Fieve heck he examination di blow bles ning ur cat eon Coane A aes [sme _) Ane. ene Number ‘Genaidate Number Jf J Pearson Edexcel International GCSE (9-1) Paper reference Time 2hours Chemistry Unit: 4CH1 Science (Double Award) 4SD0 PAPER: 1C ‘You must haver Calculator, ruler Instructions © Use black nk or bal-point pen, © Frillin the boxes at the top ofthis page with your name, centre number and candidate number. © Answer all questions. ‘© Answer the questions in the spaces provided = there may be more space than you need. © show al the steps in any calculations and state the unis. Cra Ae bli Le Information © The total mark for this paper is 10. (© The marks for each question are shown in brackets = use this a a. guide ast how much time to spend on each question. Advice Read each question carefully before you start to answer Write your answers neatly and in good English. Ty tw answer every question. Check your arswersif you have time at the end. Turnover » P70701A Ao aed Pearson _DO NOT WRITEINTHIS AREA DO NOT WRITE INTHIS AREA “requinu joys sare0u 04) 0} popunos useq you ensy suo} pus Jeddo9 Jo sessEU 3RUOHE @ANEN UL j ‘Panto useq eney (c0}-06 Ssoqumnu 2wo}) sprouse ay pur (}L-e8 SioquiMu a1O}E) sprOvENRUEL aL aps Fala | de aL aa aa fe ac ileal ze & |eBLANK PAGE \VaUY SIHLNIZLIUM LON OG VAUY SIHLNI3LRUM.LON OG VauY SIHLLNIZLIUM LON 03‘Answer ALL questions. ‘Some questions must be answered with a cross ina box. If you change your mind about an ‘answer, puta line through the box 8 and then mark your new answer witha cross53, | 1 This question is about mixtures and compounds. | (@) The box gives some methods used to separate mixtures. ‘chromatography crystallisation | fractional distilation simple distitation Choose methods from the box to answer the following questions. Each method may be used once, more than once or not at al (9 ent aetho to separate asnge ood dye roma mitre food dyes | Oneomatoneths | Wemtyametods separate gssne fom creo | Radtured _distlaken Gi Kens 2 method to separate water fom coppet sf sluton Simple _ dhstitehor nuh 10N 0a ‘vaUV SIN NILIUM JON 0a au Simin ‘Vall SiH NIZLIUM LON 0aDO NOT WRITE IN THIS AREA DO NOT WRITE INTHIS AREA DO NOT WRITEINTHIS AREA (b) The diagram represents a molecule. q) | Explain wihy this molecules @ compound. a “are.c3s, kum diffe toners Churcaly bended tyytlys (0) The molecular formula of another compound is QH.N,O, | (0 State the numberof ciferent elements in GH.NO, & (i) Determine the numberof atoms in a molecule of GH.N.O, Qe (Total for Question 1 = 7 marks) 5 Tumover »2. Tisquestonis about sing. | (0) A simplified formula for rss 0, | Name the to substances needed or ron to rst. 1 OR D9 2 Wal/ (0 Give the chemical name for rst. Vydaded km GD) onde (iy What type of reaction occurs in the rusting of ron? A combustion 1B neutralisation 1 oxidation 1D thermal decomposition () Some ron objects ae coated witha layer of zinc to preventusting. | {i} Name this type of rust prevention. Goerisng. (WExpain how this type of rust prevention continues to prtect iron when the layer of zinc is damaged. ‘vaUY SIMLNILIUM ON 00 a Rare 16 mort eacdiie: Yen ion So Ze peacts ished 4 ior’ \VaUY SIHLNIZLIUM 10N 00DO NOT WRITE IN THIS AREA DO NOT WRITE IN THIS AREA DO NOT WRITEINTHIS AREA | | ly Give two other methods used to prevent ron from rusting. 1. Feder, Plestie Carlos 2.0 | Gesing. . Chrernsuse flskny SoGificied _prtect ss Cobbet pateckion 0 0 0 A (Total for Question 2 = 9 marks)| 3. This questionis about states of matter. (2) The box gives words eating to changes of tate, condensation cooling evaporation freezing melting sublimation Complete the table by giving the correct word from the boxtor each change of state. (6) When ammonia gas and hydrogen chloride gas mix, they eect together to form a white solid called ammonium chioride. [teacher soaks a piece of cotton wool in concentrated ammonia solution and another piece of cotton wool in concentrated hydrochloric acc The teacher places the two pieces of cotton wool at opposite ends ofa glass tube atthe same time After several minutes, a white ring of solid ammonium chloride forms. ‘cotton wool soaked cotton wool soaked white ring of in concentrated aren inconcentrated ammonia solution hydrochloric acid Vay StHLLNIuM LON oa ‘vaUV SIHLNILIUM Jon 00 \VauY SIHLNIZLIUMLON 0aDO NOT WRITE INTHIS AREA DO NOT WRITE INTHIS AREA DO NOT WRITE INTHIS AREA i f (0 State the name given to the spreading out of gas particles, D: as.on (a) State how the diagram shows that the particles of ammonia gas are travelling at higher speeds than the partcies of hydrogen chloride gas. | the Ormann laid iny fms Clas fo She. fysrcsic 060 Saled (in Vaodh_ ev: (i) Gas particles travel at high speeds Give reason why the white rng of ammonium chloride akes several minutes 0 form, Gos. folkcle Mave tr Cinder dreckons end (lila With cach Abul xd Oe BB wake 4 Bu bate (iv) Concentrated ammonia solution and concentrated hydrochloric acid Give one safety precaution the teacher should take Laer alone | Spates [Neb Goa (otal fer Question 3 = 7 marks) i ee“4 Ateacher uses this apparatus to find the percentage of oxygen ina gaseous mixture ‘of oxygen and argon. ‘mixture of oxygen and argon, s copper powder — | syringe A t syringe B heat | This's the teacher's method. | Step 1 heat the copper powder Step 2 push the plunger on syringe A to pass the mixture of oxygen and argon over the hot copper so that the mixture moves into syringe B Step 3 push the plunger on syringe 8 to pass the mixture of oxygen and argon over the hot copper so thatthe mixture moves into syringe A Step 4 record the reading on syringe A | Step 5 repeat Steps 2,3 and 4 a numberof times The volume of gas decreases sth oxygen reacts with the copper. Argon is unreactive so doesnot eat withthe copper. The copper ponder tums back (2) () Gives reason why the copper powders heated. Jo otese Ke rake of feackon Te pie Bue ghdes ork eneyy fe ack. (i) State why argon s unreactive. i) Give the name of the black powder that forms when the oxygen reacts with the copper Corer (OE) onde CL | Ror Anegat reds lo, Geer Shoe glacteons: ‘wu SIMLNILIUM JON 0G vauy siti NIaLM LON oa SHY SIHLNI ALUM LON 0aDO NOT WRITE IN THIS AREA DO NOT WRITE IN THIS AREA DO NOT WRITE INTHIS AREA (©) The table shows the teacher’ results, Reading number Reading on syringe A in cm? | stor 7 | 1 | - n - ea 4 7 63 - (0) State how the results show that al the oxygen has reacted The jesulls ase Cle Some ob Yu ends (i) The volume of gas in the glass tube and connecting tubes is 175em* Use this value and the results table to calculate the percentage of oxygen in the mixture of oxygen and argon. V( Ri) «195 498 = 253 Mead + 9 88> Se “4 (Qr) + = Kaeo Turnover >(i) Suggest one reason why the calculated percentage of ygen in the mixture may not be accurate, Tha 6 Leake in He Operas Me lomeemine or Re Sine BC all readings | The _eeppemts Caate® fl be Gall gfe ay SiH NAMA LON 0A. VauV SILL NII LON 00 \Vauy SIHLNIZLIUM ON 0aBLANK PAGE VaUY SIHLNI 3LEUM 10N 0a LRM LON O@ VAY SIHLLNI LIM 10N 005. (@) Complete the table to show the relative mass and relative charge of @ proton and a neutron, (b) Magnesium has thee isotopes. (State the meaning ofthe term isotopes. | _Plors af the Game claret ith he Same nant” 2. pts bk, Au(Gereknurber sf Newtons. {i The symbol fr an atom of one isotope of magnesium is Mg Give the number of protons, neutrons and electrons in one atom of this isotope. ‘number of protons yu number of neutrons \a ‘number of electrons 1 \VaUV SIHLNIZLIUM 10N 0G vay Silt NILA 10N 04 ‘WaUY SIHLNIZLIUM JON 0DO NOT WRITE IN THIS AREA DO NOT WRITE INTHIS AREA DO NOT WRITE INTHIS AREA {iA sample of magnesium contains these percentages of the three isotopes Mg24=7900% Mg-25=10.00% — Mg26= 11.00% Use this information to show thatthe eative atomic mass of| moses 92432 fee 2a +2560) 220) \oo = W.32 (iv) One mole of magnesium has a mass of 24.329. “There are 6022 x 10 atoms in one mole. ‘Calculate the mass, in grams, of one atom of magnesium, ‘Give your answer to 4 significant figures, W.3t CoO (0) The equation for the reaction between magnesium and oxygen is 2Mg + 0; > 2Mg0 | over emi ana arsine at ane | produced from 0.50mol of magnesium and 0.20mol of oxygen, h, excess, erly om n(Q) 20% needled Bake» ( Oy: Ms0)2 2 sm (MO)= o-4e amount = (Total for Question a3 4 03g ol se) 15 Turnover >{6 This question's about sodium oxide, Na,O (@) The diagram shows the electronic configuration of atoms ofsodium and oxygen. Sodium Oxygen Describe the changes inthe electronic configuration ofthe atoms of sodium and ‘oxygen to form the ions in sodium oxide. Sri ake loses 1% elders fe_farm Na” lone Oxygen akon Gps 2 de chery be (eern OF ion Bh sere bwe tho electronic Goofyshon 1% (©) Calculate the relative formula mass (M) of sodium oxide, Na, using information {rom the Periodic Table. UC BY re =6XL \VatIY SIHLNILIMA 10N 0 ‘vay SIHLNILTUM 10N 0a \VaUY SIHLNILIUM 10N 0DO NOT WRITE INTHIS AREA DO NOT WRITE IN THIS AREA DO NOT WRITE INTHIS AREA (©) Explain why solid sodium oxide does not conduct electricity. Gedn OBE bos giaat Vone Skeatese Wun Sid, Hee tere and thetbeans Canad ave | | ta Greate shor ut som ode conten Gane flome test we yelow Came dseled Shows Sodiuse jor Goe_prsient: {) When sodium oxide is heated it reacts to form sodium metaland sodium peroxide, Na,0, Complete the equation for this reaction. Lao +2 No TR Ns, Oy,7 This questions about soluble and insoluble compounds. ‘precipitate isan insoluble compound formed when solutions of soluble compounds react after mixing. (8) Different sluions are mixed in separate test tubes Tube 1 copper sulfate oaton and calcium chloride oition Tube 2 magnesium nate solution and potassium sulfate solution Tube 3 sodium carbonate solution and copper sulfate solution Inwhich ofthe tubes la preitate frm? DA tand2only OB 2and3only oS ¢ 1and3only OD 12and3 () Astudent mixes solutions, containing equal amounts in moles, of ser nitrate ‘and sodium chloride. ‘The equation for the reaction between silver nitrate solution and sodium chloride solutions ‘AgNO,(eq) + NaCllag) > AgCls) + NaNO,iaq) () State the colour ofthe precipitate of slvr chloride. \wike \VaNV SIHLLNI@LIUM LON 00 \vauy sit ntaimim 1oN 0A VAUY SIHLNILIUM LON 00(i) The student wants to obtain pure, dry crystals of sodium nitrate. Crystals of sodium nitrate decompose at temperatures above 300°C. 4 | | Describe a method the student could use to obtain pure dry crystals of 2 | sodlum kate z | fie tha toxtise - 5 Heak he Stuukie te _evapeate Gme g the wale. 2 Leave dhe Sdubwn to Cah & Cystallise. = Ger te dhe crystals - ; |p the Crystals we tam oe PR (lle pyar a| : = : | Hl —| E| | =| - | g | 5 {i) Give an advantage of mixing solutions containing equal amounts, in moles, of sver nitrate and sodium chloride. oD Aes csses Ba Sion Moo Su mtate By rat, Se Bee gmdate Mintire only Cintas Slve/ Chica ard Seis aie DONOTWRITEINTHIS AREAThe table shows the structures of sic organic compounds. (2) (0 Give the letter of a compound not shown as a displayed ‘orm, (Give the letter ofa saturated compound with the general formula CMa, Cc tans enood Prvene (iv) Explain why compound A and compound D are isomers. Ths Weve Mee Same _mdetate/ forme bub dif splayed (Pelee: \VauV SIMLNILIM LON 0 VaUY SIHLL NII LON 00 \VaUY SIHLNIaLIUM10N 0aDO NOT WRITE INTHIS AREA DO NOT WRITE INTHIS AREA DO NOT WRITE INTHIS AREA {(b} Compound F reacts with bromine in the presence of ultravilet radiation, (i) Complete the equation for the reaction. + Be CBee HBR (Give the name ofthis typeof reaction Saustitudion (4 (0 Another compoune, G, has this percentage compositionby mass. C=378% = -H=63% = Cl=35.906 Show by calculation that the empirical fornula of compound GIs HCl Cc UW a Wess BIT 63 “wt SS YL ‘ a Sasi Ge, WS \S2 Ga 159 a 2 Gpintcd fermala CM, G (il) The relative formula mass (M,) of Gis 127 | Determine the molecular formula of | NS hsHpsss See se yea —— TGA) HBSS ‘molecular formula =(@) Compound Es used to make an addition polymer. @ Complete the equation to show part ofthe polymer formed from two molecules of compound 2 moe HHP 4 ae! reddy acetate | if I robeoyog uO es (i Give one problem caused by the disposal of addition poymers. 1 Tonic [ Grecrhouse Sess produces ular bused Fis we (entQur_shes 8 3DO NOT WRITE INTHIS AREA DO NOT WRITE IN THIS AREA DO NOT WRITE INTHIS AREA 9 Astudent uses this apparatus to investigate the rate of reaction between calcium | carbonate chips and dilute hydrochloric ai. cotton woo! plug calcium carbonate chips balance Every 20 seconds the student records the reading on the balance. (2) Explain why using a cotton wool plug increases the accuracy of the student's sults, |_Ths prevents 6 Qn Ylahny aut of Wu (bse Se CeGene ta moss 8 Onky due ke he Ass te CGaphey: (6) Complete the equation for the reaction by adding the state symbols. Caco 3) + HEU OG.) + cactiaa + HOC + COM 44 lute hydrochloric acid(0 The student uss the balance readings to find the decrease in mats ofthe flask and contents The graph shows the students results 100: Decrease inmassig °° 0 20 40 60 80 100 120 140 Time/seconds (@. Give a reason why there are some calcium carbonate chips remaining in the flask when the reaction stops. Te \ygedatne acd hes Od peaced. {State how the student would know when the reaction has stopped. The mess Guys Be Some AMY SIHLLNILIUM LON 00 \Vauy SIHLNTLIUM LON o (Vay SIHLNIZLIUM LON 00DO NOT WRITE INTHIS AREA DO NOT WRITE INTHIS AREA DO NOT WRITE INTHIS AREA | (i) Use the graph to determine the amount, in moles, of carbon dioxide produced | during the reaction. oF CO, = 44) MCCO2) = 0.8) ° | n(CO,)- O88 . | rs) | ° | = YOu, ancart= On 02% mmol | (iv) Use the graph to calculate the rate of reaction, in grams per second, at time | | eo seconds, | | ‘Show your working on the graph, | | a Woe 3) | fate. 2 2 | | Fete (oo | | = Suda" | | 23 rene oy, = Fs on Tum over >(d) The student repeats the investigation by diluting the origina hydrochloric acid | ‘The student then determines the intial ate of reaction at diferent percentage concentrations ofthe original hydrochloric acid. | ‘The graph shows the student’ results | 0.025 0.020 Initial rate of reaction ing/s ons oor | 0.005 ° 0 2 4 60 8 100 Percentage concentration of ‘original hydrochloric acid | (0) Describe the relationship between the initial rate of reaction and percentage ‘concentration of the orignal hydrochloric ac, Ta tte of Teacion Gores 04 We puranbege tnetedn| Weenes- The gts feuckon is diteehly prpstiow ko | Preccaskose _ Contanteckiar | (Explain vehy changing the concentration of hydrochloric acid as an effect on the initial rate of reaction, 2) Ts Cherges Ble nein” Fries gel uit Vai nap 4 palticles ef uit Vilune Sha Penysenig 4 ticks dhe (Total for Question 9 = 15 marks) 8 \vauV SIHLNIaLIUM ON 0a \VaV SIHLLNI LIM LON 00\VaUV SIHLNI LIM LON OG BLANK PAGE \VaUV SIHLNIZLIUM ON 04 ‘VUY SIHLNIBLRIM LON 010 This question is about substances with covalent bonds. (2) (9 Draw adot and cross diagram to show the outer shell electrons in a molecule | of nitrogen, N tems God. Qe bended “N) Ai) Describe the forces of attraction ina covalent bond, Ge Greeny hechashake aahackoo bebe Shared pors_of \VaUV SIHLNIZLIUM ON 0G ‘VaUV SIMLNIZLIUM 10N 0G \VauY SIHLLNI LIM LON 04DO NOT WRITE IN THIS AREA DONOTWRITEINTHIS AREA DO NOT WRITE IN THIS AREA (©) The diagram shows thre diferent structures of carbon. ah ma Hin Structure A Graphite ofullerene (0 Name structure A Y).csnend: {W) Graphite and Cy fullerene contain covalent bonds, but have cifferent structures. Expan why Cy flrene haa much ower melting pln than graphite. Peter. srucre an bondhgin your nse Grraghte Ios «jerk Countat Soacte- Or heliyy Shoo Cetare” Laws cre been G be a Smole maltales Skarchoe. On maltiog , byede sekeriletales (Guus coe Ovelteme Gad Warde high KeenPeratvoes Mace crery'tatrecded to break Covalert bends es Serie. Ren Bow ahamelatatey (eres on Co (Total for Question 10 = 9 marks)[11 Astudent uses this apparatus to heat crystals of hydrated zinc sulfate and collect the liquid produced, hydrated zine sulfate heat | colourless liquid (a) @ Describe a chemical testo show thatthe colourless hqul contains watt Raa_Gaby drovs Copp Sudphaie-it gies from like fp ble AE oak 1S_gresint. (i) Describe a physical test to show the colourles liquids pare water, Messe Khe poly post - pre % wnt be lone wrettty, Vay SILNIaLIIM LON 0a \VaUV SIMLNIaLIIM LON 04 VAY SILLNIALRUALON 04EA DO NOT WRITE INTHIS DO NOT WRITE IN THIS AREA DO NOT WRITE INTHIS AREA (8) The equation or the decomposition of dated anesutatels 2180.74.08) -+ 208048) + 74.00 The student records these masses mass f boing tube =n649 mas of bling tbe +2050,7H0 = 446g Calculate the maximum volume, in cm’, of pure water that could be produced. Gv your ansverto1 decimal place. {1.00cmof pre waterhas amass of 1006) (Mot 2180,7H0=287 Mot HO= 18 (BSG, [V9 2 FH. gb 87 “2 whaso,. Wee) 2 Eg onyeg rae (Heo) 4 Fx 6-049 sg. 33 w(K) 5 0.23 «1 2§.(S 3 5 Vv (M0) 2 66260 S.6R ‘maximum volume of pure water = u w 3, (9 Innerpeient nga cferet mass of 280,740 the raximumvotimet (°°) pure water that could be produced is 85cm’. ‘The student collected the pure water and calculated the percentage yield to be 20.3%. (© Gaeuate the volume, in, of pure water coleced OD eis Be ts yoo ss volume of pure water = \32 0 Tn over >(i) Explain an improvement othe apparatus that would increase the percentage yield of pure water. @ Sew He truesuiny Clady in a baler Of sGe = Less Uyak Wr oe & Le aay SIME NILA LON OA. \VaUV SIHLLNIaLIUM LON 00 ‘Vay SIL NILIUM 10N 00