
COURSE TITLE: - PHYSICAL AND ANALYTICAL CHEMISTRY-II
COURSE CODE: S 106 CHT
Pre-requisites:
Knowledge of Chemical Thermodynamics, Gaseous State, Liquid State, Electrochemistry,
Molecular Spectroscopy.
Course Objectives: To introduce students to
Understand the direction of reactions and variation of thermodynamic properties.
Learn about the ideal and real gases and its behaviors.
Evaluate physical properties of liquid state.
Understand basic electrochemistry and its applications in the electrolytic solutions
Determine equilibrium constant and to predict direction of chemical reactions.
Learn the interaction of light with matter with respect to different phenomena.
Desired Outcomes: After the completion of this course, learners will be able to:
Understand the ideal and non-ideal behavior of gaseous reactions.
Differentiate various thermodynamic properties and its applications.
Evaluate different thermodynamic parameters by heat of reaction data.
Compare the weak and strong electrolytes based on conductance measurement
Determine the thermodynamic properties and its variations with temperature and
pressure.
Determine the conductance of solutions and its applications.
Differentiate the various spectroscopic techniques.
Course Content
UNIT Description Lectures
I Chemical Thermodynamics
1.1 Chemical Thermodynamics -II: 5
1.1.1 Second law of thermodynamics,
1.1.2 Concept of entropy,
1.1.3 Physical significance of entropy,
1.1.4 Concept of free energy,
1.1.5 Helmholtz and Gibbs free energy,
1.1.6 Variation of free energy with temperature and pressure,
1.1.7 Spontaneity and Physical significance of free energy.
1.1.8 Reversible and irreversible reactions
1.1.9 Equilibrium constant Kp and Kc and its relation
1.1.10 Thermodynamic derivation of equilibrium constant
10
1.2 Gaseous State:
1.2.1 Kinetic theory of gases,
1.2.2 Maxwell-Boltzmann’s distribution of velocities
(Qualitative discussion),
1.2.3 Ideal gas laws, 6
1.2.4 Deviation from ideal gas laws,
1.2.5 Ideal and Real gases,
1.2.6 Reasons for deviation from ideal gas laws,
1.2.7 Compressibility factor,
1.2.8 Boyle’s temperature,
1.2.9 van der Waals equation of state,
1.2.10 Critical phenomena,
1.2.11 Relation between critical constants and Vander Waals
constants. (Numerical problems expected wherever necessary)
1.3 Liquid State:
1.3.1 Surface tension: 4
1. Introduction,
2. Methods of determination of surface tension by drop
number method
1.3.2 Viscosity:
1. Introduction,
2. Coefficient of viscosity,
3. Relative viscosity,
4. Specific viscosity,
5. Reduced viscosity,
6. Determination of viscosity by Ostwald viscometer
1.3.3 Refractive index:
1. Introduction,
2. Molar refraction and polarizability,
3. Determination of refractive index by Abbe’s
Refractometer.
(Numerical problems expected wherever necessary)
1.3.4 Liquid Crystals
1. Introduction,
2. Classification, and structure of thermotropic phases
3. ( nematic, smectic, cholesteric)
4. Applications of liquid crystals
I 2.1. Chemical Equilibrium:
I 2.1.1 Reversible and irreversible reactions, 4
2 . 1 . 2 E quilibrium constants (Kc and Kp),
2 . 1 . 3 R elationship between Kc and Kp.
2 . 1 . 4 Thermodynamic derivation of equilibrium constant
(Numerical problems expected wherever necessary)
11
2.2. Electrochemistry-I:
2.2.1 Terms involve in Electrochemistry – I 7
1. Conductance,
2. Specific conductance,
3. Equivalent conductance,
4. Molar conductance,
2.2.2 Variation of molar conductance with concentration of strong
and weak electrolyte. Reversible electrodes, Electrode
potential, standard electrode potential
(Numerical problems expected wherever necessary).
2.3. Molecular Spectroscopy:
2.3.1 Electromagnetic radiation, Electromagnetic Spectrum,
2.3.2 Planck’s equation,
2.3.3 Interaction of Electromagnetic Radiation with matter; 4
2.3.4 Absorption, Emission, Scattering, Electronic, Vibrational and
Rotational transitions,
2.3.5 Beers Law, Lamberts Law,
Beer-Lamberts law, validity of Beer- Lamberts law.
References:
1. Atkins, P.W. and Julio de Paulo, Atkins’ Physical
Chemistry, Oxford University Press, UK, Indian Edition
9, 2011.
2. Samuel Glasstone, Thermodynamic for chemist, East West Press
Pvt.Ltd, Edition 3, (1947) ISBN: 9788176710145
3. Barrow, G.M. Physical Chemistry Tata McGraw‐Hill (2007).
4. Castellan, G.W. Physical Chemistry 4th Ed. Narosa (2004).
5. Samuel Glasstone, An iIntroduction to Electrochemistry,
vol.1,2,3 acmillan Publishing Co., New Delhi(2001)
6. C. N. Banwell, E. M. MaCASH, Fundamentals of
MolecularSpectroscopy,Fourth Edition.
12
SEMESTER-II
COURSE TITLE:- INORGANIC & ORGANIC CHEMISTRY-II
Course Code: S107 CHP
Pre-requisites:
Knowledge of concepts of qualitative analysis, Acid-Base theories and Chemical bond and
reactivity, basic concepts of organic chemistry.
Course Objectives:
To introduce students to
Systematic and coherent understanding of the fundamental concepts of qualitative analysis.
Importance of reagent papers for testing the radicals.
Understand the various theories of Acids and Bases.
Concepts of Chemistry of Aliphatic Hydrocarbons.
Comparison between Aliphatic and Aromatic compounds.
Important characteristics of organic compounds.
Concepts of projection formulae and inter-conversion.
Course Outcomes: On successful completion of this course students will be able to:
Understand the basic theories of Acids and Bases.
Students will be able to understand the concept of common ion effect.
Comparison between ionic and covalent bonds.
Classify compounds into aromatic, non –aromatic and anti aromatic.
Predict the correct method of preparation of alkenes, alkynes.
Identify the product and complete the reaction of alkenes and alkynes.
Carry out inter-conversion of projection formulae.
Course Content
UNIT Description Lectures
I 2.1 Concept of Qualitative Analysis (4L): 15
2.1.1 Testing of Gaseous Evolutes,
2.1.2 Role of Papers impregnated with reagents in qualitative analysis
(with reference to papers impregnated with starch-iodide,
potassium dichromate, lead acetate, dimethylglyoxime and oxine
reagents).
2.1.3 Precipitation Equilibria,
2.1.4 Formation of precipitates like AgCl, AgBr, AgI and BaSO4
Effect of following terms on precipitation of ionic compounds.–
1) Common ions 2) Uncommon ions, 3) Oxidation states,
4) Buffer action, 5) Complexing agents
(Balanced chemical equations)
2.2 Acid Base Theories (4L):
Arrhenius, Lowry- Bronsted, Lewis, Solvent – Solute concept of
acids and bases, Usanovich concept, Hard and Soft acids and
bases, Applications of HSAB.
13
2.3 Chemical Bond and Reactivity (3L):
Types of chemical bond, comparison between ionic and covalent
bonds, polarizability (Fajan’s Rule), basic VSEPR theory for
ABn type molecules with and without lone pair of electrons and
limitations of VSEPR theory.
2.4 Oxidation Reduction Chemistry: (4L)
2.4.1 Introduction, Reduction potentials,
2.4.2 Redox potentials: half reactions; balancing redox equations.
2.4.3 Introduction to Frost Diagrams , Latimer Diagram
2.4.4 Applications of Redox Chemistry; Redox reagents in
Volumetric analysis;
a) I2 b) KMnO4
14
Chemistry of Natural
Products), Dorling Kindersley (India) Pvt Ltd. (Pearson Education).
5. Eliel, E. L. and Wilen, S. H. Stereochemistry of Organic Compounds,
Wiley: London, 1994
6. Kalsi, P. S. Stereochemistry Conformation and Mechanism, New Age
International, 2005.
7. Mc Murry, J.E. Fundamentals of Organic Chemistry, 7th Ed. Cengage
Learning India Edition, 2013
8. Paula Y Bruice, Organic Chemistry, 7th Ed, Pearson education,
Asia.2014
9. Bahl and Bahl, Advanced Organic chemistry by S. Chand
publication.2010
10. Peter Sykes. Guidebook to the mechanism in Organic chemistry ,6 th
edition
11. D. Nasipuri.Stereochemistry of Organic Compounds,Principles
andApplications, Second Edition.
15
SEMESTER-II
COURSE TITLE: CHEMISTRY PRACTICAL -2
Course Code: S108CHP
Expected Leaning Outcome: On successful completion of this course learners will be able to:
1. Handle Electronic Balance for Various Experiments.
2. Measure accurate Volume and Analysis for Volumetric Analysis through experiments.
3. Prepare some Organic Derivatives and their Percentage Yield with accurate melting
point.
List of the experiments:
Physical Chemistry Experiments
1. To determine the rate constant for the saponification reaction between ethyl acetate and
NaOH.
2. To verify Beer-Lambert’s law, using KMnO4 solution by colorimetric method.
3. To standardize commercial sample of HCl using borax and to write material safety data of
the chemicals involved.
Inorganic Chemistry Experiments
1. Qualitative analysis: (at least 4 mixtures to be analyzed)
Semi-micro inorganic qualitative analysis of a sample containing two cations and two anions.
Cations (from amongst):
Pb2+, Ba2+, Ca2+, Sr2+, Cu2+, Cd2+, Fe2+, Ni2+, Mn2+, Mg2+, Al3+, Cr3+, K+, NH4+
Anions (from amongst):
CO32-, S2-, SO32-, NO2-, NO3-, Cl-, Br-, I-, SO42-, PO43-
(Scheme of analysis should avoid use of sulphide ion in any form for precipitation / separation
of cations.)
2. Gravimetric analysis:
a) To determine the percent purity of sample of BaSO4 containing NH4Cl.
b) To determine the percent purity of ZnO containing ZnCO3.
Organic Chemistry Experiments
1. Characterization of organic compound containing C, H, (O), N, S, X elements.
(minimum 6 compounds)
Reference Books:
1. Systematic experimental Physical chemistry – T. K. Chondhekar & S.W. Rajbhoj,
Anjali Publications, Aurangabad.
2. Experiments in chemistry – D.V. Jahagirdhar,Himalaya Publishing House.
3. Spectrometric Identification of Organic Compounds- R.M.Silverstein, G.C.Bassler,
Wiley: New York,5th edition.
4. Experiments and Techniques in Organic Chemistry-D.J.Pasto, C.R.Johnson, Prentice-
Hall: Englewood Cliffs.
All Experiments are compulsory for the Semester-II. Experiments must be written in
Journal. Certified journal is a must to be eligible for appearing term end examination.
16
EXAMINATION PATTERN FOR MAJOR SUBJECTS
A) Continuous Internal Assessment (40 Marks):
Total 82 60
17
C) Semester End Practical Examination (50 marks):
Scheme of examination:
There will be no internal assessment for practical.
A candidate will be allowed to appear for the semester end practical examination only if
the candidate submits a certified journal at the time of practical examination of the
semester or a certificate from the Head of the Department/Institute to the effect that the
candidate has completed the practical course of that semester of F.Y.B.Sc. Chemistry as
per the minimum requirement
The practical examination will be conducted in ONE SESSIONS of three hours each.
The learners will be evaluated based on the experiments performed during the examination.
The questions on slips for the same should be framed in such a way that candidate will be
able to complete the task and should be evaluated for the skill and understanding of
Chemistry.
Examination Pattern
Distribution of Marks in Practical Examination
18
Committee for Creation of Syllabus
Sr.
Name College Name Designation Signature
No.
S.P.K.Mahavidyalaya,
1 Asso. Prof. S.L.Vairage Chairman BOS
Sawantwadi
S.P.K.Mahavidyalaya,
2 Dr. D.B.Shinde Member
Sawantwadi
S.P.K.Mahavidyalaya,
3 Dr. U.C.Patil Member
Sawantwadi
S.P.K.Mahavidyalaya,
4 Dr. A.P.Nikum Member
Sawantwadi
S.P.K.Mahavidyalaya,
5 Dr. Y.A.Pawar Member
Sawantwadi
Subject Expert
Shivaji University,
6 Prof.Rashinkar Gajanan S. Nominated by AC
Kolhapur
other University
Subject Expert
Prof. Deshmukh Dayanand college,
7 Nominated by AC
Shamkumar P Solapur
other University
Athalye Sapre Pitre Expert Nominated
8 Dr. Sankpal Sagar T.
College,Devrukh by VC
Vice President (Tech)
Representative
9 Dr. Sonawane Atul E Indo Amines, Ltd
from Industry
Mumbai
Post Graduate
S.P.K.Mahavidyalaya,
10 Mr. Parab Prathamesh P Meritorious
Sawantwadi
Alumini
Kankavli College, Expert from
11 Dr. Disale Shamrao T.
Kankavli outside the college
19
S. Z. S. P. Mandal’s
SHRI PANCHAM KHEMRAJ MAHAVIDYALAYA
SAWANTWADI
DIST: SINDHUDURG- 416 510, MAHARASHTRA
6 Level UG
8 Status Revised
Date:
Signature
HoD,
Dept. of Chemistry
Shri Pancham Khemraj Mahavidyalaya, Sawantwadi
Proposed First Year Curriculum as per NEP 2020
Department of Chemistry
Proposed Structure for Major / Minor/OE/VSE/SEC/VEC/IKS/VEC
2
Program Outcome: After successful completion of this programme learners will be able to
Develop the knowledge of basic concepts of different branches of science required for
postgraduate studies.
Inculcate the skills useful in science laboratories for pursuing jobs in Industries.
Introduce learners to the concepts useful for environment protection.
Follow interdisciplinary approach for developing scientific temperament.
Identify, formulate and analyze scientific problems and reach concrete solutions forsocietal
benefits.
3
DEPARTMENT OF CHEMISTRY
Syllabus
Proposed Syllabus for CBCS
F. Y. B. Sc.: Minor Chemistry
No of
No. of
Semester Course Code Course title Lectures
Credits
In Hours
S109CHT
Physical and AnalyticalChemistry-II 2 30
(Minor)
S110CHT
II Inorganic and OrganicChemistry -II 2 30
(Minor)
S111CHP
Chemistry Practical-II 2 60
(Minor)
4
5
SEMESTER-II
Course Title: - Physical and Analytical Chemistry-II
Course Code: S109 CHT
Pre-requisites:
Course Outcomes: After the completion of this course, learners will be able to:
1. Understand the ideal and non-ideal behavior of gaseous reactions.
2. Differentiate various thermodynamic properties and its applications.
3. Evaluate different thermodynamic parameters by heat of reaction data.
4. Compare the weak and strong electrolytes based on conductance measurement
5. Determine the thermodynamic properties and its variations with temperature and
pressure.
6. Determine the conductance of solutions and its applications.
7. Differentiate the various spectroscopic techniques.
Course Content
UNIT Description Lectures
I 1.1 Chemical Thermodynamics -II: 5L
(Physical Second law of thermodynamics, concept of entropy, Physical
Chemistry)
significance of entropy, Concept of free energy, Helmholtz and Gibbs
free energy, Variation of free energy with temperature and pressure,
Spontaneity and Physical significance of free energy.
1.2 Gaseous State:
Kinetic theory of gases, Maxwell-Boltzmann’s distribution of velocities
(Qualitative discussion), Ideal gas laws, Deviation from ideal gas laws,
Ideal and real gases, Reasons for deviation from ideal gas laws, 6L
Compressibility factor, Boyle’s temperature, van der Waals equation of
state, Critical phenomena, Relation between critical constants and vander
Waals constants. (Numerical problems expected wherever necessary)
6
1.3 Liquid State:
Surface tension: Introduction, methods of determination of surface 4L
tension by drop number method Viscosity: Introduction, coefficient
of viscosity, relative viscosity, specific viscosity, reduced viscosity,
determination of viscosity by Ostwald viscometer Refractive index:
Introduction, molar refraction and polarizability, determination of
refractive index by Abbe’s refractometer. (Numerical problems
expected wherever necessary)
References:
1. Atkins, P.W. and Julio de Paulo, Atkins’Physical Chemistry,
Oxford University Press, UK, Indian Edition
2. Samuel Glasstone, Thermodynamic for chemist, East West PressPvt.Ltd,
Edition 3, (1947) ISBN: 9788176710145
3. K. J. Laidlar, Chemical Kinetics, Third Edition, PearsonPublication, (2007)
4. Barrow, G.M. Physical Chemistry Tata McGraw‐Hill (2007).
5. Castellan, G.W. Physical Chemistry 4th Ed. Narosa (2004).
6. K.L. Kapoor A textbook of Physical Chemistry 3rd Ed. vol.1,2,3 Macmillan
Publishing Co., New Delhi (2001)
7
References:
1. Atkins, P.W. and Julio de Paulo, Atkins’ Physical
Chemistry, Oxford University Press, UK, Indian Edition 9, 2011.
2. Samuel Glasstone, Thermodynamic for chemist, East West Press Pvt.
Ltd, Edition 3, (1947) ISBN: 9788176710145
3. Barrow, G.M. Physical Chemistry Tata McGraw‐Hill (2007).
4. Castellan, G.W. Physical Chemistry 4th Ed. Narosa (2004).
5. Samuel Glasstone, An introduction to Electrochemistry,
5. K.L. Kapoor A textbook of Physical Chemistry 3rd Ed. vol.1,2,3acmillan
Publishing Co., New Delhi(2001)
6.C. N. Banwell, E. M. MaCASH, Fundamentals of MolecularSpectroscopy,
Fourth Edition.
8
SEMESTER-II
Course Title:- Inorganic & Organic Chemistry-II
Course Code: S110 CHP
Pre-requisites:
Knowledge of concepts of qualitative analysis, Acid-Base theories and Chemical bond and
reactivity, basic concepts of organic chemistry.
Course Objectives:
To introduce students to
1. Systematic and coherent understanding of the fundamental concepts of qualitative analysis.
2. Importance of reagent papers for testing the radicals.
3. Understand the various theories of Acids and Bases.
4. Concepts of Chemistry of Aliphatic Hydrocarbons.
5. Comparison between Aliphatic and Aromatic compounds.
6. Important characteristics of organic compounds.
7. Concepts of projection formulae and inter-conversion.
Course Outcomes: On successful completion of this course students will be able to:
1. Understand the basic theories of Acids and Bases.
2. Students will be able to understand the concept of common ion effect.
3. Comparison between ionic and covalent bonds.
4. Classify compounds into aromatic, non –aromatic and anti aromatic.
5. Predict the correct method of preparation of alkenes, alkynes.
6. Identify the product and complete the reaction of alkenes and alkynes.
7. Carry out interconversion of projection formulae.
Course Content
UNIT Description Lectures
I 2.1 Concept of Qualitative Analysis (8L): 15L
( Inorganic Testing of Gaseous Evolutes, Role of Papers impregnated with ents in
Chemistry) qualitative analysis (with reference to papers impregnated with
starchiodide, potassium dichromate, lead acetate, dimethylglyoxime and
oxine reagents).
Precipitation equilibria, Formation of precipitates like AgCl, AgBr, AgI and
BaSO4 effect of common ions, uncommon ions, oxidation states, buffer
action, complexing agents on precipitation of ionic compounds. (Balanced
chemical equations)
2.2 Acid Base Theories (4L):
Arrhenius, Lowry- Bronsted, Lewis, Solvent – Solute concept of acids
and bases, Usanovich concept, Hard and Soft acids and bases,
Applications of HSAB.
2.3 Chemical Bond and Reactivity (3L):
Types of chemical bond, comparison between ionic and covalent bonds,
polarizability (Fajan’s Rule), basic VSEPR theory for ABn type
molecules with and without lone pair of electrons and limitations of
VSEPR theory.
9
Reference Books:
1. Concise Graduate Chemistry – I, II, III & IV, University Text Book of
Chemistry, University of Mumbai.
2. Lee, J.D. Concise Inorganic Chemistry ELBS, 1991.
3. Douglas, B.E. and McDaniel, D.H. Concepts & Models of Inorganic
Chemistry, Oxford, 1970
4. Atkins, P.W. & Paula, J. Physical Chemistry, 10th Ed., Oxford
University Press, 2014. Day, M.C. and Selbin, J. Theoretical Inorganic
Chemistry, ACS Publications, 1962.
5. Rodger, G.E. Inorganic and Solid State Chemistry, Cengage Learning
India
II 2.1 Chemistry of Aliphatic Hydrocarbons: 15 L
(Organic
Chemistry) 2.1.1 Carbon-Carbon sigma bonds (6L):
Chemistry of alkanes: Formation of alkanes, Wurtz Reaction, Wurtz-
Fittig Reactions, Free radical substitutions: Halogenation -relative
reactivity and selectivity.
2.1.2 Carbon-Carbon pi bonds:
Formation of alkenes and alkynes by elimination reactions: Mechanism
of E1, E2, E1cb reactions. Saytzeff and Hofmann eliminations.
Reactions of alkenes: Electrophilic additions and their mechanisms
(Markownikoff/ Anti-Markownikoff addition),
Mechanism of oxymercuration-demercuration, hydroboration-oxidation,
ozonolysis, reduction (catalytic and chemical), syn and anti-hydroxylation
(oxidation).
Reactions of alkynes: Acidity, Electrophilic and Nucleophilic additions.
Hydration to form carbonyl compounds, Alkylation of terminal alkynes.
10
(Reference Book:
1. Concise Graduate Chemistry – I, II, III & IV, University Text
Book of Chemistry,University of Mumbai.
2. Morrison, R. T. and Boyd, R. N. Organic Chemistry, Dorling
Kindersley (India) Pvt Ltd.(Pearson Education).2012
3. Finar, I. L. Organic Chemistry (Volume 1), Dorling Kindersley (India)
Pvt Ltd. (PearsonEducation).
4. Finar, I. L. Organic Chemistry (Volume 2: Stereochemistry and the
Chemistry of Natural
Products), Dorling Kindersley (India) Pvt Ltd. (Pearson Education).
5. Eliel, E. L. and Wilen, S. H. Stereochemistry of Organic Compounds,
Wiley: London, 1994
6. Kalsi, P. S. Stereochemistry Conformation and Mechanism, New Age
International, 2005.
7. Mc Murry, J.E. Fundamentals of Organic Chemistry, 7th Ed. Cengage
Learning India Edition, 2013
8. Paula Y Bruice, Organic Chemistry, 7th Ed, Pearson education,
Asia.2014
9. Bahl and Bahl, Advanced Organic chemistry by S. Chand
publication.2010
10. Peter Sykes. Guidebook to the mechanism in Organic chemistry ,6 th
edition
11. D. Nasipuri.Stereochemistry of Organic Compounds,Principles and
Applications, Second Edition.
11
SEMESTER-II
Course Title: Chemistry Practical -2
Course Code: S111 CHP
Leaning Outcome: On successful completion of this course learners will be able to:
1. Handle Electronic Balance for Various Experiments.
2. Measure accurate Volume and Analysis for Volumetric Analysis through experiments.
3. Prepare some Organic Derivatives and their Percentage Yield with accurate melting
point.
List of the experiments:
Physical Chemistry Experiments
1. To determine the rate constant for the saponification reaction between ethyl acetate and
NaOH.
2. To verify Beer-Lambert’s law, using KMnO4 solution by colorimetric method.
3. To standardize commercial sample of HCl using borax and to write material safety data of
the chemicals involved.
Inorganic Chemistry Experiments
1. Qualitative analysis: (at least 4 mixtures to be analyzed)
Semi-micro inorganic qualitative analysis of a sample containing two cations and two anions.
Cations (from amongst):
Pb2+, Ba2+, Ca2+, Sr2+, Cu2+, Cd2+, Fe2+, Ni2+, Mn2+, Mg2+, Al3+, Cr3+, K+, NH4+
Anions (from amongst):
CO32-, S2-, SO32-, NO2-, NO3-, Cl-, Br-, I-, SO42-, PO43-
(Scheme of analysis should avoid use of sulphide ion in any form for precipitation / separation
of cations.)
2. Gravimetric analysis:
a) To determine the percent purity of sample of BaSO4 containing NH4Cl.
b) To determine the percent purity of ZnO containing ZnCO3.
12
EXAMINATION PATTERN FOR MAJOR/MINOR SUBJECTS
A) Continuous Internal Assessment (40 Marks):
Total 82 60
13
C) Semester End Practical Examination (50 marks):
Scheme of examination:
There will be no internal assessment for practical.
A candidate will be allowed to appear for the semester end practical examination only if the
candidate submits a certified journal at the time of practical examination of the semester or a
certificate from the Head of the Department/Institute to the effect that the candidate has
completed the practical course of that semester of F.Y.B.Sc. Chemistry as per the minimum
requirement
The practical examination will be conducted in ONE SESSIONS of three hours each.
The learners will be evaluated based on the experiments performed during the examination.
The questions on slips for the same should be framed in such a way that candidate will be able
to complete the task and should be evaluated for the skill and understanding of Chemistry.
Examination Pattern
Distribution of Marks in Practical Examination
14
AC ITEM NO. :AC
S. Z. S. P. Mandal’s
SHRI PANCHAM KHEMRAJ MAHAVIDYALAYA SAWANTWADI
DIST: SINDHUDURG- 416 510, MAHARASHTRA
No of
No of Lectures
Semester Course Code Course Title Credits in
Hours
Course Outcomes:
After completion of this course, learners will be able to
1. Determine the amount of analyte in a chemical analysis.
2. Understand the principles of titrimetric analysis.
3. Distinguish between various types of titrimetric analysis.
Practical in Skill Enhancement Course
6 Level UG
7 Pattern Semester
8 Status Revised
Date:
Signature
HoD,
Dept. of Chemistry
Shri Pancham Khemraj Mahavidyalaya, Sawantwadi
Proposed First Year Curriculum as per NEP 2020
Department of Chemistry
Structure for Indian Knowledge System
Course Outcomes:
India has a very ancient tradition of chemistry. In ancient India, chemistry was called “Rasayana”
in Sanskrit, the language in vogue. Rasayana derived its name from “Rasa,” which means “extract,”
maybe from roots, leaves, and stems of plants In ancient text, amazing information are available on metals,
ores, their quarries, compound and alloys. There are also details of hundreds of devices used in chemical
experiments in “Rasayan Shastra” which we call ‘Chemistry’ There have been many chemists in the past,
the creations of some of them are as – Nagarjuna , Vagbhatt, Govindacharya, Somdev etc. In any early
civilization, metallurgy has remained an activity from the Bronze Age and the Iron Age, to all other
civilizations that followed.
Course Objectives: To provide the learner with knowledge Benefits of Rasayana, Material and Process
with respect to the types of formulations, evaluation and regulatory aspects.
Course Outcome: Upon completion of the course, the learner shall be able to:
3. Discuss the various physico –chemical concepts in Ayurveda products w.r.t. raw materials,
functional and physiochemical evaluation.
No. of
UNIT Syllabus
Hours
A) Internal Assessment:
Sr. No. Particulars Marks
1 One assignment/test/Seminar/Presentation 10
2 Class attendance 05
3 Subject based activity 05
Total Marks 20
B) External Assessment:
6 Level UG
8 Status Revised
Date:
Signature
HoD,
Dept. of Chemistry
Shri Pancham Khemraj Mahavidyalaya, Sawantwadi
Proposed First Year Curriculum as per NEP 2020
Department of Chemistry
Structure for Major / Minor
Perfumery are products designed to cleanse, protect and change the appearance of external parts of our
bodies. The key ingredients present in most cosmetics include water, emulsifiers, preservatives,
thickeners, moisturisers, colours and fragrances. Ingredients can be naturally occurring or artificial, but
any potential impact on our health depends mainly on the chemical compounds used as raw material.
The salient feature of this programme is the emphasis being laid on the overall development of
student with major focus on application and filed work. The course manly focuses on Cosmetics,
Advances in cosmetic product development, Perfume Chemistry, Learning of analytical techniques used
in cosmetic and perfume industries etc. Students will get many opportunities of interactions with experts
in these fíelds during the course tenure. The students can gain hands on experience in the field while doing
internships in industries/research institutes/health sectors etc.
Course Objectives: To provide the learner with knowledge of cosmetics and perfumes with respect to
the types of formulations, evaluation and regulatory aspects.
Course Outcome: Upon completion of the course, the learner shall be able to:
Syllabus
Perfumery
Raw materials in Perfumery
History of Perfumes
Indian and Global Perfumery Trends
Powders, Emulsifiers, Thickeners and Gums
OECH02 Essential oils and their importance in Perfumery industries with reference to
Eugenol, Geraniol, sandalwood oil, rose oil, 2-phenyl ethyl alcohol, Jasmone,
Civetone, Muscone.
Reference:
6 Level UG
8 Status Revised
Date:
Signature
HoD,
Dept. of Chemistry
Shri Pancham Khemraj Mahavidyalaya, Sawantwadi
Proposed First Year Curriculum as per NEP 2020
Department of Chemistry
Syllabus Structure for Open Elective
COURSE OBJECTIVES:
To study about environment and ecosystems
To study about different types of natural resource.
Knowledge and concept of biodiversity and its conservation.
Basic knowledge and concept of causes, effect and control of different type of
environmental pollution.
To study population growth and its impact on environment
COURSE OUTCOMES (CO): After completion of the course, a student will be able to COURSE
OUTCOME :
CO1 - Gain knowledge about environment and ecosystem.
CO2 - Students will learn about natural resource, its importance and environmental impacts of
human activities on natural resource.
CO3-Gain knowledge about the conservation of biodiversity and its importance.
CO4 Aware students about problems of environmental pollution, its impact on human and
ecosystem and control measures.
CO5- Students will learn about increase in population growth and its impact on environment
SEMESTER-II
OPEN ELECTIVE
ENVIRONMENT SCIENCE: OECHT 03 (Credit 02) [30 L]
Environment Science:
Environmental Pollution:
b) Water pollution
c) Soil pollution
d) Marine pollution
e) Noise pollution
References: