1 year nQtes chemistry new

CHAPTER 5
ATOMIC STRUCTURE

MCQs
Q.I Splitting of spectral lines when atoms are subjected to strong
electric field is called
Zeeman effect (6) Stark effect
(a) Compton effect
(C) Photoelectric effect (d)
Q.2 The velocity of photon is
(a) independent of its wavelength
(b) depends on its wavelength
(c) equal to square of its amplitude
(d) depends its source
on
The nature of positive rays depend on
Q.3
(a) the nature of electrode

(b) the nature of discharge tube

(c) the nature of residual gas
(d) all of the above
The number of the light emitted by a certain source is 2 x
Q.4 wave
106 m. The wavelength of this light is

(a) 500 nm (6) 500 m

200 ni (d) 5x 10-1 m
(c)
Q.5 Rutherford's model of atom failed because
the atom did not have a nucleus and electrons
(a) it did not account for the attraction between protons and
(6)
neutronsS
(C) it did account for the stability of the atomn
(d) there is actually no space between the nucleus and the
electrons
Q.6 Bohr's model of atom is contradicted by
(a) Planck's quantum theory
(b) Pauli exclusion principle
(C) Heisenberg uncertainty principle
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(d) All of the above

Q.7 Quantum number value for 2p orbitals are
(a) n -2, =I (b) n=1, /=2
(c) n=1, /=0 (d) n=2, I= 0
Q.8 In the ground state of an atom, the electron is present
(a) in the nucleus (6) in the second shell
(c) nearest to the nucleus (d) farthest from the nucleus
Q.9 When the 6d orbital is complete the entering electron goes into
(a) 7f (b) 7s
(c) 7d
(d)
Q.10 Orbitals having same energy are called
(a) hybrid orbitals (b) valence orbitals
(c) degenerate orbitals (d) d-orbitals
.11 The e/m value for the positive rays is maximum for
(a) hydrogen (b) helium
(C) nitrogen (d) oxygen
Q.12 Neutron was discovered by Chadwick in
(a) 1935 (b) 1930
(c) 1932 (d) 1934
Q.13 The velocity of photon is
(a) equal to square of its amplitude
(b) independent of its wavelength
(c) Equal to its wave number
(d) cqual to the velocity of light
Q.14 Quantum number values for 3p orbitals are
(a) n =0, /=3 (b) n =3, = 1
(c) n-2, /=1 (d) n =1, /=3
Q.15 The radius offirst orbit of hydrogen atom
(a) 0.329 Ao (b) 0.429 Ao
(c) 0.529 Ao (d) 0.229 Ao
Q.16 All atoms are principally composed of few fundamental particles
which are in number
(a) 2 (6)
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Q.17
(c) 4
(d 5
Which scientist gave the name of electron to the cathode rays
(a) Planck (6) Einstein
(c) Stoney (d) Bohr
Q.18 The divisibility of atom was showed by
(a) Stoney (b) J.J. Thomson
(C) Millikan (d) Rutherford
Q.19 The nature of cathode rays remains the same irrespective ofthe
material used for
(a) gas (b) cathode
(c) glass (d) electrode
Q.20 Mass of electron is
(a) 9.1 x 10-3I kg (b) 9.109 x 10-32 gm
(c) 8.1 x 10-31g (d) 9.1 x 10-31 mg
Q.21 The charge on an electron is
(a) 1.602 x 10-19c (b) 1.602 x 10-18 c
(c) 1.602 x 10-19 c (d) 1.602x 10-21c
Q.22 The charge on the proton is
(a) +1.602 x l0-19c (b) zero

(C) -
1.602
1019 c x (d) 1.602 x 10-19 c
Q.23 The charge on the neutron is
(a) 1.602 x 10-19 c (b) Zero

(C) -

1.602 x 10-19c (d) +1.602 x 10-19c

Q.24 The calculated e/m value of electron is
1.602 x 1019 c kg-1 1.7588 10-11 kg-1
(a) (6) x c
(c) 1.7588 x l0-13 c kg-I (d) 1.759 x 109 c kg
Q.25 The of proton is
mass

(a) 9.11 x 10-31 kg (b) 1.676 x 10-27 kg

(c) 1.60 x 10-19 kg (d) 1.675 x 10-27 kg
Q.26 The mass of neutron is
(a) 1.675 x 10-27 kg (b) 1.675 x 10-25 kg
() 9.11 x 10-31 kg (d) 1.60 x 10-19 kg
Q.27 The charge on electron was determined by

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(a) J.J. Thomson (b) Millikan

(c) Rutherford (d) Bohr
Q.28 Alpha particles are identical to
(a) hydrogen atoms (6) helium atoms
(C) helium nuclei (d) fast moving electrons
Q.29 Bombardment of Beryllium with alpha particles generates
(a) proton (6) neutron
(c) electron (d) positron
Q.30 The colour of the glow produced in the discharge tube depends
upon
(a) gas (b) electrodes
(C) composition of gas (d) pressure
9.31 pressure of the gas in discharge tube is
When thebecomes reduced, which
of the following more prominent
(a) gas glowS (b) gas ionizes
(c) a discharge takes place (d) gas conducts
electricity
Q.32 Goldstein discovered that besides the cathode rays, another type
of rays are produced in the discharge tube which are called
(a) alpha rays (6) beta rays
(c) positive rays (d)
gamma ay
Q.33 The c/m value for the positive rays in the discharge tube depends
upon
(a) nature of electrode use
b) nature of gas used
(c) composition of the gas
(d) pressure
Q.34 The distance between the two adjacent crests or troughs is called
(a) wave number (6) frequency
(c) wavelength (d amplitude
Q.35 The value of Planck's constant is
"h
(a) 6.625 x 10-34 cal (b) 6.625 x 10-34 J sec
(c) 6.625 x 10-34 kJ (d) 6.625 x 10-34 k cal
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Q.36 In the Bohr's model of atom the electron in an energy level emits
or absorbs energy only when it

(a) remains in the same energy level

(b) dies out
(c) changes its energy level

(d) jumps away

Q.37 The energy associated with an electron resolving in first orbit is

(a) 2.178 x 10-18 k J/mol

(b) 1313.31 k J/mol
(c) 328.32 k J/mol
(d) 82.08 k J/mol
Q.38 The regions of spectrum are
(a) three (b) Seven
(d) fve
Q.39
(C) eight
The dispersion of the components of white light when it is passed

through prism is called

(a) rainbow (b) light pattem
C) refraction (d) spectrum
Q.40 Which of the following colours has the shortest wavelength in
the visible spectrum of light
(a) red (b) blue
(C) violet (d) green
Q41 Which of the following colours has the longest wavelength in the
visible spectrum of light
(a) red (6) blue
(c) violet (d) green
is called
Q.42 A spcctrum containing wavelength of all wavelengths
discontinuous
(a) continuous (b)
(C) line (d) atomic
Q.43 A spectrum showing only certain colours of light is called
(a) continuous (6) line

(c) discontinuous (d) band

Q.44 The wavelength range of visible spectrum is

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(a) 400-750 nm (b) 300-400 nm

(c) 350-600 nm (d) 200-400 nm
Q.45 The spectral lines of Lyman series (uv region) are produced
when electron jumps from higher orbit to
(a) lst orbit (b) 2nd orbit
(c) 3rd orbit (d) 4th orbit
Q.46 The spectral lines of Balmer series (visible region) are produced
when electron jumps from higher orbit to
(a) Ist orbit (b) 2nd orbit
(C) 3rd orbit (d) 4th orbit
0.47 The spectral lines of Paschen series (visible region) are produced
when electron jumps from higher orbit to
(a) Ist orbit (b) 2nd orbit
(C) 3rd orbit (d) 4th orbit
Q.48 The spectral lines of Bracket series (visible region) are produced
when electron jumps from higher orbit to
(a) Ist orbit (6) 2nd orbit
(C) 3rd orbit (d) 4th orbit
Q.49 A dual character of matter particles in motion was postulated by
(a) De-Broglie (b) Planck
(C) Einstein (d) Schrodinge
Q.50 Ifan electron is moving with a velocity of 2.188 x 106 m/s then
its wavelength will be
(a) 0.33 x 106 nm (b) 0.33 x 10-2 nm
(C) 0.33 nm (d) 0.22 nm
Q.51 If a stone of 1gm is many with a velocity of 10m/s then its
wavelength will be
(a) 6.65 x 10-30 m (b) 6.65 x 10-25 m
) 6.65 x 10-28 m (d) 6.65 x 10-12 m
Q.52 The space around the nucleus where the probability of finding
the electron is maximum is called
(a) an orbital (b) an orbit
(c) energy level (d) a shell
1year n0tes chemistry new

Q.53 Which orbital has dumb-bell shape

(a) s-orbital (6) p-orbital
(c) d-orbital (d) forbital
Q.54 Which of the following quantum numbers describes energy of an
electron in an atomn
(a) principal quantum (b) azimuthal quantum
(C) magneticquantum (d) spin quantum
Q.55 Which of the following quantum numbers describes shape of an
electron in an atomn
(a) principal quantum (6) azimuthal quantum
(C) magnetic quantum (d) spin quantum
Q.56 The degenerate orbital in p-subshell is
(a) (b)
(c) (d)
Q.57 When 4p orbital is complete the entering electron goes into
(a) d (6) 4f
(C) (d) 5p
Q.58 x+l value for 3d will be
(a) (b)
(c) (d)
Q.59 Maximum number of electrons in 3f orbitals is
2 (6) zero
(a
(C) 6 (d) 14
Q.60 Maximum number of electrons in M-shell is
(a) (b)
(c) 8 (d) 32
Q.61 An orbital can have maximum electrons
a) (6) 8
(C) 18 (d) 6
Q.62 n+l value for 4f will
(a) 2 (b)
(c) 7 (d)
 1"year nOteschemistry new
Q.63 When a spectrum of light is formed by the radiation given off by
a substance it is called
(a) line spectrum (b) continuous spectrum
(c) emission spectrum (d) absorption spectrum
Q.64 Neutron was discovered by
(a) Chadwick (b) Bohr
(C) J.J. Thomson (d) Einstein
Q.65 Cathode rays can drive a small paddle wheel which shows that
they
(a) are positively charged
(b) possess momentum
(C) do not possess momentum
(d) none of these
Q.66 Slow neutrons are generally more effective than fastness for the
purpose of
(a) effusion (b) fission
(C) penetration (d) absorption
Q.67 The wavelength associated with the moving stone
(a) can be measured by many methods
(b) cannot be measured by any method
C) can be measure by some method
(d) none of these
Q.68 Radius of orbit of an electron and velocity of electron are
(a) directly proportional to cach other
(b) inverscly proportional to cach other
(C) independent to each other
d) none ofthese
Q.69 The values of magnetic quantum number give us information
about the number of orbitals in a
(a) small shell b) orbit
C) subshell (d) none of these
Q.70 Which of the following terms are used for the nunmber of positive
charges on the nucleus of an atom
1year nOtes chemistry new
(a) atomic number (b) atomic mass
(C) nuclear charge (d) atomic charge
Q.71 The uncertainty principle was stated by
(a) de Broglie (b) Heinsenberg
(C) Einstein (d) Schrodinger
Q.72 When pressure in discharge tube is reduced, which of the
a a

following phenomenon becomes very prominent

(a) gas conducts electricity
(b) a discharge takes place
(C) gas ionizes
(d) gas glows
Q.73 Atom bomb is based on the principle of
(a) nuclear fusion
(b) nuclear fission
(c) fusion and fission both
(d) radioactivity
Q.74 A spinning electron creates
(a) magnetic field (b) electric field
(c) quantum field (d) none of these
volume of space in which there is 95% chance of finding an
Q.75 The
electron is
(a) orbit (6) atomic orbital
(c) degenerate orbital (d) quantized orbital
Q.76 Planck°s equation is
(a) Emc2 (b) E= hv
E = hv2
(c) (d) E= mcC
Q.77 In an atom, the electrons
(a) are stationary in various energy levels
(6) are distributed in three dimensional charge cloud around
the nucleus
(C) cmbedded in space around the nucleus
(d) revolve around the nucleus at random
Q.78 The mass number of an clement is cqual to
 1yearnOteschemistry new
a) number of electrons in an atom
(6) number of protons and neutrons in the nucleus
(C) number of protons in the nucleus
(d) number of neutrons in the nucleus
Q.79 The energy of bounded electron in H atom is
(a) positive (b) negative
(c) zero (d) none of these
Q.80 Quantum number which has symbol "n'" is called
(a) principal quantum (b) Azimuthal quantumn
(c) Spin quantum (d) Magnetic quantum
ANSWERS
Question 1 2 34
Answers b
Question 10

AnswersS
Question 1112 13 14 15

Answers C
17
d 18 19
C
20
Question16
S
Answers b
Question 21 2 23 24 25

Answers C a b_
Question 26 27 29 30

Answers a- b
Question 31|3233 34

Answers C b b
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Question 36 37 38 39 40

S
Answers C b C
Question 41 42 43 14 45
S
Answers a a b
Question 46 47 +8 49 S0

Answers b|
Question 51
52 53 54 55

Answers a a b
Question 56 8 59 60
S
Answersb_ C

Question 61 62 63 64 65

AnswerS a C a

|Question 66 69

Answers b b
Question 71 72 73 4 75

AnswerS b b b a
Question 76 77 78 79 80

Answers b|b b| b