Testing of Biodiesel
Testing of Biodiesel
calorific value?
Aim:
To determine the energy content of biodiesel from its combustion using calorimetry.
Hypothesis:
If the combustion of fuel using calorimetry is an accurate method for determining the energy
content of biodiesel made from vegetable oil, then the energy content of biodiesel will be
similar to the calorific value of 33kJ/g.
Introduction:
Biodiesel is a renewable fuel that can be derived from animal fats or plant oils. Biodiesel is
produced via a transesterification reaction with triglyceride and alcohol as reactants, forming
alkyl esters and glycerol as products with the addition of a catalyst. Biodiesel can be created
from vegetable oil and methanol with a potassium hydroxide catalyst in the laboratory.
The energy content of biodiesel can be determined through calorimetry. Calorimetry is a
process that can be used to determine the energy content of a fuel by measuring the change in
temperature of the water from the combustion of fuel.
Results:
Trial 1 Trial 2
Mass of Empty Calorimeter Can 42.755g 42.755g
Mass of Can and Water 139.986g 140.984g
Initial Mass of Burner, Cap and Burner 245.832g 245.091g
Final Mass of Burner, Cap and Burner 245.091g 244.440g
Initial Temperature of Water 25°C 22°C
Final Temperature of Water 55°C 52°C
Trial 1 Trial 2
Mass of Biodiesel Burnt: 0.741g Mass of Biodiesel Burnt: 0.651g
Temperature Change of Water: 30°C Temperature Change of Water: 30°C
Mass of Water: 97.231g Mass of Water: 98.229g
Conclusion:
It was hypothesised that the energy content of biodiesel produced from vegetable oil
determined through calorimetry would be relatively similar to the calorific value. However,
the experiment was not supported as the energy content of biodiesel determined
experimentally was an average of 17.69kJ/g, whilst the calorimetric value was 33kJ/g.