0% found this document useful (0 votes)
29 views31 pages

Examen 1 - PS1-Uribe Garcia Jairo Levi

The document contains temperature and vapor pressure data for water in Celsius degrees and mm Hg. It also contains enthalpy values (i_G) in kcal/kg. There are constants provided for the Antoine equation to calculate vapor pressure from temperature. The data is presented in a table and appears to be used to calculate vapor-liquid equilibrium values and enthalpy of vaporization for water over a range of temperatures from 0 to 100°C.

Uploaded by

Jairo Garcia
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as XLSX, PDF, TXT or read online on Scribd
0% found this document useful (0 votes)
29 views31 pages

Examen 1 - PS1-Uribe Garcia Jairo Levi

The document contains temperature and vapor pressure data for water in Celsius degrees and mm Hg. It also contains enthalpy values (i_G) in kcal/kg. There are constants provided for the Antoine equation to calculate vapor pressure from temperature. The data is presented in a table and appears to be used to calculate vapor-liquid equilibrium values and enthalpy of vaporization for water over a range of temperatures from 0 to 100°C.

Uploaded by

Jairo Garcia
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as XLSX, PDF, TXT or read online on Scribd
You are on page 1/ 31

𝑫𝒓. 𝑹𝒆𝒏𝒅𝒐𝒏 𝑯𝒆𝒓𝒏á𝒏𝒅𝒆𝒛 𝑭𝒂𝒃𝒊á𝒏 𝑱.

𝑪𝒂𝒍𝒄𝒖𝒍𝒐 𝒅𝒆 𝒍𝒂 𝒆𝒏𝒕𝒂𝒍𝒑í𝒂 (𝒙𝒙) 𝒂𝒕𝒎

𝑻𝒆𝒎𝒑𝒆𝒓𝒂𝒕𝒖𝒓𝒂 °𝑪 𝑷𝒓𝒆𝒔𝒊ó𝒏 𝒅𝒆 𝒔𝒂𝒕. 𝒎𝒎 𝑯𝒈 𝒀 𝒊_𝑮 (𝒌𝒄𝒂𝒍)


0 4.58 0.003761375 2.25
1 4.92 0.004047038 2.66
2 5.29 0.004351834 3.08
3 5.68 0.004676878 3.52
4 6.10 0.005023339 3.97
5 6.55 0.005392447 4.43
6 7.02 0.00578549 4.91
7 7.52 0.006203825 5.40
8 8.05 0.006648874 5.92
9 8.62 0.007122131 6.44
10 9.22 0.007625163 6.99
11 9.86 0.008159616 7.55
12 10.54 0.008727217 8.14
13 11.25 0.009329779 8.75
14 12.01 0.009969208 9.38
15 12.82 0.0106475 10.03
16 13.67 0.011366755 10.71
17 14.57 0.012129178 11.42
18 15.52 0.012937082 12.15
19 16.52 0.0137929 12.92
20 17.58 0.014699188 13.71
21 18.70 0.015658633 14.54
22 19.88 0.016674058 15.41
23 21.13 0.017748436 16.31
24 22.44 0.018884891 17.25
25 23.82 0.020086716 18.23
26 25.28 0.021357374 19.25
27 26.81 0.022700519 20.32
28 28.43 0.024119999 21.44
29 30.13 0.025619873 22.60
30 31.91 0.027204428 23.82
31 33.79 0.028878187 25.10
32 35.76 0.030645935 26.43
33 37.83 0.032512726 27.83
34 40.00 0.034483915 29.29
35 42.28 0.036565171 30.83
36 44.67 0.038762502 32.43
37 47.18 0.041082286 34.11
38 49.81 0.043531294 35.88
39 52.56 0.046116724 37.73
40 55.45 0.048846237 39.67
41 58.47 0.05172799 41.71
42 61.63 0.054770686 43.85
43 64.93 0.057983613 46.09
44 68.39 0.0613767 48.46
45 72.00 0.064960575 50.94
46 75.78 0.068746624 53.55
47 79.73 0.072747067 56.30
48 83.85 0.076975036 59.19
49 88.16 0.081444663 62.23
50 92.65 0.086171177 65.44
51 97.34 0.091171021 68.83
52 102.23 0.096461974 72.39
53 107.32 0.102063293 76.16
54 112.64 0.107995873 80.14
55 118.17 0.114282429 84.34
56 123.94 0.120947704 88.79
57 129.95 0.128018703 93.49
58 136.20 0.13552496 98.47
59 142.71 0.14349885 103.75
60 149.48 0.151975943 109.35
61 156.53 0.160995411 115.30
62 163.85 0.170600506 121.63
63 171.47 0.180839108 128.36
64 179.38 0.191764369 135.53
65 187.61 0.203435467 143.17
66 196.15 0.215918494 151.34
67 205.02 0.2292875 160.08
68 214.22 0.243625741 169.43
69 223.78 0.259027161 179.47
70 233.69 0.275598177 190.26
71 243.97 0.293459831 201.88
72 254.64 0.312750398 214.41
73 265.70 0.333628584 227.97
74 277.15 0.356277453 242.66
75 289.03 0.380909304 258.62
76 301.33 0.407771759 276.02
77 314.07 0.437155448 295.03
78 327.26 0.469403783 315.89
79 340.92 0.504925536 338.85
80 355.05 0.544211174 364.23
81 369.68 0.587854372 392.41
82 384.80 0.636580684 423.86
83 400.45 0.691286344 459.15
84 416.62 0.753091615 499.01
85 433.35 0.823415493 544.34
86 450.63 0.904082418 596.32
87 468.48 0.997478267 656.49
88 486.93 1.106784355 726.89
89 505.98 1.236339124 810.32
90 525.65 1.392216919 910.67
91 545.96 1.583192765 1033.60
92 566.92 1.822431061 1187.56
93 588.55 2.130622471 1385.88
94 610.86 2.542259582 1650.72
95 633.88 3.119448802 2022.05
96 657.61 3.986458781 2579.80
97 682.08 5.433448816 3510.58
98 707.31 8.33194445 5374.96
99 733.31 17.05218663 10983.88
100 760.10 -4812.73152 -3095524.91
log10 Pvap = A- [B/(T °C+ C)] mmHg

Constantes
Formula Nombre A B C
𝑯_𝟐 𝑶 𝑨𝒈𝒖𝒂 8.05573 1723.6425 233.08

Presión del sistema Equilibrio


𝑴_𝒂𝒈𝒖𝒂 18 𝒌𝒈∕𝒌𝒎𝒐𝒍 0 2.25
𝑴_𝒂𝒊𝒓𝒆 29 𝒌𝒈∕𝒌𝒎𝒐𝒍 1 2.66
Presión 760 mm Hg 2 3.08
3 3.52
𝒀=𝑴_𝒗/𝑴_𝒈 ∙𝒑_𝒔𝒂𝒕/(𝑷−𝒑_𝒔𝒂𝒕 ) 4 3.97
5 4.43
6 4.91
𝒊_𝑮=(𝟎.𝟐𝟒+𝟎.𝟒𝟔 𝒀)𝒕+𝟓𝟗𝟕.𝟐 𝒀 7 5.40
8 5.92
9 6.44
10 6.99
11 7.55
12 8.14
13 8.75
14 9.38
15 10.03
16 10.71
17 11.42
18 12.15
19 12.92
20 13.71
21 14.54
22 15.41
23 16.31
24 17.25
25 18.23
26 19.25
27 20.32
28 21.44
29 22.60
30 23.82
31 25.10
32 26.43
33 27.83
34 29.29
35 30.83
36 32.43
37 34.11
38 35.88
39 37.73
40 39.67
41 41.71
42 43.85
43 46.09
44 48.46
45 50.94
46 53.55
47 56.30
48 59.19
49 62.23
50 65.44
51 68.83
52 72.39
53 76.16
54 80.14
55 84.34
56 88.79
57 93.49
58 98.47
59 103.75
60 109.35
61 115.30
62 121.63
63 128.36
64 135.53
65 143.17
66 151.34
67 160.08
68 169.43
69 179.47
70 190.26
71 201.88
72 214.41
73 227.97
74 242.66
75 258.62
76 276.02
77 295.03
78 315.89
79 338.85
80 364.23
81 392.41
82 423.86
83 459.15
84 499.01
85 544.34
86 596.32
87 656.49
88 726.89
89 810.32
90 910.67
91 1033.60
92 1187.56
93 1385.88
94 1650.72
95 2022.05
96 2579.80
97 3510.58
98 5374.96
99 10983.88
100 -3095524.91
110
105
100
95
90
85
80
75
70
65
60
i kcal/kg

55
50
45
40
35
30
25
20
15
10
5
0
0 5 10 15 20 25 30 35 40 45 50 55 60

t °C
JAIRO LEVI URIBE GARCIA PROCESOS DE SEPARACION 1

Datos
𝑳 60000 𝑳∕𝒉
𝑮 59040 𝒌𝒈∕𝒉
𝒄_𝑳 1 𝒌𝒄𝒂𝒍∕ 〖𝒌𝒈∙ °𝑪 〗
𝑨 1 𝒎^𝟐
𝑲_𝒀 𝒂 1000 𝒌𝒈∕ 〖𝒎 ^𝟑∙𝒉 〗
𝒕_(𝑳_𝟏 ) 30 °𝑪
𝒕_(𝑳_𝟐 ) 55 °𝑪
tg 30 °C
tw 24 °C

Constantes de antoine
Especie Formula A B C
Agua H2O 8.05573 1723.6425 233.08

Magua 18 kg/kmol
Maire 29 kg/kmol
Y 0.0163 Kcal/kg

iG (0.24+0.46 Y)t + 597.2 Y

Calculo de i_G
17.1593

(LcL/Gmin) 1.01626016

i2 42.5658041 kcal/kg

Calculamos( LcL/G)max
1.01626016260163
Calculando Gmax/G
59040

Area de la sección
1 m2
100

95

90

85

80

75

70

65

60

55

i kcal/kg
50

45

40

35

30

25

20

15

10

0
0 5 10 15 20 25 30 35

n
0
1
2
3
4
5
6
Entalpia de la inte
t
30
34.1666667
38.3333333
42.5
46.6666667
50.8333333
55

𝑃=10^(𝐴−𝐵/(𝑇+𝐶))
100
95
90
85
80
75
70
65
60
55

i kcal/kg
50
45
40
35
30
25
20
15
10
5
0
0 5 10 15 20

5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80

t °C

Linea de operación Simpson 1/3


tL i_G tL
30 17.1593 0 30
55 42.5658041 30

1 34.1666667
Simpson 1/3 34.1666667

𝒉=(𝒃−𝒂)/𝒏
h 4.23441734 2 38.3333333
38.3333333
t1 i t2 i* f(x)
30 17.1593 30 23.8219053 0.15009144 3 42.5
34.1666667 21.3937173 34.1666667 29.5435908 0.12270129 42.5
38.3333333 25.6281347 38.3333333 36.4848139 0.0921092
42.5 29.862552 42.5 44.9571101 0.06624904 4 46.6666667
46.6666667 34.0969694 46.6666667 55.3659783 0.04701677 46.6666667
50.8333333 38.3313867 50.8333333 68.2498429 0.03342418
55 42.5658041 55 84.340812 0.02393776 5 50.8333333
Entalpia de la interfase 50.8333333
P Y i
31.9116436 0.02720443 23.8219053 6 55
40.373702 0.03482299 29.5435908 55
50.7121043 0.04437758 36.4848139
63.2602071 0.05635527 44.9571101
78.3951674 0.07138897 55.3659783
96.5414039 0.090318 68.2498429
118.174075 0.11428243 84.340812

0^(𝐴−𝐵/(𝑇+𝐶)) 𝑌=𝑀_𝑣/𝑀_𝑔 ∗𝑃_𝑣/(𝑃−𝑃_𝑣 )

i=(0.24+0.46Y)t+597.2Y
100
95
90
85
80
75
70
65
60
55
i kcal/kg

50
45
40
35
30
25
20
15
10
5
0
0 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80

t °C

tL i
tL i HIPOTENUSA
i A AA
17.1593 24 17.1593 24 17.1593 m
23.8219053 30 17.1593 30 23.8219053 B

21.3937173 B HIPOTENUSA
29.5435908 27.8132987 21.3937173 BB
34.1666667 21.3937173 27.8132987 21.3937173 m
25.6281347 34.1666667 29.5435908 B
36.4848139 C
31.1143084 25.6281347 HIPOTENUSA
29.862552 38.3333333 25.6281347 CC
44.9571101 31.1143084 25.6281347 m
D 38.3333333 36.4848139 B
34.0969694 33.9299359 29.862552
55.3659783 42.5 29.862552 HIPOTENUSA
DD
38.3313867 E 33.9299359 29.862552 m
68.2498429 36.3340625 34.0969694 42.5 44.9571101 B
46.6666667 34.0969694
42.5658041 HIPOTENUSA
84.340812 F EE
38.3911662 38.3313867 36.3340625 34.0969694 m
50.8333333 38.3313867 46.6666667 55.3659783 B

G HIPOTENUSA
40.1521304 42.5658041 FF
55 42.5658041 38.3911662 38.3313867 m
50.8333333 68.2498429 B

HIPOTENUSA
GG
40.1521304 42.5658041 m
55 84.340812 B

t 40.1521304
100
95
90
85
80
75
70
65
60
55
i kcal/kg

50
45
40
35
30
25
20
15
10
5
0
0 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80

t °C

RESULTADOS
Noi 1.89388435
Hoy 59.04 m
1.11043422 z 111.814932 m
-9.49112132

V 111.814932 m3
1.28276427
-14.2841884
Conclusion
Obtenemos que para las condiciones de operaciónes dadas el volumen re

1.50389828
-21.1646203

1.76131216
-29.8986566

2.05843644
-40.6943887

2.4046017
-53.9840769

2.81353547
-70.403639
𝑁_𝑜𝑖=ℎ/3[𝑓(𝑎)+𝑓(𝑏)+4∑▒ 〖𝑖𝑚𝑝𝑎𝑟𝑒𝑠 +2∑▒𝑝𝑎𝑟𝑒𝑠 〗 ]

𝐻_𝑜𝑖=𝐺′/𝐾𝑦𝑎
𝑧=𝐻𝑜𝑖 ∗𝑁𝑜𝑖

operaciónes dadas el volumen requerido será de 111.8149m3


URIBE GARCIA JAIRO LEVI PROCESOS DE SEPARACIÓN 1

Datos
𝒕_(𝑳_𝟏 20 °𝑪
)
𝒕_(𝑳_𝟐 ) 50 °𝑪
𝒕_(𝑮_𝟏 ) 18 °𝑪
𝝋 30 %
𝑮′ 2500 𝒌𝒈∕ 〖𝒎 ^𝟐∙𝒉 〗
𝑳′ 1000 𝒌𝒈∕ 〖𝒎 ^𝟐∙𝒉 〗
𝑲_𝒀 𝒂 1200 𝒌𝒈∕ 〖𝒎 ^𝟑∙𝒉 〗
𝝆_agua 1000 𝒌𝒈∕𝒎^𝟑
𝑪_𝑳 4.18 𝒌𝑱∕ 〖𝑲𝒈∙ °𝑪 〗
𝑪_𝑳 1 𝒌𝒄𝒂𝒍∕ 〖𝑲𝒈∙ °𝑪 〗
M_agua 18 𝒌𝒈∕𝒌𝒎𝒐𝒍
M_aire 29 𝒌𝒈∕𝒌𝒎𝒐𝒍
𝝆_𝒂𝒊𝒓𝒆 1.2 𝒌𝒈∕𝒎^𝟑

Constantes
Formula Nombre A B C
𝑯_𝟐 𝑶 𝑨𝒈𝒖𝒂 8.05573 1723.6425 233.08
De la carta psicometrica obtenemos:
Y 0.0036 Kg de agua/ Kg de aire seco
Calculamos i_G1 con
iG= (0.24+0.46 Y)t + 597.2 Y

iG1= 6.499728 Kcal/kg


80

75

70

65

60

55

50

45
i kcal/kg

40

35

30

25

20

15

10

0
0 5 10 15 20 25 30 35 40 45 50 55 60 65 70

t °C

Linea de operación
tL i_G
20 6.499728
50 18.499728

Pendiente de la tangente ((𝑳𝒄_𝑳)/


(LcL/G) 0.4 Kcal/kg 𝑮_𝑺
)=(𝒊_𝑮𝟐−𝒊_𝑮𝟏)/(𝒕_(𝑳
_𝟐 )−𝒕_(𝑳_𝟏 ) )
iG2 18.499728 Kcal/Kg𝒊_𝟐=( 〖𝑳𝒄 _𝑳 〗∕𝑮 )(𝒕_(𝑳_𝟐 )−𝒕_(𝑳_𝟏 ) )+
80

75

70

65

60

55

50

45
i kcal/kg

40

35

30

25

20

15

10

0
0 55 60 65 70 0 5 10 15 20 25 30 35 40 45 50 55 60 65 70

t °C

Simpson 1/3

h 2 𝒉=(𝒃−𝒂)/𝒏
n t1 i t2 i*
0 20 6.499728 20 13.7135878
1 25 8.499728 25 18.2267838
_𝑮𝟏)/(𝒕_(𝑳 2 30 10.499728 30 23.8219053
𝟏)) 3 35 12.499728 35 30.8254191
𝑮 )(𝒕_(𝑳_𝟐 )−𝒕_(𝑳_𝟏 ) )+𝒊_𝟏 4 40 14.499728 40 39.6697432
5 45 16.499728 45 50.9391392
6 50 18.499728 50 65.443364
Entalpia de la interfase
t P Y i 𝑃=10^(𝐴−𝐵/(𝑇+𝐶))
20 17.5819631 0.01469919 13.7135878
25 23.8240743 0.02008672 18.2267838
𝑌=𝑀_𝑣/𝑀_𝑔 ∗𝑃_𝑣/(𝑃−𝑃_𝑣 )
30 31.9116436 0.02720443 23.8219053
35 42.2812105 0.03656517 30.8254191
40 55.4460788 0.04884624 39.6697432 i=(0.24+0.46Y)t+597.2Y
45 72.0046967 0.06496057 50.9391392
50 92.6492056 0.08617118 65.443364
𝑁_𝑜𝑖=ℎ/3[𝑓(𝑎)+𝑓(𝑏)+4∑▒ 〖𝑖𝑚𝑝𝑎𝑟𝑒𝑠 +2∑▒𝑝𝑎𝑟𝑒𝑠 〗 ]

𝐻_𝑜𝑖=𝐺′/𝐾𝑦𝑎
𝑧=𝐻𝑜𝑖 ∗𝑁𝑜𝑖

Noi 0.75676824
Hoy 2.08333333 m
Z 1.57660049 m

Conclusiones
La altura necesaria para las condiciones a las que estamaremos trabajando será de 1.5766005 m

45 50 55 60 65 70

0
t_L i
20 6.499728
20 13.7135878
f(x)
0.13862204 1
0.10280603 25 8.499728
0.07506281 25 18.2267838
0.0545682
0.03972981 2
0.0290365 30 10.499728
0.02130214 30 23.8219053

𝑃=10^(𝐴−𝐵/(𝑇+𝐶)) 3
35 12.499728
35 30.8254191
=𝑀_𝑣/𝑀_𝑔 ∗𝑃_𝑣/(𝑃−𝑃_𝑣 )

4
i=(0.24+0.46Y)t+597.2Y 40 14.499728
40 39.6697432

5
45 16.499728
45 50.9391392

6
50 18.499728
50 65.443364
ajando será de 1.5766005 m

You might also like