BASIC ADVANCED LEVEL CHEMISTRY PRACTICAL

FORM FIVE & SIX SCIENCE

ADVANCEMENT IS NOT BY SYMPATHY

Still have problems or weak in the subject?

Recess term assistance / Holiday Program.

Contact & Book Senior Tutor: Tr.Js FELIX RUBANGAKENE Jr GEOFREY

Duty station : Pajule

Booking : +𝟐𝟓𝟔 (𝟎)𝟕𝟕𝟑 𝟗𝟏𝟓 𝟗𝟖𝟑

𝟕𝟎𝟒 𝟓𝟑𝟔 𝟏𝟔𝟗
Email : [email protected]

Objective : helping you understand Fundamental

Principles of the subject.

1ST EDITION 2018 NEW CHEMISTRY PRACTICAL GUIDE:

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 BASIC ADVANCED LEVEL CHEMISTRY PRACTICAL

Compendium new chemistry practical guide is without work/note for question

number 1 according to Ugandan syllabus (Uganda national examination board)
But compendium new chemistry practical guide contain questions number 2 & 3
which is well explained and it’s in Uganda advanced certificate of education
format and therefore, I really promised to avail question 1 at the time of
publication of 2nd edition if need arises.
IN THE NAME OF GOD MOST GRACIOUS, MOST MERCIFUL,

DEDICATION:
I dedicate this book to my parents Mr.P’Ochure Michael Ocaya & Mrs.Ocaya
Christian Akumu the late (RIP) for continued love, moral, financial, & spiritual
assistance rendered to me since childhood and throughout my life to-date.

There are those special people in this world who give & give without taking who
offer without asking for much in return, I dedicate this book to the best of them.

MAY THE ALMIGHTY FATHER REWARD ALL OF YOU ABUNDANTLY.

ACKNOWLEGEMENTS:
I am grateful to my parents for whatever they have rendered to me.
Work of this nation is by no means a single person’s effort. It has been a result of
many kind and helpful people who have willingly assisted me whenever
approached.

I am also grateful to my great teachers, Mr. Otto Stephen, Mr.Obala Peter RIP,
Okello Charles Waliky & Mr.Kilama Stephen of Sir Samuel Baker School, who
labored to take me thought the impenetrable maze of science to make me
appreciate it to the point of producing work of this nature.

I am also particularly grateful to senior Chemist Mr. Otto Stephen for the tireless
efforts, advice & guidance he accorded to me during the writing of this book so as
to reach this standard.
Am grateful to him for keeping everything going while I am off in my academic
pursuance and university.
More so I am grateful for his sharp editorial eye.

I can’t forget to move a vote of thanks to my colleagues, Dr.Oyo Benedict &

Dr.Bongomin Felix of Gulu University, Mr. Keith Obot & Mr.Onen Tony of St.
Mary’s College Kisubi, Mr.Wokorach Godfrey of St. Joseph’s College Layibi for the

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 BASIC ADVANCED LEVEL CHEMISTRY PRACTICAL

support and advise they rendered to me when I was carrying out research on the
subject.
To my former students of Lira Integrated Senior Secondary School, Especially
Adopo Julius was my greatest motivators.

PREFACE:

In this era of scientific advancement, Chemistry becomes unavoidable.

This book is intended for use in secondary especially advanced level.

It will enable both the teachers and the students to focus intensively on each
practical.
It contains detailed scientific approaches, experiments, explanations and
illustrations.

Revision questions and Answers are provided topic by topic meanwhile UNEB
sample questions are also provided.
These questions are intended to form the basics of interactions between teachers
and students or student discussion groups.

To emphasize this, the simplified language and approach used in this book aims
at making chemistry as a subject easy to understand, straight forward, attractive
& friendly to students.
This book has been developed in line with the most recent developments of
Uganda national curriculum center teaching syllabus and UNEB syllabus.
It is therefore of great advantage to all secondary schools most especially those
which may not be able to provide a wide range of text books for use by their
teachers, students & the discussion groups.
The trial questions are intended to enhance group discussion for students,
reference questions are for exams & seminars.
We hope that the student who follows the layout of this book will in the end have
got enough experience in enabling a wide range of questions in exams.
The students will be fully prepared to both mock and UNEB examinations.
We have a vision as most students will turn as scientists to meet the ever
increased demand for science graduate in various technical discipline of
medicine, agriculture & forestry.

And finally, I dedicate this book to my special wife Ms Baseke Bridget (Tutor)
Felix Rubangakene Geofrey.

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INTRODUCTION TO INORGANIC CHEMISTRY

Definition for Inorganic Chemistry: Inorganic Chemistry is the branch of
chemistry concerned with the properties and behavior of inorganic compounds.
This field covers all chemical compounds except the myriad organic compounds
(Carbon based compounds, usually containing C-H bonds).
Key learning points:
Many inorganic compounds are ionic compounds, consisting of cations and anions
joined by ionic bonding. In any salt, the proportions of the ions are such that the
electric charges cancel out, so that the bulk compound is electrically neutral. The
ions are described by their oxidation state and their ease of formation can be
inferred from the ionization potential for cations or from the electronaffinity
(anions) of the parent elements.
The structure of the ionic framework in potassium oxide, K2O
Importance classes of inorganic salts are the oxides, carbonates, sulphates and
halides. Inorganic salts typically are poor conductors in the solid state. Another
important features is their solubility in water example (see solubility chart on the
next page), and ease of crystallization. Where some salts (e.g. NaCl) are very
soluble in water, others (e.g. SiO2) are not.
Solubility of ionic solids in water is a result of an interaction between polar water
molecules and ions which make up a crystal. Two forces determine the extent to
which solution will occur:
1. Force of attraction between water molecules and ions of the solid.
This force tends to brings ions in to solution. If this is the predominant factor,
then the compound may be highly soluble in water.
2. Force of attraction between oppositely charges ions.
3. This force tends to keep the ions in the solid state. When it is a major
factor, then solubility in water may be very low.

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A solubility chart showing the solubilities of various compounds in

water at a pressure of 1 atmosphere and a room temperature (approximately
293.15K).
Catio Carbonat Chlori Hydroxi Nitrate Sulphat Oxide Ethanoate, Ethanediote,
ns e,CO32- de,Cl- de,OH- ,NO3- e,SO42- ,O2- CH3COO- C2O4
NH4+ S S S S S X S S
Al3+ I S I S S I S I
Pb2+ I I I S I I S I
Zn2+ I S I S S I S I
Ba2+ I S I S I sS S I
Ca2+ I S Ss S sS sS S I
Cr3+ I S I S S I S I
Cu2+ I S I S S I S I
Co2+ I S I S S I S I
Ni2+ I S I S S I S I
Fe2+ I S I S S I S I
Fe3+ I S I S sS I S I
Mn2+ I S I S S I S I
KEY: S = Soluble I = Insolubles sS = Slightly Soluble
Golden tips:
4. All compounds of the ammonium ion (NH4+) and of alkali metal (Group
1A) cations, are soluble.
5. All nitrates and acetates (ethanoates) are soluble.
6. All chlorides, bromides and iodides are soluble EXCEPT those of silver, lead
and mercury (I).
7. All sulphates are soluble EXCEPT those of silver, lead, mercury (I), barium,
strontium and calcium.
8. All carbonates, sulphites and phosphates are insoluble EXCEPT those of
ammonium and Alkali metal earth (Group 1A) cations.
9. All hydroxides are insoluble EXCEPT those of ammonium, Alkali metal
(Group 1) cations and Alkali earth metal (Group II) cations.
10.All oxides are insoluble EXCEPT those of calcium, barium and Alkali metal
(Group I) cations: these soluble ones actually react with water to form
hydroxides (hydrolyze).

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INORGANIC CHEMISTRY PRACTICAL NOTES:

Qualitative Analysis is concerned with the identification of unknown ions
contained in inorganic compounds. The negatively charged ions are called
anions and the positively charged ions are called cations.
Qualitative Analysis is a scientific method of identifying the chemical
components of a given substance.
The procedure involves one to:
1) Detect the presence of water of hydration/crystallization.
2) Determine which cations or anions that are contained in a compound.
 Usually a solid sample containing two or more cations or anions is
supplied for analysis.
 The solid supplied may or may not be hydrated.
The process of investigation may include:
i. Examination of appearance of a solid supplied its smell or even the
texture.
ii. Determining the effect of heat on a solid.
iii. Determining the effect of a dilute acid on a solid.
iv. Determining the effect of water on a solid.
v. Determining the effect of an oxidizing agent or reducing agent on the
substance.
vi. Separation of mixtures.
vii. Determining the effect of a concentrated acid on the substance.
viii. Carrying out tests of own choice to identify the ions.
ix. Identification of anions in solution.
x. Identification of cations in solution.
xi. Recording observations made and drawing logical
deductions/conclusions.
A candidate should master the above skills since all or nearly all, off
which are always involved in dealing with one of the questions given
in a practical exams.
The safely precautions below must be adhered to when handling reagents and
experiments in a chemistry laboratory:
i. Always check that the label on the reagent bottle is that of the chemical
you really need.
ii. Never point a test tube, which contains chemicals you are heading
towards yourself or anyone.
iii. Always hand acids and other reagents with care.
iv. Never perform unauthorized experiments.
v. Always wash your hands after practical work.

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In Qualitative analysis, a student is always provided with a table consisting of

tests, observations and conclusions or deductions as the one designed below:
Tests Observations Conclusions
(a)
Students should note the following when attempting qualitative analysis:
a) The column for tests is always filled and serves as instructions to the
students.
b) A student is required to record any observations made as soon as possible,
and the conclusions are based on these observations.
c) A student should remember that no marks would be awarded for a correct
conclusions corresponding to a wrong observation. However, a student
can score some marks if the observations are correct, but losses marks for
a wrong conclusion.
d) A student is required to read through the column for the tests before
attempting the qualitative analysis experiment because the tests provide a
clue that help the student to predict the nature of unknown substance to
be identified.
Therefore, a student is required to be well versed with theory for laboratory
reagents used in Qualitative analysis and the student should also know the
purpose of each reagent.
1. PRELIMINARY TESTS OF UNKNOWN SUBSTANCE:
i. Always note the physical properties of the unknown sample. Example:
Note the physical appearance.
ii. Colour: which is a good guide as to what metallic ions the sample contains.
1) Nature of the substance:
 Powdery substances are normally carbonates.
 Crystalline solid indicates probably a sulphate, chloride or a nitrate.
 A wet solid indicates a deliquescent salt, probably a chloride or nitrate.
A. A yellow solid may also be an oxide of lead and a black solid substance may
be an oxide of copper OR sulphide of copper or iron.
B. If the given unknown substance:
i. Is in powdered form, then it’s probably anhydrous substance such as
most carbonates, sulphides and oxides.
ii. Has a pungent chocking smell of ammonia. Then this predicts an
ammonium salt.
iii. Absorbs water from the atmosphere and gradually dissolves in it to
form a solution. Then you can predict a chloride or nitrate ions of a
metal.

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C. This involves examining the appearance, smell and texture of the given
unknown sample. The appearance of the sample gives a rough idea as to
what it could be, particularly whether hydrated or not, transitional or non-
transitional elements.
i. Bases and carbonates are mainly Powderly and anhydrous.
ii. Nitrates, Sulphates and chlorides are mainly crystalline.
iii. Most crystalline substances are hydrated.
iv. Coloured solids in pure state may give a clue (hint) about the
identity of the cation present in the solid.
Cations/anions Colour of the solid or Aqueous
solution/Deductions/Conlusions
Cu 2+ Blue or Green
Fe , Cr , Ni
2+ 3+ 2+ Green
Fe 3+ Yellow/Brown
Co 2+ Pink or Red
Mn 2+ Pink
Cr2O7 2- Orange
CrO4 2- Yellow
Zn ,Pb ,Ca ,Al ,Mg ,NH4 & Ba
2+ 2+ 2+ 3+ 2+ + 2+ White
In general coloured solids suggest the presence of transition metal cations. Non-
coloured (white) solid suggests that the sample provided contains non-transition
metal cations. Examples: Zn2+,Pb2+,Ca2+,Al3+,Mg2+,NH4+,Sn2+,Sn4+ or Ba2+
SOLUBILITY OF COMPOUNDS.
Note: Water and dilute acids are usually used as solvents to dissolve compounds.
a) Completely dissolves in water, -Soluble salt or a mixture of soluble
forming a solution. transition or non-transition salts,
depending on the colour of solution.
b) Partially dissolves in water -A mixture of soluble and insoluble
forming a suspension. salts,I.e The residue is an insoluble
salt while a filtrate is a soluble salt.
2. ACTION OF HEAT ON SOLIDS:
Heating a compound may results in to decomposition, formation of a sublimate,
colourless liquid condensing on cooler parts of the boiling tube or evolution of
gases; which must be tested for and formation of a residue.
A spatula end-ful of the unknown sample is heated gently and then very strongly
in a dry boiling tube until no further change.
Golden tips:
The purpose of heating a solid is to decompose it in to recognizable products.
During heating the following must be noted.

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1. Gases evolved. 2. Sublimation is possible.

3. Change of state e.g. melting. 4. Colourless liquid/condensate.
5. Colour of the residue formed/left.
6. Noise may be heard e.g. Decripitation/crackling.
RESIDUE (I.E SOLID SUBSTANCE LEFT IN A BOILING TUBE AFTER HEATING)
Observations Conclusions
i. Black residue CuO or CuS
ii. Yellow-hot & white-cold ZnO
𝑟𝑒𝑑𝑑𝑖𝑠ℎ − ℎ𝑜𝑡, 𝑊ℎ𝑖𝑡𝑒 − 𝑐𝑜𝑙𝑑 PbO
}
𝑏𝑟𝑜𝑤𝑛𝑖𝑠ℎ − ℎ𝑜𝑡, 𝑌𝑒𝑙𝑙𝑜𝑤𝑖𝑠ℎ − 𝑐𝑜𝑙𝑑
iii. White residue Oxides of Gp(II) & Gp (III)
iv. Green residue NiO,Cr2O3
v. Black-hot, Reddish-brown- Ferric oxide
cold
Notes:
 Most solids are hydrated and lose their water of hydration on gentle
heating.
 Gentle heating means heating the solid with a small flame or passing part
of the test-tube containing the solid in and out of the hot flame without
heating the rest of the tube. This ensures that the cooler parts of the test-
tube as a colourless condensate.
 The condensate should be tested with anhydrous copper (II) sulphate or
cobalt (II) chloride.
 The test-tube should be slanting with its mouth slightly downward so that
the condensate does not run back to the hot parts of the test-tube which
would break.
 Strong heating involves the use of the hottest flame whereby the part of
the test-tube containing the solid is stationed within the flame, on strong
heating, the anhydrous solid left undergoes thermal decomposition to
produce a gas and a residue.
 Recognizing the gases leads to identification of the anion (or of the cation)
in case of an ammonium salt.
Gas Anion or Cation
Oxygen Nitrate,Peroxide & dioxide
Ammonia Ammonium,NH4+
Hydrogen chloride Chloride,Cl-
Chlorine Chloride,Cl-

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Bromine Bromide,Br-
Iodine vapour Iodide,I-
Propanone (Acetone vapour) Ethanoate,CH3COO-
Carbon dioxide Carbonate, hydrogen
carbonate,Oxalate or Ethanoate
Nitrogen dioxide Nitrate,NO3-
Sulphur dioxide Sulphite,Sulphate or Thiosulphate
ions
Notes:
a) If an ammonium salt is heated, it may sublime, leading to the identification
of ammonium ions.
b) Most sulphates are stable to heat except iron (III) sulphate and copper (II)
sulphate. Which decomposes on heating to their respective oxides
according the equation below?
Equations:
Heat
CuSO4(s) CuO(s) + SO3(g)
2FeSO4(s) Fe2O3(s) + SO3(g) + SO2(g)
c) Many hydrated chlorides undergo self-hydrolysis on heating producing
hydrogen chloride and on stronger heating; forms chlorine e.g. hydrated
copper (II) chloride.
d) Acetates/ethanoates decompose on heating to give acetone (propanone
vapour) which has a sweet smell, carbon dioxide gas and a metallic oxide.
Equations:
(CH3COO)2Ni(s) NiO(s) + CH3COCH3(g) + CO2(g)
(CH3COO)2Pb(s) PbO(s) + CH3COCH3(g) + CO2(g)
MgC2O4(s) MgO(s) + CO2(g) + CO(g)
Certain solids leave coloured residues on heating which may or may not
change colour on cooling.
Residue (Oxide) Colour of residue
Lead (II) oxide, PbO Reddish-brown (Orange) when hot
and yellow when cold
Zinc oxide, ZnO Yellow when hot and white when
cold
Copper (II) oxide, CuO Black both when cold and hot
Iron (III) oxide,Fe2O3 Dark-brown when hot and reddish-
brown when cold
Notes:
 Zinc oxide may be confused with lead (II) oxide. To avoid this
confusion; subject the residue to prolonged heating: zinc (II) oxide

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remains Powderly while lead (II) oxide melts to a reddish-brown

liquid.
3. Action of a dilute acid on a solid sample:
Some solids do not dissolve in water; in this case, the ions in that solid
cannot be set free if the solid is insoluble in water. To dissolve such a solid,
a dilute acid must be added.
Expected observations:
 Note whether the solid dissolves with effervescence. State the
colour, odour of the gas and its effect on litmus. Furthermore, its
confirmatory test must be carried out.
 The following gases are produced when an acid in dilute form is
added to the following anions:
Gas Anion
Carbon dioxide,CO2 CO32-,HCO3-
Sulphur dioxide,SO2 SO32-,S2O32-
Hydrogen sulphide,H2S S2-
Nitrogen dioxide,NO2 Nitrate, NO3-
Notes:
 Hydrogen gas is produced when dilute sulphuric or hydrochloric acid is
added to some metals such as zinc.
 If the acid is added to the solid sample and the sample dissolves to give a
solution without effervescence, the expected deduction would be: metal
oxide or hydroxide suspected.
 When the solid sample dissolves after addition of a dilute acid, state the
colour of the resultant solution and deduce the cations accordingly:
Examples:
 Green solution: Cr3+, Ni2+, Cu2+, or Fe2+ is suspected.
 Colourless solution: Zn2+, Al3+, Pb2+, Mg2+, Ca2+, Sn2+, etc. are
suspected.
Observations Conclusions
Colourless condensate which turns -Water of crystallization (or water
anhydrous copper (II) sulphate to vapour from a hydrated compound)
blue
White sublimate: A colourless gas -Ammonium salt
turns red litmus paper to blue & forms -NH3 gas (only alkaline gas) from an
white fumes when in close contact NH4+ salt.
with a glass rod dipped in
concentrated hydrochloric acid.

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Gas turns litmus red i.e. acidic vapour -An acidic gas is evolved.
is evolved examples.
Brown fumes -NO2 gas from Nitrate ion.
Greenish-yellow gas turns litmus red -Chloride gas from chloride ion.
and bleaches it
Colourless gas on strong heating -SO2 gas from a sulphate, Sulphite OR
decolorizes acidified KMnO4 S2O32-ions.
Misty gas turns moist/damp blue -SO3 gas from sulphate ion.
litmus paper red.
NOTE: SO42- is not easily decomposed to produce sulphur dioxide gas.
Gas turns wet litmus paper slightly CO2 gas from carbonate, hydrogen
red and lime water milky. carbonate and oxalic acid ions
4. ADDITION OF CONCENTRATED SULPHURIC ACID TO A SOLID SAMPLE:
This reagent is meant to identify a chloride, Cl- ion, ethanoate, CH3COO- or
Nitrate, NO3- ion.
In case of a chloride, Cl- ion, white misty fumes that form dense white
fumes with ammonia solution are given off. The fume of hydrogen chloride.
Equation:
NaCl(s) + H2SO4(l) NaHSO4(s) + HCl(g)
Chlorine gas may be produced by adding concentrated sulphuric acid to a
chloride in the presence of an oxidizing agent such as manganese (IV)
oxide. In the case of hydrogen chloride gas is produced from concentrated
sulphuric acid and a chloride.
But this gas is oxidized to chlorine by the oxidizing agent used.
In case of ethanoate, a CH3COO- ion, a colourless gas with vinegar smells
and turns blue litmus paper red is given off. The gas is ethanoic acid/acetic
acid vapour.
Equation:
CH3COO-(s) + H+(aq) CH3COOH(g)
In the case of nitrate, nitric acid vapour is produced when concentrated
sulphuric acid is added to a solid nitrate, while heating.
5. IDENTIFYING GASES:
Gases may be produced when a solid is heated or when an acid is added to
a solid. Whenever a gas is produced marks are allocated according to:
 The colour of the gas.
 The odour (smell) of the gas.
 The confirmatory test of the gas.
 The effect of that gas on litmus paper.

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These four scoring points will be under the observation. In deduction the
following will be awarded marks.
 The name of the gas.
 The anion producing the gas.
6. SOLUBILITY IN WATER:
This is used to separate two salts whereby one is soluble in water and the other
is insoluble; a spatula end full of the given sample is shaken with about 5cm3 of
water to produce either a solution or a suspension, which is then filtered to
generate a filtrate and residue; solid substance that remains on the filter paper.
a) ADDITION OF WATER TO A SOLID SAMPLE WITHOUT FILTERING:
When water is added to unknown solid and later dissolved completely,
then the compound is most likely to be ionic.
Expected observation:
State the colour of the resultant solution.
 If the solution is colourless, deduce non-transitional metal ions such
as Pb2+, Ca2+, Mg2+, Al3+, Ba2+, etc.
 If the solution is coloured, deduce the corresponding transitional
metal cations i.e.Green solution implies the presence of Cr3+, Fe2+,
Ni2+ & Cu2+.
b) ADDITION OF WATER TO A SOLID SAMPLE,FOLLOWED BY FILTRATION:
When asked to add water to a solid sample and then filter, it means that
the sample is partially soluble or it contains both soluble and insoluble
components.
Expected observation:
After filtering, state the colour of both filtrate and residue. Then deduce
the cations according to the colour of filtrate or residue.
Examples summarized on the table:
Cations/anions Colour of the filtrate or residue
Cu2+ Blue or Green
Fe2+, Cr3+, Ni2+ Green
Fe3+ Yellow/Brown
Co 2+ Pink or Red
Mn 2+ Pink
Cr2O7 2- Orange
CrO4 2- Yellow
Zn ,Pb ,Ca ,Al ,Mg ,NH4 & Ba
2+ 2+ 2+ 3+ 2+ + 2+ White/Colourless
Observation Conclusion

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Partially dissolves in water to give a Filtrate contains soluble salt of

colourless filtrate. Residue is probably Ca2+,Ba2+,Zn2+,Al3+,Mg2+&
white/Colourless. Pb2+
Completely dissolves in water to form Soluble salt of probably Zn2+,Al3+,Mg2+
a colourless solution. Pb2+ & NH4+
Completely dissolves in water to form -Blue solution:Cu2+ion
a coloured solution Example blue, -Green solution:Fe2+or Cu2+ions
green, brown& yellow. -Yellow solution:Fe3+ion
-Pink solution:Mn2+ or Co2+ ions
Partially dissolves in water to form a -Filtrate is probably Ni2+,Cr3+,Fe2+ or
green filtrate, Residue is brown, green Cu2+ ions
etc. -Residue is probably CO32-, C2O42- or
HCO3- of transition salts.
Note:
 An insoluble salt is usually dissolved in dilute Nitric acid or dilute
hydrochloric acid to form a soluble salt.
 The colour of the residue or filtrate obtained may help to identify the ion
that is most likely to be present.
7. ADDITION OF ALKALIS I.E SODIUM AND AMMONIUM HYDROXIDE
SOLUTION TO IDENTIFY CATIONS:
a) Addition of sodium hydroxide solution, NaOH(aq):
Sodium hydroxide solution is added to a test solution drop wise until in
excess.
Observations must be made when little of reagent is added and when
excess is added.
Some metallic cations form hydroxides with the reagent as precipitates
which may or may not dissolves in excess.
In this case, state the colour of the precipitate and if it dissolves state the
colour of the resultant solution.
Notes:
The tests are used to predict and eliminate cations. The amphoteric
hydroxides dissolves in excess sodium hydroxide solution to form a
solution.
Observations Conclusion
No precipitate is formed,a colourless -NH3 gas is evolved hence NH4+ ion
gas that turns moist red litmus paper confirmed present
blue and forms a dense white fumes
with Concentrated hydrochloric acid is

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given off on warming the test solution

with sodium hydroxide solution.
Explanation: Warming or heating of a solution containing NH4+ ion gives off
ammonia gas.
Equation:
NH4+(aq) + OH-(aq) H2O(l) + NH3(g)
White precipitate, insoluble in excess -Mg2+, Ba2+ & Ca2+ ions are suspected
aqueous sodium hydroxide solution present.
White precipitate, soluble in excess -Al3+, Zn2+, Sn2+, Sn4+ & Pb2+ ions are
aqueous sodium hydroxide solution to suspected present.
form a colourless solution.
Explanation: Amphoteric hydroxides dissolves in excess sodium hydroxide
solution to form soluble complexes:
Equations:
Al(OH)3(s) + OH-(aq) Al(OH)4-(aq)
Zn(OH)2(s) + 2OH-(aq) Zn(OH)42-(aq)
Pb(OH)2(s) + 2OH-(aq) Pb(OH)42-(aq)
White precipitate, insoluble in excess -Mn2+, Ag2+ ions are suspected
sodium hydroxide solution which present.
rapidly turns brown on standing.
Blue precipitate insoluble in excess -Co2+ ion is suspected present.
sodium hydroxide solution turns pink
on standing.
Blue precipitate insoluble in excess -Cu2+ion is suspected present.
sodium hydroxide solution.
Grey-green precipitate, soluble in -Cr3+ ion is suspected present.
excess sodium hydroxide solution to
form a green solution.
Note:
Green solution turns yellow on
addition of hydrogen peroxide.
Green or pale green precipitate -Ni2+ ion is suspected present.
insoluble in excess sodium hydroxide
solution.
Dirty green precipitate insoluble in -Fe2+ ion is suspected present.
excess sodium hydroxide solution,
rapidly turns brown on standing. Aerial oxidation of Fe2+ to Fe3+ ion
Reddish brown precipitate insoluble in - Fe3+ ion is suspected present.
excess sodium hydroxide solution.

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 BASIC ADVANCED LEVEL CHEMISTRY PRACTICAL

b) Addition of ammonia solution, NH4OH(aq):

Ammonia solution is added drop wise until in excess to a test solution.
Observation must be made when little and excess reagent is added.
Note:
Evolution of ammonia gas on warming has no meaning. And its use to
eliminate cations.
Examples:
Observations Conclusions
No precipitate, Solution remains -NH4+ion is suspected present.
colourless.
No observable change occurs or No Probably Ba2+, Ca2+ ions are suspected
precipitate, Cloudy solution. present.
White precipitate insoluble in excess -Al3+, Sn2+, Mg2+, Ba2+ & Pb2+ ions are
ammonia solution. suspected present.
Green precipitate soluble in excess -Ni2+ion is suspected present.
ammonia solution forming pale-blue
solution
Dirty green precipitate insoluble in -Fe2+ion is suspected present.
excess ammonia solution, slowly
turns brown on standing Aerial oxidation of Fe2+ to Fe3+ion
Reddish brown precipitate insoluble -Fe3+ ion
in excess ammonia solution.
Grey – green precipitate insoluble in -Cr3+ ion is suspected present.
excess dilute ammonia solution.
Note:
The precipitate dissolves in
concentrated ammonia solution.
White precipitate soluble in excess -Ag2+ & Zn2+ ions are suspected
ammonia solution forming a present.
colourless solution.
Explanation: Zinc (II) hydroxides dissolve in excess ammonia solution to form
to form a soluble complex.
Equation:
Zn(OH)2(s) + 4NH3(aq) Zn(NH3)4(aq) + 2OH-(aq)
Dirty white precipitate insoluble in -Mn2+ion
excess ammonia solution rapidly
turns brown on standing

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 BASIC ADVANCED LEVEL CHEMISTRY PRACTICAL

Blue precipitate, Insoluble in excess -Co2+ ion are suspected present.

alkali, turns brown on standing.
Or:
Blue precipitate which dissolves in
relatively concentrated ammonia
solution, turns red on standing
Blue precipitate soluble in excess -Cu2+ion is suspected present.
ammonia solution forming a deep blue
solution
Explanation: Copper (II) hydroxide dissolve in excess ammonia solution to
form a soluble complex.
Equation:
Cu(OH)2(s) + 4NH3(aq) Cu(NH3)4(aq) + 2OH-(aq)
8. SEPARATION OF MIXTURES USING SODIUM HYDROXIDE SOLUTION:
Some cations form hydroxides which dissolves in excess sodium hydroxide
solution while others do not. Those which dissolves in excess sodium
hydroxide solution form soluble complexes and are said to be amphoteric.
Examples of amphoteric cations:
a) Tin (II), Sn2+ ion.
Equations:
Sn2+(aq) + 2OH-(aq) Sn(OH)2(s)
Little White p.p.t
Sn(OH)2(s) + 2OH-(aq) Sn(OH)4-(s)
Excess Colourless solution
b) Zinc (II), Zn2+ ion.
Equations:
Zn2+(aq) + 2OH-(aq) Zn(OH)2(s)
Little White p.p.t
Zn(OH)2(s) + 2OH-(aq) Zn(OH)42-(aq)
Excess Colourless solution
c) Lead (II), Pb2+ ion.
Equations:
Pb2+(aq) + 2OH-(aq) Pb(OH)2(s)
Little White p.p.t
Pb(OH)2(s) + 2OH-(aq) Pb(OH)42-(aq)
Excess Colourless solution
d) Aluminium (III), Al3+ ion.
Equations:

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 BASIC ADVANCED LEVEL CHEMISTRY PRACTICAL

Al3+(aq) + 3OH-(aq) Al(OH)3(s)

Little White p.p.t
Al(OH)3(s) + OH-(aq) Al(OH)4-(aq)
Excess Colourless solution
Those cations which are insoluble in excess sodium hydroxide solution
include:
Ba2+, Ca2+, Al3+, Mg2+, Ni2+, Cu2+, Mn2+, Fe2+, Co2+, Fe3+,e.t.c.
To separate the soluble cations from insoluble cations, excess sodium
hydroxide solution is added to the test solution, followed by filtration.
The residue will contain those cations which are insoluble in excess
sodium hydroxide solution.
The filtrate will contain the cations which are soluble in sodium hydroxide
solution.
Examples:
Zn2+, Al3+, Pb2+ & Sn2+.
9. MAKING THE SOLUTION JUST ACIDIC:
This is usually done by adding a dilute acid e.g. nitric, hydrochloric acid to
a solution obtained after treating the solution with sodium hydroxide
solution during separation of amphoteric and non-amphoteric cations.
During addition of a dilute acid, a precipitate forms and when it dissolves,
addition of the acid should be stopped.
At this stage the solution is said to be just acidic.
Explanation:
During the reaction of the amphoteric cation with sodium hydroxide
solution, a precipitate forms which dissolves in excess reagent to form a
soluble complex.
Equations:
Al3+(aq) + 3OH-(aq) Al(OH)3(s)
Little White p.p.t
Al(OH)3(s) + OH-(aq) Al(OH)4-(aq)
Excess Colourless solution
When a dilute acid is added to the above equilibrium, the added acid (H+)
withdraws hydroxyl ions from the equilibrium mixture forming water.
i.e.:
H+(aq) + OH-(aq) H2O(l)
Removal of hydroxyl ions shifts the equilibrium from the right to left,
hence leading to precipitation of aluminium hydroxide as a white
precipitate.

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 BASIC ADVANCED LEVEL CHEMISTRY PRACTICAL

When more acid is added, aluminium hydroxide (white precipitate) reacts

with excess acid forming a soluble salt of aluminium (Al3+).
i.e:
2Al(OH)3(s) + 6H+(aq) 2Al3+(aq) + 3H2O(l)
Similar reactions occur when the solution contains:
Zn2+, Pb2+, Sn2+, e.t.c.
10. WASHING THE RESIDUE WITH DISTILLED WATER AND TREATING WTH
AN ACID:
This is done by pouring water on the residue through the filter paper in a
funnel several times. This removes any traces of the soluble cations which
might be trapped in the residue.
The washed residue is then dried between filter papers and carefully
transferred to a dry test tube.
A dilute acid is then added to the residue until there is no further change.
The residue may dissolve with or without effervescence. If the residue
dissolves with effervescence, it means a certain gas is evolved which must
be identified using its confirmatory test e.g. Carbon dioxide gas from a
carbonate, CO32- ion or sulphur dioxide gas from a sulphide,SO32-or
thiosulphate,S2O32-ions.
Note the colour of the resultant solution and deduce the possible cations. if
the residue dissolves without effervescence, then residue mostly likely
contains a hydroxide or oxide.
11.USE OF REAGENTS TO IDENTIFY ANIONS:
Reagents used to identify anions include lead (II) nitrate, silver nitrate,
magnesium sulphate, dilute acids, barium nitrate barium chloride, e.t.c.
The above reagents are usually used in small quantities(y) e.g. 2.3-drops of
the reagent. Therefore there is no need of adding excess reagent.
e.g.
Add 2-3 drops of silver nitrate solution followed by dilute nitric acid.
Observation:
White precipitate insoluble in the acid indicates the presence of chloride,
Cl- ion.
12. CARRYING OUT TESTS OF OWN CHOICE TO IDENTIFY CATIONS & ANIONS:
This is done after having carried out several preliminary tests on a sample.
Two or more differentiated using an appropriate reagent that will confirm
only one ion.
It is advisable to first carry out tests for each of the ions suspected
separately.

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 BASIC ADVANCED LEVEL CHEMISTRY PRACTICAL

Then the test which comes out to be positive is written under the Test
column with an appropriate observations and deductions.
Note:
When writing a test of own choice the following should be adhered to:
 Order of addition of reagents. If order is altered, then the test may
not give the expected observation.
Example:
During identification of manganese (II) ions using concentrated
nitric acid and solid sodium bismuthate, the acid is added first
followed by solid sodium bismuthate.
 The physical state of reagent(s) i.e. it may be a solution, solid or
liquid e.g. during identification of zinc,Zn2+ ion
Ammonium chloride is used a solid, while disodium hydrogen
phosphate and ammonia are used as solutions.
 Correct spellings of chemical names of the reagents and other
technical terms. Any wrong spelling makes the whole reagent
wrong.
The spelling following chemical names and technical terms normally
disturb candidates.
Correct spelling Wrong spelling
Sooty Shooty
Amine Ammine
Dissolve Dessolve
Tertiary Tertially
Milky Milk
Anhydrous Unhydrous
Aromatic Aromantic
Aliphatic Alimphatic
Electrophilic Electrophilic
Carboxylic Carboxylic
Effervescence Effavscence
Crystallisation Crytalization
Dimethylglyoxime Dimethylglycoxime
Sodium bismuthate Sodium bimuthate
Ammoniacal silver nitrate Ammonical silver nitrate
2,4-dinitrophenylhydrazine 2-4-dinitrophenyhydrazine
Potassium hexacyanoferrate (II) Potassium hexaciynoferrate (II)
or (III) or (III)
Disodium hydrogen phosphate Disodium hydrogen phosphate

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 BASIC ADVANCED LEVEL CHEMISTRY PRACTICAL

13. EFFECT OF OXIDIZING AGENTS AND REDUCING AGENTS:

When oxidizing and reducing agents are used, we must expect redox
reactions. The following oxidizing agents are commonly used:
Chlorine water. Iodine solution.
Bromine water. Potassium iodate.
Hydrogen peroxide. Manganese (IV) oxide.
Potassium manganate (VII). Potassium dichromate (VI).
Concentrated nitric acid. Concentrated sulphuric acid.
These oxidizing agents may cause a change in the colour of the substances
due to the coloured ions being produced.
They may also oxidize intermediary products so that we have different
products at the end.
The following reducing agents are commonly used:
Oxalate, C2O42- ion.
Tin (II) chloride.
Sodium sulphite solution.
Sodium thiosulphate to reduce iodide ion in solution.
Iron (II) solution or Iron filings to reduce copper (II) ions in solution.
When reducing agents are used they get oxidized while they reduce the
other reactants. This may result in a change of colours.
Note:
When oxidizing or reducing agents are used to form intermediate products
during qualitative analysis, the cation or anion identified at the end of the
tests should be the one originally present in the sample and not the one
formed as an intermediates during a reaction.
Example:
When concentrated nitric acid is added to a solution containing iron (II)
ion the green solution turns to yellow/brown implying that iron (II) ion
have been oxidized to iron (III) ions.
The cation that should identified is Fe2+ not Fe3+ ion.
14.STATING OR IDENTIFYING IONS PRESENT IN A GIVEN SAMPLE:
Usually this the last skill tested for during qualitative analysis. The cations
or anions should have been confirmed in particular tests during
experiment.
 Don’t state/identify more ions than those mentioned in the question.
 While identifying ions, make sure you use correct symbols of ions
and /or formulae of ions with correct charges.
 Names of the ions with correct oxidation states may be used.
Eg. Copper (II) ions.

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 BASIC ADVANCED LEVEL CHEMISTRY PRACTICAL

CONFIRMATION TESTS FOR COMMON CATIONS:

Cations Reagents Observations
To the solution, add solid White precipitate
Ca2+ion Ammonium chloride followed by formed.
Disodium hydrogen phosphate
solution.
To the solution, add ammonia White precipitate
solution followed by ammonium insoluble in ethanoic
oxalate solution and then acid.
ethanoic acid.
To aqueous solution plus White precipitate is
ammonium ethanedipate formed.
solution.
To the solution, add ammonium A white precipitate is
carbonate solution. formed.
To the solution, add ammonium White precipitate is
chloride solution followed by formed.
potassium hexacyanoferrate (II)
solution.
To the solution, add 2-3 drops of White precipitate is
dilute sulphuric acid. formed.
To the solution, add potassium Yellow precipitate
Ba2+ion chromate (VI) solution followed insoluble in dilute
by dilute sodium hydroxide sodium hydroxide
solution drop wise until in excess. solution.
To the solution, add ammonium White precipitate,
oxalate (ethanedioate) solution soluble in hot ethanoic
followed by ethanoic acid acid
To the solution, add 2-3 drops of White precipitate is
dilute sulphuric acid formed.
To the solution, add aqueous White precipitate
Zn2+ ion ammonia drop wise until in dissolves in excess to
excess. form to a colourless
solution.
To the solution, add solid White precipitate,
ammonium chloride, followed 2- soluble in ammonia
3 drops of Na2HPO4 and then solution.
ammonia solution until in excess.

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 BASIC ADVANCED LEVEL CHEMISTRY PRACTICAL

To the solution, add solid White precipitate is

ammonium chloride (NH4Cl) and form.
then add aqueous ammonia until
alkaline. Pass hydrogen sulphide
through.
To the solution, add ammonia Red/pink precipitate is
Ni2+ion solution drop wise until in excess formed.
followed by 2-3 drops of
Dimethyl glyoxime (butanedione
dioxime) solution.
To the solution, add potassium Green precipitate
ferrocyanide solution followed by formed, dissolves in
aqueous ammonia. excess base to form a
green solution.
To the solution, add potassium Brown precipitate is
Co2+ ion cyanide. formed.
To the solution, add potassium A blue solution is
thiocyanate or ammonium formed.
thiocyanate.
Heat borax on wire in Bunsen A blue bead is formed.
flame to get a colourless bead.
Reheating with little solid.
To the solution, add potassium Yellow crystalline
nitrite solution precipitate is formed.
To the solution, add dilute White precipitate
Pb2+ ion hydrochloric acid solution and formed, dissolves on
warm. warming. The precipitate
reappears on cooling.
To the solution, add potassium Yellow precipitate is
iodide solution. formed.
To the solution, add potassium Yellow precipitate which
chromate (VI) solution followed dissolves in excess in
by dilute sodium hydroxide sodium hydroxide
solution drop wise until in excess. solution.
To the solution, add 2-3 drops of White precipitate is
dilute sulphuric acid or sodium formed.
sulphate solution

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 BASIC ADVANCED LEVEL CHEMISTRY PRACTICAL

To the solution, add solid White precipitate

Mg2+ion ammonium chloride followed by insoluble in excess
3-4 drops of disodium hydrogen ammonia solution.
phosphate (Na2HPO4) solution
and then ammonia solution drop
wise until in excess.
To a slightly acidic solution, add 2 A blue precipitate is
to 3 drops of magnesium and formed.
then add sodium hydroxide
solution until alkaline.
To the solution, add ammonium White precipitate is
carbonate or sodium carbonate formed.
solution.
To the solution, add dilute No precipitate formed,
NH4+ion sodium hydroxide solution and On heating, colourless
warm or heat the mixture. Test gas evolved, turns moist
the gas evolved using moist red litmus paper blue
litmus paper or a glass rod and forms a dense white
dipped in concentrated fume with a glass rod
hydrochloric acid. dipped in concentrated
hydrochloric acid.
Al3+ion To the solution, add alizarin Pink solution (Pink lake)
solution followed by ammonia is formed.
solution.
To the solution, add 2-3 drops of Blue solution (Blue lake)
litmus paper solution followed by is formed.
ammonia solution
Mn2+ion To the solution, add concentrated A purple solution is
nitric acid followed by solid solution is formed.
sodium bismuthate.
Equation:
2Mn2+(aq) + 5BiO3-(aq) + 14H+(aq) 2MnO4-(aq) + 5Bi3+(aq) + 7H2O(l)
To the solution, add a few drops Purple solution is
of concentrated nitric acid formed.
followed by solid lead (IV) oxide
and heat.
Equation:
2Mn2+(aq) + 5PbO2(s) + 4H+(aq) 2MnO42-(aq) + 5Pb2+(aq) + 2H2O(l)

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 BASIC ADVANCED LEVEL CHEMISTRY PRACTICAL

Cr3+ ion To the solution, add excess Yellow solution is

sodium hydroxide solution and formed.
few drops of hydrogen peroxide
and boil the mixture.
(do not heat please)
To the solution, add dilute Deep blue solution is
sulphuric acid. formed which fades, in a
short time to leave a
green solution.
To the solution, add butan-1-ol Blue forms in organic
and followed by dilute sulphuric layer.
acid.
To the solution, add barium Yellow precipitate is
chloride or barium nitrate formed.
solution.
To the solution, add silver nitrate Red precipitate is
solution formed.
To the solution, add lead (II) Yellow precipitate is
ethanoate or lead (II) nitrate formed.
solution.
Cu2+ion To the solution, add aqueous Blue precipitate formed,
ammonia solution drop wise until dissolves in excess to
in excess. form a deep blue
solution.
To the solution, add potassium White precipitate in
iodide solution. brown solution is formed
To the solution, add potassium Chocolate-brown
hexacyanoferrate (II) solution. precipitate formed.

To the solution, add A reddish-brown

ferrocynanide solution followed precipitate is formed.
by ammonia solution.
Fe2+ion To the solution, add potassium Dark /deep blue
hexacyanoferrate (III) solution precipitate is formed.
To the solution, add few drops of Green solution turns to
concentrated nitric acid and boil. yellow which forms a
blood-red solution with
potassium thiocynanide
solution.

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 BASIC ADVANCED LEVEL CHEMISTRY PRACTICAL

To the solution, add potassium No observable change.

thiocynanide solution.
To the solution, add potassium A dark blue precipitate,
ferric cynanide solution. Prussian blue.
Fe3+ion To the solution, add potassium Dark/deep blue
hexacyanoferrate (II) precipitate is formed.
solution.(Potassium ferro
cyanide)
To the solution, add dilute Green solution is formed.
sulphuric acid followed by zinc
powder and heat
To the solution, add potassium or Deep blood-red solution
ammonium thiocyanate solution. is formed.
CONFIRMATORY TESTS FOR COMMON ANIONS:
Cations Reagents Observations
SO42- ion To the solution, add 2-3 drops of Barium White precipitate
nitrate solution followed by dilute Nitric insoluble in the
acid. acid is formed.
To the solution, add 2-3 drops of Barium White precipitate
chloride solution followed by dilute insoluble in the
hydrochloric acid. acid is formed.
To the solution, add 2-3 drops of either White precipitate
lead (II) ethanoate or nitrate solution and insoluble on
heat. heating is formed.
SO32- ion To the solution, add dilute acid. Effervescence of a
colourless gas
turns acidified
potassium
dichromate (VI)
solution from
orange to green.
Equation:
SO32-(aq) + 2H+(aq) H2O(l) + SO2(g)
To the solution, add barium nitrate White precipitate
solution or lead (II) nitrate/ethanoate soluble in the acid
solution followed by dilute nitric acid. with
effervescence of a
colourless gas
that turns

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 BASIC ADVANCED LEVEL CHEMISTRY PRACTICAL

acidified
potassium
dichromate (VI)
solution from
orange to green.
Equations:
Ba2+(aq) + SO32-(aq) BaSO3(s)
Pb2+(aq) + SO32-(aq) PbSO3(s)
To the solution, add acidified potassium The purple colour
manganate (VII) solution. of potassium
manganate (VII)
solution turns to
colourless
Equation:
2MnO4-(aq) + 5SO32-(aq) + 6H+(aq) 2Mn2+(aq) + 3H2O(l) + 5SO42-(aq)
To the solution, add iodine solution. Brown solution of
iodine solution
turns to
colourless.
Equation:
I2(aq) + H2O(l) + SO32-(aq) SO42-(aq) + 2H+(aq) + 2I-(aq)
CO32- ions To the solution, add dilute mineral acid Effervescence of a
(i.e. hydrochloric, nitric & sulphuric acid) colourless gas
in either solid or solution state. that turns moist
blue litmus paper
red and lime
water milky.
To the solution, add barium White precipitate
nitrate/chloride solution or silver nitrate that dissolves in
solution or lead (II) nitrate/ethanoate the acid with
solution followed by dilute nitric acid. effervescence of a
colourless gas
that turns lime
water milky.
To the solution, add magnesium sulphate White precipitate
solution. is formed.
HCO3- ions To the solution, add magnesium sulphate No precipitate is
solution. formed but on

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 BASIC ADVANCED LEVEL CHEMISTRY PRACTICAL

boiling, a white
precipitate is
formed.
Boil a solution containing hydrogen White precipitate
carbonate. is formed and a
colourless gas
that turns lime
water milky is
given off.
NO3-ion To the solution, add freshly prepared iron Brown ring layer
(II) sulphate solution followed by is formed at the
concentrated sulphuric acid which is interface of the
carefully poured down the sides of the test two separate
tube. liquids.
Equation:
KNO3(aq) + H2SO4(aq) KHSO4(aq) + HNO3(aq)
6FeSO4(aq) + 3H2SO4(l) + 2HNO3(aq) 3Fe2(SO4)3(aq) + 4H2O(l) + 2NO(g)
FeSO4(aq) + NO(aq) + 5H2O(l) [Fe(NO)(H2O)5]SO4(aq) or [Fe(H2O)5(NO)]SO4(aq)
Or:
3Fe2+(aq) + NO(aq) + 4H+(aq) 3Fe3+(aq) + 2H2O(l) + NO(aq)
[Fe(H2O)6]2+(aq) + NO(aq) [Fe(H2O)5(NO)]2+(aq) + H2O(l)
Pentaaqua nitroso iron (II) sulphate

To the solution, add few copper turnings Brown fumes

and followed by concentrated sulphuric observed and
acid, warm the mixture. blue solution is
formed.

Cl- ion To the solution, add silver nitrate solution White precipitate
followed by dilute nitric acid. insoluble in the
acid is formed
Note:
White precipitate of silver chloride dissolves in ammonia
solution to a colourless solution due formation of a soluble
complex, diamine silver Ag(NH3)2+ions.
Add manganese (IV) oxide solid followed Pale green is
by concentrated sulpuric acid and warm. evolved, bleaches
damp litmus
paper.

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 BASIC ADVANCED LEVEL CHEMISTRY PRACTICAL

To the solution, add concentrated Misty white

sulphuric acid to a solid of a chloride and fumes which
warm. turns moist blue
litmus paper red
and form white
fumes with
ammonia
solution.
The gas is
hydrochloride
chloride.
To the solution, add lead (II) ethanoate or White precipitate
lead (II) nitrate solution followed by is formed.
heating. Precipitate
dissolves on
warming and
reappears on
cooling.
C2O42-ion To the solution, add acidified potassium Purple solution of
Oxalates or permanganate solution and heat. Potassium
Ethanedioates manganate (VII)
solution turns to
colourless with
evolution of a
colourless gas
that turns lime
water milky.
Equation:
2MnO4-(aq) + 5C2O42-(aq) + 16H+(aq) 2Mn2+(aq) + 10CO2(g) + 8H2O(l)
To the solution, add barium nitrate White precipitate
solution followed by strong acid e.g. Nitric which dissolves in
acid the acid without
effervescence.
To the solution, add calcium chloride White precipitate
solution. of calcium oxalate
which is insoluble
in acetic acid.

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 BASIC ADVANCED LEVEL CHEMISTRY PRACTICAL

CH3COO-ion To the solution, add freshly prepared 2-3 Deep

Ethanoate ion drops of iron (III) chloride solution and brown/brown
heat. precipitate is
formed.
To the solution, add 2cm of ethanol
3 Sweet fruity smell
followed by concentrated sulphuric acid of an ester is
and warm the mixture. given off.
The smell
becomes stronger
when the mixture
is diluted with
water in a large
container.
To the solution, add dilute hydrochloric Solution formed,
acid. with a smell of
vinegar.
To the solid containing ethanoate ions, Colourless gas
add few drops of concentrated sulphuric that turns blue
acid. litmus paper red,
the gas has a
sharp vinegar
smell.
S2O32- ion To the solution, add lead (II) nitrate or White precipitate
lead (II) ethanoate solution. Warm the soluble in excess
solution. and turns grey on
warming.
To the solution, add freshly prepared Dark violet
neutral iron (III) chloride solution. colouration which
disappears after a
short time leaving
a colourless
solution.
To the solution, add silver nitrate solution. White precipitate
that turns brown.

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 BASIC ADVANCED LEVEL CHEMISTRY PRACTICAL

To the solution, add dilute mineral acid Effervescence of

(E.g. Hydrochloric or sulphuric acid). colourless gas
that turns
acidified
potassium
dichromate (VI)
solution from
orange to green
and a yellow solid
is deposited.
Nitrite, NO2- To the solution, add acidified potassium Purple colour
ion manganate (VII) solution. turns to
colourless.
Equation:
2MnO4-(aq) + 3NO2-(aq) + 6H+(aq) 2Mn2+(aq) + 5NO3-(aq) + 3H2O(l)
To the solution, add acidified potassium dichromate (VI)
solution.
Observation:
Orange solution turns to green.
Equation:
Cr2O72-(aq) + 3NO2-(aq) + 8H+(aq) 2Cr3+(aq) + 4H2O(l) + 3NO3-(aq)

To the solution, add bromine water. Brown solution

turns to
colourless
solution.
Equation:
NO2-(aq) + Br2(aq) + H2O(l) 2Br-(aq) + NO3-(aq) + 2H+(aq)
To the solution, add dilute sulphuric or Brown fumes are
hydrochloric acid and warm. given off.
Equation:
NO2-(aq) + H+(aq) HNO2(aq)
This nitrous acid is unstable and decomposes to give nitrogen
(II) oxide when warmed. The nitrogen (II) oxide readily
combines with atmospheric oxygen to give nitrogen (IV) oxide
(brown gas).
Equation:
2NO(g) + O2(g) 2NO2(g)

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 BASIC ADVANCED LEVEL CHEMISTRY PRACTICAL

CrO42- ion To the solution, add lead (II) nitrate or Yellow precipitate
acetate solution. is formed.
Equation:
Pb2+(aq) + CrO42-(aq) PbCrO4(s)
To the solution, add silver nitrate solution. Red precipitate is
formed.
Equation:
2Ag+(aq) + CrO42-(aq) Ag2CrO4(s)
To the solution, add 2-3 drops of An intense blue
hydrogen peroxide solution followed by colouration is
dilute sulpuric acid. formed.
To the solution, add barium nitrate or Yellow precipitate
chloride solution. is formed.
Equation:
Ba2+(aq) + CrO42-(aq) BaCrO4(s)
Cr2O72- ion To the solution, add a few drops of dilute Orange solution
sodium hydroxide solution. turns to yellow
solution.
Equation:
Cr2O72-(aq) + 2OH-(aq) 2CrO42-(aq) + H2O(l)
PO43- ion To the solution, add barium White precipitate
nitrate/chloride solution followed by which dissolves in
dilute hydrochloric or nitric acid. the acid without
effervescence.
Br-/I- ion To the solution, add silver nitrate solution Pale-yellow
followed by ammonia solution drop wise precipitate
until in excess. insoluble in
ammonia
solution.
Br- ion To the solution, add lead (II) White crystalline
nitrate/ethanoate solution. precipitate is
formed which
slightly dissolves
on warming.
To the solution, add carbon tetrachloride Reddish-brown
or chloroform followed by chlorine water colour appears in
and shake the mixture. the organic layer.

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 BASIC ADVANCED LEVEL CHEMISTRY PRACTICAL

I-ion To the solution, add lead (II) Yellow precipitate

nitrate/ethanoate solution. is formed.
To the solution, add chloroform followed Brown layer
by chlorine water. appears in the
organic layer.
To the solution, add concentrated Colourless
sulphuric acid followed by sodium solution turns to
thiosulphate solution. brown and to
colourless on
adding sodium
thiosulphate
solution
O22- ion To the solution, add dilute mineral acid. Colourless gas
that relights a
glowing splint.
Equation:
2O22-(aq) + 4H+(aq) 2H2O(l) + O2(g)
OCl- ion Greenish-yellow
To the solution, add dilute hydrochloric or nitric acid to a gas with a
solid. pungent smell.
The gas turns
Equation: moist blue litmus
2OCl-(s) + 4H+(aq) 2H2O(l) + Cl2(g) paper red & then
bleaches it.
15. ADDITION OF DILUTE HYDROCHLORIC ACID:
Add little of the acid to test tube containing the solution. Observe any changes
and then add the reagent in excess. If there is no reaction, warm gently and
identify any gas evolved.
Observations Deductions
(i). Effervescence occurs and a Carbon dioxide gas from CO32- or
colourless evolved, turns damp litmus HCO3- ion insoluble salt dissolves in
red & lime water milky. acid to form a soluble salt.
Solid dissolves to form a Probably NO3-,SO42- OR Cl- of white
coloured/colourless solution. soluble salt,
(If solution is colourless is formed)
(ii). Colourless gas with pungent SO2 gas from SO32-.
smell SO2 gas produced reduces Cr2O32- to
Turns damp litmus paper red and Cr3+ ion
acidified dichromate paper green.

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 BASIC ADVANCED LEVEL CHEMISTRY PRACTICAL

(iii). White precipitate is formed. Precipitate of lead (II) chloride, which

Precipitate dissolves on dissolves in hot water. Hence Pb2+ ion
warming/boiling and solid present.
recrystallizes on cooling.
(iv). Colorless vapour with faint Ethanoic acid vapour from an
vinegar smell forms a brown ethanoate (CH3COO-) ion
precipitate with neutral iron (III)
chloride solution.
16.ADDITION OF SODIUM CARBONATE SOLUTION.
Addition of little of the sodium carbonate solution to the test tube containing the
solution precipitates the insoluble carbonate, hydroxide or oxide.
Observations Deductions
(i). No gas is evolved. Pb ,Zn ,Ca ,Ba2+ or Mg2+ metal
2+ 2+ 2+

White precipitate is formed. CO32-

(ii). White precipitate, accompanied Al(OH)3 precipitate. Carbonate is
by effervescence. unstable to produce carbon dioxide
A colourless, odourless gas evolved, gas Hence Al3+ ion is present.
turns damp litmus red paper red and
lime water milky.
(iii). Pale blue precipitate is formed. Cu2+ ion suspected, CuCO3 is
Precipitate darkens on heating and precipitated and decomposes on
turns black. heating to black, CuO.
(iv). Brown prepicitate,accompanied Fe(OH)3 precipitated. Carbon dioxide
by effervescence of a colourless gas evolved from CO32- ion.
odourless gas evolved, turns damp Hence Fe3+ ion present.
litmus paper red and lime water milky.
(v). Dark green precipitate is formed, Fe(OH)2 is precipitate,Fe2+ ion turns
turns brown on standing. brown due to aerial oxidation to Fe3+
ion.
PRACTICAL PRESENTATTION:
Experiment 1 P is a mixture of (NH4)2SO4 & MnCO3:
You are provided with substance P. Which contains two cations and two anions.
You are required to identify the cation and anion in P. Carry out the tests below
and record your observations and conclusion in the spaces provided. Where a
gas is evolved, it should be identified.
Tests Observations Deductions
(a). Heat a spatula end Dirty green white Probably P is non-
full of P in a hard glass crystalline, substance transition salt.
tube first gently and gives colourless liquid,

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 BASIC ADVANCED LEVEL CHEMISTRY PRACTICAL

then strongly until there which turns copper (II) Water of crystallization
is no further change. sulphate blue, White from a hydrated non
sublimate on the cooler transition salt.
parts of the boiling tube.
Colourless gas turns wet
litmus paper slightly red Acidic gas, CO2 gas from
and lime water milky, CO32-/HCO3-ions.
CO32- is confirmed
Colourless gas also turns present.
wet red litmus paper Ammonia gas from NH4+
blue and forms misty salt.
fumes with rod dipped in
conconcentrated acid. Residue is probably an
Residue is white. oxide of Mn2+, Mg2+ ion.
(b). To about one P partially dissolves in Filtrate probably
spatula end full of P, add water to form a contains:
5cm3 of water and filter. colourless filtrate and a Zn2+,Al3+,Or Pb2+
Keep filtrate and white residue. Residue probably
residue. contains:
Divide in to 4 parts. CO32- of Pb2+,Al3+, or
Zn2+ ions
(i). To the first portion, No precipitate is formed.
add dilute sodium Solution remains Ammonia gas from NH4+
hydroxide solution drop colourless. salt hence NH4+ ion
wise until in excess and On heating,colourless confirmed.
heat. gas given off turns wet
litmus paper blue and
forms misty fumes with
a rod dipped in
concentrated
hydrochloric acid.
(ii). To the second No precipitate formed, NH4+ ion present
portion, add dilute solution remains
ammonia solution drop colourless
wise until in excess.
(iii). To the third White precipitate is SO42-ion.
portion, add dilute acid formed. Confirmed present.
followed by 2-3 drops of
barium nitrate solution.

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 BASIC ADVANCED LEVEL CHEMISTRY PRACTICAL

(c). Wash the residue Effervescence occurs and Acidic gas, CO2 gas from
and dissolve it in dilute a colourless gas evolved, CO32- ion.
nitric acid. Divide the turns wet litmus paper
resultant solution in to 3 slightly red and lime
parts. water milky. A soluble nitrate of Mn2+
Residue dissolves in or Co2+ salt
dilute nitric acid to form
a pale pink solution.
(i). To the first part, add Dirty white precipitate, Mn2+ion
dilute sodium hydroxide insoluble in excess. Suspected present.
solution drop wise until Precipitate rapidly turns
in excess. brown.
(ii). To the second part, Dirty white Precipitate, Mn2+ion
add dilute ammonia insoluble in excess. Suspected present.
solution drop wise until Precipitate turns brown
in excess. on standing.
(iii). To the third part,
carry out a test of your
choice to confirm the
cation in the residue.
Tests:
To the last part, A purple colouration was Mn2+ is oxidized to
concentrated nitric acid observed. MnO4- ion.
was added followed by Hence Mn2+ ion
solid sodium confirmed present.
bismuthate.
Identify the:
i. Cations present in compound P.
NH4+ ion is confirmed in b (i).
Mn2+ ion is confirmed in c (iii).
ii. Anions present in compound P.
SO42-ion is confirmed in b (iii).
CO32- ion is confirmed in (a).
Experiment 2, X is a mixture of BaCl2 & PbCO3:
You are provided with substance X which contains two cations and two anions.
You are required to carry out the following tests on X to identify the cations and
anions in X. Record your observations and conclusion in the table below.
Tests Observations Deductions

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 BASIC ADVANCED LEVEL CHEMISTRY PRACTICAL

(a).Heat a spatula end- Colourless Water of crystallization

ful of X in a dry test tube. liquid/condensate that ∴hydrate/hydrated salt.
turns anhydrous copper
(II) sulphate blue.
Colourless gas that turns Carbon dioxide is given
moist blue litmus paper off.∴CO32-, C2O42- & HCO3-
red & lime water milky. are suspected present.
Reddish-brown/Orange PbO is formed.
residue when hot & ∴Pb2+ salt is suspected
yellow when cold. present.
(b).Shake two spatula White residue. Al3+, Zn2+, Ca2+ & Mg2+
end-ful of X with about ions are suspected
5cm3 of water and filter. present.
Keep both the filtrate Colourless filtrate. Pb2+, Ca2+, Ba2+, Sn2+ &
and residue. Sn4+ ions are probably
Divide the filtrate in to suspected present in
six portions. both filtrate and residue.
b.(i).To the 1st portion of White precipitate Ca2+, Mg2+ & Ba2+ ions
the filtrate, add dilute insoluble in excess. are suspected present.
sodium hydroxide
solution drop-wise until
in excess.
b.(ii).To the 2nd portion White precipitate Mg2+ & Ba2+ ions are
of the filtrate, add insoluble in excess. suspected present.
ammonia solution drop-
wise until in excess.
b.(iii).To the 3rd portion White precipitate. Ba2+ ion is suspected
of the filtrate, add 2-3 present.
drops of dilute sulphuric
acid.
b.(iv).To the 4th portion Yellow precipitate Ba2+ ion is confirmed
of the filtrate, add 2-3 insoluble in excess present.
drops of potassium sodium hydroxide
chromate (VI) solution solution.
and then add dilute
sodium hydroxide
solution drop-wise until
in excess & allow the
mixture to stand.

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 BASIC ADVANCED LEVEL CHEMISTRY PRACTICAL

b.(v).To the 5th portion White precipitate Cl- ion is suspected

of the filtrate, add 2-3 dissolves on heating & present.
drops of lead (II) nitrate reappears on cooling.
solution, heat and allow
to stand.
b.(vi).Use the 6th portion
of the filtrate to carry
out a test of your choice
to confirm one of the
anions present in X.
Test:
To the 6th portion of the White precipitate Cl- ion is confirmed
filtrate, add silver nitrate insoluble in the acid. present.
solution followed by
dilute nitric acid.
c. Wash the residue with Effervescence of Carbon dioxide gas is
water, transfer to a test colourless gas that turns given off.
tube & add dilute nitric moist blue litmus ∴CO32- ion is confirmed
acid drop-wise to red/pink & lime water present.
dissolve the residue. milky.
Divide the solution in to Colourless solution Non-transitional metal
five parts. formed. ions,Ie.Pb2+, Zn2+,
Ba2+,Ca2+,Mg2+ & Al3+
ions are suspected
present.
c.(i).To the 1st part of the White precipitate Al3+, Pb2+, Zn2+, Sn2+ &
solution, add dilute soluble in excess to form Sn4+ ions are suspected
sodium hydroxide a colourless solution. present.
solution until in excess.
c.(ii).To the 2nd part of White precipitate Al3+ & Pb2+ ions are
the solution, add dilute insoluble in excess. suspected present.
ammonia solution until
in excess.
c.(iii).To the 3rd part of White precipitate. Pb2+ ion is suspected
the solution, add 2-3 present.
drops of dilute sulphuric
acid.
c.(iv).To the 4th part of Yellow precipitate Pb2+ ion is suspected
the solution, add 2-3 soluble in excess sodium present.

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 BASIC ADVANCED LEVEL CHEMISTRY PRACTICAL

drops of potassium hydroxide solution to

chromate (VI) solution give a yellow solution.
and then add dilute
sodium hydroxide
solution drop wise until
in excess.
c.(v).Use the 5th part of
the solution to carry out
a test of your own choice
to confirm one of the
cations in X.
Test:
To the 5th part of the Pb2+ ion is confirmed
solution, add potassium Yellow precipitate. present.
iodide solution.
Identify the:
i. Cations present in compound X.
Ba2+ ion is confirmed in b (iv).
Pb2+ ion is confirmed in c (v).
ii. Anions present in compound X.
Cl- ion is confirmed in b (vi).
CO32-ion is confirmed in c.
Experiment 3, Y is a mixture of (CH3COO)2Ni & CuCO3:
You are provided with substance Y which contains two cations and two anions.
You are required to carry out the following tests on Y to identify the cations and
anions in Y. Record your observations and conclusion in the table below.
Tests Observations Deductions
(a).Heat one spatula Y is a green solid. Transitional metal ions,
end-ful of Y in a dry test Cr3+, Ni2+, Cu2+ & Fe2+
tube. ions are suspected
present.
Colourless Water is given off.
liquid/condensate that ∴hydrated salt.
turns anhydrous copper
(II) sulphate blue.
Colourless gas that turns Carbon dioxide gas is
moist blue litmus paper given off.
red & lime water milky.

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 BASIC ADVANCED LEVEL CHEMISTRY PRACTICAL

∴CO32-, C2O42- & HCO3-

Colourless vapour with a ions are suspected
sweet smell and forms a present.
yellow precipitate with Propanone vapour is
Braddy’s reagent. given off.
Black residue is formed. ∴CH3COO- ion is
suspected present.
CuO, FeO & NiO salts are
suspected present
(b).To one spatula end- Effervescence of Acetic acid vapour is
ful of Y in a dry test colourless gas that turns given off.
tube,add 2-3 drops of moist blue litmus paper ∴CH3COO- ion is
concentrated sulphuric red & has a sharp suspected present.
acid and warm it gently. vinegar smell.
(c).put two spatula end-
ful of Y in a test tube, add
about 5cm3 of distilled
water, shake well & Green filtrate & residue. Fe2+, Ni2+, Cu2+ & Cr3+
filter. Keep both the ions are suspected both
filtrate and residue in the residue & filtrate.
(d).Divide the filtrate in
to four portions.
d. (i). To the 1st portion Reddish-brown solution, ∴CH3COO- ion is
of the filtrate, add 5 forms a brown confirmed present.
drops of neutral iron precipitate on boiling.
(III) chloride solution &
heat gently to boiling.
d.(ii).To the 2nd portion Green precipitate Ni2+ ion is suspected
of the filtrate, add dilute insoluble in excess. present.
sodium hydroxide
solution drop-wise until No observable change on Rej; Fe2+ ion b’se
in excess. Heat the heating occurs. Fe(OH)2 decompose on
mixture. heating.
d.(iii).To the 3rd portion Green precipitate Ni2+ ion is suspected
of the filtrate, add soluble in excess present.
ammonia solution drop- forming a pale-blue
wise until in excess. solution.
d.(iv).Use the 4th portion
of the filtrate to carry

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 BASIC ADVANCED LEVEL CHEMISTRY PRACTICAL

out a test of your own

choice to confirm one of
the cations in Y.
Test:
To the 4th portion of the Red precipitate. Ni2+ ion is confirmed
filtrate, add dilute present.
ammonia solution drop- Rej: pink precipitate.
wise until in excess
followed by 2-3 drops of
dimethylglyoxime
solution.
(e).Wash the residue Dissolve with Carbon dioxide gas is
with a little distilled effervescence of given off.
water. Transfer in to a colourless gas that ∴CO32- ion is confirmed
test tube and dissolve in turned moist blue litmus present.
dilute hydrochloric acid paper red & lime water
& divide the solution in milky.
to three portions. Green solution is formed. Fe2+, Cu2+, Ni2+ & Cr3+
ions are suspected
present.
e.(i).To the 1st portion of Blue precipitate CuO is formed.
the filtrate, add dilute insoluble in excess, ∴Cu2+ ion is suspected
sodium hydroxide turned black on heating. present.
solution drop-wise until
in excess & heat the
mixture,
e.(ii).To the 2nd portion Blue precipitate soluble Cu2+ ion is suspected
of the filtrate, add in excess to form a deep- present.
ammonia solution drop- blue solution.
wise until in excess.
e.(iii).Use the 3rd portion
of the solution to carry
out a test of your own
choice to confirm of the
cations in Y.
Test:
To the 3rd portion of the Brown precipitate Cu2+ ion is confirmed
solution, add 2-3 drops present.
of potassium

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 BASIC ADVANCED LEVEL CHEMISTRY PRACTICAL

hexacyanoferrate (II)
solution.
Or:
Add 2 drops of White precipitate in a
potassium iodide brown solution.
solution.
Identify the:
i. Cations present in compound Y.
Ni2+ ion is confirmed in d (iv).
Cu2+ ion is confirmed in e (iii).
ii. Anions present in compound Y.
CH3COO- ion is confirmed in d (i).
CO32-ion is confirmed in e.
Experiment 4, Z is a mixture of BaCl2 & ZnCO3:
You are provided with substance Z which contains two cations and two anions.
You are required to carry out the following tests on Z to identify the cations and
anions in Z. Record your observations and conclusion in the table below.
Tests Observations Deductions
(a).Heat strongly one Colourless Water of crystallization
spatula end-ful of Z in a liquid/condensate that is given off.
dry test tube. turns anhydrous copper
(II) sulphate blue. ∴hydrated salt is present
Colourless gas that turns
moist blue litmus paper
red & lime water milky. Carbon dioxide gas is
given off.
White powder turns to ∴CO32-, C2O4 & HCO3- are
yellow residue-hot & suspected present.
white-cooling Non-transitional metal
ions, Zn2+, Ba2+, Ca2+&
Al3+ ions are suspected
present.
ZnO is formed.
(b).To one spatula end- Effervescence, Misty Hydrogen chloride gas is
ful of Z in a test-tube, fumes with a chocking given off.
add 2-3 drops of smell, turned moist blue
concentrated sulphuric litmus paper red and ∴Cl- ion is suspected
acid. forms dense white fumes present.
with ammonia solution.

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 BASIC ADVANCED LEVEL CHEMISTRY PRACTICAL

(c).To two spatula end

ful of Z in a test tube, add Colourless filtrate. Al3+, Zn2+, Pb2+, Ca2+,
about 5cm3 of distilled & Ba2+ & Mg2+ ions are
water, shake vigorously White residue. suspected present in
and filter. Keep both the both filtrate & residue.
residue and filtrate.
(d).Divide the filtrate in
to six portions.
d.(i).To the 1st portion of White precipitate Mg2+, Ca2+ & Ba2+ ions
the filtrate, add dilute insoluble in excess. are suspected present.
sodium hydroxide
solution drop-wise until
in excess.
d.(ii).To the 2nd portion
of the filtrate, add dilute White precipitate Mg2+& Ba2+ ions are
ammonia solution. insoluble in excess. suspected present.
d.(iii).To the 3rd portion
of the filtrate, add a White precipitate Mg2+& Ba2+ ions are
spatula end-ful of solid insoluble in excess suspected present.
ammonium chloride ammonia solution.
followed by 3-4 drops of
disodium hydrogen
phosphate solution & the
add ammonia solution
drop-wise until in
excess.
d.(iv).To the 4th portion
of the filtrate, add 2-3 Yellow precipitate Ba2+ ion is confirmed
drops of potassium insoluble in excess present.
chromate (VI) solution sodium hydroxide
followed by dilute solution.
sodium hydroxide
solution drop wise until
in excess.
d.(v).To the 5th portion
of the filtrate, add 2-3 White precipitate Cl- & SO42- ions are
drops of lead (II) nitrate insoluble in the acid. suspected present.
solution followed by
dilute nitric acid.

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 BASIC ADVANCED LEVEL CHEMISTRY PRACTICAL

d.(vi).Use the 6th portion

of the filtrate to carry
out a test of your own
choice to confirm one of
the anions in Z.
Test:
To the 6th portion of the White precipitate Cl- ion is confirmed
filtrate, add 3 drops of insoluble in the acid. present.
silver nitrate solution
followed by dilute nitric
acid.
(e).Wash the residue Effervescence of Carbon dioxide gas is
with distilled water, colourless gas that turns given off.
transfer the residue in to moist blue litmus paper ∴CO32- ion is confirmed
a test tube & dissolve in red & lime water milky. present.
dilute nitric acid & then
divide the solution in to Colourless solution is Al3+, Ca2+, Zn2+, Pb2+ &
three portions. formed. Mg2+ ions are suspected
present.
e.(i).To the 1st portion of
the solution, add dilute White precipitate Zn2+, Pb2+ & Al3+ ions
sodium hydroxide soluble in excess to form are suspected present.
solution drop wise until a colourless solution.
in excess.
e.(ii).To the 2nd portion
of the solution, add White precipitate Zn2+ ion is suspected
dilute ammonia solution soluble in excess to form present.
drop-wise until in colourless solution.
excess.
e.(iii).Use the 3rd portion
of the solution to carry
out a test of your own
choice to confirm one of
the cations in the
solution in Z.
Test:
To the 3rd portion of the
solution, add a spatula Zn2+ ion is confirmed
end-ful of solid ammoniu present.

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 BASIC ADVANCED LEVEL CHEMISTRY PRACTICAL

chloride followed by 4 White precipitate

drops of disodium soluble in aqueous
hydrogen phosphate ammonia solution.
solution & then add
ammonia solution drop-
wise until in excess.
Identify the:
i. Cations present in compound Z.
Ba2+ ion is confirmed in d (iv).
Zn2+ ion is confirmed in e (iii).
ii. Anions present in compound Z.
Cl- ion is confirmed in d (vi).
CO32-ion is confirmed in e.
Experiment 5, W is a mixture of MnSO4 & CuCO3:
You are provided with substance W which contains two cations and two anions.
You are required to carry out the following tests on W to identify the cations and
anions in W. Record your observations and conclusion in the table below.
Tests Observations Deductions
(a).Heat one spatula Colourless liquid that Water of crystallization.
end-ful of W strongly in turns anhydrous copper ∴hydrated salt present.
a dry test tube. (II) sulphate blue.
Colourless gas that turns Carbon dioxide gas is
moist blue litmus paper given off.
red & limet water milky. ∴CO32-, C2O42- & HCO3-
ions are suspected
present.
CuO,FeO & NiO are
Black residue remains. suspected present.
(b).To two spatula end- Colourless filtrate. Pb2+, Zn2+, Ba2+, Ca2+,
fuls of W in a test tube, Mg2+ & Al3+ ions are
add about 5cm3 of water, & suspected present.
shake & filter. Keep both
the filtrate & residue. Green residue. Cu2+, Fe2+, Ni2+ & Cr3+
Divide the filtrate in to ions are suspected
five parts. present.
b.(i).To the 1 part of
st

the filtrate, add dilute White precipitate Mn2+ ion is suspected

sodium hydroxide insoluble in excess, turns present.
brown on standing.

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 BASIC ADVANCED LEVEL CHEMISTRY PRACTICAL

solution drop-wise until

in excess.
b.(ii).To the 2nd part of
the filtrate, add dilute White precipitate Mn2+ ion is suspected
ammonia solution drop- insoluble in excess, turns present.
wise until in excess. brown on standing.
b.(iii).Use the 3rd part of
the filtrate to carry out a
test of your own choice
to confirm one of the
cation present in W.
Test:
To the 3rd part of the Purple solution. Mn2+ ion is confirmed
filtrate, add present.
concentrated nitric acid
followed by solid sodium
bismuthate.
b.(iv).To the 4th part of White precipitate. SO42-, CO32-, SO32- & Cl-
the filtrate, add 2-3 ions are suspected
drops of lead (II) nitrate present.
solution.
b.(v).Use the 5th part of
the filtrate to carry out a
test of your own choice
to confirm one of the
anions present in W.
Test:
To the 5th part of the White precipitate SO42- ion is confirmed
filtrate, add barium insoluble in the acid. present.
nitrate solution followed
by dilute nitric acid.
Or
Add barium chloride
followed by dilute
hydrochloric acid.
(c).Wash the residue Effervescence of Carbon dioxide gas is
with distilled water & colourless gas that turns given off.
dissolve in in dilute moist blue litmus red & ∴CO32- ion is confirmed
hydrochloric acid & lime water milky. present.

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 BASIC ADVANCED LEVEL CHEMISTRY PRACTICAL

divide the solution in to Blue solution. Cu2+ &

four parts. Green solution. Cu2+, Ni2+, Fe2+ & Cr3+
ions are suspected
present
c.(i).To the 1st part of the Pale-blue precipitate Cu2+ ion is suspected
solution, add dilute insoluble in excess. present.
sodium hydroxide
solution drop-wise until
in excess.
c.(ii).To the 2nd part of Blue precipitate soluble Cu2+ ion is suspected
the solution, add dilute in excess ammonia present.
ammonia solution drop- solution forming a deep-
wise until in excess. blue solution.
c.(iii).To the 3 part of
rd Greenish-brown Cu2+ ion is suspected
the solution, add 2-3 solution. present.
drops of potassium Accept: Green solution
thiocyanate solution. or Greenish black.
c.(iv).Use the 4 part of
th

the solution to carry out

a test of your own choice
to identify one of the
cations in W.
Test:
To the 2nd part of the
solution, add 3 drops of
potassium iodide White precipitate &
solution. brown solution. Cu2+ ion is confirmed
Or: present.
Add 3 drops of
potassium Dark-brown precipitate.
hexacyanoferrate(II)
solution
Identify the:
i. Cations present in compound W.
Mn2+ ion is confirmed in b (iii).
Cu2+ ion is confirmed in c (iv).
ii. Anions present in compound W.
SO42- ion is confirmed in b (v).
CO32-ion is confirmed in c.

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 BASIC ADVANCED LEVEL CHEMISTRY PRACTICAL

Experiment 6, V is a mixture of CuSO4-5-H2O & (NH4)2SO4:

You are provided with substance V which contains three cations and two anions.
You are required to carry out the following tests on V to identify the cations and
anions in V. Record your observations and conclusion in the table below.
Tests Observations Deductions
(a).Heat a spatula end- Melts to form a blue Water of crystallization.
ful of V in a dry test tube solution. ∴hydrate salt is present.
until there is no further Colourless liquid that
change. turns anhydrouse
copper (II) sulphate
blue.
White fumes that turns Sulphur dioxide gas is
moist blue litmus paper given off.
red & acidified K2Cr2O7 ∴SO32- & SO42- ions are
solution from orange to suspected present.
green.
White sublimate forms
on a cooler part of the
test tube.
White-black solid. CuO is formed.
(b).Shake two spatula Blue solution. Cu2+ ion is suspected
end-fuls of V with about Blue precipitate turns present.
3cm3 of distilled water. black on heating.
Add sodium hydroxide Colourless gas that turns Ammonia gas is given
solution to the mixture moist red litmus paper off.
drop-wise until in blue & forms dense ∴NH4+ ion is suspected
excess. Warm & filter. white fumes with present.
Keep both the filtrate & concentrated Rej:If conc.HCl isn’t used.
residue. hydrochloric acid.
Colourless filtrate. Pb2+, Zn2+, Sn2+, Al3+ &
Sn4+ ions are suspected
present.
Black residue. CuO is formed.
(c).To the filtrate, add White precipitate Al3+, Pb2+, Zn2+, Sn2+ &
dilute nitric acid drop- soluble in excess Sn4+ ions are suspected
wise until the solution is forming a colourless present.
just acidic. Divide the solution.
solution in to six
portions.

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 BASIC ADVANCED LEVEL CHEMISTRY PRACTICAL

c. (i).To the 1st part of White precipitate Al3+, Pb2+, Zn2+, Sn2+ &
acidic solution, add soluble in excess to give Sn4+ ions are suspected
dilute sodium hydroxide a colourless solution. present.
solution drop-wise until Colourless gas which
in excess. turns moist red litmus Ammonia gas is given
paper blue & forms off.
white fumes with ∴NH4+ ion is confirmed
concentrated present.
hydrochloric acid.
c. (ii).To the 2nd part of White precipitate Al3+, Pb2+, Sn2+ & Sn4+
the acidified solution, insoluble in excess. ions are suspected
add dilute ammonia present.
solution drop-wise until
in excess.
c. (iii).To the 3rd part of No observable change Pb2+ ion is absent.
the acidic solution, add occurs.
2-3 drops of potassium Or Rej:Al3+ ion present
iodide solution. No yellow precipitate.
c. (iv).To the 4th part of Blue precipitate soluble Al3+ ion confirmed
the acidified solution, forming a blue solution. present.
add 2-3 drops of litmus Or
solution followed by Blue lake.
ammonia solution drop-
wise until in excess.
c.(v).To the 5th part of White precipitate. SO42- & Cl- ions are
the acidified solution, suspected present.
add 2-3 drops of lead (II)
ethanoate solution. CO32- & SO32- are rejected
b’se the solution was
acidic.
c. (vi).Use the 6th part of
the acidified solution to
carry out a test of your
own choice to confirm
one of the anion in V.
Test:
To the 6th part of the
acidified solution, add 3 White precipitate. SO42- ion is confirmed
drops of barium nitrate present.

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 BASIC ADVANCED LEVEL CHEMISTRY PRACTICAL

solution/barium
chloride solution.
Note:
No need of adding the
acid b’se the solution
was acidic.
(d).Wash the residue Residue dissolves to give Cu2+ ion is suspected
with distilled water & a blue solution. present.
dissolve it in dilute
hydrochloric acid. Divide Accept: Green solution. Ni2+, Cu2+, Fe2+ & Cr3+
the solution in to three ions are suspected
parts. present.
d. (i).To the 1 part of
st Blue precipitate Cu2+ ion is suspected
the acidic solution, add insoluble in excess. present.
dilute sodium hydroxide
solution drop-wise until
in excess.
d. (ii). To the 1st part of Blue precipitate soluble Cu2+ ion is suspected
the acidic solution, add in excess forming a present.
dilute ammonium deep-blue solution.
hydroxide solution drop-
wise until in excess.
d. (iii). To the 1st part of Brown precipitate. Cu2+ ion is confirmed
the acidic solution, add present.
2-3 drops of potassium Accept; Maroon
hexacyanoferrate (II) precipitate.
solution.
Identify the:
i. Cations present in compound V.
Al3+ ion is confirmed in c (iv).
Cu2+ ion is confirmed in d (iii).
NH4+ ion is confirmed in c (i).
ii. Anions present in compound V.
SO42- ion is confirmed in c (vi).
Experiment 7, U is a mixture of NiCO3 & FeSO4.7H2O:
You are provided with substance U which contains three cations and two anions.
You are required to carry out the following tests on U to identify the cations and
anions in U. Record your observations and conclusion in the table below.
Tests Observations Deductions

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 BASIC ADVANCED LEVEL CHEMISTRY PRACTICAL

(a).Heat one spatula Colourless liquid Hydrate salt/water of

end-ful of U in a dry test /condensate that turns crystallization is present.
tube. anhydrous copper (II)
sulphate blue.
Colourless gas that turnsCarbon dioxide gas is
moist blue litmus paper given off.
red & lime water milky. ∴CO32-, C2O42-, HCO3- &
CH3COO- ions are
suspected present.
White fumes that turns Sulphur dioxide gas is
acidified potassium given off.
dichromate (VI) solution ∴SO42-, SO32- ions are
from orange to green. suspected present.

Green solid turns CuO & FeO or Fe2O3 (For

black/brown residue. brown solid)
(b).To two spatula end- Green filtrate. Transitional metal ions,
fuls of U, add about 5cm3 Fe2+, Cu2+, Ni2+ & Cr3+
of water. Shake ions are suspected in
vigorously and filter. Green residue. both filtrate and residue.
Divide the filtrate in to
five parts. Keep the
residue.
b. (i).To the 1st part of Green precipitate Ni2+ & Fe2+ ions are
the filtrate, add dilute insoluble in excess. suspected present.
sodium hydroxide
solution drop-wise until
in excess.
b.(ii).To the 2nd part of Green precipitate Fe2+ ion is suspected
the filtrate, add dilute insoluble in excess, turns present.
ammonia solution drop- brown
wise until in excess.
b.(iii).To the 3rd part of
the filtrate, add 3-4
drops of concentrated Green solution turns Fe2+ ion is oxidized to
nitric acid followed by 2- yellow then blood-red Fe3+ ion.
3 drops of potassium on addition of KSCN(aq). ∴Fe2+ ion is confirmed
thiocyanate solution. present.

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 BASIC ADVANCED LEVEL CHEMISTRY PRACTICAL

b.(iv).To the 4th part of White precipitate Cl- ion is absent.

the filtrate, add 2-3 insoluble on heating.
drops of lead (II) nitrate ∴SO32- & SO42- ions are
solution. Heat and allow suspected present.
the mixture to cool.
b.(v).Use the 5th part of
the filtrate to carry out a
test of your own choice
to confirm one of the
anions in U.
Test:
To the 5th part of the
filtrate, add barium White precipitate SO42- ion is confirmed
nitrate followed by insoluble in the acid. present.
dilute nitric acid.
Or
BaCl2/HCl
(c).Wash the residue Effervescence/ bubbles. Carbon dioxide gas is
with distilled water and Colourless gas that turns given off.
dissolve it in dilute moist blue litmus paper ∴CO32- ion is confirmed
hydrochloric acid & red & lime water milky. present.
divide the resultant
solution in to three Green solution is formed. Cr3+, Fe2+, Cu2+, Ni2+ are
parts. suspected present.
c.(i).To the 1st part of the Green precipitate Ni2+& Fe2+ ions are
solution, add dilute insoluble in excess. suspected present.
sodium hydroxide
solution drop-wise until
in excess.
c. (ii).To the 2nd part of Green precipitate Ni2+ ion is suspected
the solution, add dilute soluble in excess to a present.
ammonium hydroxide form a pale-blue
solution drop-wise until solution.
in excess.
c.(iii).Use the 3rd part of
the solution, add carry
out a test of your own
choice to confirm one of
the cations in U.

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 BASIC ADVANCED LEVEL CHEMISTRY PRACTICAL

Test:
To the 3rd part of the Red precipitate. Ni2+ ion is confirmed
solution, add aqueous present.
ammonia solution until
the solution is alkaline,
then add 2 drops of
dimethylglyoxime
solution.
Identify the:
i. Cations present in compound U.
Ni2+ ion confirmed in c (iii).
Fe2+ ion is confirmed in b (iii).
ii. Anions present in compound U.
SO42- ion is confirmed in b (v).
CO32- ion is confirmed in c.
Experiment 8, T is a mixture of (CH3COO)2Ni & Al2SO4:
You are provided with substance T which contains two cations and two anions.
You are required to carry out the following tests on T to identify the cations and
anions in T. Record your observations and conclusion in the table below.
Tests Observations Deductions
(a).Heat two spatula Colourless Water is given off.
end-fuls of T strongly in condensate/liquid that ∴ Hydrated salt is
a dry test tube. turns anhydrous copper present.
(II) sulphate blue.
Colourless gas that turns Sulphur dioxide gas is
moist blue litmus paper given off.
red & acidified ∴SO32-, & SO42- ions are
potassium dichromate suspected present.
(VI) solution from
orange to green.
Colourless gas with Propanone is given off.
sweet smell & forms ∴CH3COO- ion is
yellow ppt with Brady’s suspected present.
reagent.
Carbon dioxide gas is
Colourless gas that turns given off.
lime water milky. ∴CO32-, C2O42- & HCO3-
ions are suspected
present.

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 BASIC ADVANCED LEVEL CHEMISTRY PRACTICAL

NiO, CuO & FeO salts are

Green solid turns to present.
black residue.
(b).To two spatula end- Colourless that turns Gas is ethanoic acid
fuls of T in a dry test moist blue litmus red & vapour.
tube, add 5 drops of has a sharp vinegar ∴CH3COO- ion is
concentrated sulphuric smell. suspected present.
acid and warm.
(c).Dissolves three Dissolves to give a green Cr3+, Ni2+, Fe2+ & Cu2+
spatula endfuls of T in solution. ions are suspected
about 5cm3 of distilled present.
water to make a solution
c.(i).Use 1cm3 of the
solution of T to carry out
a test of your own choice
to confirm one of the
anions in T.
Test:
To the solution of T, add Reddish-brown solution
3 drops of iron (III) forms a brown CH3COO- ion is
chloride solution and precipitate. confirmed present.
heat.
Or:
Add a few drops of Sweet fruity smell.
concentrated sulphuric
acid followed by ethanol
and heat.
c.(ii).To the remaining Green precipitate Ni2+ & Fe2+ ions are
solution of T, add dilute insoluble in excess. suspected present.
sodium hydroxide
solution drop-wise until Rej: Cu2+ & Cr3+ ions.
there is no further
change.
Filter & keep both the
filtrate and residue. Colourless filtrate. Al3+, Zn2+, Pb2+, Sn2+ &
Sn4+ ions are suspected
present.
Rej: Ca2+ & Ba2+ ions.
Green residue.

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 BASIC ADVANCED LEVEL CHEMISTRY PRACTICAL

Ni2+ & Fe2+ ions are

suspected present.

Rej: Cu2+ & Cr3+ ions.

(d).Add dilute White precipitate Al3+, Zn2+ & Sn2+ ions
hydrochloric acid drop- soluble in dilute are suspected present.
wise to the filtrate until hydrochloric acid to
the solution is just acidic. form a colourless Rej: Pb2+ ion, b’se it
Divide the solution in to solution. forms a white ppt with
four portions. HCl(aq).
d.(i).To the 1st portion of White precipitate Al3+, Zn2+ & Sn2+ ions
the acidified filtrate, add soluble in dilute are suspected present.
dilute sodium hydroxide hydrochloric acid to Rej: Pb2+ ion, b’se it
solution drop-wise until form a colourless forms a white ppt with
in excess. solution. HCl(aq).
d.(ii).To the 2nd portion
of the acidified filtrate, No observable change Pb2+ ion is absent.
add potassium iodide occurs.
solution.
d.(iii).To 3rd portion of
the acidified filtrate, add Blue solution/blue lake. Al3+ ion is confirmed
5 drops of litmus present.
solution followed by
dilute ammonia solution
drop wise until in excess.
d.(iv).To the 4th portion
of the acidified filtrate, White precipitate. SO42- ion is confirmed
add 5 drops of barium present.
bitrate solution.
(e).Wash the residue
with distilled water and Dissolves to give a green Ni2+ & Fe2+ ions are
dissolve in dilute solution. suspected present.
hydrochloric acid &
divide the acidic solution
in to three portions.
e.(i).To the 1st portion of
the acidic solution, add Green precipitate Ni2+ & Fe2+ ions are
dilute sodium hydroxide insoluble in excess. suspected present.

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 BASIC ADVANCED LEVEL CHEMISTRY PRACTICAL

solution drop-wise until

in excess.
e.(ii).To the 2nd portion
of the acidic solution, Green precipitate Ni2+ ion is suspected
add dilute ammonia dissolves to give a light present.
solution drop-wise until blue solution.
in excess.
e.(iii).Use the 3rd portion
of the acidic solution to
carry out a test of your
own choice to confirm
one of the cations in T.
Test:
To the 3rd portion of the
acidic solution, add Red precipitate Ni2+ ion is confirmed
dilute ammonia solution present.
drop-wise until in excess
and follow by 3 drops of
dimethylglyoxide
solution.
Identify the:
i. Cations present in compound T.
Al3+ ion is confirmed in d (iii).
Ni2+ ion confirmed in e (iii).
ii. Anions present in compound T.
CH3COO- ion is confirmed in c (i).
SO42- ion is confirmed in d (iv).
Experiment 9, S is a mixture of MnCl2 & PbCO3:
You are provided with substance S which contains two cations and two anions.
You are required to carry out the following tests on S to identify the cations and
anions in S. Record your observations and conclusion in the table below.
Tests Observations Deductions
(a).Heat one spatula Colourless Water is given off.
end-fuls of S strongly in liquid/condensate that ∴hydrated salt is
a dry test tube until turns anhydrous copper present.
there is no further (II) sulphate blue. Carbon dioxide gas is
change. Colourless that turns given off.
moist blue litmus paper
red & lime water milky.

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 BASIC ADVANCED LEVEL CHEMISTRY PRACTICAL

∴CO32- , C2O42-, & HCO3-

ions are suspected
Reddish-brown residue present.
–hot & yellow-cold. PbO is formed.
(b).To a spatula end-fuls Effervescence, Misty Hydrogen chloride gas is
of S, add 2-3 drops of fumes which turns moist given off.
concentrated sulphuric blue litmus red and
acid and warm. forms white fumes with ∴Cl- ion is suspected
concentrated ammonia present.
solution.
(c).To two spatula end- Effervescence/bubbles Carbon dioxide gas is
fuls of S, add dilute nitric of a colourless gas that given off.
acid until there is no turns moist blue litmus ∴CO32- ion is confirmed
further change then add paper red & lime water present.
dilute sodium hydroxide milky.
solution drop-wise until Mn2+ ion is suspected
in excess. Filter & keep White precipitate present.
the filtrate & residue. insoluble in excess, turns
brown. Pb2+, Zn2+, Sn2+, Al3+ &
Colourless filtrate Sn4+_ ions are suspected
present.
& Rej: Ca2+, Ba2+ & Mg2+
ions.
Mn2+ ion is suspected
Brown residue. present.
(d).To the filtrate add
dilute nitric acid until White precipitate Pb2+, Zn2+, Sn2+, Al3+ &
the solution is just acidic. soluble in the acid to Sn4+_ ions are suspected
The divide the resultant form a colourless present.
solution in to four parts. solution.
d.(i).To the 1st part of White precipitate Pb2+, Sn2+, Al3+ & Sn4+_
the acidic solution, add soluble in the acid to ions are suspected
dilute sodium hydroxide form a colourless present.
solution drop-wise until solution.
in excess.
d.(ii).To the 2nd part of White precipitate Pb2+, Sn2+, Al3+ & Sn4+_
the acidic solution, add insoluble in excess. ions are suspected
aqueous ammonia drop- present.
wise until in excess

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 BASIC ADVANCED LEVEL CHEMISTRY PRACTICAL

d.(iii).To the 3rd part of White precipitate. Pb2+ ion is suspected

the acidic solution, add present.
dilute sulphuric acid.
d.(iv).Use the 4th part of
the acidic solution to
carry out a test of your
own choice to confirm of
the cations in S.
Test:
To the 4th of the acidic
solution, add 2-3 drops Yellow precipitate.
of potassium iodide Pb2+ ion is confirmed
solution. present.
Or:
Add potassium chromate
(VI) solution followed by Yellow precipitate
sodium hydroxide soluble to form a yellow
solution drop-wise until solution.
in excess.
(e).To two spatula end- Colourless filtrate. Non-transitional metal
fuls of S, add about 5cm3 & ions,
of water, shake & filter. White residue. Al3+,Zn2+,Pb2+,Ba2+, Ca2+
Divide the filtrate in to & Mg2+ ions are
five parts. suspected present in
both filtrate & residue.
e.(i).To the 1st part of the White precipitate Mn2+ ion is suspected
filtrate, add sodium insoluble in excess turns present.
hydroxide solution drop- to brown. Note
wise until in excess. Award no mark if
insoluble is not
mentioned.
e.(ii).To the 2nd part of White precipitate Mn2+ ion is suspected
the filtrate, add aqueous insoluble in excess turns present.
ammonia solution drop- to brown.
wise until in excess.
e.(iii).Use the 3rd part of
the filtrate to carry out a
test of your own choice

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 BASIC ADVANCED LEVEL CHEMISTRY PRACTICAL

to confirm one of the

cations in S.
Test: Purple solution. Mn2+ ion is confirmed
To the 3rd part of the Rej: Sodium bismuthate present.
filtrate, add solution.
concentrated nitric acid  Insist on order of
followed by solid sodium reagents.
bismuthate. Insist on heating.
Or:
Add concentrated nitric
acid & PbO2 & heat.
e.(iv).To 4th part of the White precipitate Cl- ion is suspected
filtrate, add 2-3 drops of soluble on heating. present.
lead (II) nitrate solution
and heat.
e.(v).Use the 3rd part of
the filtrate to carry out a
test of your own choice
to confirm one of the
cations in S.
Test:
To the 3rd part of the White precipitate Cl- ion is confirmed
filtrate, add silver nitrate insoluble on heating. present.
solution followed by
dilute nitric acid.
Identify the:
i. Cations present in compound S.
Pb2+ ion confirmed in d (iv).
Mn2+ ion is confirmed in e (iii).
ii. Anions present in compound S.
CO32- ion is confirmed in c.
Cl- ion is confirmed in e (v).
Experiment 10, R is a mixture of BaO, ZnCO3 & KI or BaCO3, ZnO & KI:
You are provided with substance R which contains two cations and two anions.
You are required to carry out the following tests on R to identify the cations and
anions in R. Record your observations and conclusion in the table below.
Tests Observations Deductions

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(a).Heat two spatula Colourless gas that turns Carbon dioxide gas is
end-fuls of R strongly in moist blue red & lime given off.
a dry test tube. water milky. ∴CO32- , C2O4 & HCO3-
ions are suspected
present.
Yellow residue-hot & ZnO is formed.
white –cold.
(b).To three spatula end- Dissolves with Carbon dioxide gas is
ful of R, add dilute nitric bubbles/effervescence given off.
drop-wise until no of colourless of a
further change & warm. colourless gas that turns ∴CO32- ion is confirmed
moist blue litmus red & present.
lime water milky.

Colourless solution. Ca2+, Ba2+ & Mg2+ ions

are suspected present.
(c).To the solution from White precipitate Ca2+, Ba2+ & Mg2+ ions
(b) above, add dilute insoluble in excess. are suspected present.
sodium hydroxide
solution drop-wise until White residue.
in excess. Filter the
mixture. Keep both the
filtrate & residue. Colourless filtrate Al3+, Zn2+, Pb2+, Sn2+ &
Sn4+ ions are suspected
present.
(d).To the filtrate, add
dilute nitric acid until White precipitate Al3+, Zn2+, Pb2+, Sn2+ &
the solution is just acidic soluble forming Sn4+ ions are suspected
& divide the acidic colourless solution. present.
solution in to six parts.
d.(i). To the 1st part of Pale-yellow precipitate Br- & I- ions are
the acidified solution, insoluble in ammonia suspected present.
add 2-3 drops of silver solution.
nitrate solution followed
by dilute ammonia
solution drop-wise until
in excess.
d.(ii). To the 2nd part of Colourless solution turns I2 vapour is given off.
the acidified filtrate, add brown & then turns to

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6 drops of concentrated colourless on adding ∴I- ion is suspected

sulphuric acid & warm Na2S2O3(aq0 present.
then to the mixture, add
sodium thiosulphate
solution.
d.(iii).To the 3rd part of Yellow precipitate. I- ion is confirmed
the acidified filtrate, add present.
2-3 drops of lead (II)
nitrate solution.
d.(iv).To the 4th part of
the acidified filtrate, add White precipiate soluble Al3+, Zn2+, Pb2+, Sn2+ &
dilute sodium hydroxide in excess forming Sn4+ ions are suspected
solution drop- wise until colourless solution. present.
in excess.
d.(v). To the 5th part of White precipiate soluble Zn2+ion is suspected
the acidic filtrate, add in excess forming present.
dilute ammonia solution colourless solution.
drop-wise until in excess
d.(vi). To the 6th part of
the acidic filtrate, add a White precipitate Zn2+ion is confirmed
spatula end-ful of soluble in ammonia present.
ammonium chloride solution forming a
solution followed by 3-4 colourless solution.
drops of disodium
hydrogen phosphate
followed by drop-wise
addition of aqueous
ammonia solution until
in excess.
(e).Wash the residue
with distilled water & Dissolves forming Ba2+, Ca2+ & Mg2+ ions
dissolve in dilute colourless solution. are suspected present.
hydrochloric acid &
divide the solution in to
three parts.
e.(i).To the 1st part of the
acidic solution, add White precipitate Ba2+, Ca2+ & Mg2+ ions
dilute sodium hydroxide insoluble in excess. are suspected present.

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 BASIC ADVANCED LEVEL CHEMISTRY PRACTICAL

solution drop-wise until

in excess.
e.(ii).To the 2nd part of White precipitate Ba2+ & Mg2+ ions are
the acidic solution, add insoluble in excess. suspected present.
dilute ammonia solution
drop-wise until in excess
e.(iii).To the 3rd part of
the acidic solution, add Yellow precipitate. Ba2+ ion is confirmed
2-3 drops of potassium present.
chromate (VI) solution.
Identify the:
i. Cations present in compound S.
Zn2+ ion confirmed in d (vi).
Ba2+ ion is confirmed in e (iii).
ii. Anions present in compound S.
CO32- ion is confirmed in b.
I- ion is confirmed in d (iii).
Experiment 11, Q is a mixture of CuCO3 & (NH4 )2FeSO4 (Ammonium ferric
sulphate:
You are provided with substance Q which contains three cations and two anions.
You are required to carry out the following tests on Q to identify the cations and
anions in Q. Record your observations and conclusion in the table below.
Tests Observations Deductions
(a).Heat one spatula Colourless liquid/condensate Water is given off.
end-ful of Q strongly in a that turns anhydrous ∴hydrate salt is
dry test tube until no copper (II) sulphate suspected present.
further change. blue. Carbon dioxide gas is
Colourless that turns given off.
moist blue litmus paper ∴CO32- , C2O42- & HCO3-
red & lime water milky. ions are suspected
Colourless gas that turns present.
moist red litmus paper Ammonia gas is given off
blue & forms white ∴NH4+ ion is suspected
fumes with concentrated present.
hydrochloric acid.
White sublimate.

Green solid decomposes FeO, NiO & CuO are

to leave black residue. formed.

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(b).Put two spatula end- Dissolves with Carbon dioxide gas is

fuls of Q in a test tube. effervescence of given off.
Add about 6cm3 of colourless gas that turns ∴CO32- ion is confirmed
distilled water & shake moist blue litmus red & present.
well, Allow the mixture lime water milky.
to stand for 5 minutes
with occasional shaking, Green filtrate. Cu2+, Fe2+, Ni2+ & Cr3+
filter. Keep both the ions are suspected
filtrate & residue & present.
divide the filtrate in to Brown residue. Fe3+ ion is suspected
five parts. present.
b.(i).To the 1st part of Blue precipitate Cu2+ ion is suspected
the filtrate, add dilute insoluble in excess, turns present.
sodium hydroxide black on heating. ∴CuO is formed.
solution drop-wise until
in excess, heat the Colourless gas turns Ammonia gas is given
mixture. moist red litmus paper off.
blue & forms white ∴ NH4+ ion is confirmed
fumes with concentrated present.
hydrochloric acid.
b.(ii).To the 2nd part of Blue precipitate soluble Cu2+ ion is suspected
the filtrate, add dilute in excess to form a deep- present.
ammonia solution drop- blue solution.
wise until in excess.
b.(iii).To the 3rd part of Dark-brown precipitate. Cu2+ ion is confirmed
the filtrate, add a few present.
drops of potassium
hexacyanoferrate (II)
solution.
b.(iv).To the 4th part of White precipitate Cl- ion is absent.
the filtrate, add 3 drops insoluble on heating. But:
of lead (II) nitrate SO42- & SO32- ions are
solution and heat. suspected present.
b.(v).Use the 5th part of
the filtrate to carry out a
test of your own to
confirm one of the
anions present in Q.
Test:

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To the 5th part of the

filtrate, add 3 drops of White precipitate SO42- ion is confirmed
barium nitrate solution insoluble in the acid. present.
followed by dilute nitric
acid.
Or:
Add barium chloride
followed by dilute
hydrochloric acid.
(c).Wash the residue Brown solid is formed. Fe2O3 formed hence:
with distilled water.
Heat a small portion of Fe3+ ion is suspected
the residue strongly present.
(d).Transfer the rest of Dissolves to give a Fe3+ ion is suspected
the residue in to a test yellow solution. present.
tube & dissolve it in
dilute hydrochloric acid
hence divide the solution
in to three parts.
d.(i).To the 1st part of Reddish-brown Fe3+ ion is suspected
the solution, add dilute precipitate insoluble in present.
sodium hydroxide excess.
solution drop wise until
in excess.
d.(ii).To 2nd part of the Reddish-brown Fe3+ ion is suspected
solution, add dilute precipitate insoluble in present.
ammonia solution drop excess.
wise until in excess.
d.(iii).To 3rd part of the Deep-red solution. Fe3+ ion is confirmed
solution, add 2-3 drops present.
of potassium thiocyanate Or
solution Blood-red solution.
Identify the:
i. Cations present in compound Q.
NH4+ ion confirmed in b (i).
Cu2+ ion is confirmed in b (iii).
Fe3+ ion is confirmed in d (iii).
ii. Anions present in compound Q.
CO32- ion is confirmed in b.

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 BASIC ADVANCED LEVEL CHEMISTRY PRACTICAL

SO42- ion is confirmed in b (v).

Experiment 12, I is a mixture of NiCO3 & CrCl3.6H2O:
You are provided with substance I which contains two cations and two anions.
You are required to carry out the following tests on I to identify the cations and
anions in I. Record your observations and conclusion in the table below.
Tests Observations Deductions
(a).Heat two spatula Colourless condensate Water is given off.
end-fuls of I strongly in a that turns anhydrous ∴hydrated salt is present
dry test tube. copper (II) sulphate blue
Colourless gas that turns Carbon dioxide gas is
moist blue litmus paper given off.
red & lime water milky. ∴CO32- , C2O42-, & HCO3-
ions are suspected
present.
Green solid turns to CuO, NiO & FeO are
black residue. formed.
∴Ni2+, Cu2+, & Fe2+ ions
are suspected present.
(b).To two spatula end-
fuls of I, add about 5cm3 Green filtrate. Ni2+, Fe2+, Cu2+ & Cr3+
of distilled water, shake ions are suspected
vigorously & filter. Keep & present in both filtrate &
both the filtrate & residue.
residue then divide the Green residue.
filtrate in four parts.
b.(i).To the 1st part of Grey-green precipitate Cr3+ ion is suspected
the filtrate, add dilute soluble forming a green present.
sodium hydroxide solution.
solution drop-wise until
in excess.
b.(ii).To the 2nd part of Grey-green precipitate Cr3+ ion is suspected
the filtrate, add dilute insoluble forming a present.
ammonia solution drop- green solution.
wise until in excess.
b.(iii).To the 3rd part of Grey-green precipitate CrO42- ion is formed.
the filtrate, add dilute soluble forming a green ∴Cr3+ ion is suspected
sodium hydroxide solution & on boiling, present.
solution drop wise until green solution turns to
in excess followed by 2-3 yellow.

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 BASIC ADVANCED LEVEL CHEMISTRY PRACTICAL

drops of hydrogen
peroxide, boil the
mixture & divide it in to
two parts.
b.(i).To the 1st part of Yellow precipitate. PbCrO4 is formed.
the solution, add 2-3
drops of lead (II) ∴Cr3+ ion is suspected
ethanoate solution. present.
Allow it to cool.
b.(ii).To the 2nd part of Blue colour in butan-1-ol Cr3+ ion is confirmed
the solution, add about layer. present.
1cm3 of butan-1-ol
followed by dilute
sulphuric acid.
(iii).To the 3rd part of the White precipitate. Cl-, SO32-, SO42- & CO32-
filtrate, add 3-4 drops of ions are suspected
lead (II) ethanoate present.
solution.
(iv).Use the 4th part of
the filtrate to carry out a
test of your own choice
to confirm one of anions
in I.
Test:
To the 4th part of the
filtrate, add 3 drops of White precipitate Cl- ion is confirmed
silver nitrate solution insoluble in the acid. present.
followed by dilute nitric
acid.
(c).Wash the residue Effervescence of Carbon dioxide gas is
with distilled water & colourless gas that turns given off.
dissolve it in 2M moist blue litmus paper ∴CO32- ion is confirmed
sulphuric acid & divide red & lime water milky. present.
the solution in to three Green solution is formed. Ni2+, Cr3+, Fe2+ & Cu2+
parts. ions are present.
c.(i).To the 1st part of the Green precipitate Ni2+ & Fe2+ ions are
solution, add dilute insoluble in excess. suspected present.
sodium hydroxide

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 BASIC ADVANCED LEVEL CHEMISTRY PRACTICAL

solution drop-wise until

in excess.
c.(ii).To the 2nd part of Green precipitate Ni2+ ion is suspected
the solution, add dilute dissolves forming a pale present.
ammonia solution drop blue solution.
wise until in excess.
c.(iii).Use the 3rd part of
the solution to carry out
a test of your own choice
to confirm one of the
cations in I.
Test:
To the 3rd part of the Red precipitate Ni2+ ion is confirmed
solution, add excess present.
ammonia solution
followed by
dimethylglyoxime
solution.
Identify the:
i. Cations present in compound I.
Cr3+ ion confirmed in b (ii).
Ni2+ ion is confirmed in c (iii).
ii. Anions present in compound I.
Cl- ion is confirmed in b (iv).
CO32- ion is confirmed in c.
Experiment 13, N is a mixture of CoCl2.6H2O & CuCO3:
You are provided with substance N which contains two cations and two anions.
You are required to carry out the following tests on N to identify the cations and
anions in N. Record your observations and conclusion in the table below.
Tests Observations Deductions
(a).Heat a spatula end- Colourless gas that turns Carbon dioxide gas is
ful of N in a dry test tube moist blue litmus paper given off.
strongly. red & lime water milky. ∴CO32- , C2O42-, & HCO3-
ions are suspected
present.

Colourless liquid that Water of crystallization.

turns anhydrous copper ∴hydrated salt is present
(II) sulphate blue.

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Colourless gas with Hydrogen chloride gas is

pungent smell that turns given off.
moist blue litmus paper ∴Cl- ion is suspected
red & forms a dense present.
white fumes with
ammonia solution.

Green-red solid that CuO, NiO & FeO are

turns to black. formed.
(b).Put two spatula end- Pink filtrate. Co2+ & Mn2+ ions are
fuls of N in a test tube, suspected present.
add about 6cm3 of &
distilled water & shake
vigorously then filter. Green residue. Cu2+, Ni2+, Fe2+ & Cr3+
Divide the filtrate in to ions are suspected
five parts. present.
b.(i).To the 1st part of
the filtrate, add dilute Blue precipitate Co2+ion is suspected
sodium hydroxide insoluble in excess turns present.
solution drop wise until to pink.
in excess.
b.(ii).To the 2nd part of
the filtrate, add dilute Blue precipitate soluble Co2+ion is suspected
ammonia solution drop in excess giving red present.
wise until in excess. solution.
b.(iii).To the 3rd part of
the filtrate, add Blue solution is formed. Co2+ion is confirmed
concentrated present.
(saturated) solution of
potassium thiocyanate.
b.(iv).To the 4th part of White precipitate is SO42-, CO32-, SO32- & Cl-
the filtrate, add 2-3 formed. ions are suspected
drops of lead (II) nitrate present.
solution.
b.(v).Use the 5th part of
the filtrate to carry out a
test of your own choice

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 BASIC ADVANCED LEVEL CHEMISTRY PRACTICAL

to confirm one of the

anions present in N.
Test:
To the 5th part of the White precipitate
filtrate, add silver nitrate insoluble in the acid. Cl- ion is confirmed
solution followed by present.
dilute nitric acid.
(c).Wash the residue & Effervescence of Carbon dioxide gas is
transfer it in to a test colourless gas that turns given off.
tube. Add dilute moist blue litmus paper ∴CO32- ion is confirmed
hydrochloric acid until red & lime water milky. present.
there is no further
change & divide the Green solution. Ni2+, Cu2+, Fe2+ & Cr3+
solution in to four parts. ions are present.
c.(i).To the 1st part of the
solution, add dilute Blue precipitate Cu2+ ion is suspected
sodium hydroxide insoluble in excess. present.
solution drop wise until
in excess.
c.(ii).To the 2nd part of
the solution, add Blue precipitate soluble Cu2+ ion is suspected
aqueous ammonia in excess forming deep- present.
solution drop wise until blue solution.
in excess.
c.(iii).To the 3rd part of
the solution, add a few White precipitate and Cu2+ ion is suspected
drops of potassium brown solution is present.
iodide solution. formed.
c.(iv).To the 4th part of
the solution, add Dark-brown precipitate. Cu2+ ion is confirmed
potassium present.
hexacyanoferrate (II)
solution.
Identify the:
i. Cations present in compound N.
Co2+ ion confirmed in b (iii).
Cu2+ ion is confirmed in c (iv).
ii. Anions present in compound N.
Cl- ion is confirmed in b (iv).

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 BASIC ADVANCED LEVEL CHEMISTRY PRACTICAL

CO32- ion is confirmed in c.

Experiment 14, M is a mixture of MgCO3 & Na2C2O4:
You are provided with substance M which contains one cations and two anions.
You are required to carry out the following tests on M to identify the cations and
anions in M. Record your observations and conclusion in the table below.
Tests Observations Deductions
(a).Heat two spatula Colourless gas that turns Carbon dioxide gas is
end-fuls of M strongly in moist blue litmus paper given off.
a dry test tube. red & lime water milky. ∴CO32- , C2O42- & HCO3-
ions are suspected
present.
White residue. MgO, CaO & BaO are
formed.
(b).To two spatula end-
fuls of M in a test tube,
add about 6cm3 of Colourless filtrate. Al3+, Mg2+, Ba2+,Mg2+,
distilled water, shake Ca2+ & Pb2+ ions are
vigorously & filter. Keep & suspected present in
both the filtrate & both filtrate & residue.
residue. Divide the White residue.
filtrate in three portions.
b.(i).To the 1st part of
the filtrate, add 2-3 White precipitate SO32- , SO42- & C2O42- ions
drops of barium nitrate dissolves giving are suspected present.
solution followed by colourless solution.
dilute nitric acid.
b.(ii).To the 2nd part of White precipitate C2O42- ion is suspected
the filtrate, add 2-3 dissolves giving present.
drops of silver nitrate colourless solution.
solution followed by
dilute nitric acid.
b.(iii).To the 3rd part of Purple colour turns to
the filtrate, add 2-3 colourless. Carbon dioxide gas is
drops of acidified Colourless gas that turns given off.
potassium manganate moist blue litmus paper ∴ C2O42- ion is confirmed
(VII) solution & heat. red & lime water milky. present.
(c).Dissolve the residue Dissolves with Carbon dioxide gas is
in dilute nitric acid & effervescence of given off.
colourless gas that turns

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 BASIC ADVANCED LEVEL CHEMISTRY PRACTICAL

divide the solution in to moist blue litmus paper ∴CO32- ion is confirmed
four portions. red & lime water milky. present.
c.(i).To the 1 part of the
st

solution, add dilute White precipitate Mg2+, Ba2+ & Ca2+ ions
sodium hydroxide insoluble in excess. are suspected present.
solution drop wise until
in excess.
c.(ii).To the 2nd part of
the solution, add dilute White precipitate Mg2+& Ba2+ ions are
ammonia solution drop insoluble in excess. suspected present.
wise until in excess.
c.(iii).To the 3rd part of No observable change Ba2+ ion is absent.
the solution, add 2-3 occurs.
drops of potassium Or
chromate (VI) solution. No yellow precipitate.
c.(iv).To the 4 part of
th

the solution, add a White precipitate Mg2+ ion is confirmed

spatula end-ful of solid insoluble in excess. present.
ammonium chloride
followed by disodium
hydrogen phosphate &
then aqueous ammonia
solution drop wise until
in excess.
Identify the:
i. Cations present in compound M.
Mg2- ion is confirmed in c (iv).
ii. Anions present in compound M.
C2O42- ion confirmed in b (iii).
C032- ion is confirmed in c.
Experiment 15, L is a mixture of ZnSO3 & (NH4)2Cr2O7:
You are provided with substance L which contains two cations and two anions.
You are required to carry out the following tests on L to identify the cations and
anions in L. Record your observations and conclusion in the table below.
Tests Observations Deductions
(a).Heat two spatula Colourless gas that turns Ammonia gas is given off
end-fuls of L in a dry test moist red litmus paper
tube. blue & forms white ∴NH4+ ion is suspected
present.

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 BASIC ADVANCED LEVEL CHEMISTRY PRACTICAL

fumes with concentrated

hydrochloric acid.
CrO3 is formed.
Green residue.
Sulphur dioxide gas is
Colourless gas that turns given off.
moist blue litmus paper ∴SO32- & SO42- ions are
red & H+/K2Cr2O7(aq) suspected present.
from orange to green.
(b).To two spatula end-
fuls of L, add about 7cm3 Orange filtrate. Cr2O72- ion is suspected
of distilled water shake present.
well & filter. Keep both &
the filtrate and residue. White residue. Ca2+, Ba2+, Mg2+, Pb2+, &
Divide the filtrate in two Al3+ ions are suspected
parts. present.
b.(i). To the 1st part of
the filtrate, add dilute Orange solution turns to Cr2O72- ion is reduced to
sulphuric acid followed green. Cr3+ ion.
by ethanol & warm.
b.(ii).To the 2nd part of Red precipitate. AgCrO4 salt is formed.
the filtrate, add excess Colourless gas that turns ∴ Cr2O72- ion is
dilute sodium hydroxide moist red litmus paper confirmed present.
solution & heat, allow to blue & forms a dense Ammonia gas is given off
cool & to a little of this white fumes with NH4+ ion is confirmed
solution, add a few drops concentrated present.
of silver nitrate solution. hydrochloric acid.
(c).Dissolves the residue Effervescence of Sulphur dioxide gas is
in about 5cm3 of dilute colourless gas with given off.
hydrochloric acid & pungent smell, gas that ∴SO42- ion is confirmed
divide the solution in to turns moist blue litmus present.
two parts. paper red & acidified
K2Cr2O7(aq) from orange
to green.
c.(i).To the 1st of the White precipitate Zn2+,Pb2+, Sn2+, Al3+ &
solution, add dilute soluble in excess Sn4+ ions are suspected
sodium hydroxide forming a colourless present.
solution drop wise until solution.
in excess.

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c.(ii).To the 2nd part of White precipitate Zn2+ion is suspected

the solution, add soluble in excess present.
aqueous ammonia forming a colourless
solution drop wise until solution.
in excess.
c.(iii).To the 3rd part of White precipitate Zn2+ion is confirmed
the solution, add a soluble in excess present.
spatula end-ful of solid forming a colourless
ammonium chloride solution.
followed by 3-4 drops of
disodium hydrogen
phosphate & then
ammonia solution drop
wise until in excess.
Identify the:
i. Cations present in compound L.
NH4+ ion is confirmed in b (ii).
Zn2+ ion is confirmed in c (iii).
ii. Anions present in compound L.
C2O42- ion confirmed in b (ii).
S042- ion is confirmed in c.
Experiment 16, K is a mixture of FeBr3 & CaCO3:
You are provided with substance K which contains two cations and two anions.
You are required to carry out the following tests on K to identify the cations and
anions in K. Record your observations and conclusion in the table below.
Tests Observations Deductions
(a).Heat a spatula end- Colourless gas that turns Carbon dioxide is given
ful of K in a dry test tube. moist blue litmus red & off.
lime water. ∴CO32- ion is suspected
Purple (brown) vapour present.
is given off.
I2 & Br2 vapour are
evolved.
I2- & Br2- ions are
suspected present.
Brown residue. Fe2O3 are formed.
(b).To spatula end-fuls Yellowish-brown filtrate. Fe3+ & CrO42- ions are
of K, add about 6cm3 of suspected present.
distilled water shake & &

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filter. Keep both the White residue. Ca2+, Ba2+, Mg2+, Zn2+ &
filtrate & residue. Divide Pb2+ ions are suspected
the filtrate in to 6 parts. present.
b.(i).To the 1st part of
the filtrate, add dilute Brown precipitate Fe3+ion is suspected
sodium hydroxide insoluble in excess. present.
solution drop wise until
in excess.
b.(ii).To the 2nd part of
the filtrate, add dilute Brown precipitate Fe3+ion is suspected
ammonia solution drop insoluble in excess. present.
wise until in excess.
b.(iii).To the 3rd part of
the filtrate, add 2-3 Dark-blue precipitate is Fe3+ion is confirmed
drops of potassium formed. present.
hexacyanoferrrate (II)
solution.
b.(iv).To the 4th part of
the filtrate, add Brown vapour with I2 & Br2 vapour are
potassium dichromate pungent smell. evolved.
(VII) solution followed
by a few drops of Orange colour of the ∴I2- & Br2- ions are
concentrated sulphuric solution turns green. suspected present.
acid & warm.
b.(v).To the 5th part of
the filtrated, add silver Yellow precipitate I2- & Br2- ions are
nitrate solution followed insoluble in the acid. suspected present.
by dilute nitric acid.
b.(vi).To the 6th part of
the filtrate, add 1cm3 of Reddish-brown Br2- ion is confirmed
carbon tetrachloride colourless appears in the present.
followed by chlorine CCl4 layer.
water.
(c).Wash the residue
with distilled water &
then dry it between the
filter paper. Heat a little White solid remains. BaO, CaO & MgO are
of the residue strongly in formed.
a dry test tube strongly.

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(d).Dissolve the Effervescence of Carbon dioxide gas is

remaining residue in colourless gas that turns given off.
dilute nitric acid & lime water milky & ∴CO32- is confirmed
divide the resultant moist blue litmus paper present.
solution in to three red.
portions. Colourless solution. Ca2+, Mg2+ & Ba2+ ions
are suspected present.
d.(i).To the 1st part of
the solution, add dilute White precipitate Ca2+, Mg2+ & Ba2+ ions
sodium hydroxide insoluble in excess. are suspected present.
solution drop wise until
in excess.
d.(ii).To the 2nd part of
the solution, add No observable change. Mg2+ & Ba2+ are absent.
aqueous ammonia
solution drop wise until ∴Ca2+ ion is suspected
in excess. present.
d.(iii).To the 3 part of
rd

the solution, add White precipitate ∴Ca2+ ion is confirmed

ammonia solution insoluble in excess. present.
followed by ammonium
ethanedioate (oxalate) &
ethanoic acid.
Identify the:
i. Cations present in compound K.
Fe3+ ion is confirmed in b (iii).
Ca2+ ion is confirmed in d (iii).
ii. Anions present in compound K.
Br- ion confirmed in b (vi).
C032- ion is confirmed in d.
Experiment 17, J is a mixture of NiSO4 & CuCO3:
You are provided with substance J which contains two cations and two anions.
You are required to carry out the following tests on J to identify the cations and
anions in J. Record your observations and conclusion in the table below.
Tests Observations Deductions
(a).Heat strongly one J is green solid. Transitional metal
spatula end-ful of J in a cations, Cr3+, Ni2+, Fe2+
dry test tube & Cu2+ ions are
suspected present.

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Colourless liquid that Water of crystallization.

turns anhydrous copper ∴hydrated salt is present
(II) sulphate blue.

Colourless gas that turns Carbon dioxide gas is

moist blue litmus paper given off.
red & lime water milky. ∴CO32- ,C2O42- & HCO3-
ions are suspected
present.
Black residue. CuO, FeO & NiO are
formed.
(b).To two spatula end-
fuls of J, add 5cm3 of Green filtrate. Cu2+, Fe2+ & Ni2+ ions
distilled water, shake are suspected present in
well & filter. Keep both & both filtrate & residue.
the filtrate & residue.
Divide the filtrate in five Green residue.
parts.
b.(i).To the 1st part of
filtrate, add dilute Green precipitate Fe2+ & Ni2+ ions are
sodium hydroxide insoluble in excess. suspected present
solution drop wise until
in excess.
b.(ii).To the 2nd part of
the filtrate, add aqueous Green precipitate Ni2+ ion is suspected
ammonia solution drop soluble forming pale- present
wise until in excess. blue solution.
b.(iii).To the 3rd part of
the filtrate, add dilute Red precipitate. Ni2+ ion is confirmed
ammonia solution drop present
wise until in excess &
then add 3 drops of
dimethylglyoxime
solution.
b.(iv).To the 4th part of
the filtrate, add 3-4 White precipitate SO42- & Cl- ions are
drops of lead (II) nitrate insoluble in the acid. suspected present.
solution followed by
dilute nitric acid.

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b.(v).Use the 5th part of

the filtrate to carry out a
test of your own choice
to confirm one of the
anions present in J.
Test:
To the 5th part of the White precipitate SO42- ion is confirmed
filtrate, add barium insoluble in the acid. present.
nitrate solution followed
by dilute nitric acid.
Or
Add barium chloride
solution followed by
dilute hydrochloric acid.
(c).Wash the residue Colourless gas that turns Carbon dioxide gas is
with a little distilled moist blue litmus red & given off.
water, Heat a small lime water milky. ∴CO32- , C2O42- & HCO3-
portion of the residue. ions are suspected
present.
Black residue. CuO is formed.
∴Cu2+ ion is suspected
present.
(d).Transfer the rest of Effervescence of Carbon dioxide gas is
residue in to a test tube colourless gas that turns given off.
& dissolve it in dilute moist blue litmus paper
nitric acid. Divide the red & lime water milky. ∴CO32- is confirmed
solution in to three present.
parts.
Blue solution. Cu2+ ion sis suspected
Or: present.
Green solution. Cu2+, Ni2+, Fe2+ & Cr3+
ions are suspected
present.
d.(i).To the 1st part of
the solution, add dilute Blue precipitate CuO is formed.
sodium hydroxide insoluble, turns black on ∴Cu2+ ion is suspected
solution drop wise until heating. present.
in excess.

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d.(ii).To the 2nd part of

the solution, add Blue precipitate soluble Cu2+ ion is suspected
aqueous ammonia forming deep blue present.
solution drop wise until solution.
in excess.
d.(ii).Use the 3rd part of
the solution to carry out
a test of your own choice
to confirm one of the
cations in J.
Test:
To the 3rd part of the Brown precipitate is
solution, add 3 drops of formed.
potassium
hexacyanoferrate (II) Cu2+ ion is confirmed
solution. present.
Or
Add 3 drops of White precipitate in
potassium iodide brown solution.
solution.
Identify the:
i. Cations present in compound J.
Ni2+ ion is confirmed in b (iii).
Cu2+ ion is confirmed in d (ii).
ii. Anions present in compound J.
SO42- ion confirmed in b (v).
C032- ion is confirmed in d.
Experiment 18, W is a mixture of MnSO4 & PbCO3:
You are provided with substance W which contains two cations and two anions.
You are required to carry out the following tests on W to identify the cations and
anions in W. Record your observations and conclusion in the table below.
Tests Observations Deductions
(a).Heat one spatula Colourless Hydrated salt is
end-ful of W strongly in liquid/condensate that suspected present.
a dry test tube until turns anhydrous copper
there is no further (II) sulphate to blue.
change.
Carbon dioxide gas is
given off.

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Colourless gas that turns ∴CO32-, C2O42- & HCO3-

moist blue litmus paper ions are suspected
red & lime water milky. present.

PbO, MnO & Fe2O3 are

formed.
Reddish-brown residue-
hot & yellow-cold.
Black residue.
(b).To a spatula end-ful Effervescence/bubbles Carbon dioxide gas is
of W, add 2-3 drops of of colourless that turns given off.
concentrated sulphuric moist blue litmus paper ∴CO32- suspected
acid & warm. red & lime water milky. present.

Rej: C2O42- ion.

(c).To two spatula end- Effervescence/bubbles Carbon dioxide gas is
fuls of W, add dilute of colourless gas that given off.
nitric acid until there is turns lime water milky. ∴CO32- ion is confirmed
no further change. Add White precipitate present.
sodium hydroxide insoluble in excess, turns
solution drop wise until brown. Mn2+ is suspected
in excess. Filter & keep present.
the filtrate. Rej: C2O42- & HCO3- ions.

Colourless filtrate. Pb2+, Zn2+, Sn2+, Al3+ &

Sn4+ ions are suspected
present.
Rej: Ca2+, Ba2+ & Mg2+
ions suspected present.

Brown residue. Mn2+ is suspected

present.
(d).To the filtrate add White precipitate Pb2+, Zn2+, Sn2+, Al3+ &
dilute nitric acid until soluble in acid to form a Sn4+ ions are suspected
the solution is just acidic. colourless solution. present.
Divide the resultant
solution in to four parts.

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d.(i).To the 1st part of White precipitate Pb2+, Zn2+, Sn2+, Al3+ &
the acidic solution, add soluble in excess to form Sn4+ ions are suspected
sodium hydroxide a colourless solution. present.
solution drop wise until
in excess.
d.(ii).To the 2nd part of White precipitate Pb2+, Sn2+, Al3+ & Sn4+
the acidic solution, add insoluble in excess. ions are suspected
aqueous ammonia present.
solution drop wise until
in excess.
d.(iii).To the 3rd part of White precipitate. Pb2+ion is suspected
the acidic solution, add present.
dilute sulphuric acid.
d.(iv).Use the 4th part of
the acidic solution to
carry out a test of your
own choice to confirm
one of the cations
present in W.
Test:
To the 4th part of the Yellow precipitate Pb2+ion is confirmed
acidic solution, add 3 present.
drops of potassium
iodide solution.
Or
Add potassium chromate Yellow precipitate
(VI) solution followed by soluble forming a yellow
sodium hydroxide solution.
solution until in excess.
(e).To two spatula end- Colourless filtrate. Non-transitional metals
fuls of W, add about ions, I.e.:
5cm3 of distilled water, & Al3+, Pb2+, Zn2+, Mg2+,
shake & filter. Ca2+& Ba2+ ions are
Divide the filtrate in to White residue. suspected present in
five parts. both the filtrate &
residue.
e.(i).To the 1 part of the White precipitate
st Mn2+ ion is suspected
filtrate, add sodium insoluble in excess, turns present.
brown.

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 BASIC ADVANCED LEVEL CHEMISTRY PRACTICAL

hydroxide solution drop

wise until in excess.
e.(ii).To the 2nd part of White precipitate Mn2+ ion is suspected
the filtrate, add aqueous insoluble in excess turns present.
ammonia solution drop brown.
wise until in excess.
e.(iii).Use the 3rd part of Insist on the order of
the filtrate to carry out a addition of reagent.
test of your own choice Rej: Sodium bismuthate
to confirm one of the solution.
cations in W. Insist on heat if PbO2 is
Test: used.
To the 3 part of the
rd

filtrate, add Purple solution.

concentrated nitric acid Mn2+ ion is confirmed
followed by sodium present.
bismuthate.
Or
Add concentrated nitric
acid followed by lead
(IV) oxide & heat
e.(iv).To the 4th part of White precipitate Cl- ion suspected absent.
the filtrate, add 2-3 insoluble on heating. ∴SO42- & SO32- ions are
drops of lead (II) nitrate suspected present.
solution & heat.
e.(v).Use the 5th part of
the filtrate to carry out a
test of your own choice
to confirm one one of the
anions present in W.
Test:
To the 5th part of the
filtrate, add barium White precipitate SO42- ion is confirmed
nitrate solution followed insoluble in the acid. present.
by dilute nitric acid.
Identify the:
i. Cations present in compound W.
Pb2+ ion is confirmed in d (iv).
Mn2+ ion is confirmed in e (iii).

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 BASIC ADVANCED LEVEL CHEMISTRY PRACTICAL

ii. Anions present in compound W.

CO32- ion confirmed in c.
S042- ion is confirmed in e (v).
Experiment 18, Y is a mixture of ZnCO3 & BaCl2:
You are provided with substance Y which contains two cations and two anions.
You are required to carry out the following tests on Y to identify the cations and
anions in Y. Record your observations and conclusion in the table below.
Tests Observations Deductions
(a).Heat strongly one White powder turned Transitional metal ions
spatula end-ful of Y in a yellow-hot & white-cold. are absent.
dry test tube. Or
Non-transitional metal
ions are probably Mg2+,
Ca2+, Zn2+, & Pb2+
suspected present.

Colourless Water of crystallization

condensate/liquid that is present.
turns anhydrous copper ∴Hydrated salt is
(II) sulphate blue. present.

Colourless gas turned Carbon dioxide is given

moist blue litmus paper off.
red & lime water milky. ∴CO32- , C2O42-& HCO3-
ions are suspected
present.

Yellow residue turned ZnO is formed.

white on cooling. ∴Zn2+ ion is suspected
present.
(b).To one spatula end- Effervescence/misty Hydrogen chloride gas.
ful of Y in a test tube, fumes with a chocking ∴Acidic gas probably Cl-
add 2-3 drops of smell turned wet blue ion is suspected present.
concentrated sulphuric litmus paper red, formed
acid. dense white fumes with
ammonia gas.
(c).To two spatula end- Partly dissolves to form Transition metal ions are
fuls of Y, add about 5cm3 a colourless filtrate & suspected absent.
white residue. Or

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of distilled water. Shake Rej: Clear solution, white Non-transition metal

vigorously & filter. p.p.t & white solid. ions are suspected
Keep both the filtrate & present.
residue. Or
Accept a list of non-
transition metal ions of:
Mg2+,Zn2+,Ca2+,Ba2+,Pb2+
& Al3+.
(d).Divide the filtrate in White precipitate Mg2+, Ca2+ & Ba2+ ions
to six portions. insoluble in excess. are suspected present.
(i).To the 1st portion of
the filtrate, add dilute
sodium hydroxide
solution drop wise until
in excess.
(ii).To the 2nd portion of White precipitate Mg2+& Ba2+ ions are
the filtrate, add aqueous insoluble in excess. suspected present.
ammonia solution drop
wise until in excess. Rej: Ca2+ ion b’se it
shows no observable
change.
(iii).To 3rd portion of the White precipitate Mg2+& Ba2+ ions are
filtrate, add a spatula insoluble in excess suspected present.
end-fuls of solid ammonia solution.
ammonium chloride,
followed by 3-4 drops of Note:
disodium hydrogen Insoluble must be
phosphate solution & mentioned.
then ammonia solution
drop wise until in excess
(iv).To the 4th portion of Yellow precipitate Ba2+ ion is confirmed
the filtrate, add 2-3 insoluble in excess alkali. present.
drops of potassium
chromate (VI) solution Rej: Orange precipitate.
followed by 2-3 drops of
dilute sodium hydroxide
solution.
(v).To the 5th portion of White precipitate SO42- & Cl- ions are
the filtrate, add 2-3 insoluble in the acid. suspected present.

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drops of lead (II) nitrate

solution, followed by
dilute nitric acid.
(vi).Use the 6th portion
of the filtrate to carry
out a test of your own
choice to confirm one of
the anions in Y.
Test:
To the 6th portion of the White precipitate Cl- ion is confirmed
filtrate, add silver nitrate insoluble in the acid. present.
solution followed by
dilute nitric acid.
(e).Wash the residue Effervescence of Carbon dioxide gas is
with a little distilled colourless gas that given off.
water. Transfer the turned lime water milky. ∴CO32- is confirmed
residue in to a test tube present.
& dissolves in dilute Rej: HCO3- & C2O42- ions.
nitric acid.
Divide the solution in to A colourless solution is Ba2+, Mg2+, Ca2+, Zn2+ &
three portions. formed. Al3+ ions are suspected
present.
e.(i).To the 1st portion of White precipitate Zn2+, Pb2+ & Al3+ ions are
the solution, add dilute soluble in excess to form suspected present.
sodium hydroxide a colourless solution.
solution drop wise until
in excess.
e.(ii).To the 2nd portion White precipitate Zn2+ ion is suspected
of the solution, add soluble in excess to form present.
aqueous ammonia a colourless solution.
solution drop wise until
in excess.
e.(iii).Use the 3rd portion
of the solution to carry
out a test of your own
choice to confirm one of
the cations present in
the solution.
Tests:

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To the 3rd portion of the

solution, add solid White precipitate Zn2+ ion is confirmed
ammonium chloride soluble in aqueous present.
followed by disodium ammonia solution.
hydrogen phosphate &
aqueous ammonia
solution.
Note:
Order of addition of the
reagents matter.
Identify the:
i. Cations present in compound Y.
Ba2+ ion is confirmed in d (iv).
Zn2+ ion is confirmed in e (iii).
ii. Anions present in compound Y.
Cl- ion confirmed in d (vi).
C032- ion is confirmed in e.
Experiment 18, Z is a mixture of Al2(SO4)3 ,FeSO4.7H2O & Na2S2O3.2H2O:
You are provided with substance Z which contains two cations and two anions.
You are required to carry out the following tests on Z to identify the cations and
anions in Z. Record your observations and conclusion in the table below.
Tests Observations Deductions
(a).Heat one spatula Colourless liquid that Water of crystallization
endful of Z in a dry test turned anhydrous is present.
tube. copper (II) sulphate blue ∴Hydrate salt is present.

Colourless gas turned Sulphur dioxide gas is

moist blue litmus paper given off.
red & acidified ∴SO32- & SO42- ions are
K2Cr2O7(aq) green. suspected present.

White fumes, Yellow Fe2O3 is formed.

sublimate/Reddish-
brown residue.
(b).Dissolve three
spatula end-fuls of Z in
water. Divide the
solution in to four parts.

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(i).To the 1st part of the No observable change Pb2+, Ag2+ & Hg2+ ions
solution, add dilute occurs. are suspected present.
hydrochloric acid.
(ii).To the 2nd part of the No observable change
solution, add iron (III) occurs.
chloride solution.
(iii).To the 3rd part of the White precipitate. SO42- , SO32- & CO32- ions
solution, add barium are suspected present.
nitrate solution.
(iv).To the 4th part of the Dirty green gelatinous Fe2+ ion is suspected
solution, add dilute precipitate persisted in present.
sodium hydroxide excess.
solution drop wise until
in excess & filter. Keep White precipitate Al3+, Zn2+ & Sn2+ ions
both the filtrate & dissolves in excess. are suspected present.
residue.
(c).Acidify the filtrate
with dilute hydrochloric
acid & divide it in to
three portions.
(i).To the 1st portion of No observable change Al(OH)4- & Zn(OH)42-
the acidified filtrate, add occurs. are formed.
dilute sodium hydroxide
solution drop wise until
in excess.
(ii).To the 2nd portion of No observable change Al(OH)4- is formed
the acidified filtrate, add occurs. ∴Al3+ ion is confirmed
dilute ammonia solution present.
drop wise until in excess.
(iii).To the 3rd portion of No observable change Pb2+ ion is suspected
the acidified filtrate, add occurs. absent.
2-3 drops of potassium
iodide solution
(d).Wash the residue &
dissolves it in dilute
hydrochloric acid. Divide
the resultant solution in
to two parts.

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(i).To the 1st part of the Dirty green gelatinous Fe2+ ion is suspected
resultant solution, add precipitate insoluble in present.
dilute sodium hydroxide excess.
solution until in excess.
(ii).To the 2nd part of the Dirty green gelatinous Fe2+ ion is confirmed
resultant solution, add precipitate insoluble in present.
dilute ammonia solution excess.
drop wise until in excess.
Identify the:
i. Cations present in compound Z.
Al3+ ion is confirmed in c (ii).
Fe2+ ion is confirmed in d (ii).
ii. Anions present in compound Z.
S042- ion is confirmed in b (iii).
Experiment 18, U is a mixture of CuCO3 & Fe(SO4)3:
You are provided with substance U which contains two cations and two anions.
You are required to carry out the following tests on U to identify the cations and
anions in U. Record your observations and conclusion in the table below.
Tests Observations Deductions
(a).Heat a spatula end- U is agreen solid. Cu2+, Fe2+, Ni2+ & Cr3+
ful of strongly in a dry ions are suspected
test tube. present.

Colourless liquid turned Water of crystallization

anhydrous copper (II) is formed.
sulphate blue. ∴Hydrated salt is
present.

Colourless gas that turns Carbon dioxide gas is

lime water milky. given off.
∴CO32-, C2O42- & HCO3-
ions are present.

Colourless gas that turns Sulphur dioxide gas is

acidified potassium given off.
dichromate from orange ∴SO32- & SO42- ions are
to green. suspected present.

Black residue remains. CuO, NiO & FeO forms

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(b).Place two spatula Green-blue filtrate. Cu2+, Fe2+& Ni2+ ions are
end-fuls of U in a test suspected present.
tube, add about 5cm3 of Brown residue. Fe(OH)3 & MnO2 are
distilled water, shake & formed.
filter. Keep both the Effervescence of Carbon dioxide gas is
filtrate & residue. Divide colourless gas that given off.
the filtrate in to five turned lime water milky. ∴CO32- ion is present.
portions.
(i).To the 1st portion of Blue precipitate Cu2+ ion is suspected
the filtrate, add dilute insoluble in excess. present.
sodium hydroxide
solution drop wise in
excess.
(ii).To the 2nd portion of Blue precipitate soluble Cu(NH3)42+ is formed
the filtrate, add dilute to form a deep-blue Cu2+ ion is suspected
ammonia solution drop solution. present.
wise until in excess.
(iii).To the 3rd portion of Dark-brown precipitate. Cu2+ ion is confirmed
the filtrate, add few present.
drops of potassium
hexacyanoferrate (II)
solution.
(iv).To the 4th portion of White precipitate CO32-,SO32- & SO42- ions
the filtrate, add 2 drops insoluble on warming. are suspected present.
of lead (II) nitrate
solution & warm.
(v).Use the 5th portion of
the filtrate to carry out a
test of your own choice
to confirm one of the
anions in U.
Test:
To the 5th portion of the White precipitate SO42- ion is confirmed
filtrate, add dilute nitric insoluble in dilute nitric present.
acid followed by barium acid.
nitrate solution.
Or
Dilute HCl/BaCl2

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(c).Wash the residue Brown residue remains. Fe(OH)3 ,Fe2O3 & MnO2
with distilled water. are formed.
Heat a small portion of
the residue strongly in a
dry test tube.
(d).Transfer the rest of Brown residue dissolves Fe3+ ion is suspected
the residue to a test tube to give green-yellow present.
& dissolve in in dilute solution.
hydrochloric acid. Divide
the solution in to three
portions.
(i).To the 1st part of the Brown precipitate Fe3+ ion is suspected
solution, add dilute insoluble in excess. present.
sodium hydroxide
solution drop wise until
in excess.
(ii).To the 2nd part of the Brown precipitate Fe3+ ion is suspected
solution, add dilute insoluble in excess. present.
ammonia solution drop
wise until in excess.
(iii).To the 3rd part of the Blood-red solution. Fe3+ ion is confirmed
solution, add 2-3 drops present.
of potassium thiocyanate
solution
Identify the:
i. Cations present in compound U.
Cu2+ ion is confirmed in a (iii).
Fe3+ ion is confirmed in d (iii).
ii. Anions present in compound U.
CO32- ion is confirmed in a.
S042- ion is confirmed in b (v).
ORGANIC PRACTICALS ANALYSIS:
Organic chemistry is a branch of chemistry concerned with the compounds of
carbon: Originally confined to compounds produced by living organisms but now
extended to include man made substances based on carbon, such plastics.
Organic compounds consist of molecules held together by weak Vander waals
forces or hydrogen bonds. As a result organic compounds are often liquids at
room temperature. If they are solids, they easily melt or sublime on heating.

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QUALITATIVE ANALYSIS OF ORGANIC COMPOUNDS:

The following skills are tested for during analysis of functional groups in organic
chemistry.
1. Physical characteristics of organic compounds.
In this test note the colour, odour & physical state i.e. solid & liquid of the
organic compound provided.
1) Physical state.
 In case of liquid sample, may be low molecular mass alcohols,
aldehydes, ketones, aliphatic, amines, esters & carboxylic acid.
 In case of solid sample, may be aromatic carboxylic acid, salts of
organic acids & bases or higher members of alcohols, aldehydes,
ketones, amines & esters.
2) Odour.
 Sweet alcoholic: Aliphatic alcohols.
 Unpleasant: Lower aldehydes.
 Pleasant fruity smell: Ketones or esters.
 Pungent smell/sour smell: Lower carboxylic acids.
 Fishy ammoniacal smell: Lower amines.
2. Action of heat on the sample.
During this test, note the nature and colour of the flame.
 If it is yellow (luminous) & sooty, most likely the substance is
aromatic or unsaturated aliphatic or aliphatic with high carbon
content i.e high carbon: hydrogen ratio.
 If the flame is yellow or blue non-sooty, most likely aliphatic
compound.
 Yellow luminous sooty & smoky flame-Aromatic organic compound
& unsaturated organic compound.
3. Solubility in water.
During this test, the organic sample is shaken with distilled water.
 If the compound is easily soluble in cold water, then most likely
polar aliphatic compound of low molecular E.g. alcohol, carboxylic
acid, ketones, e.t.c
 If the compound is insoluble in cold distilled water but soluble on
warming, then most likely polar aromatic e.g. aromatic carboxylic
acid.
 If the compound is completely insoluble or immiscible with water,
then most likely non-polar. All aromatic compounds are insoluble in
cold distilled water.
Notes:

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Polar organic compound with carbon atoms ranging from C1 to C2

are miscible with water in all proportions. Such polar compounds
include: Alcohols, aldehydes & ketones (Carbonyl compounds),
carboxylic acid (alkanoic acid) & amines.
Reasons:
Such compounds interact with water through hydrogen bonding.
Notes:
Polar organic compounds having carbon atoms ranging from C4
onwards are partially soluble in water to form two layers are
formed. Polar aromatic compounds are partially soluble in water.
Such polar aromatic organic compounds include: phenol, benzoic
acid, bromobenzene, nitrobenzene, aminobenzene, phenylmethanal
(benzaldehyde),phenylmethanol & benzenesulphonic acid.
Non-polar organic compounds are immiscible with distilled water &
form two distinct layers.
4. Litmus/pH test.
Here the organic sample or its solution is tested with litmus paper or
universal indicator.
 If blue litmus paper turns to red, then the solution is most likely to
carboxylic acid, amines or phenol since the solution is acidic.
 Phenol partially dissolves in cold distilled water but very soluble in
hot water & the solution is slightly acidic hence turns blue litmus
pink.
 If the solution has no effect on litmus papers or pH = 7, most likely
to be neutral compounds like, alcohols, carbonyl compounds or
esters.
TESTS BASED ON THE REACTIONS OF DIFFERENT FUNCTIONAL GROUPS:
The common examinable areas in organic analysis include alcohols,
carbonyl compounds, amines & carboxylic acids.
Preliminary tests are carried out which gives some clue about the identity
of the functional groups.
Then the confirmatory tests are also carried out. From the knowledge of
the organic chemistry acquired from this book & other organic text books,
you can be able to identify the reagents that can confirm a vague
(particular) functional groups present.
The reagents used to identify the following groups are as follows:
a) Aldehydes:
 Brady’s reagent.  Tollen’s reagent.
 Fehling’s solution.

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 Sodium hydrogen sulphite (saturated).

 Acidified potassium dichromate or acidified potassium
permanganate (VII) solution.
 Iodine solution in dilute sodium hydroxide solution (Iodoform test).
b) Ketones:
 Brady’s reagent.
 Sodium hydrogen sulphite (saturated).
 Iodine solution in dilute sodium hydroxide solution (Iodoform test).
c) Alkanols (alcohols):
 Phosphorus pentachloride.
 Concentrated sulphuric phosphoric acid.
 Anhydrous zinc chloride & concentrated hydrochloric acid (Luca’s test).
 Ethanoic or methanoic acid with concentrated sulphuric acid.
(Esterification reaction).
 Acidified potassium dichromate or acidified potassium
permanganate (VII) solution.
d) Carboxylic acids:
 Soda lime.
 Iron (III) chloride solution.
 Sodium carbonate solution.
 Sodium hydroxide solution.
 Fehling’s solution (for methanoic acid).
 Ethanol or methanol & concentrated sulphuric acid
(Esterification reaction).
e) Phenols:
 Bromine water.
 Sodium carbonate solution.
 Sodium hydroxide solution.
 Neutral iron (III) chloride solution.
f) Amines (aliphatic):
 Ethanoic acid.  Dilute sulphuric acid.
 Concentrated hydrochloric acid.
 Nitrous acid (concentrated hydrochloric acid and sodium nitrite solution.
g) Aromatic amines (e.g phenylamine):
 Bromine water.  Dilute sulphuric acid.
 Naphthaleine-2-ol.
 Alkaline solution of phenol.
 Alkaline solution of B-naphthol.
 Concentrated hydrochloric acid.
 Nitrous acid (concentrated hydrochloric acid and sodium nitrite solution.

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5. Addition of various reagents to identify functional groups.

The following reagents are commonly used to identify functional groups in
organic compounds.
1)Sodium hydroxide solution.
When this reagent is add, note whether the compound dissolves or not.
If the compound dissolves readily in sodium hydroxide solution, most
likely it is acidic.
Examples:
Phenol. Carboxylic acid.
2)Sodium carbonate or sodium hydrogen carbonate solution.
If the compound dissolves with effervescence, most likely carboxylic
acid is present. If there is no observable change occurs/no
effervescence then carboxylic acid is absent.
3)Dilute hydrochloric acid.
If the compound is soluble in dilute hydrochloric acid, most likely an
amine.
4)2, 4-dintrophenylhydrazine (Brady’s reagent) solution.
This reagent test for carbonyl compounds (functional) groups in
aldehydes & ketones.
If yellow precipitate is formed then aldehyde or ketone is suspected
present.
If there is no yellow precipitate or orange/yellow colour of Brady’s
reagent remains, then carbonyl compounds are absent.
5)Tollen’s reagent (Ammoniacal silver nitrate solution).
If silver mirror is formed on warming the compound with the reagent,
then aldehyde or methanoic acid is probably present.
6)Fehling solution (copper (II) ions in excess ammonia solution).
If a red precipitate or reddish-brown precipitate is formed, then an
aldehyde is probably present.
7)Iodine solution & sodium hydroxide solution (Iodoform test).
This gives a positive result (i.e yellow precipitate) with secondary
alcohols with methyl (-CH3) attached to the carbon carrying the
functional group or ketones with a methyl group attached to the
carbonyl carbon.
Notes:
Ethanol is the only primary alcohol which gives a positive results while
ethanal is the only aldehyde which gives a positive results with
iodoform test.
8)Acidified potassium dichromate (VI) solution.

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This reagent identifies reducing agents such as primary & secondary

alcohols or aldehydes. In this case the reagent turns from orange to
green if a reducing agent is present.
Note:
Tertiary alcohols & ketones do not give a positive result with this
reagent.
9)Acidified potassium manganate (VII) solution.
This reagent identifies reducing agents such as primary & secondary
alcohols or aldehydes. It also tests for unsaturated compounds (i.e.
alkenes & alkynes).
In this case the reagent turns from purple to colourless if a reducing
agent or unsaturated compound is present.
10) Concentrated sulphuric acid with an alcohol E.g.Ethanol,Methanol & warming.
This test identifies the presence of a carboxylic acid. If carboxylic acid is
present, then a sweet fruity smell is observed implying that an ester is
formed from esterification of carboxylic acid.
11) Addition of concentrated sulphuric acid & carboxylic acid E.g.
Ethanoic & Methanoic acid followed by warming.
This reagent tests for the present of an alcohol. In case the alcohol is
present, a sweet fruity is formed meaning that an ester is formed from
esterification of an alcohol.
12) Bromine water.
This reagent tests for the presence of unsaturated compounds, phenol
and aromatic amines.
 In case of unsaturated compound, the solution turns from brown to
colourless.
 In case of phenol & aromatic amines, a white precipitate is formed.
13) Neutral iron (III) chloride solution.
This reagent tests for the presence of phenol. In case of phenol is
present, a violent/purple colouration is formed.
14) Anhydrous zinc chloride & concentrated hydrochloric acid (Luca’s
reagent).
This reagent distinguishes primary, secondary & tertiary alcohols.
Observations:
 Formation of an immediate cloudy solution indicates presence of
tertiary alcohol.
 If the cloudy solution appears within 5-10 minutes then secondary
alcohol is present.

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 If no cloudy solution appears at room temperature, then the alcohol

is a primary one.
15) Aluminium (III) oxide.
During this tests, the unknown sample is passed over heated aluminium
oxide & the gas formed passed over bromine water or acidified
potassium manganate (VII) solution.
If both solutions are decolourised then an alcohol is dehydrated to an
alkene.
16) Concentrated sulphuric acid.
In this test, the unknown is heated with concentrated sulphuric acid
and the gas formed passed via bromine water or acidified potassium
manganate (VII) solution. Both solution are decolourized.
In case alcohol is present, implying that the alcohol is dehydrated to an
alkene.
SUMMARY ON THE ORGANIC ANALYSIS FOR A NUMBER OF FUNCTIONAL
GROUPS IS GIVEN BELOW.
A. Analysis on alcohols.
You are provided substance E which is an organic compound. Carry out the
following tests to identify the nature of E. Record your observations and
deductions in the table below.
Tests Observations Deductions
(a).Burn a small Colourless liquid burns Aliphatic saturated
amount of E on a with a non-sooty compound of low C:H
crucible lid. yellow/blue flame. ration is suspected
present.
(b).To 1cm of E add Miscible/dissolves in
3 Alkanol, alkanal,
1cm of distilled
3 water to form colourless alkanone or ester are
water and test with solution. suspected present.
litmus paper. The solution is neutral to
litmus.
(c).To 1cm of E add No observable change
3 Carbonyl compounds
few drops of Brady’s occurs. are absent.
reagent. Or: ∴Alkanol is suspected
The solution remains present.
yellow.
(c).To 1cm of E add On warming, orange
3 E is reducing agent. It
1cm of acidified
3 solution turns green. is oxidized to
potassium carbonyl compound.
dichromate (VI)

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 BASIC ADVANCED LEVEL CHEMISTRY PRACTICAL

solution & warm. ∴primary or

Divide the solution in secondary alcohol is
to two parts. suspected present.
c.(i).To the 1st part, Orange/yellow Carbonyl compounds
add 5 drops of precipitate is formed. are formed.
Brady’s reagent. ∴primary or
secondary alcohol is
suspected present.
c.(ii).To the 2nd part, Purple colour of K2MnO7 Alkanal present.
add 5 drops of solution is ∴primary alcohol is
acidified potassium discharged/decolourized. confirmed present.
manganate (VII)
solution and warm.
(e).To 1cm3 of E add Yellow precipitate is Primary alcohol with
4cm of iodine in
3 formed on heating. CH3 group attached
potassium iodide to carbon atom
solution followed by carrying the
dilute sodium functional group.
hydroxide solution ∴E is ethanol.
drop wise until the
iodine colour is
discharged & warm.
Identify the nature of E: E is a saturated aliphatic alcohol.
B. Analysis on phenols.
You are provided substance W which is an organic compound. Carry out
the following tests to identify the nature of W. Record your observations
and deductions in the table below.
Tests Observations Deductions
(a).Burn 1 drop of W Red liquid burns with a Aromatic compound is
on the tip of spatula. sooty & smoky flame. suspected present.
(b).To two drops of W Slight soluble in water Phenol is suspected
add 2cm3 of distilled & solution turns blue present.
water & shake. Allow litmus paper red & no
to stand & test with observable change
litmus paper & add occurs with sodium
sodium carbonate carbonate solution.
solution.

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(c).To 1 drop of W add Red-brown colour of Aromatic compound

bromine water drop bromine is discharged with polar group such
wise until in excess. & white precipitate is as –OH & -NH2
formed. present.
Phenol is suspected
present.
(d).To 2 drops of W W dissolves in sodium Acidic compound is
add dilute sodium hydroxide solution present.
hydroxide solution. forming a colourless ∴Phenol is suspected
solution. present.
(e).To 1 drop of W add Blue-violet coloured Phenol is confirmed
few drops of neutral solution is formed. present.
iron (III) chloride
solution.
Equation:

OH O

6 + FeCl3 (Neutral) H3Fe3+( ) + 3HCl(aq)

Comment on the nature of W.W is phenol.

C. Analysis on carbonyl compounds.
a) Aldehydes.
You are provided substance Y which is an organic compound. Carry out the
following tests to identify the nature of Y. Record your observations and
deductions in the table below.
Tests Observations Deductions
(a).Burn a small Cloudy liquid burns Aliphatic saturated
amount of Y on a with a yellow non- compound with low
crucible lid. sooty flame. C: H ratio.
(b).To 1cm of Y add
3 Y is soluble in water Alkanol, Alkanal,
1cm of distilled
3 forming a colourless Alkanone or ester are
water & test with solution which is suspected present.
litmus paper. neutral to litmus.
(c).To 1cm of Y add
3 Yellow/orange Alkanal & Alkanone
few drops of Brady’s precipitate is formed. are suspected
reagent. present.

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(d).To 2cm3 of Y add On warming, the Reducing agent is

1cm of acidified
3 orange solution turns suspected present.
potassium dichromate green. ∴Alkanal is present.
(VI) solution.
(Keep the mixture for
test in (h) below.)
(e).To 1cm3 of Y add 5 Silver mirror is Alkanal is suspected
drops of Tollen’s observed on the sides present.
reagent. of the test tube.
(f).To 1cm of Y add 5 Red-brown
3 Alkanal is suspected
drops of Fehling’s precipitate is formed. present.
solution & heat the
mixture.
(g).To 1cm3 of Y add No observable change Ethanol is suspected
4cm of iodine in
3 occurs. absent.
potassium iodide ∴Methanal is
solution followed by suspected present.
dilute sodium
hydroxide solution
drop wise until the
iodine colour is
discharged & warm.
(h).To 2cm3 of the The purple of Methanoic acid is
mixture from (d) potassium suspected present.
above, add 3cm of3 permanganate (VIII) ∴Methanal is
acidified potassium solution is discharged. confirmed present.
permanganate (VIII)
solution & warm.
Identify the nature of Y. Y is a saturated aliphatic aldehyde.
b) Ketones.
c) You are provided substance M which is an organic compound. Carry out
the following tests to identify the nature of M. Record your observations
and deductions in the table below.
Tests Observaions Deductions
(a).Burn a drop of M Colourless liquid Aliphatic saturated
on the tip of the burns with yellow compound with low
spatula. noon sooty flame. C: H ratio.

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(b).To 1cm3 of M add M is soluble in water Alkanol, Alkanal,

1cm3 of distilled to form a colourless Alkanone or ester is
water and test with solution which is suspected present.
litmus paper. neutral to litmus.
(c).To 1cm3 of M add Yellow/Orange Alkanal or Alkanone
few drops of Brady’s precipitate is formed. is suspected present.
reagent.
(d).To 2cm3 of M add No observable change Alkanal is suspected
2cm3 of acidified occurs. absent.
potassium ∴Alkanone is
dichromate VI) suspected present.
solution and warm.
(e).To 1cm3 of M add No observable change Alkanone is
1cm3 of Fehling’s occurs. suspected present.
solution & heat the
mixture.
(f).To 1cm3 of M add Yellow precipitate is Alkanone with -CH3 is
5cm3 of iodine in formed on warming. attached to carbon
potassium iodide atom next to the one
solution, followed by carrying the
dilute sodium functional group.
hydroxide solution ∴Propanone is
drop wise until the confirmed present.
colour of the iodine
discharged & warm.
O

Identify the nature of M.M is aliphatic ketone with structure of CH3C R

D. Analysis on carboxylic acids.
a) Aliphatic carboxylic acids.
You are provided substance Q which is an organic compound. Carry out
the following tests to identify the nature of Q. Record your observations
and deductions in the table below.
Tests Observations Deductions
(a).Burn a small Colourless liquid with Aliphatic carboxylic
amount of Q on the irritating vinegar acid with low C: H
tip of the spatula. smell burns with ratio.
yellow non-sooty
flame

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(b).To 1cm3 of Q add Miscible with water to Carboxylic acid is

2cm3 of distilled form a colourless suspected present.
water & test with solution that turns
litmus paper then blue litmus paper red.
add aqueous sodium On addition of sodium
carbonate solution. carbonate solution,
there is effervescence
of colourless gas that
turns lime water
milky.
(c).To 1cm3 of Q ad No observable Phenol is suspected
few drops of iron change/solution absent.
(III) chloride remains yellow. ∴Carboxylic acid is
solution & warm the suspected present.
mixture.
(d).Mix about 1cm3 of Colourless gas that Methane gas is
Q with a spatula end- burns with yellow evolved.
ful of soda lime & flame is evolved. Decarboxylation
heat the mixture. Another colourless occurs.
gas that turns lime ∴Carboxylic acid is
water milky is suspected present.
evolved.
(e).Add 1cm3 of Q to Fruity/sweet smell Esterification has
about 2cm of3 detected. taken place.
ethanol followed by 5 ∴Carboxylic acid is
drops of confirmed present.
concentrated
sulphuric acid. Heat
the mixture & then
pour it in to a beaker
containing distilled
water.
(f).To 2cm3 of Q add No observable change Reducing agent is
1cm3 of acidified occurs. suspected absent.
potassium ∴Ethanoic acid is
dichromate (VI) suspected present.
solution and warm.
Identify the nature of Q.Q is aliphatic carboxylic acid.
b) Aromatic carboxylic acids.

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You are provided substance Z which is an organic compound. Carry out

the following tests to identify the nature of Z. Record your observations
and deductions in the table below.
Tests Observations Deductions
(a).Burn a small White crystals burns Aromatic compound
amount of Z on a with yellow sooty is suspected present.
crucible lid. flame.
(b).Shake few crystals Z partially dissolves & Aromatic carboxylic
of Z in about 3cm3 of colourless solution acid is suspected
distilled water & test formed turns blue present.
with litmus paper & litmus red.
then add a little On addition of sodium
sodium hydrogen hydrogen carbonate,
carbonate powder. effervescence of
colourless gas that
turns lime water
milky.
(c).To a spatula end- Dissolves to give a Aromatic carboxylic
ful of Z add 2cm of
3 colourless solution. acid is suspected
dilute sodium present.
hydroxide solution &
warm to dissolve the
solid. Cool & divide
the resultant solution
in to two parts.
c.(i).To the 1st part of Brown precipitate. Benzoate ion is
the solution, add iron formed.
(III) chloride solution. ∴Benzoic acid is
suspected present.
c.(ii).To the 2nd part White precipitate. Benzoic acid is
of the solution, add suspected present.
dilute sulphuric acid.
(d).To the spatula Pleasant fruity smell Esterification has
end-ful of Z add 2cm3 detected & the taken place.
of ethanol. Shake well product is insoluble in ∴Benzoic acid is
to dissolve the solid & water. confirmed present.
add 5 drops of
concentrated

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sulphuric acid and

heat the mixture.
Pour the product in to
a beaker of cold water
Identify the nature of Z.Z is an aromatic carboxylic acid.
E. Analysis on amines.
a) Aliphatic amines.
You are provided substance S which is an organic compound. Carry out
the following tests to identify the nature of S. Record your observations
and deductions in the table below.
Tests Observations Deductions
(a).Burn a small Colourless liquid Aliphatic saturated
amount of S on the tip burns with yellow compound with low
of the spatula. non-sooty flame. C: H ratio.
(b).To 1cm of S add
3 Miscible with water to Aliphatic amine is
2cm of distilled
3 form a colourless suspected present.
water & test with solution that turns
litmus paper. red litmus paper blue.
(c).Place 1cm of S in Dense white fumes
3 Alkyl ammonium salt
a test tube & bring a are formed. is formed.
bottle containing ∴ Aliphatic amine is
concentrated suspected present.
hydrochloric acid
near the mouth of the
test tube.
(d).To 1cm3 of S add Yellow oily liquid is Secondary aliphatic
cold sodium nitrite formed. amine is confirmed
solution followed by present.
concentrated
hydrochloric acid.
Identify the nature of S.S is secondary aliphatic amine.
b) Aromatic amines.
You are provided substance K which is an organic compound. Carry out
the following tests to identify the nature of K. Record your observations
and deductions in the table below.
Tests Observations Deductions
(a).Burn a drop of K K burns with Aromatic compound
on a crucible lid. luminous sooty flame. is suspected present.

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(b).Put two drops of K K is slightly soluble in Aromatic amine is

in a test tube & add water & the solution suspected present.
about 1cm3 of distilled turns red litmus
water. Shake the paper blue.
mixture. Test the
mixture with litmus.
(c).To 1cm3 of K add K dissolves to form a K contain basic
2cm3 of concentrated colourless liquid & functional group.
hydrochloric acid. dense white fumes ∴ Aromatic amine is
are formed. suspected present.
(d).To 5cm3 of K, add Reddish-brown Polar functional
bromine water drop colour of bromine group attached to
wise until in excess. water discharged. benzene ring.
White precipitate is ∴ Aromatic amine is
formed. suspected present
E.g. Phenylamine.
(e).To 1cm3 of K add K dissolves to form a Diazonium salt is
concentrated colourless solution. formed.
hydrochloric acid ∴ Aromatic amine is
followed by cold suspected present.
solution of sodium
nitrite (5C).Divide
the solution in to two
portions.
e.(i).Warm the 1st Effervescence of a Aromatic diazonium
portion. colourless neutral salt decomposed to
gas. form nitrogen gas.
Oily liquid is formed.∴ Aromatic amine is
suspected present.
e.(ii).To 2 part, add Yellow precipitate is
nd An azo dye is formed.
alkaline solution of formed. ∴ Aromatic amine is
naphathaleine-2-ol. confirmed present.
Identify the nature of K.K is an aromatic amine, Eg. Phenylamine.
Alcohols.
Functional group: Hydroxyl group (-OH)
Organic compounds Alcohols:
 Aliphatic primary, secondary & tertiary alcohols.
 Aromatic primary, secondary & tertiary alcohols.
Physical Properties:

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The presence of the -OH group means that hydrogen bonding occurs
between the molecules of alcohols/hydrogen bonding has two
consequences.
 All alcohols with relatively short carbon chains (up to and including
propanol) mix with water forming a neutral solution.
The shorter chain alcohols are normally colourless liquids at room
temperature with a pleasant spirit smell.
 They have boiling points (and melting points) being much higher than
those of alkanes of comparable relative molecular mass.
Common Tests Observations
Addition of sodium metal Colourless gas which explodes
with a pop sound when lit is given
off.(Hydrogen gas)
Add of anhydrous zinc (II) chloride (i). Tertiary alcohol-An
followed concentrated hydrochloric immediate cloudy solution is
acid (Lucas reagent) formed at room temperature.
(ii). Secondary alcohol-A cloudy
solution is formed after standing
for five minutes at room
temperature.
(iii). Primary alcohol-No cloudy
solution is formed at room
temperature.
Lucas’s test for primary, secondary and tertiary alcohols is summarized
in the equations below:
Anhy. ZnCl2
R3COH + Conc.HCl 25°C R3C Cl + H2O
3°C Alcohol Anhy. ZnCl2 Immediate cloudy solution
R2CHOH + Conc.HCl 25°C R2CHCl + H2O
2°Alcohol Anhy. ZnCl2 Cloudy solution on standing about 5Mins
RCH2OH + Conc.HCl RCH2Cl + H2O
1° Alcohol 25°C No observable change occurs.
Oxidation of Alcohols: Acidified potassium dichromate
Addition of acidified potassium solution changes from orange to
dichromate, and heat. green
Explanation:
(i).Primary alcohol-Oxidized to
aldehydes and further to
carboxylic acids.

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(ii).Secondary alcohol-Oxidized to
ketones and resistant to further
oxidation.
Note: Tertiary alcohol: No observable colour change. Solution remains
orange (3°alcohols are resistant to oxidization)
Dehydration of alcohols: All primary, secondary or tertiary
alcohols gives off a colourless
vapour,if bubbled in:
(i).Addition of concentrated Bromine water, changes it from
sulphuric acid, and heat. brown to colourless.
Acidified potassium
permanganate, from purple to
pink.
(ii).Addition of iodine solution A yellow precipitate of CHI3 is
followed by sodium hydroxide formed.
solution until the colour of iodine is
just discharged. (Iodoform test).
Equation:
OH
CH3C + 3I2 + 4NaOH CHI3 + CH3CO2-Na+ + 3H2O + 3NaI
(Yellow ppt)
Methyl alcohols from a yellow precipitate of CHI3 (Iodoform).
 Ethanol (CH3CH2OH) also gives a yellow precipitate.
 Tertiary alcohols with structure formula,(CH3)3COH do not gives a
yellow precipitate of CHI3
Addition of dilute sulphuric acid A solution with sweet smell is
followed by few drops of ethanoic formed.
acid and heat.
Pour the resultant solution in a
beaker containing water.
Equation:
H+
RCO2H + CH3CH2OH RCO2CH2CH3 + H2O
Addition of phosphorus Evolution of misty gas hat forms
pentachloride solution. white fumes with ammonia.
NEUTRAL COMPOUNDS: CARBONYL COMPOUNDS:
(Aldehydes and ketones)
Functional Group: Carbonyl group (C═O)
Organic Compounds:

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 Aldehydes: Aliphatic Aldehydes & Ketones.

 Ketone: Aromatic Aldehydes & Ketones.
Physical Properties:
The carbonyl group is strongly polar C═O so dipole-dipole forces between
molecules are quite significant:
(i). the shorter chained carbonyl compounds are normally colourless
liquids at room temperature and are completely miscible with water due to
formation of hydrogen bonds. Solubility decreases with increasing length of
the carbon chain. Long chained carbonyl compounds are normally solids
e.g. glucose.
(ii). this leads to boiling points (and melting points) being higher than
those of alkanes of comparable relative molecular mass but not as those of
alcohols, where H-bonding can occur between molecules.
General Test Observations
To about 1cm of compound, Add 2,4- A yellow precipitate is formed
3

dinitrophyenylhydrazine (Brady’s with both ketones and

reagent). aldehydes.
Equation:
HN-NH2 HN-N=C
CO + NO 2 NO2
NO2 NO2 Yellow precipitate
To about 1cm3 of compound, Add A white precipitate is formed
saturated sodium hydrogen sulphite with both ketones and
and warm. aldehydes.
NOTE:
Precipitate is not obtained from
aliphatic Aldehydes and ketones
with C1.
FUNCTIONAL GROUP TESTS
Aldehydes Observations
Add acidified potassium dichromate A green solution is formed I.e.:
and warm. Aldehyde is oxidized to
carboxylic acid.
Equation:
O
=

C=O Cr3+(aq) + C OH
Add ammoniacal silver nitrate A silver deposit on the walls of
(Tollen’s reagent). the test tube.

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Equation:
R-CHO + Ag(NH3)2+OH- Ag(s) + RCOO- + Other product
Aldehyde Tollen's reagent Silver mirror
Add Fehling’s solution. Brown precipitate is formed.
Equation:
RCHO + Cu2+(aq) + 3OH-(aq) Cu2O(s) + CH3CO2H +H2O
(Blue tartrate complex) Brick red ppt)
Ketones:
Add Iodine solution followed by A yellow precipitate is formed
sodium hydroxide solution until for methyl ketones.
colour of iodine is just discharged. (CH3CO-)
Equation:
CH3COR + 3I2 + 4NaOH CHI3 + CH3COO-Na+ +3H2O + 3NaI
Yellow p.p.t
OH

ACIDIC COMPOUNDS: 1. PHENOLS:

Functional group: Hydroxyl group (-OH) Organic compounds: Phenols
Physical properties:
The presence of the OH group means that hydrogen bonding occurs
between the molecules of phenols/Hydrogen bonding has two
consequences:
 It is colourless crystalline solid, with a distinctly antiseptic smell. Phenol
acquires a reddish brown tint on exposure to air/light.it is only
sparingly soluble in cold water, forming an acidic solution.
 They have boiling points (and melting points) being much higher than
those of alkanes of comparable relative molecular mass.
Tests Observations
Addition of universal indicator or Turns universal indicator red
litmus solution. ( showing that is acidic)
Equation:
OH O-

+ H2O
(aq) + H3O+(aq)
Add neutral iron (III) chloride Purple/violet colouration is
solution observed.
Equation:

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OH O-

+ FeCl3(aq)
+ 3HCl(aq)
3 Fe
Addition of bromine water. White precipitate
Equation:
OH OH
Br Br
+ Br2/H2O + 3HBr
Room Temp
Br
White p.p.t
ACIDIC COMPOUNDS: 2.CARBOXYLIC ACIDS.
Functional group : Carboxylate group (-CO2H)
Organic compounds : Carboxylic acids: (i). Aliphatic carboxylic acids.
(ii). Aromatic carboxylic acids.
Physical Properties:
 The acids have a characteristic smell as that of vinegar, the shorter
chain acids are normally colourless liquids at room temperature.
 They form hydrogen bonds with water molecules, this result in
carboxylic acids dissolving well in water, provided that their carbon
chains are fairly short.
Tests Observations
Addition of universal indicator Turns universal indicator red
or litmus solution (Showing that it’s acidic)
Equation:
H+
RCO2H(l) + H2O(l) RCO2-(aq) + H3O+(aq)
Addition of saturated Na2CO3. Colourless gas turns lime water
milky (CO2 gas) is evolved
Equation:
Na2CO3(aq)
2RCO2H(l) 2RCO2-Na+(aq) + CO2(g) + H2O(l)
Saturated
Add Neutral Iron (III) chloride Brown precipitate is formed.
solution.
Equation:

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CO2H CO2-

+ FeCl3(aq)
+ 3HCl(aq)
3 Fe
Add soda lime solution and heat Colourless gas that turns
limewater (CO2 gas)
Equation:
Soda lime
RCO2H(l) RH + CO2(g)
Heat
Clear solution
Add dilute sulphuric acid A solution with a sweet smell is
followed by 1cm3 of ethanol and formed.
heat. Pour the resultant solution
in a beaker containing Water.
Equation:
H+
RCO2H + CH3CH2OH RCO2CH2CH3 + H2O
Addition of sodium metal Colourless gas with ‘pop’ sound
when lighted is evolved.
A colourless solution is formed.
Equation:
RCO2H + Na(s) RCO2-Na+ + H2(g)
BASIC COMPOUNDS: AMINES
Functional group: Amino group (-NH2)
Organic compounds: Amines
 Aliphatic primary, secondary or tertiary Amines.
 Aromatic primary, secondary or tertiary Amines.
Physical properties:
 They have a characteristic fishy smell. Indeed of rotting fish. Smell
produced by decomposition of proteins.
 Primary and secondary amines can hydrogen bond to molecules of water
or alcohols, so primary amines with chain length up to C4 are colourless
and very soluble in water. Forming a basic solution.
 Phenyl amine is a brown liquid and not very soluble in water due to the
benzene ring.
Tests Observations
Detect the smell (Take care) Aliphatic amines have a fishy smell.
I.e smell of decaying fish.

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With dilute hydrochloric acid Compound dissolves (Showing that

is basic).
Equation:
RNH2 + H+ RNH3
Addition of bromine water White precipitate formed with a
primary aromatic amine
Equation:
NH2 NH2
Br Br
+ Br2/H2O + 3HBr
Room Temp
Br
White p.p.t
Addition of nitrous acid (can be prepared in situ by using sodium nitrite and
concentrated hydrochloric acid) and allow to stand in ice cold water.
(i). Primary aliphatic amine A bubble of colourless, Nitrogen gas
is evolved and a colourless solution
is formed, with primary aliphatic
amine.
Equation:
Cold
R-NH2 + HNO2(aq) R-N N RH + H2O + N2(g)
10°C Unstable Clear solution
(ii). Aliphatic and aromatic Yellow oily emulsion of Nitroso
secondary amines compounds.(Yellow turbid solution)
Equation:

(iii).Tertiary amines Clear solution containing

substituted ammonium nitriles
Equation

(iv). Primary aromatic amine No bubbles of colourless gas are

evolved with aromatic amines.
Yellow crystalline aromatic salts
formed.

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Equation:

(i). Addition of sodium hydroxide Bright red precipitate (Azo-dye)

solution followed by 2-3 drops of confirms a primary aromatic amine.
napthalein-2-ol

SAMPLE MARKING GUIDE FOR AN ORGANIC PRACTICAL TYPICAL

QUESTIONS ON ORGANIC QUALITATIVE ANALYSIS.
Experiment 1:
1. You are provided with substance G which is an organic compound. You are
required to determine the nature of G. carry out the following tests and
identify any gases liberated. Record your observations in the table below.
Tests Observations Deductions

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(a). Note the G is a colourless liquid G is an alcohol,

appearance of with a spirit smell. carbonyl compound or
substance G. a carboxylic acid.
(b). Burn a small G burns with a yellow Probably G is an
amount of G on a non-sooty flame. aliphatic compound
spatula or porcelain with high molecular
dish. mass.
(c). Divide the
remaining G in to five
portions.
(i). To the 1st portion, G is miscible with Probably G is an
add 3cm3 of water. water, it’s neutral to aliphatic neutral
Test the solution with litmus. compound such as an
litmus paper. alcohol, ketone or
aldehyde.
(ii). To the 2nd portion, G turns acidified G is a reducing agent.
add acidified potassium potassium dichromate Ketone absent,
dichromate (VI) (VI) solution from Probably an aliphatic
solution and heat. orange to green. aldehyde, secondary or
primary alcohol
present.
(iii).To the 3rd portion, A yellow precipitate Secondary or primary
add about 3cm3 of was formed. alcohol absent. An
Brady’s reagent. aliphatic aldehyde is
suspected present.
(iv). To the 4th portion, A silver mirror An aliphatic aldehyde is
add silver nitrate deposited on the sides confirmed present.
solution followed by of the test tube.
ammonia solution and
warm.
(v).To the 5th portion, No cloudy solution was Secondary or tertiary
add 2cm3 of Lucas’ formed. alcohol absent. An
reagent. aliphatic aldehyde is
present.
Name:
(i). the functional group(s) in G:
Carbonyl group.
(ii). the class of compounds to which G belongs to.
G is an aliphatic aldehyde.

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Experiment 2 (H = Acetone or Butanone):

2. You are provided with substance H which is an organic compound. You are
required to determine the nature of H. carry out the following tests and
identify any gases liberated. Record your observations in the table below.
Tests Observations Deductions
(a).Burn a spatula Colourless liquid that Aliphatic saturated
end-ful of H on a burns with a blue-non compound with low C:
procelain dish (or at sooty flame. H ratio or with low
the end of a spatula). carbon content.
(b).Add 2cm of3 Dissolves/soluble or Polar aliphatic
distilled water to 1cm miscible with water to compound of low
3

of H. Test the mixture form a colourless molecular mass.

with litmus paper. solution that has no ∴alcohols, ketones,
effect on litmus papers. aldehydes, ester or
carboxylic acid are
suspected present.
(c).To 1cm of H, add Yellow precipitate
3 Aldehyde, ketone &
Brady’s reagent. carboxylic acid are
suspected present.
(d).To 4cm of
3 White precipitate is Aldehyde & ketone
saturated sodium seen. are suspected present.
hydrogen sulphite
solution, add 2cm3 of
H.
(e).To 5 drops of H, Yellow precipitate CHI3 is formed.
add 4cm of iodine
3 ∴Ketone with a methyl
solution followed by group attached to the
dilute sodium carbon carrying the
hydroxide solution functional group or
until the solution is ethanol or ketone of
pale-yellow. Warm the the type:
mixture gently & then O
=

cool. CH3 C R
(f).To 3cm3 of H, add No observable change Ethanol is suspected
1cm of acidified
3 occurs. absent.
potassium dichromate ∴Ketone is suspected
(VI) solution & warm present.
the mixture.

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 BASIC ADVANCED LEVEL CHEMISTRY PRACTICAL

(g).To 3cm3 of silver No observable change Aldehyde is suspected

nitrate solution, add 2 occurs. absent.
drops of dilute sodium Or: ∴Ketone is suspected
hydroxide solution. No silver mirror. present.
Then add ammonia
solution drop wise
until the precipitate
just dissolves, Add
about 5cm3 of H &
warm.
From your results above, comment on the nature of compound H.
H is saturated aliphatic ketone with a methyl group attached to the carbon
atom carrying the functional group or ketone of the type:
O
=

CH3 C R
Experiment 3 (B = Propan-2-ol or Butan-2-ol):
3. You are provided with substance B which is an organic compound. You are
required to determine the nature of B. carry out the following tests and
identify any gases liberated. Record your observations in the table below.
Tests Observations Deductions
(a).Burn a small Colourless liquid that Saturated aliphatic
amount of B on a burns with a yellow compound with low C:
spatula end or in a non-sooty flame. H ratio or low carbon
porcelain dish. content.
(b).Add 6 drops of B Miscible with Polar aliphatic
to about 3cm of3 water/dissolves to compound of low
distilled water, shake form a colourless molecular mass or
& allow to stand. solution that has no neutral compound
Divide the solution in effect on litmus. probably alcohol,
to three parts. ketone, aldehyde or
ester.
b.(i).To the 1 part of No observable change/ Carboxylic acid is
st

the solution, add 2-3 No effervescence. suspected present.

drops of dilute sodium
hydrogen carbonate
solution.
b.(ii).To the 2nd part of No observable change. Phenol is suspected
the solution, add 2-3 absent.

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 BASIC ADVANCED LEVEL CHEMISTRY PRACTICAL

drops of iron (III)

chloride solution.
b.(iii).To the 3rd part No observable change. Ketone & aldehyde are
of the solution, add 2- Or suspected absent.
3 drops of Brady’s No yellow precipitate.
reagent.
(c).Add 2-3 drops of Solution turns from Reducing agent
acidified potassium orange to green. probably primary &
dichromate (VI) secondary alcohols are
solution to 2cm of B
3 suspected present.
in a test tube & then
heat. Divide the
resultant solution in
to two parts.
c.(i).To the 1st part of Yellow precipitate. Primary & secondary
the resultant solution, alcohols are oxidized
add Brady’s reagent. to carbonyl.
c.(ii).To the 2 part of No observable change Aldehyde not formed.
nd

the solution, add occurs. ∴ Primary alcohol is

Tollen’s reagent and suspected absent.
warm.
(d).To about 0.5cm3 of Yellow precipitate is CHI3 formed.
B, add about 4cm of 3 formed. ∴Secondary alcohol of
iodine solution the type,
followed by dilute OH
sodium hydroxide
CH3CH R
solution drop wise
until a pale yellow
solution is formed.
Heat & allow to stand.
(e).To about 1cm3 of Cloudy solution formed Secondary alcohol is
B, add 5 drops of within 5-10 minutes. presnt.
Luca’s reagent.
Comment on the nature of compound B.
B is saturated aliphatic secondary alcohol with a methyl group attached to
the carbon atom carrying the functional group.
∴ Secondary alcohol of the type:

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 BASIC ADVANCED LEVEL CHEMISTRY PRACTICAL

OH

CH3CH R
Experiment 4 (C = Propan-2-ol or Ethanol):
4. You are provided with substance C which is an organic compound. You are
required to determine the nature of C. carry out the following tests and
identify any gases liberated. Record your observations in the table below.
Tests Observations Deductions
(a).Burn a small Colourless liquid that Saturated aliphatic
amount of C on a burns with a blue non- compound with C: H
crucible lid or spatula sooty flame. ratio.
end.
(b).To 5 drops of C, Dissolves to form a Polar aliphatic
add about 1cm of3 colourless solution & compound with low
distilled water & solution has no effect molecular mass.
shake. Test the on litmus paper. ∴Neutral compound
mixture with litmus. like alcohol, ketone,
aldehyde or ester.
(c).To 5 drops of C, Purple solution turns Reducing agent
add 2-3 drops of to colourless. probably primary &
acidified potassium secondary alcohols or
manganate (VII) aldehyde are
solution & warm. suspected present.
(d).To 5 drops of C, Pale-yellow precipitate Alcohol of the type:
add 1cm of iodine
3 OH
solution followed by
dilute sodium CH3 C Or ethanol.
hydroxide solution ∴Yellow precipitate is
drop wise until the CHI3.
mixture is pale-yellow.
Warm, then cool under
running tap
(e).To 5 drops of C, No observable change Aldehyde & ketone are
add 2-3 drops of occurs. suspected absent.
Brady’s reagent.
(f).Carry out a test of
your own choice to
confirm the functional
group in C.

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 BASIC ADVANCED LEVEL CHEMISTRY PRACTICAL

Test:
To a few drops of C, Colourless solution Ester is formed.
add 3 drops of with pleasant fruity ∴Alcohol is conformed
ethanoic acid followed (sweet) smell. present.
by 2 drops of
concentrated
sulphuric acid & warm.
Or
Add phosphorus White fumes which
pentachloride solution forms dense white
or add sodium metal. fumes with
Or concentrated ammonia
solution.
Add concentatred Effervescence of Alkene.
sulphuric acid & heat. colourless gas that ∴Alcohol is present.
turns potassium
permanganate (VII)
solution from orange
to colourless.
Comment on the nature of C.
C is saturated aliphatic primary or secondary alcohol.
∴ Primary or secondary alcohol of the type:
OH

CH3 C
Experiment 5 (D = 2-Methylpropan-2-ol):
5. You are provided with substance D which is an organic compound. You are
required to determine the nature of D. carry out the following tests and
identify any gases liberated. Record your observations in the table below.
Tests Observations Deductions
(a).Burn a spatula end- Colourless liquid that Aliphatic compound
ful of D on a porcelain burns with a yellow with low C: H ration.
dish or at the end of non-sooty flame. Or
spatula. Saturated aliphatic
compound of low
carbon content.
(b).Shake 1cm of D
3 Immiscible with water. Neutral compound
with about 3cm of 3 Mixture has no effect probably alcohol,
distilled water & test on litmus. esters re carbonyl

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 BASIC ADVANCED LEVEL CHEMISTRY PRACTICAL

the solution with compound s are

litmus. Divide the suspected present.
solution in to three
parts.
b.(i).To the 1st part of No observable change Carboxylic acid is
the solution, add 2-3 occurs. suspected absent.
drops of sodium Or
carbonate solution. No effervescence.
b.(ii).To the 2nd part ofNo observable change Phenol is suspected
the solution, add 2-3 occurs. absent.
drops of iron (III) Or
chloride solution. No violet colouration.
b.(iii).To the 3rd part of
No observable change Ketone & aldehyde are
the solution, add 2-3 occurs. suspected absent.
drops Brady’s reagent. Or
No yellow precipitate.
(c).To about 1cm of D, Colourless solution
3 Ester is formed.
add about equal with a pleasant fruity ∴Alcohol is suspected
volume of ethanoic (sweet) smell. present.
acid followed by 4-5
drops of concentrated
sulphuric acid.
Heat the mixture &
pour it in to a small
beaker of cold water &
stir.
(d).To about 0.5cm3 of No observable change Alcohol with methyl
D, add about 4cm3 of Or radical group attached
iodine solution No yellow precipitate. to the carbon atom
followed by sodium containing the
hydroxide solution functional group is
drop wise until the absent.
solution is pale yellow. Or
Warm the mixture & OH
allow to stand. R CHCH3
(e).To about 1cm3 of Immediate cloudiness Tertiary alcohol is
D, add about 5 drops Or present.
of Lucas ‘reagent. White precipitate is
formed immediate.

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 BASIC ADVANCED LEVEL CHEMISTRY PRACTICAL

Comment on the nature of D.

D Tertiary alcohol.
Experiment 6 (E = Methanoic acid):
6. You are provided with substance E which is an organic compound. You are
required to determine the nature of E. carry out the following tests and
identify any gases liberated. Record your observations in the table below.
Tests Observations Deductions
(a).Burn a small Colourless liquid that Aliphatic saturated
amount of E on a burns with a blue non- Or
crucible lid or sooty flame. Low C: H ratio or
spatula end. carbon content.
(b).To about 1cm of Readily miscible
3 Acidic compound
E, add about 1cm of soluble/dissolves to form probably carboxylic
3

dilute sodium colourless solution. acid is suspected

hydroxide solution. present.
(c).To about 1cm of No observable change
3 Phenol is suspected
E, add 2-3 drops of occurs. absent.
neutral iron (III) Or
chloride solution & No violet/purple
warm.
(d).To about 1cm3 of Miscible/soluble/dissolves Carboxylic acid is
E, add about 1cm3 of in water to form a suspected present.
distilled water. colourless solution that
Shake & allow to turns blue litmus red.
stand. Test the
resultant solution
with litmus paper &
divide the solution
in to two portions.
d.(i).To the 1st Effervescence colourless Carboxylic acid is
portion of the gas that turns lime water confirmed present.
solution, add 1cm3 milky.
of sodium hydrogen
carbonate solution.
d.(ii).To the 2nd Yellow precipitate Methanoic acid is
portion of the suspected present.
solution, add 2-3
drops of Brady’s
reagent.

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 BASIC ADVANCED LEVEL CHEMISTRY PRACTICAL

(e).To about 0.5cm3 Silver mirror is formed. Methanoic acid is

of E, add about 1cm 3 confirmed present.
of Tollen’s reagent,
warm & allow the
mixture to stand.
From your results above, deduce the nature of compound E.
E is a saturated aliphatic carboxylic acid or simply methanoic acid.
Experiment 7:
7. You are provided with substance F which is an organic compound. You are
required to determine the nature of F. carry out the following tests and
identify any gases liberated. Record your observations in the table below.
Tests Observations Deductions
(a).Burn a spatula end- White solid burns with Aromatic compound.
ful of F on a porcelain a yellow sooty flame. Or
dish or at the end of a Aliphatic unsaturated.
spatula. Or
Aliphatic with high C:
H ratio or high content
of carbon.
(b).Transfer two Sparingly soluble in High molecular mass
spatula end-fuls of F to cold water but polar, acidic
a test tube containing dissolves on warming compound probably
5cm of distilled water, to form a colourless
3 phenol & carboxylic
warm the mixture & solution that turns acid are suspected
test with litmus. Divide blue litmus red/ present.
the warmed solution
in to four parts
(b).(i).To the 1st part Slight effervescence. Carboxylic acid is
of the warmed Or suspected present.
solution, add 2-3 drops Colourless gas
of sodium carbonate bubbles.
solution.
b.(ii).To the 2nd part of No observable change Phenol is suspected
the warmed solution, occurs. absent.
add 2-3 drops of iron
(III) chloride solution.
b.(iii).To the 3rd part of No observable change Primary, secondary
the warmed solution, occurs. alcohols or aldehyde
add 2-3 drops of are suspected absent.

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 BASIC ADVANCED LEVEL CHEMISTRY PRACTICAL

potassium dichromate
(VII) solution and
warm.
(c).Dissolves one No observable change Carbonyl compounds
spatula end-ful of F in occurs. are suspected absent.
2cm of methanol &
3 Or
add 2-3 drops of No orange precipitate.
Brady’s reagent.
(d).To about a spatula Pleasant fruity (sweet) Ester is formed.
end-fuls of F, add smelling liquid. ∴Carboxylic acid is
about 5cm of ethanol
3 suspected present.
followed by 2-3 drops
of concentrated
sulphuric acid. Heat
the mixture & pour it
in to a small beaker of
cold water, allow to
stand.
(e).To a spatula end ful Purple solution turns Unsaturated
of F in a test tube, add to colourless solution. compounds are
3cm3 of distilled water, suspected present.
warm and add 2-3
drops of acidified
potassium
permanganate (VII)
solution.
From your results above, Comment the nature of compound F.
F is unsaturated aromatic carboxylic acid.
Experiment 8 (G = Secondary alcohol):
8. You are provided with substance G which is an organic compound. You are
required to determine the nature of G. carry out the following tests and
identify any gases liberated. Record your observations in the table below.
Tests Observations Deductions
(a).Burn a small Colourless liquid that Aliphatic
amount of G on a burns with a yellow non- saturated/with low
spatula end. sooty flame. C: H ratio or low
carbon content.

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(b).To about 1cm3 Miscible/soluble/dissolves Polar aliphatic

of G, add about in water to form colourless compound with low
2cm3 of distilled solution which has no molecular mass.
water, shake & test effect on litmus. Neutral compound
the mixture with probably alcohol,
litmus. Divide the carbonyl or ester.
mixture in to three
parts.
b.(i).To the 1st part No observable change Carbonyl compound
of the mixture, add occurs. is suspected absent.
2-3 drops of Brady’s
reagent.
b.(ii).To the 2nd part No observable change Phenol is suspected
of the mixture, add occurs. present.
2-3 drops of iron
(III) chloride
solution.
(c).To the 3rd part of Orange solution turns to Primary & secondary
the mixture above, green. alcohol are suspected
add 2-3 drops of present.
acidified K2Cr2O7(aq).
Heat the mixture &
divide the solution
in to two parts.
c.(i).To the 1st part Yellow precipitate. Primary & secondary
of the solution, add alcohol are oxidized
2-3 drops of Brady’s to carbonyl
reagent. compounds.
c.(ii).To the 2nd part No observable change Aldehyde not formed
of the solution, add occurs. from oxidation.
about 2-3 drops of ∴ Primary alcohol is
Tollen’s reagent & suspected absent.
warm. Or
Secondary alcohol is
oxidized to alkanone.
(d).To about 0.5cm3 Cloudy solution formed Secondary alcohol is
of G, add 2-3 drops within 5-10 minutes. suspected present.
of Lucas reagent.

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(e).To about 0.5cm3 Yellow precipitate. Secondary alcohol

of G, add 2-3 drops with a methyl radical
of sodium adjacent to the
hydroxide solution carbon atom carrying
followed by iodine the functional group.
solution until the Or:
solution is pale- OH
yellow. Warm the
R CHCH3
mixture & allow to
stand.
From your results above, Comment the nature of compound G.
G is aliphatic secondary alcohol with a methyl group adjacent to the carbon
atom carrying the functional group.
OH

/ R CHCH3 .
OH
COOH

Experiment 9 (H = Salicylic acid ( ):

9. You are provided with substance H which is an organic compound. You are
required to determine the nature of H. carry out the following tests and
identify any gases liberated. Record your observations in the table below.
Tests Observations Deductions
(a).Burn a small White solid burns with a Aromatic compound.
amount of H on a yellow sooty flame. Or
spatula end-ful or on Aliphatic unsaturated
a crucible lid. compound.
Or
Aliphatic of
compound with low C:
H ratio.
(b).Add a spatula Readily Acidic compound
end-ful of H to about soluble/dissolves to probably carboxylic
5cm of sodium
3 form a colourless acid & phenol are
hydroxide solution. solution. suspected present.
(c).To spatula end-ful Slightly soluble in cold High molecular
of H in a test tube add water & dissolves on mass/aromatic
about 5cm of water. warming forming a
3 compound which is
Shake vigorously & colourless solution that acidic probably

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warm. Test the turns blue litmus paper carboxylic acid &
solution with litmus red. phenol are suspected
paper & divide it in to present.
three equal portions.
c.(i).To the 1st portion No observable change Carbonyl compounds
of the solution, add 2- occurs. are suspected absent.
3 drops of Brady’s Or
reagent. No orange precipitate.
c.(ii).To the 2 part
nd Violet/purple Phenol is suspected
of the solution, add 2- colouration. present.
3 drops of iron (III)
chloride solution.
c.(iii).To the 3rd Effervescence/bubbles Carboxylic acid is
portion of the of colourless gas. suspected present.
solution, add a
spatula end-ful of
solid sodium
hydrogen carbonate.
(d).To 2cm3 of Sweet fruity smell. Esterification has
ethanol, add a spatula occurred.
end-fuls of H then ∴Carboxylic acid is
add 2-3 drops of confirmed present.
concentrated
sulphuric acid &
warm the mixture.
From your results above, Comment the nature of compound H.
H is aromatic compound with a hydroxyl group attached to the benzene
ring & also contains a carboxyl (-COOH) group.
Or aromatic carboxylic acid with a hydroxyl group attached to.
O

Experiment 10 (J = Benzoquinone ( ):
10.You are provided with substance J which is an organic compound. You are
required to determine the nature of J. carry out the following tests and
identify any gases liberated. Record your observations in the table below.
Tests Observations Deductions

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(a).Burn a spatula White crystalline solid Aromatic compound.

end-ful of J in a burns with a yellow Or
porcelain dish or at sooty flame. Unsaturated aliphatic
the end of a spatula. compound.
Or
Aliphatic compound
with high C: H ratio.
(b).Shake two spatula Insoluble in cold water High molecular mass /
end-fuls of J with but slightly soluble on aromatic compound.
about 5cm of distilled warming.
3 ∴Neutral compound
water, warm & test Solution formed has no probably alcohol, ester
with litmus. effect on litmus. or carbonyl are
suspected present.
(c).Dissolve two
spatula end-fuls of J in
methanol & divide the
solution in to four
parts.
c.(i).To the 1st part of No observable change Phenol is suspected
the solution, add 2-3 occurs. absent.
drops of iron (III) Or
chloride solution. No violet/purple
colouration.
c.(ii).To the 2 part of Orange (Yellow)
nd Carbonyl compound is
the solution, 2-3 drops precipitate. suspected present.
of Brady’s reagent.
c.(iii).To the 3rd part of No observable change Alkanal (Aldehyde) is
the solution, add about occurs. suspected absent.
1cm3 of Fehling’s Or ∴Ketone is suspected
solution & boil. No red precipitate/ present.
Reddish-brown.
c.(iv).To the 4th part of No observable change No methyl group
the solution, add about occurs. attached to the
1cm3 of iodine Or carbonyl compound.
solution followed drop No yellow precipitate.
wise addition of
sodium hydroxide
solution until the

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solution is pale-yellow
& warm.
From your results above, Comment the nature of compound J.
J is aromatic ketone without a methyl group attached to the carbon
carrying the functional group.
OH
CHO

Experiment 11 (K = Vaniline ( ):
11.You are provided with substance J which is an organic compound. You are
required to determine the nature of J. carry out the following tests and
identify any gases liberated. Record your observations in the table below.
Tests Observations Deductions
(a).Burn a small White crystals/solid Aromatic compound.
amount of K on a burns with a yellow Or
spatula end. sooty flame. Aliphatic unsaturated
compound.
Or
Aliphatic compound
with low C: H ration.
(b).To a spatula end- Dissolves in sodium Acidic compound
ful of K in a test tube, hydroxide solution to probably phenol &
add 3cm of sodium
3 form a colourless carbonyl compounds
hydroxide solution solution & on adding are suspected present.
followed by dilute dilute sulphuric acid,
sulphuric acid. white precipitate is
formed.
(c).To a spatula end- Insoluble in cold, but High molecular
fuls of K in a test tube, dissolves on warming mass/aromatic
add about 4cm3 of to form a colourless compound probably
water, warm the solution that turns phenol & carboxylic
mixture & test the blue litmus to red. acid are suspected
solution with litmus. present.
Divide the solution in
to five parts.
c.(i).To the 1st part of No observable change carboxylic acid is
the solution, add a half occurs. suspected absent
spatula end-ful of Or
sodium carbonate. No effervescence.

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c.(ii).To 2nd part of the Purple/violet solution Phenol is confirmed

solution, add neutral is formed. present.
iron (III) chloride
solution.
c.(iii).To the 3rd part Purple solution of Primary, secondary
of the solution, add 3- KMnO4(aq) turns to alcohol & aldehyde are
4 drops of acidified colourless. suspected present.
potassium manganate
(VII) solution & warm.
c.(iv).To the 4th part of Orange precipitate is Aldehyde is suspected
the solution, add 2-3 formed. present.
drops of Brady’s
reagent.
c.(v).To the 5th part of Red precipitate. Aldehyde is suspected
the solution, add Or present.
fehling’s solution & Reddish-brown
heat. precipitate.
Or
Brown precipitate.
(d).To about 3cm3 of Silver mirror is Aldehyde is confirmed
silver nitrate solution, formed. present.
add 2 drops of sodium
hydroxide solution
followed by ammonia
solution until the
precipitate is just
dissolves. Add a
spatula end-ful of K,
shake & heat in water
bath for about 5
minutes.
From your results above, Comment the nature of compound K.
K is aromatic aldehyde with an –OH group attached to the carbon benzene
ring.
Or
K is an aromatic compound with both –OH group and aldehyde group
attached the ring. Or K is a phenol with an aldehyde group.
Experiment 12 (L = 2-methylpropan-2-ol:

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 BASIC ADVANCED LEVEL CHEMISTRY PRACTICAL

12.You are provided with substance L which is an organic compound. You are
required to determine the nature of L. carry out the following tests and
identify any gases liberated. Record your observations in the table below.
Tests Observations Deductions
(a).Burn a spatula Colourless liquid that Aromatic compound.
end-ful of L on a burns with a yellow Or
porcelain. sooty flame. Aliphatic unsaturated
compound.
Or
Aliphatic with high C:
H ratio.
Or
High carbon content.
(b).Shake 1cm of L3 Miscible Polar aliphatic
with about 2cm of 3 with/soluble/dissolves compound of low
distilled water & test to form a colourless molecular mass.
with litmus paper. solution. Or
Divide the mixture in Solution has no effect no Neutral compound
to four parts. effect on litmus. probably alcohol,
ester or carbonyl
compounds.
b.(i).To the 1 part of No observable change
st Carboxylic acid is
the mixture, add 2-3 occurs. suspected absent.
drops of sodium Or
carbonate solution. No effervescence.
b.(ii).To 2nd part of No observable change Phenol is suspected
the mixture, add 2-3 occurs. absent.
drops of neutral iron Or
(III) chloride solution No violet/purple
colouration.
b.(iii).To the 3rd part No observable change Ketone & aldehyde
of the mixture, add 2- occurs. are suspected absent.
3 drops of Brady’s Or
reagent. No yellow precipitate.
b.(iv).To the 4th part No observable change Reducing agent i.e
of the mixture, add 2- occurs. primary & secondary
3 drops of acidified alcohols are
potassium suspected present.
dichromate (VI)

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solution & heat the

mixture.
(c).To about 1cm3 of Cloudy solution is Tertiary alcohol is
L, add 4 drops of formed immediately. suspected present.
Lucas reagent.
(d).To about 1cm3 of Sweet fruity smell. Ester is formed.
L, add about an equal ∴Alcohol is suspected
volume of ethanoic present.
acid followed by 4-5
drops of concentrated
sulphuric acid. Heat
the mixture & pour it
in to a beaker of
water.
(e).To about 1cm3 of White fumes/colourless Alkene is formed.
L, add about 1cm of 3 gas that turns acidified ∴Alcohol is suspected
concentrated potassium manganate present.
sulphuric acid. Heat (VII) solution from Or
the mixture & pass purple to colourless. Alcohol is dehydrated
the gas produced to an alkene.
through acidified
potassium manganate
(VII) solution
Comment on the nature of L.
L is aliphatic tertiary alcohol.

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