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Bsce1-2 Pascua L04

This document contains a 10-page chemistry assignment answering questions about thermochemistry, heat of reaction, and calorimetry. It includes calculations of changes in internal energy, enthalpy, work and heat for various chemical processes. The assignment was completed by Michaela Alexa S. Pascua, a 1st year BSCE student, and submitted on January 12, 2024.

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michaellapascua05
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47 views10 pages

Bsce1-2 Pascua L04

This document contains a 10-page chemistry assignment answering questions about thermochemistry, heat of reaction, and calorimetry. It includes calculations of changes in internal energy, enthalpy, work and heat for various chemical processes. The assignment was completed by Michaela Alexa S. Pascua, a 1st year BSCE student, and submitted on January 12, 2024.

Uploaded by

michaellapascua05
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
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CHEMISTRY FOR ENGINEERS – LECTURE ANSWER SHEET FOR ACTIVITIES AND ASSESSMENT

LESSON NO. & TITLE: LESSON 04: THERMOCHEMISTRY


UNIT NO. & TITLE: UNIT 01: THE FIRST LAW OF THERMODYNAMICS
NAME: MICHAELLA ALEXA S. PASCUA DATE OF SUBMISSION: JAN. 12,2024
ID NO.: 2023-00116-MN-0 PAGE NO: 1
YEAR/COURSE/SECTION: 1/BSCE/2 TOTAL NUMBER OF PAGES: 10

1. When gasoline burns in an automobile engine, the heat released causes the products CO2 and H2O to
expand, which pushes the pistons outward. Excess heat is removed by the car’s cooling system. If the
expanding gases do 451 J of work on the pistons and the system loses 325 J to the surroundings as heat,
calculate the change in internal energy in joules.
CHEMISTRY FOR ENGINEERS – LECTURE ANSWER SHEET FOR ACTIVITIES AND ASSESSMENT

LESSON NO. & TITLE: LESSON 04: THERMOCHEMISTRY


UNIT NO. & TITLE: UNIT 01: THE FIRST LAW OF THERMODYNAMICS
NAME: MICHAELLA ALEXA S. PASCUA DATE OF SUBMISSION: JAN. 12,2024
ID NO.: 2023-00116-MN-0 PAGE NO: 2
YEAR/COURSE/SECTION: 1/BSCE/2 TOTAL NUMBER OF PAGES: 10

2. Liquid water at 180°C and 1002.7 kPa has an internal energy of 762.0 kJ/kg and a specific volume of 1.128
cm3/g. (a) What is its enthalpy? (b) The water is brought to the vapour state at 300°C and 1500 kPa, where its
internal energy is 2784.4 kJ/kg and its specific volume is 169.7 cm3/g. Calculate the change in internal energy
and the change of enthalpy for the process.
CHEMISTRY FOR ENGINEERS – LECTURE ANSWER SHEET FOR ACTIVITIES AND ASSESSMENT

LESSON NO. & TITLE: LESSON 04: THERMOCHEMISTRY


UNIT NO. & TITLE: UNIT 01: THE FIRST LAW OF THERMODYNAMICS
NAME: MICHAELLA ALEXA S. PASCUA DATE OF SUBMISSION: JAN. 12,2024
ID NO.: 2023-00116-MN-0 PAGE NO: 3
YEAR/COURSE/SECTION: 1/BSCE/2 TOTAL NUMBER OF PAGES: 10

2. Liquid water at 180°C and 1002.7 kPa has an internal energy of 762.0 kJ/kg and a specific volume of 1.128
cm3/g. (a) What is its enthalpy? (b) The water is brought to the vapour state at 300°C and 1500 kPa, where its
internal energy is 2784.4 kJ/kg and its specific volume is 169.7 cm3/g. Calculate the change in internal energy
and the change of enthalpy for the process.
CHEMISTRY FOR ENGINEERS – LECTURE ANSWER SHEET FOR ACTIVITIES AND ASSESSMENT

LESSON NO. & TITLE: LESSON 04: THERMOCHEMISTRY


UNIT NO. & TITLE: UNIT 01: THE FIRST LAW OF THERMODYNAMICS
NAME: MICHAELLA ALEXA S. PASCUA DATE OF SUBMISSION: JAN. 12,2024
ID NO.: 2023-00116-MN-0 PAGE NO: 4
YEAR/COURSE/SECTION: 1/BSCE/2 TOTAL NUMBER OF PAGES: 10

3. Two liters of N2 at 0°C and 5 atm pressure are expanded isothermally against a constant pressure of 1 atm
until the pressure of the gas is also 1 atm. Assuming the gas to be ideal, what are the values of W, ∆E, Q and
∆H. Express you final answers in calories. (NOTE: 24.22 cal = 1 L-atm)
CHEMISTRY FOR ENGINEERS – LECTURE ANSWER SHEET FOR ACTIVITIES AND ASSESSMENT

LESSON NO. & TITLE: LESSON 04: THERMOCHEMISTRY


UNIT NO. & TITLE: UNIT 01: THE FIRST LAW OF THERMODYNAMICS
NAME: MICHAELLA ALEXA S. PASCUA DATE OF SUBMISSION: JAN. 12,2024
ID NO.: 2023-00116-MN-0 PAGE NO: 5
YEAR/COURSE/SECTION: 1/BSCE/2 TOTAL NUMBER OF PAGES: 10

4. A gas expands against a variable opposing pressure given by P = 10/V atm, where V is the volume of the
gas at each stage of expansion. Further, in expanding from 10 to 100 liters, the gas undergoes a change in
internal energy of ∆E = 100 cal. How much heat, in calories, is absorbed by the gas during the process? [NOTE:
1 atm = 24.22 cal]
CHEMISTRY FOR ENGINEERS – LECTURE ANSWER SHEET FOR ACTIVITIES AND ASSESSMENT

LESSON NO. & TITLE: LESSON 04: THERMOCHEMISTRY


UNIT NO. & TITLE: UNIT 02: HEAT OF REACTION
NAME: MICHAELLA ALEXA S. PASCUA DATE OF SUBMISSION: JAN. 12,2024
ID NO.: 2023-00116-MN-0 PAGE NO: 6
YEAR/COURSE/SECTION: 1/BSCE/2 TOTAL NUMBER OF PAGES: 10

1. It is interesting to compare the “fuel value” of a hydrocarbon in a world where fluorine rather than oxygen is
the combustion agent. The enthalpy of formation of CF4(g) is -679.9 kJ/mol. The enthalpy of formation two
reactions is the more exothermic?
CHEMISTRY FOR ENGINEERS – LECTURE ANSWER SHEET FOR ACTIVITIES AND ASSESSMENT

LESSON NO. & TITLE: LESSON 04: THERMOCHEMISTRY


UNIT NO. & TITLE: UNIT 02: HEAT OF REACTION
NAME: MICHAELLA ALEXA S. PASCUA DATE OF SUBMISSION: JAN. 12,2024
ID NO.: 2023-00116-MN-0 PAGE NO: 7
YEAR/COURSE/SECTION: 1/BSCE/2 TOTAL NUMBER OF PAGES: 10

2. ) Calculate the standard enthalpy of formation of gaseous di-borane (B2H6) using the following
thermochemical information:
CHEMISTRY FOR ENGINEERS – LECTURE ANSWER SHEET FOR ACTIVITIES AND ASSESSMENT

LESSON NO. & TITLE: LESSON 04: THERMOCHEMISTRY


UNIT NO. & TITLE: UNIT 02: HEAT OF REACTION
NAME: MICHAELLA ALEXA S. PASCUA DATE OF SUBMISSION: JAN. 12,2024
ID NO.: 2023-00116-MN-0 PAGE NO: 8
YEAR/COURSE/SECTION: 1/BSCE/2 TOTAL NUMBER OF PAGES: 10

3. At the end of 2009, global population was about 6.8 billion people. What mass of glucose (C6H12O6) in kg
would be needed to provide 1500 Cal/person/day of nourishment to the global population for one year? Assume
that glucose is metabolized entirely to CO2 and H2O(l).
CHEMISTRY FOR ENGINEERS – LECTURE ANSWER SHEET FOR ACTIVITIES AND ASSESSMENT

LESSON NO. & TITLE: LESSON 04: THERMOCHEMISTRY


UNIT NO. & TITLE: UNIT 03: CALORIMETRY
NAME: MICHAELLA ALEXA S. PASCUA DATE OF SUBMISSION: JAN. 12,2024
ID NO.: 2023-00116-MN-0 PAGE NO: 9
YEAR/COURSE/SECTION: 1/BSCE/2 TOTAL NUMBER OF PAGES: 10

1. When a 0.235-g sample of benzoic acid is combustion in a bomb calorimeter, the temperature rises 1.642°C.
When a 0.265-g sample of caffeine, C8H10O2N4, is burned, the temperature rises 1.525°C. Using the value
26.38 kJ/g for the heat of combustion of benzoic acid, calculate the heat of combustion per mole of caffeine at
constant volume.
CHEMISTRY FOR ENGINEERS – LECTURE ANSWER SHEET FOR ACTIVITIES AND ASSESSMENT

LESSON NO. & TITLE: LESSON 04: THERMOCHEMISTRY


UNIT NO. & TITLE: UNIT 03: CALORIMETRY
NAME: MICHAELLA ALEXA S. PASCUA DATE OF SUBMISSION: JAN. 12,2024
ID NO.: 2023-00116-MN-0 PAGE NO: 10
YEAR/COURSE/SECTION: 1/BSCE/2 TOTAL NUMBER OF PAGES: 10

2. ) If 25 J are required to change the temperature of 5.0 g of substance A by 2.0°C, what is the specific heat of
substance A?

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