Name, 12-2 Practice Problems Date Class How much heat will be released when 6. 6.44 g of sulfur reacts with excess O, according to the following equation? 28 +30, +280, AH? =-791.4 kj -14-S eT How much heat will be released when 7. 4.72 g of carbon reacts with excess O, according to the following equation? C+0,+C0, AH? =-3935 1 2. iL 1G 16643 3. How much heat will be absorbed when 8. 38.2 g of bromine reacts with excess H according to the following equation? H,+Br, > 2HBr AH? = 72.80 KI i leat How much heat will be released when 9. 148 g of chlorine reacts with excess phosphorus according to the following equation? 2P + 5Cl, + 2PCl 4. AH? =-886 Kj 3.70 + How much heat will be released when 4.77 g of ethanol (C,H.OH) reacts with excess O, according to the following equation? G)H,OH + 30, > 2CO, + 3H,O AH? =~1366.7 kJ 5. , POET idler 10. How much heat will be absorbed when 13.7 g of nitrogen reacts with excess O, according to the following equation? N, +0, +2NO AH? = 180 KJ ‘, « 12O. 24 BROT How much heat will be released when 118 g of iron reacts with excess O, according to the following equation? 3Fe+20,+ FeO, AH? =-1120.48 We, \ 1120.4 . , oh 70.4 55.85 ¥ How much heat will be released when 18.6 g of hydrogen reacts with excess O, according to the following equation? 2H, +0, +H,0 -2630 “yt How much heat will be transferred when 149 g of ammonia reacts with excess O, according to the following equation? Is this reaction endothermic or exothermic? ANH, +50, 4NO + 64,0 [° = -1170 k} 44a ric Tro -25be3 How much heat will be transferred when: 5.81 g of graphite reacts with excess H, according to the following equation? Is this reaction endothermic or exothermic: 6C(graphite) + 3H, + CH, ‘AH? = 49.03 KJ eBAGE Chapter 12. 13Name, Date Class 12-4 Practice Problems Tase en OTT 1, When a 12.8-g sample of KCI dissolves in 6. What is the specific heat of gold if the 75.0 g of water in a calorimeter, the temperature of a 8.21-g sample of gold is temperature drops from 31.0°C to 21.6°C. increased by 6.2 C° when 6.51 J of heat Calculate AH for the process. is added? KCI(s) > K*(aq) + CHa) aH b61 = (6.210()(6.2) 1.6)(4194)(26- 21) 40 ‘mo Qe 3453.19 at om A Zetfmoly = 66.12 - 0.24 2, What is the specific heat of aluminuni if ——7.— When a 19.2-g sample of KCN dissolves in the temperature of a 28.4-g sample of 65.0 g of water in a calorimeter, the aluminum is increased by 8.1 C? when 207 temperature drops from 28.1°C to 15.4°C. J of heat is added? Calculate AH for the process. 207 = (2. AO(B-0) KCN(s) + K*(aq) + CN-(aq) AH =? i ce G GA2)4.194)(-12 ie @+ - 4474 7 5144.84 = 0.171 mot Ber ~ $4474 47 /0.24 mol > C1S-4 KT 3. When a 25.7-g sample of Nal dissolves in 8. What is the specific heat of silver if the nel 80.0 g of water in a calorimeter, the temperature of a 15.4-g sample of silver is. temperature rises from 20.5°C to 244°C. increased by 11.2 C° when 40.5J of heat g Calculate AH for the process. is added? Nall(s) > Na(aq) + F(a) ) x 40.6 ae) he @ 206. NAAERS (24.4 ° < 7 ° 12643 a) Qu = 1124.77 5 a 8 hae = Qroe = 1.725 ¥T 8. et 7 CF 10.) hve on72 4. What is the specific heat of silicon if the ~—_9.. When a 28.7-g Sample of KI dissolves in temperature of a 4.11-g sample of silicon 60.0 g of water in a calorimeter, the is increased by 3.8 C° when 11.1 J of heat temperature drops from 27.2°C to 13.2°C. is added? Calculate AH for the process. ht = Kis) + K*(aq) + Faq) AH Wt ose @ =(B8.1)(4104)(-14) eat Gs -5195.6412 7 7 AD = 0.4226 mat Gren = + 6.146 5 Jo. \73me{ = = 30.025 fry ) 5. When a 16.9-g sample of NaOH dissolves 10. What is the specific Meat of titanium-if the __- in 70.0 g of water in a calorimeter, the temperature of a 36.7-g sample of titanium temperature rises from 22.4°C to 86.6°C. is increased by 4.8 C? when 91.6 J of heat Calculate AH for the process. is added? NaOH(s) -* Na*(aq) + OHM(aq) AH =? qe Q = (94.164 )(64.2) Be 342 5 4 AZ eS 24s Chapter 12 Typ eyie sate XL Name. Date. Class 12-3 Practice Problems a 1. From the following enthalpy changes, Cls) +40,(@) + COW) Ow) +40,6) + CO,() calculate the value of AH" for the reaction Cla) + O,(g) + COAG). 2. From the following enthalpy changes, 2P(6) + 3Cl(g) + 2PCI4(0) AH? = ~640 KJ 2P(s) + SCL{g) > 2PCIg(s) AH = -886 KJ calculate the value of AH? for the reaction PCI) + Chg) > PCIE). + 3, From the following enthalpy changes, — C,H,OH() + 30,(g) + 2C0,(g) + 3H,0(8) (QH® =-1234.7 kJ CH,OCH,() + 30,(g) + 2CO,{g) + 3H,0(8) ‘AH? = -1328.3 kJ calculate the value of AH® for the reaction C,H,OH() + CH,OCH,(0). 4. From the following enthalpy changes, Culs) + Chy(g) + CuCh(s) AH? = -206 kK} 2Culs) + Cl,(g)-* 2CuCI6)_—-- AH? =-136 Ky calculate the value of AH® for the reaction CuCh{s) + Culs) > 2CuCl@). 5. From the following enthalpy changes, H,(g) + Fx(g) > 2HF() AH? =-542.2K) 2H,(g) + 0,(g) > 2H,0() —AH® = 571.6) calculate the value of AH® for the reaction 2F,(g) + 2H,0() > AHF(g) + O,(g)- toed. +6116 18. Chapier 12 6. From the following enthalpy changes, Xelg) + Fy(g) + XeF,(6) aH? Xelg) + 2F,(g) + XeF,(6) AH? = 262K) calculate the value of AH® for the reaction XeF,(6) + Fg) > XeF (6). 23 7. From the following enthalpy changes, ANH,(g) + 50,(g) > 4NOG) + 61,0) AH? = -1170 KJ 4NH,(g) + 30,(g) + 2No(@) + 6H,0(0) AH? = ~1530 KJ calculate the value of AH" for the reaction Nx(g) + 0,(g) > 2NOG). 55 8. From the following enthalpy changes, 2Al(6) +20,(g) + ALO36) AH = 1601 KJ 2Fe(s) + 3 On(g) + Fe,O,(s) AH? = -821 1) calculate the value of AH® for the reaction 2AI(G) + Fe,0,(6) > 2Fe(s) + Al,0,(). - (60) + @2\ 9, From the following enthalpy changes, H,O,(0) + H,0()) +40,@) AH? = 94.6 K) Hg) + 40,() + 1,00), AH? = -286.0 calculate the value of AH® for the reaction H,(g) + H,0,(l) + 24,00). 10. From the following enthalpy changes, Cle) + Og) + CO,K8) AH? =-393.54) H,@)+}0,@)+ 1,00, AH" = -285.8.) 2CH,(g) + 50,(@) > 4CO,G) + 2,010) AH®=-2598.8 kJ calculate the value of AH” for the reaction 2C(s) + HQ) > GHG). BT 296.8 + 1299.4 (© Prenton Hal, yy 23K Lip some Ship x2. $i sName. Date, Class 12-3 Review and Reinforcement (continued) \ > Solve the following problems in the space provided. Show all your work. 7. The combustion of propene proceeds in two steps: (CH,CHCH,(g) + H,(g) > CH,CH,CH,(g) AHP = ~124 (CH,CH,CH,(g) + 50,(g) + 3CO,(g) + 4H,0(g) AH? = -2220 KJ Calculate the value of AH® for the combustion of 2.70 mol of propene into carbon dioxide and water. i ete — 6326.BeT Z1* -2220=+ 8. From the following enthalpy changes, 2PbS{s) + 30,(g) > 2PLO(s) + 2S0,(¢) AH? = -827.0 J PbO(s) + C(s) + Pb(5) + COL) AH?=+1068K) X 2 =+213.¢ calculate the value of AH® when 1.55 mol of PbS reacts to form lead in the following reaction: 2PbS(6) + 30,(g) + 2C\s)~ 2Pb(s) + 2CO(g) + 250,{¢). Is the reaction endothermic or exothermic? (65% ~827 = ~1Z81.85 1.26 * 21B.G = + : - exothermic 9. Determine the change in enthalpy for the following reaction: C (graphite) + 2H,(g) > CH,(g) Use these reaction equations: C (graphite) + O,(g) - CO,(g) AH? =-394 KJ H,(g)+502(g) 9 H,0(0) AH? =-286K} * Z CO;(g)+2H,O(1) + CHy(g)+202(g) AH? = +890.3 KJ ee (© Prentice-Hall, Ine. Chapter 12 21NAME PERIOD BOND ENERGIES Calculate the amount of energy required or released in each of the following processes. Be sure to use the appropriate sign convention in your answer. 1. Breaking the bonds of water HGH Ah x2 = G26 vs/wet) Forming the bonds of ammonia 4 . Breaking the bonds of carbon dioxide nN D=L=6. 442 x2 - Cage s/w) 4, Forming the bonds of oxygen FAG / wel) yen ZEA K+) = CB , - 5. Forming 2 moles of methane H 6. Breaking apart 3 res of ethanl “ c- c- 6-4 7. Breaking apart 5 moles of nitrogen NEN: 6(4465) = A126 > 8. Forming 4 moles of formaldehyde (CH,0) 10; C=0 ~ ~144 CH = -Al4*2——— ENTHALPY OF REACTIONS | Aas ~ 2Wp — 24, | Use ENTHALPY OF FORMATION VALUES to calculate the amount of energy absorbed or released by each reaction. Then, identify each reaction as endothermic or exothermic. 1, 2H,0(g) ~ 2H, (g) + 0, (9) . ' -(- 492.04) = (497.64 2 (~241 © 0 0 AM eva OO alee) (344 - ~ 494, 0 ‘ — 2H Oe eho a ff n 2 e aay ae eee Man = 91-86 - 62.26 W037 er ex 51.66 3. 2C(5) +2H, (g) + GH, (9) ive > 9240-0 = (6270 4 endo) 0 0 52.0 rs 4. 2H,0, (I) + 2H,0(I) + 0, (9) Baa - -97L7 —(-375.6) = 6146.1 ua 2(-197.6) 20-28985) 0 exo _/ ~ 375.6 - $11.9 5. Ne(g) + 3H. (a) = 2NH,(9) AL > 0 0 20 4e14) 12.35 6 C(s) + 0, (9) + CO; (9) Don = CO ito 7. CH, (g) + Cl, (9) + CH,CI(g) + HCI (g) Dra = ~ (45.48 -(-14.8) = = 100.66 -14.G o — (05.18 42.40 __&xo, -146 ~ 195.44 8. CS, (I) + 2H,0() ~ CO, (g) + 2H,S(9) SLCC MAL (-24%99)2 - 243.6 C2017) 2 = (Aa 3 = (46.4545 endo -4 42.24 432.54 Chaser ends) 9. CoH, (g) +3 0, (a) ~ 2 €0, (@) + 2H,0 (9) May = - 1270.64 - 52.30 $1.40 0 2(-393.6) E241.82)2 : on yoLAA D 92.30 = 1210.64 exo