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CHEM102 051 Old-Exam First-Major Unsolved

The document contains 20 multiple choice questions about chemical equilibrium and kinetics. The questions cover topics like Le Chatelier's principle, reaction rates, rate laws, and acid/base chemistry. Answer choices with the corresponding letter are given for each question.

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Abdullah Altwirqi
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20 views5 pages

CHEM102 051 Old-Exam First-Major Unsolved

The document contains 20 multiple choice questions about chemical equilibrium and kinetics. The questions cover topics like Le Chatelier's principle, reaction rates, rate laws, and acid/base chemistry. Answer choices with the corresponding letter are given for each question.

Uploaded by

Abdullah Altwirqi
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as DOCX, PDF, TXT or read online on Scribd
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M1 51

For the reaction: 1.


2HI (g) ⇌ H2 (g) + I2(g)
this system is at equilibrium at 520 °C when the partial pressure of HI is 0.80
atm, the partial pressure of H2 is 0.10 atm and the partial pressure of I2 is 0.10
atm. If enough HI is added to this equilibrium mixture to raise the partial pressure
of HI temporarily to 0.96 atm, what will be the partial pressure of HI when
equilibrium is restored?
0.93 atm A.
0.80 atm B.
0.54 atm C.
0.23 atm D.
1.5 atm E.

The equilibrium constant (Kc) for the reaction: 2.


N2O4(g) ⇌ 2NO2(g)
is 4.63 x 10-3 at 25 °C. What is the value of Kp at this temperature?
0.0189 A.
0.270 B.
0.113 C.
1.38 D.
0.875 E.

The effect of increasing the temperature of an endothermic reaction is the same 3.


as;
Q (reaction quotient) < K (equilibrium constant) A.
Q (reaction quotient) > K (equilibrium constant) B.
Q (reaction quotient) = K (equilibrium constant) C.
removing reactants D.
adding products E.

Consider the equilibrium: 4.


SO2(g) + NO2(g) ⇌ SO3(g) + NO(g)
for which K = 3.75 at a particular temperature. If all four gases had initial
concentrations of 0.800 M, what are the equilibrium concentrations of NO2 (g)
and SO3(g) ?
[NO2] = 1.54 M, [SO3] = 1.56 M A.
[NO2] = 1.06 M, [SO3] = 0.54 M B.
[NO2] = 0.54 M, [SO3] = 1.06 M C.
[NO2] = 2.55 M, [SO3] = 2.06 M D.
[NO2] = 0.54 M, [SO3] = 1.76 M E.

Consider the following reaction; 5.

NaHCO3(s) ⇌ Na2CO3(s) + CO2(g) + H2O(g) Kp = 0.23 at 100ºC

If a sample of NaHCO3 is placed in an evacuated flask and allowed to achieve


equilibrium at 100 ºC, what will the total gas pressure be?
0.11 atm A.
0.46 atm B.
0.23 atm C.
0.68 atm D.
0.96 atm E.

Consider the following gas phase equilibrium system: 6.


PCl5(g) ⇌ PCl3(g) + Cl2(g) ΔHºrxn = +87.8 kJ/mol.
Which of the following statements is not true?
Decreasing the total pressure of the system shifts the equilibrium to the A.
right.
Increasing the temperature shifts the equilibrium to the right. B.
Increasing the system volume shifts the equilibrium to the right. C.
A catalyst speeds up the approach to equilibrium and shifts the position of D.
equilibrium to the right.
Increasing the temperature causes the equilibrium constant to increase. E.

Consider the reaction: 4PH3(g) → P4 (g) + 6H2 (g) 7.


If, in a certain experiment, over a specific time period, 0.0048 mol of PH3 is
consumed in a 2.0 L container each second of reaction, what is the rate of
production of H2 in this experiment?
1.6 x 10-3 M/s A.
2.4 x 10-3 M/s B.
6.0 x 10-4 M/s C.
3.6 x 10-3 M/s D.
8.5 x 10-5 M/s E.

Consider the hypothetical reaction: A + B + 2C → 2D + 3E 8.


where the rate law is Rate = - Δ[A]/Δt = k [A][B]2.
If the reaction is started with [A]o = 1.0 x 10-2 M, [B]o = 3.0 M, and [C]o = 2.0
M, after 8.0 seconds, the concentration of A is 3.8 x 10-3 M. Calculate the
concentration of A after 13.0 seconds.
7.5 x 10-3 M A.
1.3 x 10-2 M B.
1.5 M C.
5.3 x 10-1 M D.
2.1 x 10-3 M E.

Nitric oxide reacts with chlorine to form nitrosyl chloride, NOCl. Use the 9.
following data to determine the rate equation for the reaction.
NO + (1/2)Cl2 → NOCl
Expt. # [NO] [Cl2] Initial Rate
1 0.22 0.065 0.96 M/min
2 0.66 0.065 8.6 M/min
3 0.44 0.032 1.9 M/min
rate = k[NO] [Cl2]1/2 A.
rate = k[NO]2 [Cl2] B.
rate = k[NO] [Cl2] C.
rate = k[NO] D.
rate = k[NO]2 [Cl2]2 E.

The isomerization of methyl isocyanide, CH3NC → CH3CN, follows first-order 10.


kinetics. The half-lives were found to be 161 min at 199°C and 12.5 min at
230°C. Calculate the activation energy for this reaction.
31.4 kJ/mol A.
163 kJ/mol B.
78.2 kJ/mol C.
124 kJ/mol D.
6.17 kJ/mol E.

With respect to the figure below, which choice correctly identifies all the 11.
numbered positions?

1234
reactants intermediate activated complex catalyst A.
catalyst intermediate activated complex product B.
reactant activated complex intermediate product C.
reactants activated complex catalyst product D.
reactants intermediate activated complex product E.

Which of the following increases most rapidly with increasing temperature? 12.
fraction of molecular collisions with energy greater than the energy of A.
activation
proper orientation B.
collision frequency C.
energy of activation D.
heat of reaction E.

A certain reaction has the following general form: 13.


aA → bB
At a particular temperature, a plot of 1/[A] versus time resulted in a straight line
with a slope value of +3.60 x 10-2 L/mol. s and an intercept of 357. M-1
respectively. What is the half-life for this reaction?
.68 x 102 s A.
5.24 x 104 s B.
9.92 x 103 s C.
1.35 x 103 s D.
2.25 x 105 s E.

A 0.15 M solution of a weak acid (HX) is 3.0% dissociated. Calculate Ka for the 14.
acid.
3.0 x 10-4 A.
7.2 x 10-2 B.
1.6 x 10-3 C.
5.2 x 10-5 D.
1.4 x 10-4 E.

What is the concentration of an aqueous Sr(OH)2 solution that has pH = 10.50? 15.
6.2 x 10-5 M A.
3.2 x 10-4 M B.
3.5 x 10-3 M C.
1.6 x 10-4 M D.
2.5 x 10-2 M E.

Calculate the pH of 0.100 M HC2H3O2 (acetic acid) if Ka = 1.8 x 10-5. 16.


1.24 A.
7.84 B.
2.89 C.
5.42 D.
8.50 E.

Arrange the following 0.10 M solutions in order of decreasing acid strength. 17.
KOH, KCl, KCN, NH4Cl, HCl
HCl > NH4Cl > KCl > KCN > KOH A.
KCl > NH4Cl > HCl > KCN > KOH B.
KOH > KCN > KCl > NH4Cl > HCl C.
KCN > NH4Cl > KCl > HCl > KOH D.
NH4Cl > KCl > HCl > KCN > KOH E.

A solution is prepared by mixing 90.0 mL of 5.00 M HCl and 30.0 mL of 8.00 18.
M HNO3. Water is then added until the final volume is 1.00 L. Calculate the pH
for this solution.
1.52 A.
0.161 B.
2.68 C.
5.22 D.
0.523 E.

Which one of the following statements about strong acids is true? 19.
Strong acids are very concentrated acids. A.
All strong acids have H atoms bonded to electronegative oxygen atoms. B.
The conjugate base of a strong acid is itself a strong base. C.
Strong acids are 100% ionized in water. D.
Strong acids produce solutions with a higher pH than weak acids. E.

Which of the followings is a Lewis acid? 20.


F- A.
H2O B.
NH3 C.
SO3 D.
CN- E.

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