QA (i) (ii) (iii) (iv) ) Q2 (i) (ii) (ii) (iv) Q3 Qz Q4 Note : (i) All quest No. of printed pages: 02 Vv. P. & R. P. T. P. Science College, Vallabh Vidyanagar T. Y. B, Se. [SEMESTER — VI] EXAMINATION INTERNAL EXAM Monday, 4"" March, 2024 3.00 PM to 4.30 PM USOGCCHES1 - ORGANIC CHEMISTRY Total Marks : 25 tions are to be attempted. (ii) Figures to the right indicate marks. Choose the correct option for the following : Which one of the following is an aliphatic amino acid ? (a) Leucine (b) Phenyl Alanine (c) Histidine (d) Proline Atropine upon hydrolysis in presence of Ba(OH), produces ? (a) tropinic acid & tropine (b) tropic acid & tropinone (c) atropic acid & tropine (d) tropic acid & tropine Which one is a Vat dyes ? d (a) alizarin (b) eosin (c) pyrazolone yellow (d) Indigo Which drugs is used in the treatment of arthritics ? (a) novalgine (b) phenyl butazone —(c) hetrazen (d) all of these In which method 2,4-dinitrofluorobenzene reagent is used for N-terminal residue analysis ? (a) Pehr-Edman (b) Frederick Sanger's (c) Edmans degradation (d) both ‘a’ & 'b’ [05] Answer the following short Questions (Attempt any two) : [04] Write synthesis of alanine via direct ammonolysis method. Write synthesis of Coniine. Write the structure and uses for: (a) Aldrin (b) PETN Write a note on Emde degradation of an alkaloid and its importance. Answer the following : [04] (a) Write a note on isoelectric point of amino acid. — (b) Discuss the geometry of peptide linkage. OR Write the synthesis of (a) Purine using uric acid. { < [04] (b) Aspartic acid using phthalamido malonic ester method. Discuss the point of attachment of N-methylpyrrolidine to the pyridine nucleus in the structure of Nicotine, [04] : OR Write the synthesis of papaverine, eyQs Qs Qs Qs Write the synthesis and uses of: (a) Congo red OR What is dyes ? Give broad classification of dyes. (b) Methoxy chlor Write the synthesis and uses of : (a) Sulphafurazole (b) Atenelol OR Write the synthesis for the following : (a) Substance used for the treatment of cholera. (b) Substance used as an oral hypoglycemic agent. mee Qaeme {04] (04) (04) [04]‘VITTHALBHAI PATEL & RAJRATNA P, T, PATEL SCIENCE COLLEGE, VALLABH VIDYANAGAR INTERNAL TEST B. Sc. (Semester-V1) Date: 05/03/2024 Time: 3.00 PM to 430 PM Day : Tuesday Total Marks: 25 Subject: Inorganic Chemistry (US06CCHES2) Q:1 Answer the following multiple-choice questions. 1. For the boundary states ‘Y must at infinity. (@) finite (b) continuous (€) variable (4) vanish 2. Number of electrons in Ferrocene electronic configuration are _. (@12 b) 19 (18 (@) 22 3. Diborane is an inflammable gas. (a)yellow —(b) colourless_——_(c) brown (@) green 4. For greater than half-filled orbital value of J will be used. (a) lower (b) higher © zero (@) infinite 5, The chief ore of Ni is, (a) smeltite __(b) dolomite (c) haematite (4) pitchblende Q:2 Short Answer Questions (Attempt Any Two): {o4] 1. Explain vector operator. 2. Give any three general properties of boron hydrides. 3. Calculate the ground state term symbol for N (2=7). 4, Define calcination and roasting. __Q:3 Derive the wave equation for electron travelling in one dimensional box. [04] oR 3 Write notes on fourth postulate of quantum mechanics. [04] * Q:4 Discuss types of substitution reactions by which organometallic compounds can [04] be prepared, OR O24 Discuss the structure and bonding in BsHy and BicH« [04] +5 Draw Pigeonhole diagram for p* configuration and arranged according to {04} their energy levels. OR G5 Draw and explain the combined Orgel diagram of d’ and d. <6 Describe the froth flotation process and magnetic separation process for the [04] concentration of ores. oR <6 Describe the extraction of Silver by Air reduction process and Carbon reduction [04] process. seeeeeeeee\V.P. AND R.P.T.P.SCIENCE COLLEGE, VALLABH VIDYANAGAR B.Sc. (SEM-VI)INTERNAL EXAMINATION PHYSICAL CHEMISTRY (USOSCCHES3) t.06.03.2024, Wednesday tine [apolar Phe Q-1. Choose the most appropriate option. (0s) {i) The correct equation which relates standard free energy and equilibrium constant. (g)4G6°=-RT Ink — (b) AG=-RT Ink (¢) QG°=-RTlogk — (d) AG= -RT log k (ii) na reaction, the threshold energy is equal to (aJactivation energy ~ normal energy of reactants {b) activation energy + normal energy of reactants (c)normal energy of reactants - activation energy (Gjaverage kinetic energy of molecules of reactants (ii) For which reaction the collision thecry is generally satisfactory? (a) zeroorder —(b) first order {c) second order (d) any order (iv) Which one is a copolymer? (a) Nylon-66 _(b) Teflon {pve (4) polybutadine (v) Kinetic activity of particles suspended in a liquid is called, . (a)tyndall effect (b) visibility (¢) Brownian movement (4) zeta potential Q-2 Give answers of any two questions out of four in short. (04) (i)Give statement of Trouton’s rule. Why acetic acid and formic acid have entropy of vaporization values lower than the average value? {li) Suggest a probable mechanism for the reaction: Hg2"? + TI'?—- which is consistent with the experimental differential rate law, r= k [Hg2]{T]/[He"]. (ii) What isthe molecular mass of polypropylene molecule containing 4,000 repeat units? (iv) Write the preparation of colloidal solution of sulphur and gold. > 2Hg??+TI* Q-3 Derive the equation to calculate rotational entropy for non-lit ar molecules. (04) : oR Q-3Calculate the equilibrium constant, which can be expressed as the equilibrium (04) pressure of carbon dioxide, for the decomposition of calcium carbonate at 1000 K. ‘Hass for CaCOs ,CaO and CO2 are ~1206.92, ~635.09, and ~393.51 K respectively =(GP H®,ge)/T for CaCOs ,CaO and CO2 are 144.22, 63.85, and 235.9 JK* respectively. (R= 8.3143K%mol*). Q-4 Give mechanism of a reaction:Hatey+ Brajey~-->2HBriq) Discuss each step Of @ mechanism. (04) OR 0.4 Discuss the effect of temperature and catalyst on the rate of a reaction. Q-5 Explain the méchanism and kinetics of ftee radicals chain polymerization with suitable example. ( : OR (04) Q5 Differentiate between addition and condensation polymerization. rey 6 Discuss the methods for the purification of colloidal solutions. OR (04) -6 Distinguish between Lyophilic Sols and Lyophobic Sols.No. of printed pages: V.P. & R. P. T. P. Science College, Vallabh Vidyanagar T.Y. B. Se, [SEMESTER — VI] EXAMINATION INTERNAL EXAM Thursday, 7" March, 2024 3.00 PM to 4.30 PM USOGCCHES4 - ORGANIC CHEMISTRY i) All questions are to be attempted. (ii) Figures to the right indicate Q1 Choose the correct option for the following : [05] (i) Which of the following is in plane bending vibration? (a) Wagging . (b) Twisting (¢) Rocking (4) Symmetrical (ii) Which of the following is used as reference in NMR spectroscopy? (a) TMS —(b) Water (c) Ethanol (d) Benzene (iii) The scale of 5 (delta) ppm in CMR spectroscopy is (a)0-50 (b) 50-100 (c) 100-200 (d) 0-200 (iv) Which of the following indicator is used in mohr's method? (a) KeCrOs(b) KSCN_ (c) Eosin (4) Thorin w™ . is water soluble compound. (a) Zn0:* —(b) ZnOH2 — (c) AIOHs (4) SiOs” @Q2. Answer the following short Questions (Attempt any two) : [04] (i) Give classification of different vibration modes in IR. (ii) Give the various aspects of NMR spectroscopy. (iii) What is gravimetric analysis? (iv) Give the uses of sodium hydroxide. Answer the following : 3 Explain different factors affecting IR spectroscopy. 04] oR Q.3 Deduce the structure. (04) (A) MF: CzHN: IR om’! 3010-2950, 2255, 1370 J (B) MF: CgHgO2: IR cmv 3485, 3005-2855, 1745, 1245, 1043 Q.4 Write a note on phenomenon of the splitting of NMR signals indicating how the multiplicity of splitting reflects the number of proton adajacent to the absorbing 5 protons, [04] oR fos) Q4 Deduce the structure t P.T.O.Qs Qs Qé Qé PM G8 Is, ie) Vo (A) CMR (8 ppm): (2) 14.3 Quartet (b) 28.2 Triplet (c) 423.4 Doublet (d) 149.8 Doublet (e) 152.8 Singlet (B) NMR (6 ppm): (2) 4.75, 3H, T (b) 3.65, 2H, T CaWs Rama fFe Or) Write a note on fajan's method to determine chloride or bromide ion in given sample. [04] OR Explain co-precipitation method. [04] Discuss manufacturing process of sulphuric acid by contact process. [04] OR Discuss manufacturing process of nitrtic acid by Ostwald's process. [04] AMR Data [ippeet tt Sppt type aft Spar Tope of 78 pmIR Group frequency : SELECTED SPEC ‘TRAL DATA | Group Compound (a) -C-H. Alkane, stretching 2850~ 2950 1340 ~ 1480 3040 - 3100 ‘Alkene, stretching ‘Alkene, bending (cis) 700 ~ 780 ‘Alkene bending (trans) tif 900 ~ 980 (seu “alkyne, stretehing 3200 - 3300 | | -c-" ‘Aromatic, stretching 3000 — 3100 ‘Aromatic bending (mono) 690-710 “Aromatic bending (0, mB} 730-770 D=C-H | Aldehyde (two bands) 2700-2740 . 2830 - 2900., Oo) Alkyne 600 — 1500 Alkene cis 1650 - 1660 1620 — 1680 ‘cans 1670 — 1680 Alkyne 2100 - 2260 ‘Aromatic, 1500 ~ 1600 (G} ‘Alcohols, Phenols, Acids, Ethers 1050 - 1200 [ ‘Aldehyde, Ketone, Acid, Ester 1690 — 1760 ‘Armide (-CONH,) —_[ 1650 1680 ‘Anhydride (two bands) 1740-1790 1800 — ia | _-0-H __| Alcohols, Phenols, monomeric ar 7 -O-H Acids, manomeric 2500 - 3000" =0-H Hydrogen bonded 730023500 fey | =c=Nn_ [ Niwite 240. DRO =C-X Halide 300 aod C-N ‘Amide, Amine 1220-1340 =N-H ‘Amide, Amine 3200 = 3500 -NO, Nitro (two bands) 1300~ 1370 1500 - 1580